• Title/Summary/Keyword: 수소액화

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Thermal Analysis of a Cold Box for a Hydrogen Liquefaction Pilot Plant with 0.5 TPD Capacity (0.5 TPD 급 수소액화 파일럿 플랜트의 콜드박스 열해석)

  • KIM, HYOBONG;HONG, YONG-JU;YEOM, HANKIL;PARK, JIHO;KO, JUNSEOK;PARK, SEONG-JE;IN, SEHWAN
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.6
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    • pp.571-577
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    • 2020
  • Thermal analysis was performed for a cold box of a hydrogen liquefaction pilot plant with 0.5 ton/day capacity. The pilot plant has adopted a hydrogen liquefaction process using two-stage helium Brayton cycle with precooling of liquid nitrogen. The cold box for hydrogen liquefaction has generally vacuum insulation but inevitable heat invasion by conduction and radiation exists. The heat loads were calculated for cold box internals according to multilayer insulation emissivity. Total heat load of 181.7 W is estimated for emissivity of 0.03 considered in field condition.

Biosolubilization of Australian lignite: effect of pretreatment method on biosolubilization (호주산 갈탄의 미생물에 의한 가용화 연구: 전처리 방법이 가용화에 미치는 영향)

  • 신현재;양지원
    • KSBB Journal
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    • v.7 no.1
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    • pp.73-78
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    • 1992
  • The solubilizations of Australian lignite by the fungus Poria cocos, Trichodermareesei, Candide tropicalis, and niger were investigated. Three different types of chemical pretreatment methods were used for increasing biosolubility of lignite. Nitric acid and hydrogen peroxide were proven to be proper chemical pretreatment materials of Australian lignite. Poria cocos showed much better solubilization ability than other strains. Interpretation of the nature of coal solubilization by Poria cocos was based primarily on infrared, ultraviolet and nuclear magnetic resonance spectrum analyses.

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Comparison of the Internal Pressure Behavior of Liquid Hydrogen Fuel Tanks Depending on the Liquid Hydrogen Filling Ratio (액체수소 충전 비율에 따른 액체수소 연료탱크의 내부 압력 거동 비교)

  • Dongkuk Choi;Sooyong Lee
    • Journal of Aerospace System Engineering
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    • v.18 no.3
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    • pp.8-16
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    • 2024
  • Because hydrogen has very low density, a different storage method is required to store the same amount of energy as fossil fuel. One way to increase the density of hydrogen is through liquefaction. However, since the liquefied temperature of hydrogen is extremely low at -252 ℃, it is easily vaporized by external heat input. When liquid hydrogen is vaporized, a self-pressurizing phenomenon occurs in which the pressure inside the hydrogen tank increases, so when designing the tank, this rising pressure must be carefully predicted. Therefore, in this paper, the internal pressure of a cryogenic liquid fuel tank was predicted according to the liquid hydrogen filling ratio. A one-dimensional thermodynamic model was applied to predict the pressure rise inside the tank. The thermodynamic model considered heat transfer, vaporization of liquid hydrogen, and fuel discharging. Finally, it was confirmed that there was a significant difference in pressure behavior and maximum rise pressure depending on the filling ratio of liquid hydrogen in the fuel tank.

An Experimental Study on the Performance and Emission Characteristics with Hydrogen Enrichment at Part Load Conditions Using a LPG Engine (LPG기관의 부분부하 조건에서 수소 혼합에 따른 성능 및 배출가스 특성에 관한 실험적 연구)

  • Kim, Ingu;Kim, Kijong;Lee, Seangwock;Cho, Yongseok
    • Transactions of the Korean hydrogen and new energy society
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    • v.24 no.3
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    • pp.242-248
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    • 2013
  • The purpose of this study is to obtain low-emission and high-efficiency by hydrogen enriched LPG fuel in LPG engine and is to clarify the effects of hydrogen enrichment in LPG fuelled engine on exhaust emission and performance. An experimental study was carried out to obtain fundamental data for performance and emission characteristics of hydrogen enrichment in LPG engine. The research was held by changing the hydrogen ratio to 0, 5, 10, 20% in 1500rpm, bmep 2 and 4bar. The result turned out that the combustion duration was shortened due to fast flame propagation of hydrogen. And the amount of Carbon dioxide and Hydrocarbon decreased. However, the amount of NOX increased, which is thought to be the result of high adiabatic flame temperature of hydrogen. It has been confirmed that this phenomenon has changed by the Hydrogen mixing ratio.

Financial Analysis and Validity Study for the Introduction of Liquid Hydrogen in Changwon City (창원시 액화수소 도입에 따른 재무성 분석 및 타당성 검토)

  • KANG, BOO MIN;JEONG, CHANG-HOON;HA, SEUNG WOO;JIN, HONG-DEOK;KIM, HAK-MIN;JEONG, DAE-WOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.33 no.4
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    • pp.293-300
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    • 2022
  • The Changwon city which announced 2040 hydrogen policy vision is planning to establish the new hydrogen-centered city. The building of plant which is available to produce the 5 ton/day of liquid hydrogen is promoted as one of the projects in order to achieve the vision. However, the analysis in terms of local economic and environmental aspects is insufficient because this liquid hydrogen plant is the first in Korea. Therefore, in this study, the financial feasibility of the liquid hydrogen plant project was analyzed by reviewing the benefits of liquid hydrogen supply and environmental improvement, and the feasibility of this project has been investigated which is being built based on the hydrogen industrial plan of Changwon city.

