• Title/Summary/Keyword: 수지계열

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Effects of laminated structure and fiber coating on tensile strength of radiation shielding sheet (방사선 차폐시트의 적층 구조와 섬유 코팅의 융합적인 현상이 인장강도에 미치는 영향)

  • Kim, Seon-Chil
    • Journal of the Korea Convergence Society
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    • v.11 no.6
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    • pp.83-88
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    • 2020
  • Recently, radiation shielding sheets made of eco-friendly materials have been widely used in medical institutions. The shielding sheet is processed into a solid form by thermoforming by mixing a shielding material with a polymer material. The base is resin-based and has a limit in tensile strength, and for this purpose, fibers such as non-woven fabrics are used on the surface. The shielding sheet process technology has a problem in that the tensile strength rapidly decreases when the content of the shielding material is increased to increase the shielding performance. In order to improve this, this study intends to compare and evaluate the method of laminating and coating the fibers in the sheet process. In comparison of the three types of sheets, there was no difference in shielding performance between the fiber-coated sheet and the compression sheet, but there was a large difference in tensile strength.

Calibration of the WASP4 Model Applied to Lake Paldang (WASP4 모형의 매개변수 추정 - 팔당호(八堂湖)를 중심으로 -)

  • Cho, Hong Yeon;Jun, Kyung Soo;Lee, Kil Seong;Han, Kwang Suk
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.13 no.4
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    • pp.177-188
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    • 1993
  • Model parameters of the WASP4 applied to Lake Paldang were estimated. The methodology is based on grouping water quality constituents and relevant parameters and successively estimating each group of parameters by a trial-and-error procedure. Chlorophyll a, nitrogen cycles, phosphorus cycles, BOD and DO were simulated at the complexity level 4. A water budget analysis using the monthly records of reservoir inflows and outflows in 1989 and 1990 was made to determine seasonally-averaged flowrates at model boundaries. Estimated flowrates were used, together with the seasonal average of water quality measurements in 1989 and 1990 for the calibration and verification, respectively, of the model. Grouping water quality constituents and associated parameters proved to be efficient in estimating a number of model parameters. From the results of model calibration and verification, it was found that quantitative evaluations of nonpoint and benthic sources of organic matters are essential. Benthic sources near the entrance of the Kyeongancheon were the most significant.

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Preparation and Properties of PVP (poly-4-vinylphenol) Gate Insulation Film For Organic Thin Film Transistor (유기박막 트랜지스터용 PVP (poly-4-vinylphenol) 게이트 절연막의 제작과 특성)

  • Baek, In-Jae;Yoo, Jae-Hyouk;Lim, Hun-Seung;Chang, Ho-Jung;Park, Hyung-Ho
    • Journal of the Microelectronics and Packaging Society
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    • v.12 no.4 s.37
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    • pp.359-363
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    • 2005
  • The organic insulation devices with MIM (metal-insulator-metal) structures as PVP gate insulation films were prepared for the application of organic thin film transistors (OTFT). The co-polymer organic insulation films were synthesized by using PVP(poly-4-vinylphenol) as solute and PGMEA (propylene glycol monomethyl ether acetate) as solvent. The cross-linked PVP insulation films were also prepared by addition of poly (melamine-co-formaldehyde) as thermal hardener. The leakage current of the cross-linked PVP films was found to be about 300 pA with low current noise. and showed better property in electrical properties as compared with the co-polymer PVP insulation films. In addition, cross-linked PVP insulation films showed better surface morphology (roughness), showing about 0.11${\~}$0.18 nF in capacitance for all PVP film samples.

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The Effects of Silica-Alumina Type Inorganic Compounds on the Pyrolysis Reaction of EVA to Produce Fuel-Oil (EVA 수지 이용 연료유 생성을 위한 열분해 반응에서 실리카-알루미나 계열 무기물의 영향)

  • Bak, Young-Cheol;Choi, Joo-Hong;Oh, Se-Hui
    • Transactions of the Korean hydrogen and new energy society
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    • v.22 no.5
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    • pp.706-713
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    • 2011
  • The effects of silica-alumina type catalysts addition on the thermal decomposition of ethylene vinyl acetate (EVA) resin have been studied in a thermal analyzer (TGA, DSC) and a small batch reactor. The silica-alumina type compounds tested were kaolinite, bentonite, perlite, activated clay and clay. As the results of TGA experiments, pyrolysis starting temperature for EVA resin had the 1st pyrolysis temperature range of 300~$400^{\circ}C$ and the 2nd pyrolysis temperature range of 425~$525^{\circ}C$. The silica-alumina type catalysts did not affect the pyrolysis rate in EVA pyrolysis reaction. In the DSC experiments, addition of kaolinite and bentonite catalysts reduced the heat of fusion and heat of 2nd pyrolysis reaction. In the batch system experiments, the mixing of silica-alumina type catalysts enhanced the yield of fuel oil, and affected to the distribution of carbon numbers. In the silica-alumina type inorganic material used in this experiments, bentonite was the most effective from the pyrolysis heat, yields, and the characteristics of fuel oil.

