• 한국신재생에너지학회:학술대회논문집
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• 2009.06a
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• pp.648-651
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• 2009

탄소섬유강화플라스틱(CFRP:Carbon Fiber Reinforced Plastic)용기의 외부에 화재가 발생할 경우 함침된 수지(Resin)가 탄화되면서 자체 강도가 약화되고 충전된 가스가 외부 온도 상승에 따라 압력 상승이 발생하여 용기의 폭발로 이어지는 사고가 발생할 개연성이 높다. 화염 노출조건에서 복합재료 용기의 폭발을 방지하기 위하여 용기용 밸브에 내장된 온도감응식 압력안전장치(TPRD:Thermally activated Pressure Relief Device) 작동 성능을 검증하기 위한 방법으로 화염실험(Bonfire test)를 실시하고 있으나, 개방 공간에서 실시되는 이 실험은 표면 온도 변화가 매우 크게 발생하여 실험에 대한 재현성(Reproducibility)에 의문이 제기되고 있다. 따라서, 표면 온도를 일정하게 유지하기 위한 실험 방법의 개선이 필요하다. 본 연구에서는 경유+heptane을 이용한 전체 화염에 노출되는 경우와, 천연가스를 이용한 단일화염에 노출되는 경우의 실험 결과 비교를 통하여 화염 노출 표면 온도를 일정하게 유지하기 위한 가열 방법의 타당성을 검토하였다. 또한, 복합재료 라이너(Liner)의 온도 변화 비교를 통하여 집중화염 노출 조건에서 열전달 특성을 알아보았다.

• Journal of Energy Engineering
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• v.17 no.1
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• pp.8-14
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• 2008

The effects of calcium type catalysts addition on the thermal decomposition of low density polyethylene (LDPE) and ethylene vinyl acetate (EVA) resin have been studied in a thermal analyze. (TGA, DSC) and a small batch reactor. The calcium type catalysts tested were calcinated dolomite, lime, and calcinated oyster shell. As the results of TGA experiments, pyrolysis starting temperature for LDPE varied in the range of $330{\sim}360^{\circ}C$ according to heating rate, but EVA resin had the 1st pyrolysis temperature range of $300{\sim}400^{\circ}C$ and the 2nd pyrolysis temperature range of $425{\sim}525^{\circ}C$. The calcinated dolomite enhanced the pyrolysis rate in LDPE pyrolysis reaction, while the calcium type catalysts reduced the pyrolysis rate in EVA pyrolysis reaction. In the DSC experiments, addition of calcium type catalysts reduced the melting point, but did not affect to the heat of fusin. Calcinated dolomite reduced 20% of the heat of pyrolysis reaction. In the batch system experiments, the mixing of calcinated dolomite and lime enhanced the yield of fuel oil, but did not affect to the distribution of carbon numbers.

• Journal of the Korean Chemical Society
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• v.40 no.1
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• pp.81-86
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• 1996

The physical properties of epoxy molding compound (EMC) according to the change of softening point of epoxy resin have been investigated in order to study the relationship between the properties of o-cresol novolac epoxy resin, which is main component of EMC for semiconductor encapsulation, and EMC. The softening points of used epoxy resin are 65.1 $^{\circ}C$, 72.2 $^{\circ}C$, and 83.0 $^{\circ}C$, respectively. The flexural strength and flexural modulus as mechanical properties were measured, and thermal expansion coefficient, thermal conductivity and glass transition temperature (Tg) as thermal properties, and spiral flow as moldability have been investigated to see the change of physical properties of EMC. The flexural modulus, thermal expansion coefficients in the glass state (${\alpha}_1$), and thermal conductivity of EMC were found to be keep constant value irrespective of the change of softening point, but Tg increased with softening point of epoxy resin, and the spiral flow decreased with that. It can be considered that these phenomena are due to the increase of crosslinking density of EMC according to the increase of softening point. The transition points were found out in the thermal expansion coefficient data in the rubbery state (${\alpha}_2$) and the flexural strength data. These can show the decrease of filler dispersion according to increase of epoxy resin viscosity.

