• Resources Recycling
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• v.13 no.3
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• pp.43-49
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• 2004

In this study. an experimental work was performed to mold tensile specimens by using the injection molding machine. Melt temperature, mold temperature and the mixed ratio of recycled resin were selected as processing parameters for studying the effect of those conditions on the shrinkage and weight of molded parts. As a result, the shrinkage was increased with the higher mold and melt temperature and it was more sensitive to the change of mold temperature. On the other hand, the weight of molded parts was decreased with the increment of mold and melt temperature.

• Journal of the Korean Society of Manufacturing Process Engineers
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• v.2 no.3
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• pp.62-68
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• 2003

In this study, an experimental work was performed to mold tensile specimens by using the injection molding machine. Melt temperature, mold temperature and the mixed rate of recycled resin were selected as processing parameters for studing the effect of those condition on the shrinkage and weight of molded parts. As a result, the shrinkage was increased with the higher mold and melt temperature and It was more senstive to the change of mold temperature. On the other hand, the weight of molded parts was decreased with the increment of mold and melt temperature.

• Proceedings of the Korea Institute of Fire Science and Engineering Conference
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• 2011.11a
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• pp.470-473
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• 2011

본 연구에서는 산업현장에서 에폭시 강화촉진제, 도로용 첨가제 등으로 많이 사용되고 있는 경화제(M.E.K)의 혼합비에 따른 자연발화 위험성을 알아보고 산업 현장의 화재 예방을 위한 기초자료로 제공하고자 하였다. M.E.K와 에포비아 수지를 각기 다른 비율로 혼합한 상태에서 시간경과에 따른 시료의 온도변화 와 유증기 발생 및 자연발화 여부를 관찰한 결과 합성수지와 경화제의 혼합시 경화제가 5% 이상으로 혼합될 경우 혼합 수지의 내부온도가 약 $40^{\circ}C$ 이상으로 상승하면서 발포 현상과 함께 다량의 유증기가 발생하였고, 유증기가 발생된 모든 조건에 대하여 자연발화 여부는 확인할 수 없었다.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2006.06a
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• pp.214-215
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• 2006

Colloidal Silica(CS)와 유기수지를 혼합하여 서로의 단점을 보완하는 나노복합재료를 합성하기 위해 친수성인 CS를 유기실란으로 표면처리하여 소수성화하고 유기수지와 복합체를 제조하였다. CS표면의 -OH기와 실란의 -OH기가 축합반응하여 화학결합을 형성함으로서 CS의 표면은 실란의 $CH_3$에 의해 소수성화되어 CS sol이 제조된다. CS sol과 유기수지는 공동용매에 의해 균일한 분산이 가능하고 필름 및 코팅제로의 제조가 가능하다. 사용된 무기물은 40nm 의 크기를 가지므로 가시광선영역의 빛을 산란하지 않아 투명하고 사용된 수지 또한 투명하여 우수한 광학적 특성을 나타낸다. 만들어진 필름은 CS의 영향으로 유기수지의 내열성보다 향상된 열분해온도와 높은 접촉각, 높은 절연율을 보였다.

• Korean Journal of Dental Materials
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• v.44 no.4
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• pp.311-318
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• 2017

The purpose of this study was to examine the effects of the curing sequence and polymerization temperature on the flexural strength and microhardness of two provisional resins (Bis-acryl resin composite and polymethyl methacrylate (PMMA)). Polymerization was carried out under various conditions, in air at $25^{\circ}C$ (control) and in hot water (40, 50, 60, 70, and $80^{\circ}C$). The flexural strength test was conducted according to ISO-4049. The Knoop hardness was measured. For the Bis-acryl resin, the temperature up to $50^{\circ}C$ did not increase the flexural strength nor the hardness of the bis-acryl resin composite (p>0.05) but higher temperatures increased the strengths. For the PMMA resin, flexural strength increased with temperatures up to $70^{\circ}C$ and then decreased slightly. Bis-acryl resin composite had higher mechanical properties than the PMMA resin. The effect of heat was more pronounced in the bis-acryl resin composite than in the PMMA resin (p<0.05).

• The Korean Journal of Rheology
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• v.11 no.2
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• pp.135-142
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• 1999

The effects of 1 wt.% N-benzylpyrazinium hexafluoroantimonate (BPH) as a thermal latent initiator and blend compositions composed of 0, 5, 10, 20 and 40 wt.% of phenol-novolac resin to epoxy resin were investigated in terms of cure kinetics, thermal stabilities and rheological properties. Thermal latent properties of BPH were measured from the conversion as a function of reaction temperature on a dynamic DSC. This cationic BPH system turned out to be an effective thermal latent initiator in the epoxy-phenol curing system. And the increase of phenol-novolac resin concentration led to the decrease in the latent temperature and to the increase of cure activation energy ($E_a$) of the blend system. The thermal stability and activation energy ($E_t$) for decomposition, gel-time and activation energy ($E_c$) for cross-linking from rheometer increased within the composition range of 20~40 wt.% of phenol-novolac resin. This implies that the three-dimensional cross-linking may take place among hydroxyl group within phenol resin, epoxide ring within epoxy resin and BPH.

