• Korean Journal of Soil Science and Fertilizer
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• v.29 no.3
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• pp.218-225
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• 1996

Using water vapor adsorption data foe some typical Korean soils. we calculated the adsorption energy distribution functions and average adsorption energies for these soils using theory of adsorption on hetergeneous surfaces. As a local adsorption models the BET and a new Aranovich equations were applied. The distribution functions were broad, indicating rather high energetic inhomogeneity of the surface.

• Proceedings of the Korean Nuclear Society Conference
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• 1997.05b
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• pp.86-91
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• 1997

지르칼로이는 피복관으로 우수한 성질을 갖고있으나 고온에서 수증기와 발열반응을 일으켜 원자로의 안전성을 떨어뜨리는 단점을 가지고 있다. 사고시 1차 계통수에 함유된 수산화 리튬이니 붕소산은 지르칼로이에 흡착되어 산화에 영향을 줄 수 있다. 본 연구에서는 고온 수증기중의 지르칼로이 산화의 정확한 기술에 대한 연구를 수행하였으며 흡착물의 영향에 대한 실험을 수행하였다. 지르코늄 산화막이 단사정으로 존재하는 온도구간($650^{\circ}C$-105$0^{\circ}C$)에서 지르칼로이의 기존의 자료를 기반으로 계산 모형을 설정하였고 계산결과 Baker-just의 실험식은 상당히 보수적임을 알 수 있었다. 수산화리튬이 흡착된 시편은 1기압 고온 수증기중에서 산화시 푸른 간섭무늬의 막이 생성되어 산화가 억제되었다. 붕소산과 리튬의 혼합용액을 흡착한 시편은 푸른 간섭무늬의 막이 생성되지 않았으며 아무것도 흡착하지 않은 시편과 산화속도가 거의 같았다 고온 산화에서 열충격은 산화막의 균열을 발생하게 하여 산화가 가속되게 하고 지르칼로이의 기억효과를 상실케 한다.

• Journal of Energy Engineering
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• v.23 no.4
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• pp.160-168
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• 2014

In the present study, water vapor adsorption was evaluated at 298.15K for 9 different zeolites having LTA, FAU, CHA, and RHO frameworks, and then effect of framework type, Si/Al molar ratio, and alkali ion type on water up-take was investigated. Zeolites showed water up-takes which were increased in an order of $RHO<CHA{\approx}LTA<FAU$ frameworks. NaY zeolite having FAU framework showed a water up-take of 406 mg/g at p/po=0.5. The up-take was a little larger than that of 13X zeolite with the same framework. Among LTA zeolites, Ca-type 5A zeolite showed the highest water adsorption (282 mg/g at p/po=0.5) which could be explained by the large pore volume. Both CHA zeolite with a Si/Al molar ratio of 2.35 and RHO zeolite with a Si/Al molar ratio of 3.56 showed considerable water up-takes, even though the Si/Al molar ratio was much larger than that of LTA zeolite. In the present study, it is announced that in addition to FAU and LTA zeolites, CHA and RHO zeolites can be a promising dehumidification adsorbent.

• Clean Technology
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• v.12 no.4
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• pp.217-223
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• 2006

The operating variables of a desorption step were experimentally investigated tor the cycle of the process made up of benzene adsorption, steam desorption, and drying step. The effect of adsorbent regeneration depending on existence and nonexistence of drying step was studied by breakthrough curves obtained in the adsorption step of the second cycle. The duration of drying step was determined by the experimental results. In case that the amount of nitrogen gas was fixed, the regeneration efficiency increased with the amount of steam. However, the effect of steam decreased as the amount of nitrogen increased. Therefore, it would be possible to predict the optimum amount of steam comparing the amount of nitrogen gas with amount of steam in economic view.

