• Title/Summary/Keyword: 수소이온 농도

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Distribution of potential risky species on phytoplankton at ports in Korea (항만 환경에서 식물플랑크톤 잠재적 위해종의 분포)

  • Kwon, Oh Youn;Kang, Jung-Hoon
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.14 no.1
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    • pp.506-510
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    • 2013
  • This study aimed to understand relationship between potential risky species and environmental factors at ports in Korea. During the study periods, 25 potential risky species (red tide and toxic species) representing 20 red-tide species, 5 toxic species were observed in the all ports. Skeletonema costatum (red-tide species) was predominated in all study area. This species showed positive correlation with pH, while negative correlation with dissolved oxygen (p<0.05) at Busan port. Also, this species showed positive correlation with total suspended solids and pH (p<0.05) at Ulsan port. However, Sk. costatum showed positive correlation with nitrate at Incheon port (p<0.01). Pseudo-nitzschia spp. producing amnesic shellfish poison (domoic acid) showed positive correlation with nitrate and silicate in all study areas (p<0.05). Alexandrium spp. (paralytic shellfish poison) and Dinophysis acuminata (diarrhetic shellfish poison) were affected by chemical oxygen demand (p<0.01). Our results indicated that red-tide species were affected by physical factors, while chemical factors affected toxic species.

Changes in Habitats of Fish and Amphibian Due to Erosion Control Dam Constructed in a Mountain Stream, Gongju, Chungchoengnamdo (충청남도 공주시 소재 산지계류 내 시공된 사방댐에 의한 어류 및 양서류 서식의 변화)

  • Lee, Sang In;Seo, Jung Il;Kim, Suk Woo;Chun, Kun Woo
    • Journal of Korean Society of Forest Science
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    • v.108 no.2
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    • pp.241-258
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    • 2019
  • The aim of this study was to analyze the factors that affect the habitat of fishes and amphibians in a mountain stream that is part of an experimental forest at Kongju National University, Gongju, Chungcheongnam, Korea, and examine the differences in the presence of fishes and amphibians in the stream before and after construction of an erosion control dam. The results showed that the factors that affect the presence of fishes are pH, electrical conductivity (EC), dissolved oxygen (DO), flow velocity, and step-pool number, and that the factors that affect the presence of amphibians are monthly rainfall, pH, EC, DO, and crown density. Of these factors, pH, EC, flow velocity, and monthly rainfall were significantly different before and after dam construction; however, the differences among the other three factors from dam construction, except EC, might not have been enough to affect the presence of fishes and amphibians. Our results suggest that the difference in the frequency of fishes and amphibians surveyed before and after dam construction in the upper and lower stream sections were not statistically significant. One exception to this was the presence of amphibians in the lower stream section during and after dam construction, which could have been the result of a large amount of sediment produced by excavation that led to high EC.

Performance improvement of artificial neural network based water quality prediction model using explainable artificial intelligence technology (설명가능한 인공지능 기술을 이용한 인공신경망 기반 수질예측 모델의 성능향상)

  • Lee, Won Jin;Lee, Eui Hoon
    • Journal of Korea Water Resources Association
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    • v.56 no.11
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    • pp.801-813
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    • 2023
  • Recently, as studies about Artificial Neural Network (ANN) are actively progressing, studies for predicting water quality of rivers using ANN are being conducted. However, it is difficult to analyze the operation process inside ANN, because ANN is form of Black-box. Although eXplainable Artificial Intelligence (XAI) is used to analyze the computational process of ANN, research using XAI technology in the field of water resources is insufficient. This study analyzed Multi Layer Perceptron (MLP) to predict Water Temperature (WT), Dissolved Oxygen (DO), hydrogen ion concentration (pH) and Chlorophyll-a (Chl-a) at the Dasan water quality observatory in the Nakdong river using Layer-wise Relevance Propagation (LRP) among XAI technologies. The MLP that learned water quality was analyzed using LRP to select the optimal input data to predict water quality, and the prediction results of the MLP learned using the optimal input data were analyzed. As a result of selecting the optimal input data using LRP, the prediction accuracy of MLP, which learned the input data except daily precipitation in the surrounding area, was the highest. Looking at the analysis of MLP's DO prediction results, it was analyzed that the pH and DO a had large influence at the highest point, and the effect of WT was large at the lowest point.