• Polymer(Korea)
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• v.25 no.1
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• pp.122-132
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• 2001

Thermoplastic film infusion process was investigated by using a rubber tool, which intrinsically contains a thermally-expandable characteristic and effectively compensates for the pressure loss caused by thermoplastic polymer infusion. Increasing temperature up to the melting temperature of matrix, the polymer melt subsequently infused into the dry fabric, but the pressure was successfully sustained by the rubber tool. Even with the decreased resin volume, the rubber tool produced sufficiently high elastic force for continuous resin infusion. Combining D'Arcy's law with the compressibility of rubber tool and elastic fiber bed, a film infusion model was developed to predict the resin infusion rate and pressure change as a function of time. In addition, the film infusion process without the rubber tool was viewed and analyzed by a compression process of the elastic fiber bed and viscous resin melt. The compressibility of fiber bed was experimentally measured and the multiple-step resin infusion was well described by the developed model equations.

• Korean Chemical Engineering Research
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• v.50 no.3
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• pp.588-593
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• 2012

Compatibility of unsaturated polyester (UP) and low profile agent (LPA) of polystyrene (PS) have been investigated under various mixing conditions such as the ratio of UP and LPA, mixing time, mixing temperature, and input amount of 2nd UP. It was possible to obtain mixture with small particle size and low phase separation in condition of 35 g of LPA, 25 g of 1st UP input, 5 min of mixing time, 1700 rpm of mixing speed, and 45 g of 2nd UP input. It was found that compatibility of UP and LPA was very sensitive to mixing conditions. In addition, molded sample using sheet molding compound prepared by stable mixing condition appeared good properties such as low water adsorption, low shrinkage, and high gloss.

• Proceedings of the KAIS Fall Conference
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• 2000.10a
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• pp.74-77
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• 2000

사출성형에 관한 연구는 오랜 역사를 가지고 있으며 공정 시뮬레이션을 위한 상용화된 CAE 프로그램을 포함하여 많은 연구가 진행되는 분야중의 하나이다. 그러나 다양한 고분자 재료의 성질, 금형의 복잡한 형상 및 성형조컨 둥의 변화로 인해 금형설계 및 제작 그리고 사출성형시 상당한 어려움을 겪게 된다. 사출성형 공정에서는 금형온도, 플라스틱 재료, 냉각수, 보압과 사출압 등의 여러 가지 공정변수가 있어 현장전문가의 경험에 의해 사출금형의 제작이 이루어지는 경우가 보통이다 이와 같은 경험에 의한 금형 제작은 상당한 납기지연과 노동집약적인 방식으로 흘러가게 된다. 금형 제작시 가장 고려해야 될 사항 중의 하나는 사출성형품의 수축이다. 사출성형에서 광음수지는 냉각, 고화하면서 수축하는데 성형품 치수를 유지하기 위해서는 수축하는만큼 금형의 치수를 보정하여야 한다. 이 수축률은 사용수지의 종류와 성형품 크기, 살두께 등에 따라 다르다. 또 동일한 수지일 경우에도 성형조건에 따라 변화하고 특히 배향성을 가진 수지는 유동방향에 따라서도 변화가 있다. 즉, 금형의 온도가 높으면 수축률은 증가하고 사출압력이 높으면 감소한다. 또한 살두께가 두껍고 길이가 길 때 수축률은 증가한다 방향성이 있는 수지는 유동방향에 대하여 지각방향에서 가장 적다. 특히 방향성이 현저한 HDP에서는 유동방향에 따라 수축차가 크므로 성형할 때 변형을 일으키는 경우가 많다. 일반적으로 PE, PP. PA와 같은 결정성 수지는 PS, SAM, ABS 등의 비결정성 수지보다 수축률이 크다. 본 연구에서는 한조산업사에서 제작한 '클랠프 척' 금형 제작과정에서 성형품의 수축으로 인한 금형의 치수보정에 있어서의 문제점을 유동해석 전용 CAE 프로그램인 C-mold를 사용하여 해석하고 평가하였다. 그리하여 현장 전문가가 경험적으로 여러 번의 시행착오를 거쳐 완성된 금형을 제작하던 기존의 방법보다 체계적이고 합리적이며 또한 신속하게 문제를 해결함으로써 궁극적으로 금형설계 및 제작기간을 단축하고자 한다.

• Applied Chemistry for Engineering
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• v.9 no.5
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• pp.689-697
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• 1998

In this work, we studied the equilibrium, rate and rate determining step of uranium adsorption on RGP resins of MR type prepared by varying the degree of crosslinking and the amount of diluent. The equilibrium of uranium adsorption on RGP resins were well explained by Frendrich isotherm as well as Langmuir isotherm model. The amount of adsorption and adsorption rate increase with the adsorption temperature. The heat of the adsorption was 11 kcal/mol. The adsorption rates of uranium on RGP resins were decreased in the order of RGP-10(50)>RGP-1(50)>RGP-2(50)>RGP-5(50)>RGP-0(50) and RGP-2(75)>RGP-2(100)>RGP-2(50)>RGP-2(30)>RGP-2(0). The diffusion resistance of uranium into RGP resin increased as follows; molecular diffusion < pore diffusion < surface diffusion. On the other hand, the surface diffusion was more dominative than the pore diffusion in intraparticle region. Thus, this result indicates that the adsorption mechanism of uranium on RGP resins is intraparticle diffusion controlled.