• Title/Summary/Keyword: 수소저장재료

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Storability and Material Compatibility Test of Blended Hydrogen Peroxide Propellant (블렌딩 기법을 적용한 과산화수소 추진제의 저장성 및 재료 적합성 평가)

  • Lee, Jeong-Sub;Jang, Dong-Wuk;Kwon, Se-Jin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.16 no.5
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    • pp.20-28
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    • 2012
  • Blending method was applied to increase the performance of hydrogen peroxide which is called green propellant. 90 wt.% hydrogen peroxide was blended with ethanol which is less toxic fuel, and there was no storability decrease due to fuel addition. Inconel X750 and Tophet A showed good compatibility and high heat resistance, and SUS 316L was compatible. $Al_2O_3$, $Y_2O_3$, and $ZrO_2$, were coated on the material to improve heat resistance, and it was proved from endurance test that $Y_2O_3$ coating is not suitable and adhesive strength between coating and material is related with allowable temperature of material. Thruster test was performed to confirm the performance increase by blending method, and chamber temperature was $870^{\circ}C$ which is higher than $760^{\circ}C$ that is adiabatic chamber temperature of 90 wt.% hydrogen peroxide.

Storability and Material Compatibility Test of Blended Hydrogen Peroxide Propellant (블렌딩 기법을 적용한 과산화수소 추진제의 저장성 및 재료 적합성 평가)

  • Lee, Jeong-Sub;Jang, Dong-Wuk;Kwon, Se-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2011.11a
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    • pp.150-158
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    • 2011
  • Blending method was applied to increase the performance of hydrogen peroxide which is called green propellant. 90 wt.% hydrogen peroxide was blended with ethanol which is less toxic fuel, and there was no storability decrease due to fuel addition. Inconel X750 and Tophet A showed good compatibility and high heat resistance, and SUS 316L was compatible. Al2O3, Y2O3, and ZrO2, were coated on the material to improve heat resistance, and it was proved from endurance test that Y2O3 coating is not suitable and adhesive strength between coating and material is related with allowable temperature of material. Thruster test was performed to confirm the performance increase by blending method, and chamber temperature was $870^{\circ}C$ which is higher than $760^{\circ}C$ that is adiabatic chamber temperature of 90 wt.% hydrogen peroxide.

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Development of Evaluation Technique for Hydrogen Embrittlement Behavior of Metallic Materials Using in-situ SP Testing under Pressurized Hydrogen Gas Conditions (고압수소가스하 in-situ SP시험법을 사용한 금속재료의 수소취화거동 평가기법 개발)

  • Shin, Hyung-Seop;Kim, Ki-Hyun;Baek, Un-Bong;Nahm, Seung-Hoon
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.11
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    • pp.1377-1382
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    • 2011
  • Recently, alternative and novel energy resources have been developed for use in the future because of the current environmental problems and exhaustion of fossil energy resources. Hydrogen energy has many merits, such as its environmental friendliness, easy storage, and easy production, but it also has disadvantages, in that it is highly combustible and explosive. In this study, a test procedure using a simple SP test under highly pressurized hydrogen gas conditions was established. In order to evaluate its applicability, SP tests were carried out using a stainless steel (SUS316L) sample under atmospheric, pressurized helium, and pressurized hydrogen gas conditions. The results under the pressurized hydrogen gas condition showed fissuring and produced a reduction of the elongation in the plastic instability region due to hydrogen embrittlement, showing the effectiveness of the current in-situ SP test.

Technology Trend for Non-carbon Nanomaterials Hydrogen Storage by the Patent Analysis (특허분석에 의한 비탄소계 나노재료 수소저장 기술 동향)

  • Lee, Jin-Bae;Kang, Kyung-Seok;Han, Hye-Jeong;Kim, Jong-Wook;Kim, Hae-Jin
    • Transactions of the Korean hydrogen and new energy society
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    • v.19 no.3
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    • pp.248-259
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    • 2008
  • There are several well-known materials for the hydrogen storage such as metallic alloy, carbon nanomaterials, non-carbon nanomaterials, and compounds etc. Efficient and inexpensive hydrogen storage methods are an essential prerequisite for the utilization of hydrogen, one of the new and clean energy sources. Many researches have been widely performed for the hydrogen storage techniques and materials to improve the high storage capacity and stability. In this paper, the patents concerning the non-carbon nanomaterial hydrogen storage method were collected and analyzed. The search range was limited in the open patents of Korea(KR), Japan(JP), USA(US) and European Union(EP) from 1996 to 2007. Patents were collected by using key-words searching and filtered by filtering criteria. The trends of the patents was analyzed by the years, countries, companies. and technologies.