• Journal of the Korean Applied Science and Technology
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• v.38 no.2
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• pp.476-487
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• 2021

To prepare acrylic resin coatings containing 70% of solids, we used n-butyl methacrylate(BMA), methyl methacrylate(MMA), 2-hydroxyethyl methacrylate(2-HEMA), and acetoacetoxyethyl acrylate(AAEA), caprolactone acrylate(CLA) as raw materials, the glass transition temperature(T_g) of acrylic copolymer was adjusted around 50 ℃. The viscosity and molecular weight of the acrylic resins was increased with increasing OH values. Di-tert-amyl peroxide was found to be the suitable initiator to get high-solids acrylic resins. The optimum reaction conditions found in the study are 5 wt% of initiator, 4 wt% of chain transfer agent, 4 hrs of dropping time, and 140 ℃ of reaction temperature. The structure of the synthesized resins were characterized by FT-IR and ¹H-NMR spectroscopy. Number average molecular weight of 1900~2600 and molecular wight distribution of 1.4~2.1 were obtained. Crosslinked acrylic urethane clear coatings were obtained by curing reaction between the synthesized acrylic resins and hexamethylene diisocyanate trimer(Desmodur N-3300), the equivalent ratio of NCO/OH was 1.2/1.0. The physical properties from the following studies were carried out: viscosity(Zahn cup #2), adhesion, drying time, pot-life, pensil hardness, and 60° specular gloss. Various properties of the acrylic urethane clear coatings were also evaluated on the coating specimens. Adhesion property to a substrate, drying time, pot-life, pencil hardness, and 60° specular gloss of prepared paint showed quite good properties. Futhermore, prepared paint containing 10% of CLA showed quite good properties for adhesion, low viscosity and high hardness.

• Journal of the Korean Institute of Landscape Architecture
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• v.40 no.6
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• pp.190-197
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• 2012

The purpose of this study was to evaluate thermal environment and heat budget of light thin layer green roof through an experiment in order to quantify its heat budget. Two concrete model boxes($1.2m(W){\times}1.2m(D){\times}1.0m(H)$) were constructed: One experiment box with Zoysia japonica planted on substrate depth of 10cm and one control box without any plant. Between June 6th and 7th, 2012, outside climatic conditions(air temperature, relative humidity, wind direction, wind speed), evapotranspiration, surface and ceiling temperature, heat flux, and heat budget of the boxes were measured. Daily maximum temperature of those two days was $29.4^{\circ}C$ and $30^{\circ}C$, and daily evapotranspiration was $2,686.1g/m^2$ and $3,312.8g/m^2$, respectively. It was found that evapotranspiration increased as the quantity of solar radiation increased. A surface and ceiling temperature of those two boxes was compared when outside air temperature was the greatest. and control box showed a greater temperature in both cases. Thus it was found that green roof was effective in reducing temperature. As results of heat budget analysis, heat budget of a green roof showed a greater proportion of net radiation and latent heat while heat budget of the control box showed a greater proportion of sensible heat and conduction heat. The significance of this study was to analyze heat budget of green roof temperature reduction. As substrate depth and types, species and seasonal changes may have influences on temperature reduction of green roof, further study is necessary.

• International Journal of Highway Engineering
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• v.13 no.4
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• pp.19-28
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• 2011

This study developed a solar radiation reflection pavement, so called a cool pavement, to lessen the urban heat island effect by coating a pavement surface with acrylic resins mixed with light-colored pigments. From a laboratory test, simulating solar heating process in pavements, the cool pavement reduced more than $12^{\circ}C$ of pavement temperature at $60^{\circ}C$ compared to a control porous pavement. With the increase of the mixing ratio of the pigments to acrylic resins, the temperature reduction effect increased, but its workability became worse due to higher viscosity. As a result, an appropriate mixing ratio was determined as 15%. The cool pavement had better durability than the control pavement: One quarter of Catabro loss and twofold dynamic stability. Its adhesion was also higher enough not to be debonded under traffic loading. In-situ noise and friction tests conducted in two field sites showed that the cool pavement reduced its noise level by 3.7dB in average and increased its friction level by 30% compared to the control pavement. The permeability of the cool pavement was little lower than the control pavement, but higher enough to satisfy the minimum requirement for porous pavements.

