• Title/Summary/Keyword: 수소 발생기

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A Study on the Process Improvement of RJ-4 fuel Preparation using a Heteropoly Acid Catalyst (Heteropoly acid촉매를 이용한 RJ-4연료의 제조공정 개선연구)

  • Jeong Byung-Hun;Han Jeong-Sik;Choi Chang-Sun;Hong Myung-Pyo
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2005.11a
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    • pp.229-232
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    • 2005
  • The study on the improvement of manufacturing process of RJ-4 liquid fuel that have high flash point, was carried out. In preparing of RJ-4 using commercially available MCPD, 1st, 2nd hydrogenation and isomerization reaction were enabled 1 step continuous process by combined use of heteropoly phosphoroustungstic cesium salt catalyst and 2nd stage-heat-controllable reactor. Also when heteropolyacid cesium salt was used as a isomerization catalyst instead of aluminum chloride, formation rate of exe-THDMCPD was higher, the catalyst could be easily separable from product and there was no production of waste acid, so this new reaction condition was confirmed as the environment friendly process.

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Study of Separation of carbon dioxide through hollow fiber membrane contactor (중공사막 접촉장치를 통한 이산화탄소 분리에 관한 연구)

  • 염봉열;김민수;이용택;박유인;이규호
    • Proceedings of the Membrane Society of Korea Conference
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    • 1997.10a
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    • pp.61-64
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    • 1997
  • 1. 서론 : 적절한 이산화탄소의 분리는 지구온난화의 가속현상을 늦출 수 있을 뿐만 아니라 각종 탄화수소가스의 원료로 분리 정제된 이산화탄소를 재이용할 수 있으므로 경제적으로 매우 중요하다. 이산화탄소 분리에 사용되던 기존 공정들의 단점을 보완할 수 있는 대체방안으로 최근에 개발되기 시작한 것이 소수성의 다공성 고분자 분리막(hydrophobic porous ploymeric membrane) 방법인데, 이는 모듈의 유효 막 표면적이 상대적으로 크고 기체와 액체의 흐름을 독립적으로 제어할 수 있으므로 범람 등의 현상이 없으나 막 자체의 저항이 비교적 큰 단점을 가지고 있다. Qi와 Cussler는 이러한 특성을 가지는 중공사막 모듈에서의 기-액 흐름에 대한 물질전달 상관관계식을 얻었으며[1], Karoor 등은 여러 가지 중공사막 모듈을 사용하여 순수물과 diethanolamine(DEA) 등의 흡수제에 대한 이산화탄소의 물질전달 거동을 수치모델과 실험을 통하여 고찰하였다[3]. 또한 중공사막 접촉기의 실제적 응용에 대하여 Matsumoto 등은 화력발전소에서 발생하는 연소가스 내의 이산화탄소 흠수에 대한 연구를 수행하였다[4]. 본 연구에서는 중공사막 접촉장치를 사용하여 흡수제를 순수물과 탄산칼륨($K_2CO_3$)을 사용했을 경우의 이산화탄소의 분리 거동을 수치모델과 실험을 통하여 고찰하였다. 수치모델의 경우 이전까지의 연구가 반응이 없는 경우나 반응식을 간략화시킨 경우에 한정되었는데 비하여, 반으이 있는 경우 각각의 반응물질들의 거동을 고려한 반응식을 유도하여 해를 구하고자 하녔다.

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An Experimental Study of Shock Wave Effects on the Model Scramjet Combustor (모델 스크램제트 연소기에서 충격파 영향에 대한 실험적 연구)

  • 허환일
    • Journal of the Korean Society of Propulsion Engineers
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    • v.3 no.1
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    • pp.65-71
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    • 1999
  • An experimental study was carried out in order to investigate the effect of shock waves on the supersonic hydrogen-air jet flames stabilized in the Mach 2.5 model scramjet combustor. This experiment was the first reacting flow experiment interacting with shock waves. Two identical $10^{\cire}$ wedges were mounted on the diverging sidewalls of the combustor in order to produce oblique shock waves that interacted with the flame. Schlieren visualization pictures, wall static pressures, and combustion efficiency at two different air stagnation temperatures were measured and compared to corresponding flames without shock wave-flame interaction. It was observed that shock waves significantly altered the shape of supersonic jet flames, but had different effects on combustion efficiency depending on air temperatures. At the higher air stagnation temperature and higher fuel flow rates, combustion of efficiency showed a better result.

