• Journal of the Korean Institute of Gas
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• v.26 no.6
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• pp.65-75
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• 2022

Recently, the possibility of fire and explosion due to hydrogen leakage and the resulting risk are increasing since the operating pressure of the electrolysis increases. This study performed the hazardous area classification in accordance with KS C IEC 60079-10-1 and KGS GC101 in consideration of the general operating conditions of the electrolysis. In addition, in order to achieve a To Non-hazardous, an appropriate ventilation rate was estimated to maintain a concentration of less than 25 % of the lower explosive limit. As a result, it was reviewed that the electrolysis is classified as an hazardous area when only natural ventilation is applied, and a huge amount of ventilation is required to classify it as a non-hazardous area.

• Tuberculosis and Respiratory Diseases
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• v.63 no.6
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• pp.497-506
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• 2007

Background: The present investigation was performed in rats and isolated human neutrophils in order to confirm the presumptive role of the positive feedback loop of cytosolic phospholipase $A_2$ ($cPLA_2$) activation by plateletactivating factor (PAF). Methods: The possible formation of the positive feedback loop of the $cPLA_2$ activation and neutrophilic respiratory burst was investigated in vivo and in vitro by measurement of the parameters denoting acute lung injury. In addition, morphological examinations and electron microscopic cytochemistry were performed for the detection of free radicals in the lung. Results: Five hours after intratracheal instillation of PAF ($5{\mu}g/rat$), the lung leak index, lung myeloperoxidase (MPO) activity, the number of neutrophils and the concentration of cytokine-induced neutrophil chemoattractant (CINC) in bronchoalveolar lavage fluid were increased by PAF as compared with those of control rats. The NBT assay and cytochrome-c reduction assay revealed an increased neutrophilic respiratory burst in isolated human neutrophils following exposure to PAF. Lung and neutrophilic $cPLA_2$ activity were increased following PAF exposure and exposure to hydrogen peroxide increased $cPLA_2$ activity in the lung. Histologically, inflammatory findings of the lung were observed after PAF treatment. Remarkably, as determined by $CeCl_3$ cytochemical electron microscopy, increased production of hydrogen peroxide was identified in the lung after PAF treatment. Conclusion: PAF mediates acute oxidative lung injury by the activation of $cPLA_2$, which may provoke the generation of free radicals in neutrophils.

• Journal of Environmental Impact Assessment
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• v.26 no.4
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• pp.242-256
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• 2017

In this paper, dispersion scenarios concerning various meteorological conditions and real urban structures were made to estimate the impacts of hazardous substance leakage accidents and to reduce damages. Based on the scenario of the hazardous substance dispersion, the characteristics of the risk in the pedestrian environment were analyzed in Gangnam, Seoul. The scenarios are composed of 48 cases according to the meteorological conditions of wind direction and wind speed. In order to analyze the dispersion characteristics of the hazardous substances, simulations were conducted using a computational fluid dynamic (CFD) model with hydrogen fluoride releases. The validation for the simulated wind was conducted at a specific period, and all the calculated verification indices were within the valid range. As a result of simulated dispersion field at pedestrian level, it was found that the dispersion pattern was influenced by the flow, which was affected by the artificial obstacles. Also, in the case of the weakest wind speed of the inflow, the dispersion of the hazardous substance appeared in the direction of the windward side at the pedestrian level due to the reverse flow occurred at lower layers. Through this study, it can be seen that the artificial structures forming the city have a major impact on the flow formed in urban areas. The proposed approach can be used to simulate the dispersion of the hazardous substances and to assess the risk to pedestrians in the industrial complexes dealing with actual hazardous substances in the future.

• Korean Chemical Engineering Research
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• v.55 no.1
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• pp.48-53
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• 2017

Since the number and the amount of toxic substances handled by domestic companies have been increased, the possibility of serious chemical accidents has become severe. According to Chemistry Safety Clearing-house (CSC), the number of chemical accidents for the last five years has been rapidly raised. A representative example which shows the serious impact of a chemical accident is HF (Hydrogen Fluoride) accident generated in Gumi in 2012. In order to make effective responses for mitigating losses of accidents, the most suitable consequence model has to be selected and implemented throughout the considerations of chemical properties and environments. Even if each consequence model has been verified by the results of experiments, it is necessary to analyze and compare the usability of them according to various scenarios. In this study, the Gumi HF accident is simulated by HGSYSTEM, which is the most specialized model for the release and dispersion of HF. It is found that the ending point of ERPG-2 is about 1 km from the accident point. In order to investigate the usability of the most representative consequence models (ALOHA and CARIS), the results of them are compared with one of HGSYSTEM.

