• Elastomers and Composites
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• v.35 no.3
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• pp.196-204
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• 2000

SBR, polyurethane, acryl and epoxy latex were separately mixed with ethylene -vinylacetate emulsion(EVA) in the range of $0{\sim}50wt%$. For the mixtures, the various physical properties such as defoamerability, mechanical property, and water resistance were experimentally examined. The excellent defoamer was BYK-021 and the appropriate use of it was 0.3 phr for the total components. The shrinkage of compounds was influenced by the compatability of resins and the formation of voids. The mechanical properties was related to the cohesive force of resin particles, the coagulation of cement particles and the co-bonding of resin particles with cement particles. Mixing latex separately showed better properties then non-mixing in the shrinkage ratio, flexural strength, adhesive strength, and impact strength. The water resistance of composites mixed with cement was worse than that of EVA resin.

• Journal of Nuclear Fuel Cycle and Waste Technology(JNFCWT)
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• v.5 no.3
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• pp.221-227
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• 2007

Fenton's reagent is applied to directly decompose the ion-exchange resins, IRN-78 and the mixed resin with IRN-77. The newly applied procedures is to dry the resin first and the catalyst solution is completely absorbed into the resin, then a limited dose of $H_2O_2$ is introduced for an effective reaction between the reagents within the resin. As a characteristic on the decomposition of IRN-78, the resin mixture should be heated to $40^{\circ}C$ to induce the initial reaction and lag time is also needed for about 20 minutes until the main reaction occurs. The effectiveness of the decomposition is investigated using $CuSO_4,\;Cu(NO_3)_2\;and\;FeSO_4$ as a catalyst and the decomposition rate is compared depending on the concentration of each catalyst and the amount of $H_2O_2$. The most effective catalyst was found to be $FeSO_4$ for IRN-78 alone and the mixed resin with IRN-77, and $FeSO_4$ showed a special effect that the reaction was initiated without heating and a lag time. Furthermore, the optimum concentration of the catalyst for each resin and the mixed one is suggested in the view point of the amount of $H_2O_2$ needed and the stability of the decomposition reaction.

• Applied Chemistry for Engineering
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• v.31 no.3
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• pp.310-316
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• 2020

Terpene-modified phenolic resins were used to improve the tires wet traction related to the driving safety and also rolling resistance related to fuel efficiency. In this work, alpha-pinene, beta pinene, and delta limonene resins, which constitute different basic structures of terpene-modified phenolic resins, were individually added to the tread compounds of tires and their physical properties were compared with those of the alkyl phenol resin compounds. Alkyl phenolic resins showed no significant difference in tangent delta from terpene-modified phenolic resins at 0 ℃, which is related to wet traction, but showed higher tangent delta at 80 ℃, which is related to rolling resistance, indicating smaller fuel efficiency improvement effects. Among the terpene-modified phenolic resins, beta pinene one showed improved wet traction and fuel efficiency compared to those of other resins. Delta limonene resin showed the best wet traction improvement effect, and alkyl phenolic resins showed relatively high tensile strength and abrasion property. All terpene-modified resins exhibited better rolling resistance than those of alkyl phenolic ones so that they can be said to have better fuel efficiency improvement effects and also to improve other properties compared to those of blanks. Terpene-modified phenolic resins could be used when mixing tire compounds referring to the properties of the phenolic resins revealed in this work, which could result in preparing compounds with improved wet traction and rolling resistance.

• Journal of Sericultural and Entomological Science
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• v.20 no.1
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• pp.15-23
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• 1978

This studies have been carried out for several years to develop more better urea resin treating process on silk textiles which may be better crease resist without harming on the textile touch feeling. Specially, this paper payed attention to minimize the necessary formaldehyde content to be condensed with urea and created a new processing method which is named as Homo Metalic Urea Resin found to be better than urea resin process. The obtained results are as followings. 1. The prepared urea resin was found to be smell-less because of minimized formaldehyde content is the least than any other reports carried out before than this. 2. A new type of urea resin has been created by using uric 2incchloride and formaldehyde which is named as Homo Metalic Urea Resin. This processing method may carry both weighing process and urea resin process. 3. Crease resistance, stiffness and bulkiness were increased through such resin treats. Homo metalic urea resin process showed better results than the urea resin process. 4. Spun silk or low twisted silk have shown better crease resistance than raw silk or high twisted silk upon the both resin treats. 5. Both treat methods were found to be good economical feasibility upon the silk finishing process. 6. Tenacity and elongation of silk fibers were found to decrease some what because of grafting or weighing results. 7. Wooly silk has been also created with specific urea resin process. Such silk could be obtained by formaldehyde gas treat with urea soaken silk in a chamber, which induced to form scale on the surface of silk fibers.

• Journal of Conservation Science
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• v.27 no.3
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• pp.301-312
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• 2011

Epoxy resin has superior durability and adhesive strength and proper physical strength so that it is used to diversity materials for multi-purposes. However epoxy resin is hardly removed after hardening specially once it is applied to artefacts, it is difficult to remove them under re-conservation. This paper is an experimental study on removing epoxy resin applied to iron objects using Nd:YAG laser cleaning system. Tests conducted in this study investigated how increasing laser energy and pulses would give effect on samples. The samples were prepared in a way that epoxy resin, itself pure and one which was mixed with pigment and they were applied to iron coupons and corroded iron coupons respectively. As a result of experiment, pure epoxy resin applied to corroded iron coupons was ablated at high laser energy but epoxy resin applied to iron coupons and mixing with pigment were not ablated but discolored and bubbled due to laser-induced heat generation. Results of FT-IR showed no component alteration of shifted resins and no residues on the surfaces ablated by laser irradiation. From SEM-EDS for removed surfaces, the debris from epoxy resin and melting iron was observed. Therefore, this study demonstrated the possibilities and limitations for laser cleaning to remove epoxy resin from iron objects.