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Combustion Characteristics of Hypersonic SCRamjet Engine (극초음속 스크램제트 엔진의 연소특성)

  • 원수희;정은주;정인석;최정열
    • Journal of the Korean Society of Propulsion Engineers
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    • v.8 no.1
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    • pp.61-69
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    • 2004
  • This paper describes numerical efforts to characterize the flame-holding and air-fuel mixing process of model SCRamjet engine combustor, where a hydrogen jet injected into a supersonic cross flow and in a cavity Combustion phenomena in a model SCRamjet engine, which has been experimentally studied at University of Queensland and Australian National University using a free-piston shock tunnel, was observed around separation region of upstream of the normal injector and inside of cavity. The results show that the separation region and cavity generates several recirculation zones, which increase the fuel-air mixing. Self ignition occurs in the separation-freestream and cavity-freestream interface.

Noise Generation by Water-Sodium Reaction and its Absorption on Hydrogen Bubbles for KALIMER Steam Generator (칼리머 증기발생기에서 물-소듐 반응에 의한 소음 발생과 수소 기포의 소음 흡수)

  • Kim, Tae-Joon;Yughay, Valeri S.;Hwang, Sung-Tai
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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    • 2000.06a
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    • pp.1829-1835
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    • 2000
  • The experimental results of sodium-water reaction noise measurement in frequency range $1{/sim}200kHz$ are presented. The experiments of noise generation under the condition of sodium test facility, water leak rate $0.01{\sim}1.2g/s$ and temperature of sodium $250{\sim}500^{\circ}C$, were carried out. From theoretical study it is noted that the noise resonant attenuation on hydrogen bubbles in liquid sodium plays the significant role for leak noise spectra formation. Interaction of leak noise and hydrogen bubbles in sodium being accompanied by thermal, emission and viscosity energy dissipation was studied. Acoustic noise spectra were investigated from point of view of water leak detection in sodium/water steam generator. The results of sodium-water reaction noise absorption on hydrogen bubbles in liquid sodium by temperature $250{\sim}500^{\circ}C$ are presented. The theoretical model of noise absorption using the coefficients of attenuation was developed. From calculation the coefficients of attenuation were estimated.

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Sediment Oxygen Consumption Rate and Hydrogen Sulfide Release by Dissolved Oxygen Depletion in Hypoxic Area of the Gamak Bay, Korea (가막만 빈산소 해역의 퇴적물 산소소모율과 용존산소 고갈에 의한 황화수소 용출)

  • Lee, Taehee
    • Journal of Wetlands Research
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    • v.17 no.3
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    • pp.293-302
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    • 2015
  • This study investigated sediment oxygen consumption rates and geochemical characteristics of sediment in hypoxic area of the Gamak Bay based on the chamber experiments and geochemical analyses. The organic carbon contents of surface sediment in the Gamak Bay showed that the inner bay area has higher organic carbon content than those of the outer bay. They toward the outer bay, contents dropped off. The vertical profiles of calcium carbonate ($CaCO_3$) content at piston core sediment assumed that the hypoxia have been frequently occurred during past century in the northern inner bay. The benthic chamber experiments were conducted in February, May, August and November 2010, 2011 in the hypoxic area of the Gamak Bay. In the sediment incubation experiment with chamber at site C3 in the northern inner bay and site C17 in the southern outer bay, the sediment oxygen consumption rate ranged from $3.98mmol\;m^{-2}d^{-1}$ to $12.43mmol\;m^{-2}d^{-1}$ and $3.28mmol\;m^{-2}d^{-1}$ to $8.18mmol\;m^{-2}d^{-1}$, respectively. When the oxygen was completely depleted, the toxic hydrogen sulfide was released with $1.38mmol\;m^{-2}d^{-1}$ and $1.3mmol\;m^{-2}d^{-1}$, respectively.

Study on the Feasibility of Utilization of Pine Cone Byproduct as a Natural Deodorizing Agent for Composting Process (퇴비화 시설용 천연 악취저감제로의 잣송이 부산물의 활용 가능성에 관한 연구)