• Fire Science and Engineering
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• v.32 no.6
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• pp.84-90
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• 2018

Chemical accidents occur in various forms, such as explosions, leaks, spills, and fires. In particular, chemical accidents caused by fires seriously affect the surrounding air environment due to soot, causing anxiety to the residents. Therefore, it is important to identify the causative substances quickly and examine the influence of air quality in the surrounding area. In this paper, proton transfer reaction-time of flight mass spectrometry(PTR-ToFMS) was used to identify the causative material in a fire and monitor the air quality in real time. This analyzer is capable of real-time analysis with a rapid response time without sample collection and pretreatment. In addition, it is suitable for quantitative and qualitative analysis of most volatile organic compounds with high hydrogen affinity, to identify the cause of fire and examine the influence of ambient air. In April 2018, when a local fire occurred, methanol, acetone, and methyl ethyl ketone were the main causative agents in PTR-ToFMS.

• Korean Journal of Remote Sensing
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• v.38 no.6_3
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• pp.1817-1826
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• 2022

After the hydrogen fluoride leak in Gumi in 2012, the government has been systemizing the disaster management system, such as responding to and managing chemical accidents. In particular, the Ministry of the Interior and Safety (MOIS) is in charge of evacuation of residents following chemical accidents based on the Framework Act on Management of Disaster and Safety. In this study, an application plan was presented to support and utilize the decision-making support for evacuation of residents after a chemical accident using the chemical accident investigation equipment of the National Disaster Management Research Institute (NDMI). In the equipment operation system for scientific information collection due to chemical accidents, the roles and purpose of use of long/short distance measurement equipment were presented according to regular and emergency situations. Using the data acquired through long/short distance measurement equipment, it can be used as basic data for resident evacuation decision-making by monitoring whether chemicals are detected in an emergency and managing data on detected substances by company in a regular situation. As a result of measuring chemical substances in order to verify on-site usability by equipment only for the regular operation system, it was confirmed that real-time detection of chemical substances is possible with long distance measuring equipment. In addition, it was confirmed that it was necessary to check the measurable distance and range of the equipment in the future. In the case of short distance measurement equipment, hydrocarbon-based substances were mainly detected, and it was confirmed that it was measured at a higher level in Ulsan-Mipo National Industrial Complex than in Onsan National Industrial Complex. It is expected that it can be used as basic data to support decision-making in the event of chemical accidents through continuous data construction in the future.

• Journal of Soil and Groundwater Environment
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• v.10 no.4
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• pp.45-53
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• 2005

The objective of this study is to evaluate the effects of changes in soil temperature on biodegradation rate of diesel compounds from a field pilot test using hot air injection process. Total remediation time was estimated from in-situ biodegradation rate and temperature for optimum biodegradation. All tests were conducted by measuring in-situ respiration rates every about 10 days on highly contaminated area where an accidental diesel release occurred. The applied remediation methods were hot air injection/extraction process to volatilize and extract diesel compounds followed by a bioremediation process to degrade residual diesels in soils. Oxygen consumption rate varied from 2.2 to 46.3%/day in the range of 26 to $60^{\circ}C$, and maximum $O_2$ consumption rate was observed at $32.0^{\circ}C$. Zero-order biodegradation rate estimated on the basis of oxygen consumption rates varied from 6.5 to 21.3 mg/kg-day, and the maximum biodegradation rate was observed at $32^{\circ}C$ as well. In other temperature range, the values were in the decreasing trend. The first-order kinetic constants (k) estimated from in-situ respiration rates measured periodically were 0.0027, 0.0013, and $0.0006d^{-1}$ at 32.8, 41.1, and $52.7^{\circ}C$, respectively. The estimated remediation time was from 2 to 9 years, provided that final TPH concentration in soils was set to 870 mg/kg.