• Title/Summary/Keyword: 수직 성장

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Fabrication and Test Results of Superconducting Magnet for Crystal Growing System (실리콘 웨이퍼 성장용 초전도 마그네트의 제작 및 성능평가)

  • Sim, K.D;Choi, S.J.;Kim, K.H.;Han, H.H.;Kim, H.J.;Jin, H.B.;Lee, B.K.;Kwon, Y.K.
    • Proceedings of the KIEE Conference
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    • 2002.07b
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    • pp.824-827
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    • 2002
  • 12inch 이상의 웨이퍼 성장에는 실리콘 용탕의 대류를 억제하여 웨이퍼의 순도를 높이기 위해 자기장 특히, 웨이퍼의 성장방향에 수직인 '수평자장'을 인가하는 방법이 사용된다. 현재 '자기장인가 방식', 특히 초전도를 사용한 자장인가 방식이 직경 1600mm에 이르는 용탕의 용액을 제어하는 유일한 방법으로 받아들여지고 있다. 본 논문에서는 12inch 실리콘 웨이퍼 성장용 초전도 마그네트 개발의 전단계로 개발중인 8inch 웨이퍼 성장용 수평자장형 초전도마그네트의 제작과정과 성능평가 결과에 대해 다루었다. 본 연구를 통해 액체헬륨의 증발을 최소화하기 위한 재응축형 극저온 용기에 대한 기술이 개발 되었으며, diode를 이용한 ��치보호부, HTS 전류리드의 ��치 protection부 등의 부속기술이 개발되었다. 초전도 마그네트는 내경 1400mm의 saddle type으로 이의 제작에 있어 많은 기술적 난재들을 경험해야 했다. 전체 시스템에 대한 성능평가 결과, 극저온용기 및 부속장치에 대한 결과는 만족스러웠으나, 코일부의 성능은 계획한 목표에 미치지 못했다.

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Synthesis Long Multi-Walled Carbon Nanotubes by Water-Assisted Thermal-CVD (물 첨가 열화학기상증착을 이용하여 긴 다중벽 탄소나노튜브의 합성)

  • Jeon, Hong-Jun;Kim, Young-Rae;Lee, Nae-Sung
    • Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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    • 2008.06a
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    • pp.220-220
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    • 2008
  • 물 첨가 열화학기상증착을 이용하여 750도에서 길고 수직 성장한 다중벽 탄소나노튜브를 합성하였다. 사용된 기판으로는 우선 실리콘 웨이퍼에 열 증착기로 확산 방지층으로 Ti 50 nm를 입히고 그 위에 Al 15 nm를 입히고 난 후 촉매 층으로 Invar 36 (63 wt% Fe, 37 wt% Ni)을 1 nm 얇게 증착하였다. 탄소나노튜브의 성장에 사용된 가스는 Ar, $C_2H_2$ 이다. Ar은 분위기 가스로 사용되었고, $C_2H_2$는 탄소나노튜브의 성장에 관여하는 가스이다. 또한, 합성중에 약간의 물을 첨가함으로 기존의 탄소나노튜브 성장 길이보다 10배 가량 더 성장 하였다. 이것은 합성 중의 물 첨가로 인해 촉매 입자들의 활동성이 기존에 비해 더 증가했다는 것을 보여준다. 합성된 탄소나노튜브의 길이와 정렬도를 보기 위해 주사전자현미경 (scanning electron microscopy, SEM)을 이용하였고, 탄소나노튜브의 지름과 벽의 개수를 파악하기 위해 투과전자현미경 (transmission electron microscopy)을 이용하였다.

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Magnetic properties and the shapes of magnetic domain for $CoCr_{16.2}Pt_{10.8}Ta_4$ alloy films with the prior deposition of Ti layer ($CoCr_{16.2}Pt_{10.8}Ta_4$ 합금박막의 Ti 우선증착에 따른 자기적 특성과 자구형상변화)

  • 이인선;김동원
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.10 no.1
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    • pp.17-22
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    • 2000
  • A quaternary alloy film of $CoCr_{16.2}Pt_{10.8}Ta_4$was investigated for its magnetic properties and c-axis orientation with and without Ti underlayer. Additional elements such as Ta, Pt have been frequently introduced in CoCr alloy film for perpendicular recording as a means of improving magnetic performance. It has been reported that the addition of Pt and Ta in CoCr increase the coercivity and the magnetic isolation of columnar grains, respectively. However, CoCrPtTa perpendicular magnetic layer should be more increased its perpendicular magnetic anisotropy than at present for the application of ultrahigh recording density. The improvement of underlayers and substrate materials is one of the promised schemes to intensify the perpendicular magnetic anisotropy. In this study, the insertion of Ti underlayer shows the remarkable improvement of c-axis orientation compare with the direct deposition on the bare glass. The mechanism about this effect of Ti underlayer on CoCrPtTa is not to be clarified yet. Meanwhile, it is found that the magnetic domain of CoCrPtTa on 20 nm Ti underlayer has the continuous stripe pattern but the one of CoCrPtTa on 90 nm Ti underlayer shows the discrete mass type from the results of MFM investigation. This phenomenon is to be a distinct evidence that the improvement of perpendicular anisotropy by the adoption of Ti underlayer is originated from the reinforcement of the grain boundary segregation in CoCrPtTa alloy. Moreover, the transition of the M-H hysteresis pattern with the thickness of Ti underlayer indicates that the major contribution of Ti underlayer is not the magnetocrystalline anisotropy but the shape anisotropy due to the formation of uniform columnar grains by the nonmagnetic alloy segregation.

