• Journal of the Korea Concrete Institute
• /
• v.24 no.5
• /
• pp.605-612
• /
• 2012

Spalling of concrete occurs due to vapor pressure ignited explosion, temperature difference across a section, and combination of these factors. Factors affecting spalling can be classified into internal and external factors such as material property and environmental condition, respectively, have to be considered to precisely understand spalling behavior. An external environmental factor such as differences in heating rate cause internal humidity cohesion and different vapor pressure behavior. Therefore, spalling property, vapor pressure and thermal strain property were measured from concrete with compressive strengths of 30 MPa, 50 MPa, 70 MPa, 90 MPa, and 110 MPa, applied with ISO-834 standard heating curve of $1^{\circ}C/min$ heating rate. The experimental results showed that spalling occurred when rapid heating condition was applied. Also, when concrete strength was higher, the more cross section loss from spalling occurred. Also, spalling property is influenced by first pressure cancellation effect of thermal expansion caused by vapor pressure and heating rates.

• Resources Recycling
• /
• v.18 no.2
• /
• pp.51-55
• /
• 2009

Sawdust and sewage sludge and PE gasification by high temperature steam of Brown gas have been performed in this study. Steam/carbon ratio has been changed from 1 to 5 and the effect of steam/carbon ratio on the produced gas concentrations, gasification rate and tar generation has been determined. Also, the temperature distribution in the gasification reactor has been studied. Highest combustible content in the produced gas is around 70vol% and $H_2$ shows highest content among the combustible compounds. However, the heating value of the produced gas and tar content have been reduced with increasing steam/carbon ratio.

• Korean Chemical Engineering Research
• /
• v.47 no.2
• /
• pp.243-247
• /
• 2009

This study is purposed to analyze thermodynamic properties on the hydrogen production by ethylene glycol steam reforming. Various reaction conditions of temperatures(300~1,600 K), feed compositions(steam/carbon= 0.5~4.5), and pressures(1~30 atm) were applied to investigate the effects of the reaction conditions on the thermodynamic properties of dimethyl ether steam reforming. An endothermic steam reforming competed with an exothermic water gas shift reaction and an exothermic methanation within the applied reaction condition. Hydrogen production was initiated at the temperature of 400 K and the production rate was promoted at temperatures exceeding 500 K. An increase of steam to carbon ratio(S/C) in feed mixture over 1.0 resulted in the increase of the water gas shift reaction, which lowered the formation of carbon monoxide. The maximum hydrogen yield with minimizing loss of thermodynamic conversion efficiency was achieved at the reaction conditions of a temperature of 900 K and a steam to carbon ratio of 3.0.

• Korean Journal of Remote Sensing
• /
• v.32 no.3
• /
• pp.331-337
• /
• 2016

Water vapor is main absorption factor of outgoing longwave radiation. So, it is essential to monitoring the changes in the amount of water vapor and to understanding the causes of such changes. In this study, we monitor temporal variability of Total Precipitable Water (TPW) which observed by satellite. Among climate variables, precipitation play an important part to analyze temporal variability of water vapor because it is produced by water vapor. And El $Ni{\tilde{n}}o$ is one of climate variables which appear regularly in comparison with the others. Through them, we analyze relationship between temporal variability of TPW and climate variable. In this study, we analyzed long-term change of TPW from Moderate-Resolution Imaging Spectroadiometer (MODIS) data and change of precipitation in middle area of Korea peninsula quantitatively. After these analysis, we compared relation of TPW and precipitation with El $Ni{\tilde{n}}o$. The aim of study is to research El $Ni{\tilde{n}}o$ has an impact on TPW and precipitation change in middle area of Korea peninsula. First of all, we calculated TPW and precipitation from time series analysis quantitatively, and anomaly analysis is performed to analyze their correlation. As a result, TPW and precipitation has correlation mostly but the part had inverse correlation was found. This was compared with El $Ni{\tilde{n}}o$ of anomaly results. As a result, TPW and precipitation had inverse correlation after El $Ni{\tilde{n}}o$ occurred. It was found that El $Ni{\tilde{n}}o$ have a decisive effect on change of TPW and precipitation.