Hydrogenation Properties of $Mg_2$Ni-(5, 10mass)$NbH_x$ Composites by Reactive Mechanical Alloying (기계적 합금화법에 의한 $Mg_2$Ni-(5, 10mass%)$NbH_x$ 복합재료의 수소화 특성)

  • Cho, Kyoung-Won;Park, Ji-Hee;Kim, Kyeong-Il;Kim, Soo-Hyun;Jung, Mi-Ewon;Kim, Sang-Hern;Choi, Jae-Ha;Hong, Tae-Whan
    • Transactions of the Korean hydrogen and new energy society
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    • v.20 no.6
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    • pp.512-518
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    • 2009
  • Mg 및 Mg합금은 수소 저장량이 7.6wt.%로 비교적 높고 자원도 풍부하여 값이 싼 장점을 가지고 있으나 산화반응성이 높고 활성화 에너지가 크기 때문에 반응온도가 높고 반응시간이 긴 단점을 가지고 있다. 이러한 단점을 극복하기 위해 일반적으로 Mg 및 Mg합금의 표면 개질화, 금속간 화합물 형성, 전이금속 첨가에 대한 연구가 활발히 진행되고 있다. 본 연구에서는 전이금속인 Nb를 촉매제로 사용하여 수소화 특성을 개선하고자 기계적 합금화법(MA;Mechanical Alloying)을 실시하여 복합재료를 합성한 후 수소화 반응을 평가하였다. XRD, SEM, TEM, PSA, TG/DSC 분석을 수행하였으며 Sievert's 형 PCT를 이용하여 온도 및 압력 변화에 따른 특성평가를 하였다. 전이금속인 Nb의 첨가로 수소화 반응개시온도가 낮아지고 수소 저장량이 향상되는 거동을 보였다. 특히, 5mass%Nb가 10mass%Nb 보다 수소 저장량 및 반응속도가 좋은 결과를 보였다.

A Numerical Analysis on the Stress Behavior Characteristics of a Pressure Vessel for Hydrogen Filling by FEM (유한요소법을 이용한 수소충전용 압력용기의 응력 거동특성에 관한 수치적 연구)

  • Chol, Seunghyun;Byonl, Sung Kwang;Kim, Yun Tae;Choi, Ha Young
    • Journal of the Korean Institute of Gas
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    • v.26 no.3
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    • pp.38-44
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    • 2022
  • As the supply of hydrogen charging stations for hydrogen supply accelerates due to the hydrogen economy revitalization policy, the risk of accidents is also increasing. Since most hydrogen explosion accidents lead to major accidents, it is very important to secure safety when using hydrogen energy. In order to utilize hydrogen energy, it is essential to secure the safety of hydrogen storage containers used for production, storage, and transportation of liquid hydrogen. In this paper, in order to evaluate the structural safety of a hydrogen-filled pressure vessel, the behavioral characteristics of gas pressure were analyzed by finite element analysis. SA-372 Grade J / Class 70 was used for the material of the pressure vessel, and a hexahedral mesh was applied in the analysis model considering only the 1/4 shape because the pressure vessel is axisymmetric. A finite element analysis was performed at the maximum pressure using a hydrogen gas pressure vessel, and the von Mises stress, deformation, and strain energy density of the vessel were observed.

Hydrogen Storage Material as an Dream Energy Resources (꿈의 에너지원 수소저장재료)

  • 권호영;이갑호;강길구
    • Journal of the Korean Society of Safety
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    • v.12 no.4
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    • pp.249-256
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    • 1997
  • 1973년 OPEC가 원유 수출을 규제하면서 일어난 석유 위기는 국내는 물론 세계에 큰 충격을 주었다. 더욱 석유, 석탄 등의 화석연료 중 석유자원의 고갈에 대한 불안과 화석연료의 연소로 인한 대기오염, 환경파괴에 대한 불안이 증대되었다. 이를 계기로 화석연료를 대신하는 새로운 에너지 자원의 개발과 효율적인 에너지 이용시스템의 개발이 세계 각국에서 착실히 진행되었다. 즉, 에너지 정세의 변화, 지구 환경문제의 대응, 새로운 에너지 기술개발 대책은 절대적으로 필요하고, 21세기의 장기 전망에서 보면, 에너지 문제는 매우 심각한 사태라는 것은 의심할 여지가 없다.

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