  • Chun, H.S.;Kwag, J.YH.;Ga, C.H.;Park, J.I.;Kim, C.H.;Ra, C.S.
    • Journal of Animal Environmental Science
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    • v.13 no.2
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    • pp.129-138
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    • 2007
  • A natural deodorizing agent (NDA) was made using pine cone byproduct, and its effects on malodor emission and composting were analyzed in this study. NDA was manufactured by mixing pine cone byproduct with three species of microorganisms and water containing mineral nutrients and molasses, and then by incubating for 48 hours at $30^{\circ}C$. Lab scale experiments were done with three treatment groups, T1 (control, sawdust treatment), T2 (microorganisms and sawdust treatment group), and T3 (NDA and sawdust treatment group). During composting, temperatures reached over $55^{\circ}C$, a minimum temperature for the inactivation of pathogenic microorganisms. No differences were found in physicochemical composition of compost among treatments. However, it was observed that over usage of NDA could obstruct temperature increase, since the biodegradation rate of organic matter of NDA was relatively low, Nitrogen loss due to ammonia gas emission, which normally happens during composting, was reduced by using NDA, and hence the nitrogen level of final compost was higher in T3 than in others. During experiment, it was found that ammonia gas emission was entirely lasted through compositing duration, but the $CH_3SH$ and $H_2S$ gases were produced only at early stage of composting. The ammonia concentration trapped in $H_2SO_4$ solution during 31 days of composting in T1, T2 and T3 was 12,660mg/L, 11,598mg/L and 7,367mg/L, respectively, showing distinguishable reduction of ammonia gas emission in T3. The emissions of $CH_3SH$ and $H_2S$ gases were also remarkably reduced in T3. Based on these obtained results, usage of the deodorizing agent made with pine cone byproduct could reduce the emission of malodor during composting, without any deterioration of compost quality.

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Hydrogenated and annealed effect of CdTe:In

  • ;Yuldashev
    • Proceedings of the Korean Vacuum Society Conference
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    • 1999.07a
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    • pp.96-96
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    • 1999
  • CdTe는 일반적으로 광전 소자나 Xtjs 및 λ선 감지 소자로서 많은 연구가 되어지고 있는 물질이다. 특히 적외선 감지 소자로 쓰이고 있는 HgCdTe 물질의 기판으로서도 많은 연구가 진행되고 있다. 이러한 여러 가지 목적으로 사용함에 있어서 CdTe 내에 가지고 있는 여러 가지 불순물에 의한 영향으로 각종 결함밴드들이 형성됨으로서 소자로서의 응용에 많은 지장을 주고 있다. 이러한 이유로 여러 가지 방법으로 불순물 및 결합에 의한 준위에 관한 연구들이 진행되고 있다. 본 실험에서는 MBE 법으로 성장된 In 도핑된 CdTe 박막의 광학적 성질을 관찰하기 위하여 수소화 및 열처리를 하여 PL 법을 이용하여 관찰하여 보앗다. 열처리는 Cd 분위기의 50$0^{\circ}C$에서 5시간 동안 수행하였으며 수소화는 rf plasma 장치를 이용하여 8$0^{\circ}C$에서 50mW/c2의 출력으로 1시간동안 수행하여 주었다. 열처리한 시료의 경우 PL 신호는 갓 성장한 시료와 비교하여 깊은 준위에 관련된 신호들만 변화가 있었을뿐 그리 큰 변화가 있지는 않았다. 그러나 수소화시킨 시료의 경우 전체적으로 피크의 크기가 5배정도 감소하는 것을 볼 수 있었는데 이것은 수소에 의하여 passivation된 효과로 볼 수 있다. 정량적인 passivation 효과를 보기 위하여 온도의존성 PL 측정을 하여 보았다. 측정에서 관측된 (D,h) emission lines의 FWHM을 비교하여 본 결과 FWHM 온도가 증가함에 따라 선형적으로 증가하는 것이 아니라 급격한 증가를 q이는 구간을 관착할 수 있었다. 이것은 CdTe내에 존재하는 전하를 띠고 있는 주게와 받게의 결합의 결과로 나타나는 현상으로 보여진다. 이러한 결과를 통하여 얕은 준위에 있는 주게 불순물의 농도를 계산해 보았고 Hall 측정을 얻은 결과와 비교하여 보았다.판단된다. 따라서 이 기술은 기존의 광소자 제작을 위한 IFVD 방법의 문제점을 해결할 뿐만 아니라 결정 재성장 없이 도일한 기판상에 국부적으로 상이한 bandgap 영역을 만들 수 있기 때문에 광소자 제작에 적극 이용될 수 있다.나지 않았으며 BST 박막에서는 약 1.2V의 C-V이력현상이 보였다.를 이용하였으며, 이온주입후 열처리 온도에 따른 활성화 정도의 관찰을 위하여 4-point probe와 Hall measurement를 이용하였다. 증착된 다결정 SiGe의 두게를 nanospec과 SEM으로 분석한 결과 Gem이 함량이 적을 때는 높은 온도에서의 증착이 더 빠른 증착속도를 나타내었지만, Ge의 함량이 30% 되었을 때는 온도에 관계없이 일정한 것으로 나타났다. XRD 분석을 한 결과 Peak의 위치가 순수한 Si과 순수한 Ge 사이에 존재하는 것으로 나타났으며, ge 함량이 많아짐에 따라 순수한 Ge쪽으로 옮겨가는 경향을 보였다. SEM, ASFM으로 증착한 다결정 SiGe의 morphology 관찰결과 Ge 함량이 높은 박막의 입계가 다결정 Si의 입계에 비해 훨씬 큰 것으로 나타났으며 근 값도 증가하는 것으로 나타났다. 포유동물 세포에 유전자 발현벡터로써 사용할 수 있음으로 post-genomics시대에 다양한 종류의 단백질 기능연구에 맡은 도움이 되리라 기대한다.다양한 기능을 가진 신소재 제조에 있다. 또한 경제적인 측면에서도 고부가 가치의 제품 개발에 따른 새로운 수요 창출과 수익률 향상, 기존의 기능성 안료를 나노(nano)화하여 나노 입자를 제조, 기존의 기능성 안료에 대한 비용 절감 효과등을 유도 할 수 있다. 역시 기술적인 측면에서도 특수소재 개발에 있어 최적의 나노 입자 제어기술 개발 및 나노입자를 기능성 소재로 사용하여 새로운 제품의 제조와 고압 기상 분사기술의 최적화에 의한 기능성 나노 입자 제조 기술을 확립하고 2차 오염 발생원인 유