Removal of Orthophosphate Ions from Aqueous Solutions Using the Anion Exchange Resin in the Form of $Cl^-$ Ion ($Cl^-$ 형태의 음이온 교환 수지를 이용한 오쏘인산 이온의 제거에 관한 연구)

  • Kim, Ki-Chul;Park, Su-Jin;Cha, Ran;Jeong, Tae-Young;Chung, Hyung-Keun
    • Journal of Korean Society of Environmental Engineers
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    • v.34 no.3
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    • pp.162-167
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    • 2012
  • The removal of orthophosphate ions from aqueous solutions by the anion exchange resin in the form of $Cl^-$ ion was investigated to elucidate the ion exchange mechanism which depends on the forms of orhthophoshate ions. In addition, the effects of alkalinity and other common anions were studied. The results showed that the orhthophosphate ions with the oxidation state of 2 and 3 ($HPO{_4}^{2-}$ and $PO{_4}^{3-}$) were effectively removed by the anion exchange resin, whereas the part of the $H_2PO_4{^-}$ ion passed through the ion exchange column. This suggested that the affinity of $H_2PO_4{^-}$ to the ion exchange resin was comparable with that of $Cl^-$ ion. In all cases, the effluent pHs have shown to be much lower than the calculated values, indicating that more $Cl^-$ ions than the orthophosphate equivalents in the influent were eluded. As the alkalinity increases, the decrease in pH was minimized. When the alkalinity was 100 mg/L ($CaCO_3$) or greater, 100 mg/L orthophosphate ions including $H_2PO_4{^-}$ were completely removed. The common anions such as $SO{_4}^{2-}$ and $NO_3{^-}$ were also removed by the anion exchange resin, and thus decreased the ion exchange capacity for the removal of orthophosphate.

Mineralogical Properties and Paragenesis of H-smectite (H-스멕타이트의 광물학적 특성과 생성관계)

  • Noh, Jin-Hwan;Hong, Jin-Sung
    • Journal of the Mineralogical Society of Korea
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    • v.23 no.4
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    • pp.377-393
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    • 2010
  • Pumiceous tuffs occurring in the Beomgockri Group are examined applied-mineralogical characteristics and their controling factors to evaluate their potentials as the adsorption-functional mineral resources. The pumiceous tuffs are diagenetically altered to low-grade zeolitcs and bentonites in the Janggi area. Compositional specialty due to the presence of pumice fragments induces the altered tuffs to exhibit the characteristic adsorption property combined with cation exchange capacity, specific surface area, and acidic pH. Unusual lower pH in the adsorption-functional mineral substances is turned out to be originated from the presence of H-smectite having $H^+$ in the interlayer site of the sheet structure. On account of disordered crystallinity resulting from the exchanged $H^+$ in the interlayer site, the smectite commonly forms crenulated edges in the planar crystal form and exhibits characteristic X-ray diffraction patterns showing comparatively lower intensities of basal spacings including (001) peak than conventional Ca-smectite. Based on the interpretation of paragenetic relations and precursor of the H-smectite, a genetic model of the peculiar clay mineral was proposed. The smectite formation may be facilitated resulting from the precipitation of opal-CT at decreasing pH condition caused by the release of H+ during diagenetic alteration of pumice fragments. Because of the acidic smectite, the low-grade mineral resources from the Beomgockri Group may be applicable to the adsorption industry as the raw materials of acid clays and bed-soil.