Prediction of a Leakage in a Liquid Hydrogen Pump Using a Finite Element Method (유한요소 해석을 이용한 액화수소 펌프 누설량 예측)

  • HYUNSE KIM;YOUNG-BOG HAM
    • Transactions of the Korean hydrogen and new energy society
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    • v.34 no.3
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    • pp.292-296
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    • 2023
  • Until recently, ships, automobiles, and drones using hydrogen energy are being actively researched. In addition, stations and facilities for hydrogen supply are being developed widely. Among them, a hydrogen pump is necessary for compressing it and transfer to other stations. The liquid hydrogen pump is operated at very high pressure up to 90 MPa. In our research, a reciprocating plunger pump is studied. Especially, a leakage in a liquid hydrogen pump is predicted using a finite element method. As a result, it was found that leak mass flow rates changed from 0.09 to 2.20 kg/h, when the gaps were given from 2 to 6 ㎛. Thus pump efficiencies were calculated from 99.9 to 97.9%, when the gaps changed from 2 to 6 ㎛. These results are useful for the design of the liquid hydrogen pump.

Effects of Additives on Yield of Coal Liquefaction (석탄액화시 첨가제에 의한 수율 향상 효과)

  • 김종원;명광식;김연순;심규성;한상도
    • Journal of Energy Engineering
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    • v.5 no.2
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    • pp.176-182
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    • 1996
  • The effects of some additives (black liquor, NaOH, water and wood) on the conversion of coal and product were investigated in the lab-scale, high pressure reacting system around 375$^{\circ}C$. The addition of black liquor enhances the coal conversion yield about 38.6%, which is mainly due to NaOH in black liquor. Also, sulfur of the black liquor in coal liquefaction process evolved hydrogen sulfide, which causes the odor problem. Addition of water in coal liquefaction increased CO$_2$content in the gas phase, and low boiling range components in liquid products. Coprocessing of wood and coal at 400$^{\circ}C$ increased yield of liquid product about 8%, but higher temperature above 400$^{\circ}C$ reduced liquid product due to increase of gas products.

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Process Analysis and Simulation for System of Air Liquefaction Separation Using LNG Cold Energy (LNG 냉열을 이용한 공기액화분리시스템의 시뮬레이션 및 공정 해석)

  • HAN, DANBEE;BAEK, YOUNGSOON
    • Transactions of the Korean hydrogen and new energy society
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    • v.30 no.3
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    • pp.276-281
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    • 2019
  • The process of separating oxygen and nitrogen from the air is mainly performed by electric liquefaction, which consumes a lot of electricity, resulting in higher operating costs. On the other hand, when used for cold energy of LNG, electric power can be reduced compared to the electric Linde cycle. Currently, LNG cold energy is used in the cold refrigeration warehouse, separation of air-liquefaction, and LNG cold energy generation in Japan. In this study, the system using LNG cold energy and the Linde cycle process system were simulated by PRO/II simulators, respectively, to cool the elevated air temperature from the compressor to about $-183^{\circ}C$ in the air liquefaction separation process. The required amount of electricity was compared with the latent heat utilization fraction of LNG, the LNG supply pressure, and the LNG cold energy usage. At the air flow rate of $17,600m^3/h$, the power source unit of the Linde cycle system was $0.77kWh/m^3$, compared with $0.3kWh/m^3$.

A Study on the Utilization of the LNG Cold Heat for the Reduction of the Power Consumption in Main Air Compressors in Cryogenic Air Separation (심냉 공기분리공정의 공기압축공정에서 전력비 절감을 위한 액화천연가스 냉열 활용에 대한 연구)

  • CHO, DUHEE;CHO, JUNGHO
    • Transactions of the Korean hydrogen and new energy society
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    • v.31 no.3
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    • pp.322-327
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    • 2020
  • In this work, a study for the reduction of the electric power consumption has been estimated in main air compressors in the air separation unit through cryogenic distillation columns with PRO/II with PROVISION V10.2 at AVEVA company. Both required LNG mass flow rate and cold heat contained in 1 ton of LNG were also predicted using Peng-Robinson equation of state with Twu's new alpha function. Through this work, we concluded that 32.33-48.69% of electric power could be saved by using LNG cold heat.

Estimation of the Ammonia Refrigeration Cycle Using LNG Cold Heat (액화천연가스 냉열을 활용한 암모니아 냉동 사이클의 추산)

  • NOH, SANGGYUN
    • Transactions of the Korean hydrogen and new energy society
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    • v.29 no.4
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    • pp.357-362
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    • 2018
  • In this study, computer simulation and optimization works have been performed for a refrigeration cycle using ammonia as a refrigerant and also how much power was saved when the liquefied natural gas cold heat is replaced for the refrigeration cycle. PRO/II with PROVISION release 10.0 from Schneider electric company was used, and Peng-Robinson equation of the state model was selected for the modeling of the refrigeration cycle and LNG cold heat utilization process.