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Effects of Seeding Dates on Lodging in Water Seeding of Rice (벼 담수표면 직파재배에서 파종기가 도복에 미치는 영향)

  • 송동석;김용재;이성춘
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.41 no.2
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    • pp.157-167
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    • 1996
  • The method of direct seeding on flooded paddy surface in rice is known to be the most labor saving cultural practice in rice. However, this method has a problem in practical use such as severe lodging occurring at the reproductive growth stage. The objectives of this study were observated degree of field lodging and variation of lodging-related characteristics with different seeding dates. The number of seedlings per m$^2$ were from 91 to 144 plants, and seedling ratios were from ranged from 61.7% to 91.8%. Days from seeding to flowering were shortened from 5 to 15 days by the later seeding dates. Heading dates of Ilpumbyeo, Seoanbyeo, Daecheongbyeo and Donjinbyeo on June 9 showed slightly elapsed on the critical stable heading time from, August 28 to 29. The culm length was effective in longer clum varieties than semidwarf varieties. The degree field lodging (degree of lodging: 0~9< 9 : complete lodging) in Obongbyeo and S101 with semidwarf varieties were 0.17, whereas 1.25 in Dongjinbyeo with long culm. The lodging resistant varieties and later seeding dates shortened the length of fibrous in the clum, and thickened fibrous in the clum, respectively. Obongbyeo and Sl0l showed stronger resistance to field lodging. The lodging resistant varieties, Obongbyeo and Sl0l, showed lower values of lodging index from 1.03 to 1.15 than those of lodging susceptible varieties, Daecheongbyeo and Palgongbyeo ranged from 1.42 to 1.70. Bending moment with leaf sheath were greater in lodging resistant varieties (Obongbyeo and Sl0l),1510.0~1930.4g.cm, than those in the lodging susceptible varieties (Daecheongbyeo and Palgongbyeo), 1127.2~1287.6g.cm.

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Performance Analysis of Methane Fueled Marine Solid Oxide Fuel Cell and Steam Turbine Hybrid Power System (선박동력용 SOFC/ST 하이브리드시스템의 성능 평가)

  • Lee, Kyung-Jin;Oh, Jin-Suk;Kim, Sun-Hee;Oh, Sae-Gin;Lim, Tae-Woo;Kim, Jong-Su;Park, Sang-Kyun;Kim, Mann-Eung;Kim, Myoung-Hwan
    • Journal of Advanced Marine Engineering and Technology
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    • v.35 no.5
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    • pp.590-599
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    • 2011
  • The electrification of the waste heat of fuel cell is necessary to enhance the efficiency of fuel cell system. For this purpose, the SOFC/ST(Solid oxide fuel cell/Steam turbine) hybrid system is suitable. The purpose of this work is to predict the performance of methane fueled SOFC/ST hybrid power system and to analyze the influence of operating temperature of stack, current density of stack, combustor outlet gas temperature, and boiler outlet gas temperature. According to the analysis, it is proved that making the best use of the waste heat of stack and minimizing the fuel consumption of combustor are essential for the high-efficiency of SOFC/ST hybrid system.