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Growth of $BaTiO_3$ Single Crystals by TSSG Technique (TSSG법에 의한 $BaTiO_3$ 단결정 육성)

  • 박봉모;정수진
    • Korean Journal of Crystallography
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    • v.3 no.2
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    • pp.120-128
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    • 1992
  • Single crysals of BaTiO3 were grown by TSSG technique at various cooling rates. Morpolo girts, defects and domain structures of the grown crystals were investigated. At the cooling rates below 0.5℃/hr, equant single crystals were obtained and the 11111 faces were dominantly developed. If the cooling rate was much faster or if the vortical temperature gradient in the so lotion was very large, the solution became unstable and the needle formed BasTil04 o crystals were precipitated. Two sets of parallel lamella domains are arranged perpendicular to each other and the irregularly shaped boundaries are fixed between them. These sets of domains show remarkable orientation contrast in x-ray topography. Heating the crystal above 127℃, the phase transition from tetragonal to cubic occurs. The phase transition front (PTF) moves in the direction of temperature gradient. Domains in the tetragonal phase are successively rearranged and regular strain patterns appear in the cubic phase. The habit plane of PTF in BaTi03 is found to deviate from a l1101 lattice plane by app roximately 9°.

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The influence of temperature gradient and rotation rate on Bi4Ge3O12 crystal growth by czochralski method (쵸크랄스키법에 의한 $Bi_4Ge_3O_{12}$ 단결정 육성에서 온도구배와 회전속도가 미치는 영향)

  • 배인국;황진명
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.9 no.6
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    • pp.585-589
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    • 1999
  • In order to grow $Bi_4Ge_3O_{12}$ crystals by the Czochralski method equipped with the auto-diameter control system, we used the resistance heater of our own design. We measure the temperature gradients under-arious thermal configurations. The relation between the critical rotation rate corresponding to the flat interface and the temperature gadient was investigated, and the importance of the axial temperature gradient was pointed out. The results from this work were compared with those obtained by other authors when RF heating was used. The optimal conditions for the crystal growth were determined as follows; under $O_2$ atmosphere with the pulling rate fixed at 2 mm/hr, rotation rate changed from 30 to 23 rpm as the crystal growth proceeded, radial and axial temperature gradients were 50 and $40^{\circ}C$/cm near melts respectively, and the composition was chemically stoichiometric.

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Structural Characteristics on InAs Quantum Dots multi-stacked on GaAs(100) Substrates

  • Roh, Cheong-Hyun;Park, Young-Ju;Kim, Eun-Kyu;Shim, Kwang-Bo
    • Journal of the Microelectronics and Packaging Society
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    • v.7 no.1
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    • pp.25-28
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    • 2000
  • The InAs self-assembled quantun dots (SAQDS) were grown on a GaAs(100) substrate using a molecular beam epitaxy (MBE) technique. The InAs QDs were multi-stacked to have various layer structures of 1, 3, 6, 10, 15 and 20 layers, where the thickness of the GaAs spacer and InAs QD layer were 20 monolayers (MLs) and 2 MLs, respectively. The nanostructured feature was characterized by photoluminescence (PL) and scanning transmission electron microscopy (STEM). It was found that the highest PL intensity was obtained from the specimen with 6 stacking layers and the energy of the PL peak was split with increasing the number of stacking layers. The STEM investigation exhibited that the quantum dots in the 6 stacking layer structure were well aligned in vertical columns without any deflect generation, whereas the volcano-like deflects were formed vertically along the growth direction over 10 periods of InAs stacking layers.

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Laser Patterning of Vertically Grown Carbon Nanotubes (수직성장된 탄소나노튜브의 선택적 패터닝)

  • Chang, Won Seok
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.36 no.12
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    • pp.1171-1176
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    • 2012
  • The selective patterning of a carbon nanotube (CNT) forest on a Si substrate has been performed using a femtosecond laser. The high shock wave generated by the femtosecond laser effectively removed the CNTs without damage to the Si substrate. This process has many advantages because it is performed without chemicals and can be easily applied to large-area patterning. The CNTs grown by plasma-enhanced chemical vapor deposition (PECVD) have a catalyst cap at the end of the nanotube owing to the tip-growth mode mechanism. For the application of an electron emission and biosensor probe, the catalyst cap is usually removed chemically, which damages the surface of the CNT wall. Precise control of the femtosecond laser power and focal position could solve this problem. Furthermore, selective CNT cutting using a femtosecond laser is also possible without any phase change in the CNTs, which is usually observed in the focused ion beam irradiation of CNTs.