Problem Analysis and Improvement of an Experiment on Reactivityof Metals in ChemistryⅠ (화학Ⅰ 금속의 반응성 실험의 문제점 분석 및 개선방안)

  • Seong, Suk-kyoung;Choi, Chui-Im;Jeong, Dae-Hong
    • Journal of the Korean Chemical Society
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    • v.53 no.3
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    • pp.368-376
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    • 2009
  • In this study we investigated and tried to understand problems monitored in an experiment on reactivity of metals in chemistry I. Three problems were discussed. First, the reason that aluminium plate does not react with other metal ions such as zinc, iron and copper was studied and the way to overcome this problem was suggested. Second, the reason that the bubbles were generated when FeS$O_4$(aq) and Zn(s) react was discussed. Third, the precipitates which appeared in the reaction of FeS$O_4$(aq) and Zn(s) were identified. Through reference study and experimental investigation, we could reach the following results. First, aluminium could not react with other metal ions due to the surface oxide layer that is formed very fast and prevents aluminium from reacting with metal ions in solution. This problem could be overcome by allowing a competing reaction of acid and aluminium during the reaction of aluminium and metal ions. Second, the observed bubbles were identified to be hydrogen gas, produced by the reaction between metals and hydronium ion in the solution. Third, black precipitates that were produced on the surface of zinc plate and exhibited magnetic property were characterized to be $Fe_3O_4$(s), and brown precipitates that were produced in the solution phase were to be $Fe_2O_3$(s) by the analysis of X-ray photoelectron spectra.

Seasonal Variations of Water Environment Factors and Phytoplankton in Nammae Reservoir (남매지의 수환경 요인과 식물플랑크톤의 계절적인 변동)

  • Park, Jung-Won;Lee, Yung-Ok;Kim, Mi-Kyung
    • Korean Journal of Ecology and Environment
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    • v.36 no.1 s.102
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    • pp.48-56
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    • 2003
  • This study was evaluated about the seasonal variations of ecosystem in Nammae Reservoir based on the interrelation of physico-chemical characteristics, nutrients, chlorophyll a, b, c and standing crops of phytoplanktons. The amounts of chlorophyll a, b, c were respectively maximum (295 mg/, 9.5mg/l and 48mg/l) at station 1 in June and the standing crop of phytoplanktons was the highest ($1.7{\time}10^5$ cells/1) at stations 3 in July. The range of temperature was $7{\sim}37.4^{\circ}C$. The maxium of pH was $9.9{\sim}10.1$ at all stations in August, the minimum was 7 in September. SS was maximum (308 mg/1) at station 1 in June, while it was minimum (4 mg/l) at the same station in November. The maximal COD and DOC were 33 mg/1 and 16 mg/1 respectively at station 1 in June. As for phytoplanktons, Microcystis aeruginosa, blue-green alga in July${\sim}$August, Scenedesmus acutus, green alga in March${\sim}$May and November${\sim}$January and Cyclotella orientalis, Diatoms in October were dominant species. The amounts of P and Si were generally high in summer, they were low in autumn and winter. Nammae Reservoir assessed by trophic state index was eutrophicated and overtrophicated. These results indicated that Nammae Reservoir was faced with heavy water pollution. As preceding management for the basin of the Reservoir, it will have to be continually studied for an ecosystem reservation.

A Study on Dental Caries Activity Test Targeting Female Undergraduates in Their 20s (20대 여대생을 대상으로 한 치아우식활성검사 연구)