• Journal of the Korean Wood Science and Technology
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• v.35 no.6
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• pp.108-117
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• 2007

This research was performed to investigate the feasibility of bamboo as a raw material for the manufacture of plywood. Wood veneer-bamboo zephyr composite boards (WBCB) were manufactured using keruing (Dipterocarpus sp.) veneers and hachiku bamboo (Phyllostacbys nigra var. henonis Stapf) using various adhesives, and the effect of the method and amount of resin spread on the mechanical properties of the composites were investigated. The WBCB manufactured using polymeric isocyanate (PMDI) showed the best mechanical properties, followed by phenol-formaldehyde resin (PF), phenol-melamine-formaldehyde resin, urea-melamine-formaldehyde resin, and urea-formaldehyde resin. However, considering the operation feasibility as well as mechanical properties, PF resin proved to be the appropriate adhesive for the practical purpose. As the amount of resin spread increased, the mechanical properties of 5-ply WBCB with 12 mm thicknesses manufactured using PF resin tended to increase, and more failure occurred at the interface between veneer and bamboo zephyr than at the interface among bamboo zephyrs. This result suggests that penetration of resin into bamboo zephyr could be the important factor. In this research, the appropriate amount of resin amount was $320g/m^2$. 5-ply WBCBs were manufactured using various methods of resin spread but the effect of the methods on the mechanical properties showed no little difference, which meant that the method of resin spread could be chosen considering the manufacturing conditions and operation feasibility.

• Polymer(Korea)
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• v.28 no.1
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• pp.35-40
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• 2004

The formation mechanism of void defect which deteriorate composite's property is various according to each composite process. In this paper, void formation and growth mechanism is analyzed by thermal analysis and GC/MS. We made a vacuum chamber for observing pressure effect. Thermal analysis has been done in various condition. Elements of volatiles during resin curing were turned out by GC/MS. The most of volatiles of polyester were composed of styrene (over 80%) and a small quantity of toluene. In case epoxy resin, butyl glycidyl ether was the main element of volatiles (over 90%). We concluded that the original sites of void growth existed in resin and they were eliminated by vacuum and heating process. And the growth of void was influenced by water, diluents, solvent, and reactants in resin.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.7 no.4
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• pp.727-732
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• 2006

The object of this study was to investigate the influence of composition and concentration of electrolyte, ratio of cation to anion exchange resin of mixed ion exchange column in the performance of ion exchange. Also this work examined the removal capability of suspended solids by ion exchange resin and the effect of particule on the characteristics of ion exchange. Breakthrough time was extended as the amount of ions and particles present in liquid was decreased. The case of anion, the breakthrough sequence is $Cl^{-}, but the case of cation, the breakthrough sequence is $Na^{+}. As for the ratio of cation to anion exchange resin of 1:2, the breakthrough time was prolonged compared with that of 1:1 and 1:3. For the electrolyte of equal concentration containing suspended solid, breakthrough time was contracted less than 20%. It results in the increase in the removal capacity of cation exchange resin. For the higher ratio of cation exchange resin, suspended solids are shorten the cation's breakthrough time so that the runtime of ion exchange resin tower is increased.

• Journal of agriculture & life science
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• v.46 no.2
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• pp.43-48
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• 2012

This study was investigated on the properties of board made from Miscanthus sinensis var. purpurascens particles differed in density of board and mixed ratio of powder type- and liquid type-phenolic resin. As the board density increase, thickness swelling and bending strength increased while water absorption decreased. With increasing the resin content, water absorption and thickness swelling decreased while MOR and internal bond strength increased. The board made of liquid type phenol-formaldehyde resin was low in water absorption and thickness swelling, and there were similar bending strengths between power type- and liquid type-phenol resin in resin cont of 11% and 13% at the board density $0.4g/cm^3$ and internal bond strength was higher with liquid type-phenolic resin in its bending strength.

• Composites Research
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• v.36 no.6
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• pp.388-394
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• 2023

In composites manufacturing, increasing resin impregnation is a key way to speed up the manufacturing process and improve product quality. While resin improvement is important, simple fiber surface treatments can also improve resin flowability. In this study, different plasma treatment times were applied to carbon fiber fabrics to improve the impregnation between resin and fiber. Electrical resistivity measurements were used to evaluate the dispersion of resin in the fibers, which changed with plasma treatment. The effect of fiber surface treatment on resin spreadability could be observed in real time. When inserting a carbon fiber tow into the resin, the amount of resin that soaked into the tow was measured to objectively compare resin impregnation. Five minutes of plasma treatment improved the tensile and compressive strength of the composite by more than 50%, while reducing the void content and increasing the fire point impregnation flow rate. Finally, a dynamic flexural fatigue test was conducted using a portion of the composite used as an architectural composite part, and the composite part did not fail after one million cycles of a 3 kN load.