Analysis of structural properties of epitaxial BST thin films prepared by pulsed laser deposition (펄스형 레이저 증착법으로 제조된 에피탁시 BST 박막의 구조 분석)

  • 김상섭;제정호
    • Journal of the Korean Vacuum Society
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    • v.7 no.4
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    • pp.355-360
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    • 1998
  • Epitaxial $Ba_{0.5}Sr_{0.5}TiO_3$thin films of two different thickness (~250 $\AA$ and ~1340 $\AA$) on MgO(001) prepared by a pulsed laser deposition method were studied by synchroton x-ray scattering measurements. The film initially grew on MgO(001) with a cube-on-cube relationship, maintaining it during further growth. As the film grew, the surface of the film became rough significantly, but the interface between the film and the substrate seemed to have changed little. In the early stage, the film was highly strained in a tetragonal structure with the longer axis parallel to the surface normal direction. As the growth proceeded further, it was mostly relaxed to a cubic structure with the lattice parameter of the bulk value and the mosaic distribution improved significantly in both in-plane and out-of-plane directions.

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수직형 LED의 광 추출효율 향상을 위한 표면 roughening에 대한 연구

  • Kim, Tae-Hyeong;Bae, Jeong-Un;Yeom, Geun-Yeong
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.02a
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    • pp.323-324
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    • 2011
  • 현재 많은 blue LED소자의 제작 공정과 소자 표면에 texturing하는 과정이 보고되어 있다. 그 중n층이 위로 올라오는 수직형 LED 구조로 인해 표면 texturing 기술은 빛의 발광 효율을 증가 시킬 수 있는 중요한 기술 중 하나가 되었다. 1 이 연구에서, 우리는 InGaN을 바탕으로 한 LED 소자의 표면 roughening을 건식과 습식 공정을 모두 거치는 과정을 통하여 소자의 발광 효율을 높이는 시도를 하였다. 최근 전도성 물질 기판 위에 증착 되어 있는 수직형 LED 소자 2,3,4는 과거의 사파이어 기판 위에 증착 되어 있는 형태의 LED 소자에 비해 우수한 소자 특성을 보인다. 이는 과거 사파이어 기판을 사용함으로써 낮은 열적 특성과 더불어 전기 정도성에 몇 가지 제약을 초래하게 되었기 때문이다. 반면, 전도성 기판은 LED 구조의 back side ohmic contact을 가능하게 하였고, 더 나은 확산 특성을 보여 주었고 작동 전압 또한 감소 하였다. N층이 위에 있는 수직형 LED 소자는 KrF pulsed excimer laser로 인해 실현 되었다. 이 laser 빛이 투명한 사파이어 기판을 통해 얇은 GaN층에 입사되면, 기판과 GaN가 분리된다. 이 레이저 기술은 laser lift-off(LLO)로 성장된 기판으로부터 LED 구조를 분리하는데 성공하게 하였다. 우리는 건식 식각 공정을 이용하여 n 층이 위에 올라와 있는 구조인 수직형 LED 소자에 roughening을 주고 다시 이 표면에 습식 식각 공정을 적용하여 거친 부분의 거칠기를 또 한번 증가시켰다. 그리고 이 거칠어진 표면은 이 공정이 진행 되기 전의 소자에 비해 빛의 발광 효율이 증가 되었다. 이 두 공정을 포함한 식각 공정은 두 가지 장점이 생겼는데, 한가지는 GaN에서 외부로 방출할 수 있는 표면 지역이 증가되었고, 다른 한가지는 가파른 거칠기 특성으로 인해 critical angle을 증가시킨 것이다.

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Full-mouth rehabilitation with increasing minimum vertical dimension in the patient with severely worn dentition and deep bite (과도한 치아 마모와 과개교합을 보이는 환자에서 최소한의 수직 고경 증가를 동반한 전악 구강 회복 증례)

  • Lee, Kang-Shin;Park, Ju-Mi;Ahn, Seung-Geun;Seo, Jae-Min;Han, Chang-Hee;Lee, Jung-Jin
    • The Journal of Korean Academy of Prosthodontics
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    • v.59 no.4
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    • pp.431-441
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    • 2021
  • Full-mouth rehabilitation with increasing vertical dimension can be used for patients with severely worn teeth. In severely worn teeth also, the alveolar process can be elongated to compensate for the reduced vertical dimension, and the patient's vertical dimension of occlusion can be kept constant. However, full-mouth rehabilitation with increasing vertical dimension must be carefully chosen, because the vertical dimension can be reduced by tooth wear. It is important to establish a treatment plan with the systematic diagnosis of the change in the vertical dimension and gain space for the prosthesis. It is necessary to change the vertical dimension to secure the restoration space and select the minimum vertical dimension elevation for the esthetic and functional goal. In this case report, the patient complained of difficulty during chewing due to a worn dentition and wanted esthetic improvement of the short mandibular anterior teeth. After systematic evaluation and diagnosis, we performed full-mouth rehabilitation with minimum vertical dimension elevation to obtain the space for restoration. This resulted in a stable and harmonious occlusion, and the functional and esthetic problems of the patient were solved after treatment. The patient was satisfied with the results of the treatment and maintained stable occlusion during the follow-up period.