Effect of Silane Coupling Agent on Thermal Stability and Adhesion Properties of DGEBF Epoxy Resin (실란 커플링제에 따른 DGEBF 계열 에폭시의 열안정성 및 접착특성 평가)

  • Lee, Dong Su;Lee, Seul-Yi;Min, Byung-Gak;Seo, Young Soo;Lee, Bong Han;Park, Soo-Jin
    • Polymer(Korea)
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    • v.38 no.6
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    • pp.787-790
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    • 2014
  • In this work, the epoxy specimens were prepared from diglycidyl ether of bisphenol F (DGEBF) with silane coupling agents (3-glycidoxypropyl trimethoxysilane (GPTMS)) in different ratios. Thermal stability was studied in terms of polymer decomposition temperature (PDT), temperature of maximum rate of weight loss ($T_{max}$), integral procedural decomposition temperature (IPDT), and decomposition activation energy ($E_a$) using TGA analysis. Adhesion properties of epoxy composite specimens were measured by UTM (universal testing machine) at atmosphere temperature. In this result, the adhesion properties of DGEBF were improved by addition of silane coupling agents compared to non-treated epoxy resin. However, when the content of GPTMS agent is more than 10 phr, adhesion properties decreased with increasing GPTMS agent.

Effect of VAE Type Powder Polymer on Strength Properties of High Strength Polymer Cement Mortars (VAE 분말수지가 고강도 폴리머 시멘트 모르타르의 강도 특성에 미치는 영향)

  • Choi, Jung-Gu;Lee, Gun-Cheol;Ko, Kyung-Taek;Ryu, Gum-Sung
    • Journal of the Korea Institute of Building Construction
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    • v.15 no.3
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    • pp.299-306
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    • 2015
  • In construction materials area, many research on polymer for cement-based materials have been conducted. In spite of these research, general research scope is limited to the normal strength range, and thus in this research, for both normal and high strength range mixtures, the strength and mechanical properties of high strength cement mortar incorporating Vinyle Acetate-Ethylene(VAE) type powder polymer are evaluated. As a result of experiment, in the case of high strength mixture, as the amount of VAE polymer addition was increased the compressive and flexural strengths were decreased while the tensile and bonding strengths were increased because of the formation of the polymer membrane inside of the mortar matrix.

Qualitative Hazard Analysis for a Batch Radical Reaction Process using HAZOP Method (HAZOP 기법을 이용한 회분식 라디칼 반응 공정에 대한 정성적 위험성 평가 방법 연구)

  • Park, KyungMin;Lee, DongKyu;Lee, JoonMan;Ahn, WonSool
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.2
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    • pp.385-393
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    • 2019
  • Potential fire, explosion and safety hazards exist in medium- or small-scale chemical plants using radical batch reaction processes due to the various conditions of materials, works or products. To minimize the potential damage, a study was conducted on qualitative hazard analysis using the HAZOP technique, which is a typical method for a qualitative risk assessment and analysis of the potential risks encountered in these chemical plants. For this purpose, a domestic chemical plant, which produces the acrylic resin by a radical batch reaction process, was selected and a risk assessment and analysis according to the procedure of HAZOP method was performed for the process. As the result of the study, to prevent the hazard, the input of inert gas and the installation of a pressure gauge were indispensable. In addition, the initiator and monomer should also be separated, and inhibiting substances and equipment are also necessary to prevent a runaway reaction.

Statistical Analyses of Long-Term Water Quality Variation in the Geumgang-Reservoir: Focused on the TP Load by Migrating Birds Excrement (금강호의 장기 수질 변화요인 분석: 철새배설물에 의한 TP부하의 중요성)