• Korean Journal of Food Science and Technology
• /
• v.28 no.5
• /
• pp.827-833
• /
• 1996

Along with the increased necessity for an efficient utilization of Korean wild edible plants growing in fields and mountains, attempts were made to investigate the patterns of flavor changes accompanied hy various conditions of dispersion medium. The effect of various pH values and concentration of sucrose or NaCl of dispersion medium on volatile flavor patterns was investigated to evaluate the applicability of flavor components extracted from Capsella bursa-pastoris for food industry. Essential oils from this wild plant were isolated by simultaneous steam distillation-extraction (SDE) method using diethyl ether as solvent. Concentrated samples were analyzed s chromatography (GC) and combined gas chromatography-mass spectrometry (GC-MS). Most volatile flavor components of Capsella bursa-pastoris showed good recovery when steam distilled at pH 7 by SDE method. Increasing concentration of sucrose and 15% by NaCl, resulted in greater numbers of identified flavor components from Capsella bursa-pastoris.

• Clean Technology
• /
• v.29 no.3
• /
• pp.163-171
• /
• 2023

Hydrogen has been gaining a lot of attention as a possible clean energy source that can aid in reaching carbon neutrality. Currently, hydrogen production has relied on the steam reforming of fossil fuels. However, due to the carbon dioxide emissions caused by this process, hydrogen production based on the steam reforming of bio-oil derived from biomass has been proposed as an alternative approach. In order to use this alternative approach efficiently, one of the key issues that must be overcome is that the complexity of bio-oil, which has a large molecular weight and diverse functional groups of hydrocarbons, promotes the catalytic deactivation of nickel-based catalysts. In this review, research efforts to improve nickel-based catalysts for the steam reforming of bio-oil have been discussed in terms of the active phase, support, and promoters. The active phases are involved in activating C-C and C-H bonds of high-molecular-weight hydrocarbons, and noble and transition metals can be utilized. In terms of the support and promoters, the catalytic deactivation of Ni-based catalysts can be inhibited by utilizing reactive lattice oxygen for support or by suppressing the acidity. The development of active and stable Ni-based reforming catalysts plays a critical role in clean hydrogen production based on bio-oils.

• Journal of Korean Society of Environmental Engineers
• /
• v.30 no.12
• /
• pp.1268-1272
• /
• 2008

Low temperature plasma applied with partial oxidation is a technique to produce synthesis gas from methane. Low temperature plasma reformer has superior miniaturization and start-up characteristics to reformers using steam reforming or CO$_2$ reforming. In this research, a low temperature plasma reformer using GlidArc discharge was proposed. Reforming characteristics for each of the following variables were studied: gas components ratio (O$_2$/CH$_4$), the amount of steam, comparison of reaction on nickle and iron catalysts and the amount of CO$_2$. The optimum conditions for hydrogen production from methane was found. The maximum Hydrogen concentration of 41.1% was obtained under the following in this condition: O$_2$/C ratio of 0.64, total gas flow of 14.2 L/min, catalyst reactor temperature of 672$^{\circ}C$, the amount of steam was 0.8, reformer energy density of 1.1 kJ/L with Ni catalyst in the catalyst reactor. At this point, the methane conversion rate, hydrogen selectivity and reformer thermal efficiency were 66%, 93% and 35.2%, respectively.