• Journal of Korean Society of Environmental Engineers
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• v.29 no.5
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• pp.515-520
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• 2007

Recently, the treat of sludge is usually progressed by ocean disposal. But it will be totally banned by content of its heavy metal according to London Dumping Convention, gradually. The stable way of treat of sewage sludge should be examined urgently. To solve the problem, recently, there are efficient and environment-oriented method. One of them is to produce absorbent through the activation. This study produces absorbent through steam activation. As basic experiment, optimum activation condition for preparation of good absorbent is researched through study of the fellowing variables : steam flow rate, activated temperature, activation time. As the result of this with standard on iodine adsorptivity, it is chosen, that steam flow rate "30 mL/hr", activation temperature $"500^{\circ}C"$, activation time "60 minutes". At the time, iodine adsorptivity and yield shown that 228.4 mg/g, 77.23%. And also, by using nitrogen adsorption, SEM and EDS are confirmed that pore development, specific surface area, mean pore size, chemical component and content. Pore developed by steam activation is also confirmed that it is micropore.

• Korean Journal of Soil Science and Fertilizer
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• v.29 no.2
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• pp.86-91
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• 1996

Water vapor adsorption isotherms were measured for samples of the A horizons of five typical Korean soils. The experimental data were fitted to the BET and Aranovich adsorption equations. The adsorption isotherms studied followed the BET equation for the relative water vapor pressures in 0.03-0.33 range and the Aranovich equation in 0.03-0.6 range. The calculated surface areas were higher for Aranovich than for BET and opposite relations were found for adsorption energies. For the description of the water adsorption on soils, the use of the Aranovich theory is recommended.

• Applied Chemistry for Engineering
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• v.17 no.2
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• pp.201-209
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• 2006

Various desorption methods were investigated for an activated carbon and zeolite 13X packed bed after benzene adsorption. Desorption experiments using hot steam, purge gas, and evacuation were performed. As a result, the desorption with hot steam showed the best performance. Hot steam makes the temperature in the adsorption column increase and gives arise to the desorption. Drying process should be accompanied to increase the efficiency because steam vapor prevents the adsorption later. The vacuum desorption showed poor performance and it reveals that temperature swing operation is more effective than pressure swing operation. In the purge gas desorption, good performance was achieved using evacuation.

• Proceedings of the Optical Society of Korea Conference
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• 2003.07a
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• pp.176-177
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• 2003

진공 환경 및 가스에 함유된 미량의 수증기를 정량적으로 분석할 수 있는 계측기는 각종 산업 분야에서 그 필요성이 절실하다. 몇 가지 예를 들면 다음과 같다. 전구 속에 함유된 수증기로 인해 야기되는 텅스텐 필라멘트의 산화현상은 전구의 수명을 현저히 감소시킨다. 밀봉된 금속 전기소자 표면에 흡착된 수증기를 통해 누전 현상이 발생함으로써 소자가 비정상적으로 동작될 우려가 있다. 반도체 산업분야에서는 1 ppb의 수증기가 64 Mb DRAM 제조에 영향을 줄 수 있다는 것이 보고된 바 있다. (중략)

• Applied Chemistry for Engineering
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• v.19 no.4
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• pp.439-444
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• 2008

The oyster shell adsorbents were prepared by steam activation method to evaluate their adsorption characteristics. Washed and pulverized waste oyster shells were prepared by steam activated process in converter at the temperature range of about $700{\sim}800^{\circ}C$ after carbonized at the range of $600{\sim}1000^{\circ}C$. The shell carbonized at $1000^{\circ}C$ showed the best performance among those of other temperature ranges. Also, comparison between gas and liquid phase adsorption was performed to verify adsorbent possibility of waste shell. In case of gas phase, the adsorbent showed lower performance than existing commercial adsorbents. On the other hand, the liquid phase, they showed similar adsorption performance to commercial adsorbents when benzene was used.

• The Journal of Natural Sciences
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• v.8 no.1
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• pp.81-85
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• 1995

This experiment was conducted to develop ethylene adsorbents for removing the ethylene produced from fruit during storage. The effect of ethylene adsorbent on the removing ethylene was the highest when $ICI_3$and $KBrO_3$ were used as the base of reactant and $H_2SO_4$ auxiliary reagent of reactant. It was decreased under the saturated water vapor condition and was sligthly decreased under the high carbon dioxide condition.