  • Jeong, Yong-Hoon;Kim, Hyun-Soo;Yang, Jae-Sam
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.13 no.4
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    • pp.223-233
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    • 2010
  • Spatio-temporal variations of long-term water qualities (COD, SS, $Chl-{\alpha}$, N-related nutrients (TN, TDN, $NO_3^-$, $NH_4^+$), P-related nutrients (TP, TDP, $PO_4^{3-}$)) at two stations (St. SD, St. GG) in the Geumgang Reservoir were investigated from August 2001 to July 2008. Statistical methods such as t-test, factor analysis, and multi-regression analysis were applied to the water quality data in the reservoir as well as mass balances on TP. From the temporal comparisons of the water qualities between 2002 and 2007, average concentrations of $NH_4^+$, $PO_4^{3-}$, and TDP gradually decreased down by 60%, 24%, 52% in 2007. However, those of TP and $Chl-{\alpha}$ increased to 99% and 423% during the period. From the spatial comparisons between the two stations, St. GG showed higher concentrations for all of the N- and P-related nutrients than in St. SD, while opposite result for the $Chl-{\alpha}$. The factor analysis showed that "the seasonal variations of N- and P-related nutrients" were the two dominant factors occupying 49% of total variances of water qualities. Based on this result, multi-regression analysis executed for the two most influential parameters (TP and $Chl-{\alpha}$) focusing on the seasonal variations of these parameters: SS and $Chl-{\alpha}$ has contributed decisively to the concentrations of TP during the wet and dry season, respectively. On the other hand, COD and TP has been important for the $Chl-{\alpha}$ during the wet and dry season, respectively. From the established mass balances of TP loadings in the Geumgang Reservoir, Other Sources (60%) occupied the greatest contribution and Fluvial Input (38%) and Sediment (1%) during the wet season. However, both Fluvial Water (48%) and Other Sources (47%) supplied comparable amount of inputs and Sediment (5%) showed significantly increased input during the dry seasons. Recently especially during the dry winter seasons, migrating bird's excretion was estimated to contribute up to 8% of total TP input and 21% of Other Sources.

Pharmaceutical Characteristics of Korean Lumbricus rubellus Lumbrokinase (한국산 지렁이[Lumbricus rubellus]에서 분리한 Lumbrokinase의 약리학적 특성)

  • 조일환;이철규;임헌길;이형환
    • KSBB Journal
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    • v.19 no.4
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    • pp.274-283
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    • 2004
  • Six lumbrokinase (LK) fractions from Lumbricus rubellus lysates were purified by a series of column chromatographies. The molecular weights of the six LK fractions appeared to range from 24.6 to 33.1 kDa. In the experimental model of rat venous thrombosis, the thrombus weight and PAI activity decreased significantly when the LK was administered orally. However, the activities of APTT, PT and plasmin showed a significant increase. The aggregation of rat platelets pretreated with various LK doses was inhibited by thrombin, and the MDA generation decreased. The rat thoracic aorta and mesentric arteries contracted with phenylephrine relaxed due to the treatment of the LK fractions. These results suggest that the fibrinolytic effects of LK were mediated not only by proteolytic activity, but also by the inhibition of platelet agregation and the relaxation of blood vessels. It is concluded that the LK may be useful as a hemolytic agent for treatment of fibrin clot.

Study on Color Formation of Cheolhwa Buncheong Stoneware Glaze by Pigment Raw Materials of Iron Oxides and Firing Conditions (철산화물 안료 원료와 번조조건에 따른 철화분청사기의 유약 발색 연구)

  • Kim, Ji Hye;Han, Min Su;Jeong, Young Yu;Choi, Sung Jae
    • Journal of Conservation Science
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    • v.35 no.6
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    • pp.573-587
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    • 2019
  • In this study, reproducing specimens were made from mixing domestically produced magnetite, clay and non-plastic raw materials to reproduce the pigments used in the manufacture of traditional cheolhwa buncheong stoneware. In order to reveal the color fomation of glaze, 30 specimens with good color development were analyzed scientifically. Magnetite, which is the main raw material of the pigment, is a pigment capable of creating a dark black color in a reducing environment at 1,200℃. However, it reacts with the additionally added lime component and discolors to greenish yellow color in oxidizing environment at 1,230℃. Hematite is not significantly affected by the firing temperature and environment, but develops a dark black color when mixed with clay with iron content of more than 10%. The fluidity of the pigment is determined by R2O3/RO2 value, which also affects the color development. In the microtexture observation, the color formation of the glaze layer and the iron oxide crystals identified some differences depending on the particle size of the pigment and the firing environment. Reproduced specimens made of magnetite are present in the form of aggregates of iron oxide in the interface between glaze layer and slip layer in the oxidizing environment at 1,200℃. However, in the reducing environment, aggregates of iron oxides do not exist in the reproduced specimens, and they are homogeneously distributed in the glaze layer and formed a dark black color. In contrast, hematite-based specimens form dendritic structures in the glaze layer in an oxidizing environment and develop black.