• Korean Journal of Remote Sensing
• /
• v.35 no.6_3
• /
• pp.1299-1312
• /
• 2019

As land remote sensing applications are expanding to the extraction of quantitative information, the importance of atmospheric correction is increasing. Considering the difficulty of atmospheric correction for land images, it should be applied when it is necessary. The quantitative information extraction and time-series analysis on biophysical variables in land surfaces are two major applications that need atmospheric correction. Atmospheric aerosol content and column water vapor, which are very dynamic in spatial and temporal domain, are the most influential elements and obstacles in retrieving accurate surface reflectance. It is difficult to obtain aerosol and water vapor data that have suitable spatio-temporal scale for high- and medium-resolution multispectral imagery. Selection of atmospheric correction method should be based on the availability of appropriate aerosol and water vapor data. Most atmospheric correction of land imagery assumes the Lambertian surface, which is not the case for most natural surfaces. Further BRDF correction should be considered to remove or reduce the anisotropic effects caused by different sun and viewing angles. The atmospheric correction methods of optical imagery over land will be enhanced to meet the need of quantitative remote sensing. Further, imaging sensor system may include pertinent spectral bands that can help to extract atmospheric data simultaneously.

• Journal of the Korean earth science society
• /
• v.35 no.7
• /
• pp.537-542
• /
• 2014

The Gravity Recovery and Climate Experiment (GRACE) has observed the Earth's mass redistribution mainly caused by the variations of groundwater, ice sheet, and sea level since its launch in April 2002. The global gravity model estimated by the GRACE observation is corrected by barometric pressure, and thus represents the change of Earth mass on the Earth's surface and below Earth's surface excluding air mass. However, the total air mass varies due to the water exchange between the Earth's surface and the atmosphere. As a result, the nominal GRACE gravity model should include the Earth's gravity spectrum associated with the total air mass variations, degree 0 and order 0 coefficients of spherical harmonics ($C_{00}$). Because the water vapor content varies mainly on a seasonal time scale, a change of $C_{00}$ (${\delta}C_{00}$) is particularly important to seasonal variations of sea level, and mass balance between northern and southern hemisphere. This result implies that ${\delta}C_{00}$ coefficients should be accounted for the examination of continental scale mass change possibly associated with the climate variations.

• 한국신재생에너지학회:학술대회논문집
• /
• 2005.06a
• /
• pp.256-259
• /
• 2005

본 연구에서는 기존 니켈 활성성분만의 알루미나담지 촉매에 비해 고온에서의 수소를 사용한 환원 전처리 과정을 거치지 않고도 높은 반응활성을 나타내며, 반응 중 탄소침적에 대한 촉매 저항성에서도 우수한 결과를 나타낸 루테늄-니켈 촉매에 대해보고 하고자 한다. 메탄 수증기 개질 반응을 통해, 루테늄을 최종적으로 담지한 알루미나 담지니켈계 촉매는 별도의 전처리과정 없이 $650^{\circ}C$에서부터 높은 반응성을 보였으며, 루테늄과 니켈을 동시에 담지한 경우보다 더 우수한 활성을 나타내었다. Ru의 담지량을 달리한 실험에서는$RU(0.5)/Ni(20)/Al_2O_3$ 촉매가 가장 높은 활성을 보였다. $H_2-TPR$ 분석 결과, $Ru(0.5)/Ni(20)/A1_2O_3$촉매의 경우 세 가지 환원 피크가 나타났으며, $Ni(20)/A1_2O_3$촉매와 비교해 볼 때, 저온(<$130^{\circ}C)$에서 환원가능한 $RUO_2$의 존재를 확인할 수 있었다. 담지된 RU은 분산도가 높아, XRD분석 결과에서 Ru이나 $RuO_2$의 특성 피크가 존재하지 않았다. 또한 $650^{\circ}C$에서 10시간 개질반응 후 얻어진 촉매에 대해 $O_2-TGA$를 분석한 결과, $Ni(20)/Al_2O_3$촉매는 $-7.2wt\%$ 정도의 큰 무게 감소를 보였으며, 이는 촉매 표면에 생성된 carbon tube에 의한 것임을 SEM 분석을 통해 알 수 있었다 이에 반해, $Ru(0.5)/Ni(20)/Al_2O_$ 촉매는 $O_2-TGA$시 $0.3wt\%$ 정도 무게 증가에 그쳤으며, SEM 분석상 carbon tube의 생성이 크게 억제되었음을 알 수 있었다.