• Journal of the Korean Applied Science and Technology
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• v.33 no.4
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• pp.676-685
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• 2016

This study investigated the conversion of oil products from polystyrene by using dispersed Co and Mo catalyst on reaction time and concentration change for knowledging on characteristics at low temperature (425, 450 and $475^{\circ}C$) pyrolysis and reaction time(20~80 min, 15 min interval) in a batch reactor. It will be showed the conditions for optimum pyrolysis at reaction temperature $450^{\circ}C$ and the reaction time 35min, and the main components of the converted liquid oil were styrene and benzene derivatives by GC/MS. The oil products formed during pyrolysis were classified into gas, gasoline, kero, diesel and heavy oil according to the domestic specification of petroleum products. The pyrolysis conversion rate was showed as Co catalyst > Mo catalyst > Thermal in all reaction time at reaction temperature $450^{\circ}C$. The yields rate of gas, kerosine, diesel were the most hight at Mo Catalyst, gasoline was at thermal and heavy oil was at Co catalyst. The conversion rate and yields of the pyrolysis products were the most height when Co catalyst ratio was 100%.

• 한국신재생에너지학회:학술대회논문집
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• 2008.05a
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• pp.260-262
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• 2008

최근 고유가의 지속과 국제적인 환경 규제에 대응하기 위하여 환경친화적인 대체연료의 개발이 시급한 가운데 재생가능한 동식물성 유지로부터 생산되는 바이오 디젤에 대한 연구가 활발히 진행되고 있다. 특히 자원 재활용 및 에너지 생산관점에서 폐유지로부터 바이오디젤 원료로 사용하는 연구가 활발히 진행되어 왔다. 이러한 폐유지로부터 바이오디젤을 효율적으로 생산하기 위해서는 폐유지내 함유되어 있는 유리지방산을 전처리공정에서 산촉매에 의한 에스테르화 반응에 의해 전환제거하고자 한다. 본 연구에서는 폐유지내 함유된 유리지방산 전환제거에 효과적인 불균일계 이온교환수지 촉매를 이용하여 공정변수 즉 사용된 촉매의 양, 반응온도, 유리지방산 농도에 따른 유리지방산 전환제거특성을 조사해 보았다. 또한 각각의 반응조건에서 속도상수를 계산하여 이온교환수지 촉매를 사용한 유리지방산 전환 제거에 필요한 활성화 에너지 값을 구하였다.

• Proceedings of the Korean Society of Precision Engineering Conference
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• 2001.10a
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• pp.269-275
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• 2001

정밀가공기계 및 소음발생원의 방진재료로서 사용될 수 있는 재료는 우선 내부 및 외부진동의 흡수성과 감쇠성이 뛰어나야 하고, 시간 및 온도변화에 따라 형상 및 치수 정밀도가 안정되어야 하며, 불규칙한 외력과 운동전달기구의 변동 하중 하에서도 높은 정적, 동적 강성을 유지해야 한다. 본 연구에서 개발한 재료인 Ferrite-Resin 복합재료는 Resin-Concrete에 미세한 산화철을 filler 재료로 사용함으로써 주철 및 강의 구조재료가 갖는 강성과 비중의 값에 접근시킬 수이었다. 일반적으로 불포화 폴리에스테르 수지나 에폭시계 수지는 glass 전위점의 근처에서 진동에너지의 흡수가 큰 영역이 존재하며 이는 10 .mu.m 이내의 미세한 filler재료가 포함되었을 경우에도 그 종류에 관계없이 큰 변화가 없는 성질이다. 시험편을 통한 재료실험을 통하여 개발된 복합재료를 모델 구조물에 적용시킴으로서 그 적용성을 검토하였다. 앞으로의 수지와 Ferrite 함유량 및 제조 공정이 적절히 모색되면, 이 방진재료가 정밀기계의 구조재료로서 뿐만 아니라 냉동기, 소형선박의 기관실, 가전제품 및 기어박스 등의 케이싱 재료로 사용되는 방진재료로서 그 응용이 확대될 수 있을 것으로 본다.

• Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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• 2003.10a
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• pp.805-808
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• 2003

기존에 적용중인 유전가열 합성수지 접착기술의 경우 진공관 소자를 사용하여 10MHz 대역 이상의 스위칭 주파수를 사용하고, 유전손실이 비교적 높은 PVC 소재에 제한적으로 적용해 왔다. 다른 합성수지 소재에 비해서 유전손실이 낮은 친환경적인 소재에 대해서는 적용이 어려운 기술인 관계로 최근들어 부각되는 친환경적 소재의 적용 확대로 인하여 기존 유전가열 방식의 접착기술은 한계에 접하고 있다. 본 논문에서는 고주파 유도가열 관련 기술을 응용하여 친환경적인 합성소재의 직접가열의 문제점을 간접가열에 의한 온도제어를 적용하여 고주파 유도가열 접착기를 설계하였다.