  • Yoon, Mi sook;Youn, Hye-jeong
    • Journal of dental hygiene science
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    • v.10 no.6
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    • pp.465-472
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    • 2010
  • This study surveyed salivary flow rate, salivary viscosity, and salivary buffering capacity in order to intensively analyze salivary factors among factors of occurrence in dental caries for finding mutually different factors that function in occurrence of dental caries depending on each individual. Even the acid body within dental plaque has great influence upon dental caries. Thus, the comparative analysis was carried out by surveying the hydrogen ion concentration in dental plaque. The following results were obtained in this study. 1. The average decayed teeth in the survey subjects stood at 1.67 piece. The extracted teeth caused by dental caries stood at 0.47 piece. The filled teeth were indicated to be 6.31 pieces. Accordingly, the average permanent dental caries experience teeth were surveyed to be 8.44 pieces. 2. The results according to dental caries activity test method were indicated to be $12.56{\pm}4.15ml$ for the average stimulated salivary flow rate, $3.89{\pm}1.83ml$ for non-stimulated salivary flow rate, $1.49{\pm}0.69$ for salivary viscosity, and $8.51{\pm}2.44$ for salivary buffering capacity. The hydrogen ion concentration test in dental plaque was indicated to be $5.62{\pm}0.50$ for before brushing teeth, $5.23{\pm}0.58$ for 5 minutes after brushing teeth, $5.25{\pm}0.56$ for 10 minutes after brushing teeth, $5.29{\pm}0.62$ for 15 minutes after brushing teeth, $5.34{\pm}0.58$ for 20 minutes after brushing teeth, $5.40{\pm}0.53$ for 25 minutes after brushing teeth, and $5.61{\pm}0.59$ for 30 minutes after brushing teeth. 3. Stimulated salivary and non-stimulated salivary flow rate, salivary viscosity, and salivary buffering capacity were indicated to be higher in group with non-caries than group with caries. However, it was statistically insignificant. The hydrogen ion concentration in dental plaque showed wholly statistical significant in the relationship with people with dental caries under progression. However, people without dental caries were indicated to be higher than people with dental caries. 4. As for correlation between caries activity test methods, the stimulated salivary flow rate had significantly positive correlation with non-stimulated salivary flow rate(p<0.001). Non-stimulated salivary flow rate showed negative correlation with salivary buffering capacity(p<0.01). The hydrogen ion concentration test in dental plaque showed positive correlation according to the passage of time after brushing teeth. However, there was no significant correlation with salivary viscosity and salivary buffering capacity(p>0.05).

Electrical Properties of Silicon Implants in Cr-Doped GaAs (실리콘을 주입한 크롬이 도핑된 GaAs의 전기적 성질에 관한 연구)

  • 김용윤
    • Journal of the Korean Institute of Telematics and Electronics
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    • v.20 no.5
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    • pp.50-55
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    • 1983
  • A comprehensive study of the electrical properties of low-dose Si implants in Cr-doped GaAs substrates has been made using the Hall-effect/sheet-resistivity measurement technique for various ion doses and annealing temperatures. The samples were implanted at room temperature and annealed with silicon nitride encapsulants in a hydrogen atmosphere for 15 minutes. H-type layers were produced at all dose levels investigated, and the optimum annealing temperature was 850$^{\circ}C$ for all doses. The highest electrical activation efficiency was 89% for Cr-doped GaAs substrates. Depth profiles of carrier concentrations and mo-bilities are highly dependent upon ion dose and annealing temperature. Significant im-plantation damage still remains after an 800$^{\circ}C$ anneal, and a 900$^{\circ}C$ anneal produces signi-ficant outdiffusion as well as indiffusion of the implanted Si ions.

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Solubilization Mechanism of Hydrocarbon Oils by Polymeric Nonionic Surfactant Solution (고분자 비이온 계면활성제 수용액에 의한 탄화수소 오일의 가용화 메커니즘)

  • Bae, Min Jung;Lim, Jong Choo
    • Korean Chemical Engineering Research
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    • v.47 no.1
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    • pp.24-30
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    • 2009
  • In this study, solubilization experiments of n-decane, n-undecane and n-dodecane oil were performed by micellar solutions of polymeric nonionic surfactant Pluronic L64($EO_{13}PO_{30}EO_{13}$) at room temperature. A single spherical drop of hydrocarbon oil was injected into aqueous surfactant solution using an oil drop contacting technique and solubilization rate of hydrocarbon oil was measured by observing the size of oil drop with time. It was shown that solubilization rate decreased with the alkane carbon number(ACN) of the hydrocarbon oil. The solubilization rate was also found to be independent of initial oil dorp size and almost linearly proportional to the initial surfactant concentration. These results revealed that solubilization of n-decane, n-undecane and n-dodecane oils by L64 micellar solution is controlled by interface-controlled mechanism but not by diffusion-controlled mechanism. The equilibrium solubilization capacity(ESC) was measured by a turbidimeter and the result showed that EAC decreased with an increase in ACN but increased with both increases in surfactant concentration and solubilization rate. Dynamic interfacial tension measurements showed that interfacial tension and equilibrium time increased with an increase in ACN of hydrocarbon oil but decreased with an increase in surfactant concentration.