• Title/Summary/Keyword: 수성 수지

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수성잉크용 분산제와 바인더의 합성 및 응용

  • 박영준;오석헌
    • Proceedings of the Korean Printing Society Conference
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    • 2001.06a
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    • pp.91-91
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    • 2001
  • 환경문제에 대해 오래 전부터 관심을 가져온 선진국은 잉크의 수성화에 주력하여 왔으며, 그 결과 이미 수용성 소재의 양산체재에 들어가 수성 원료 사업을 대형화하는 추세에 있다. 이에 한화석유화학 중앙연구소에선 스티렌/아크릴계 수용성 High Solid 수지를 개발하여, 수성 잉크용 분산제, Resin Fortified Emulsion (RFE), UV Resist 잉크, 수성코팅제, 바닥광택제 등에 적요하기 위한 응용기술을 개발하였다. 본 연구는 수성 잉크의 주요 구성 성분인 grinding vehicle. let-down vehicle로 사용되는 수용성 High Solid 수지 (SAA 수지) 및 이를 이용한 에멀젼 수지의 합성과 수성 잉크로의 응용에 대한 것이다. SAA(HCC Soluryl Resin) 수지는 구조적으로 Styrene, Alpha-methyl Styrene, crylic Acid의 삼원공중합체이며 약 70%의 소수성 물질과 30%의 친수성 물질이 Random 하게 중합되어 있으며 약 5000∼15000정도의 낮은 분자량을 가진 물질로, 고고형분에서도 낮은 점도를 유지하기 위하여 분자량과 좁은 분자량과 좁은 분자량을 가지는 수지를 연속벌크중합방법으로 합성하였다. 또한 이를 고분자 유화제로서 사용하여 수지보강 에멀젼수지 (RFE 수지, HCC Soluryl Emulsion) 를 제조하는데 사용하였으며, SAA수지 및 RFE수지를 수성잉크용 분산제, 잉크 바인더용으로 적용하였다.

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A Fundamental Study on the Attachment Performance of Impervious Waterproof Asphalt Mixture (불투수성 방수아스팔트의 부착성능에 관한 기초적 연구)

  • Kim, Kyeong-Jin;Kim, In-Joong;Kim, Kyong-Tae;Cho, Jae-Hyeong
    • Proceedings of the Korean Society of Disaster Information Conference
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    • 2016.11a
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    • pp.353-356
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    • 2016
  • 불투수성 방수아스팔트는 아스팔트 혼합물이 골재와 골재 사이를 강력하게 부착하며, 골재간의 공간을 메우고, 골재표면을 두껍게 코팅하여 골재 상호간의 강한 접착을 유지시켜주는 열가소성 폴리머를 사용한 포장공법이다. 이러한 불투수성 아스팔트는 기존의 가열식 일반아스팔트 공법에서 문제시 되고 있는 내구성 저하와 잦은 유지보수로 인한 문제점을 해결할 수 있는 공법으로 차세대 고내구성 포장공법으로 주목을 받고 있다. 본 연구는 불투수성 방수아스팔트 혼합물 개발을 위한 연구의 일환으로 상온과 영하 $10^{\circ}C$의 조건하에서 기존 아스팔트수지와 새로운 개념의 불투수성 고분자계 수지의 부착성능 비교 검토하였으며, 아스팔트혼합물의 부착성능도 실험을 통해 비교 하였다. 실험결과 불투수성 아스팔트의 부착성능이 기존 아스팔트에 비해 상온은 물론 저온에서도 뛰어난 성능을 발휘하는 것을 확인 하였다.

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Effect of Vehicle Resin on Coating Performance of Dan-Chung (교착제 종류에 따른 단청의 도막 성능)

  • Han, Gyu-Seong;Shin, Soo-Jeong
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.1
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    • pp.44-50
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    • 2007
  • The objective of this study was to investigate the influence of the vehicle resin on the coating performance of Dan-Chung. The starch glue (F), fish glue (G), and aqueous acrylic resin emulsion (E) were used as vehicle resins. Panels coated with Dan-Chung were tested at accelerated weathering and outdoor conditions. Aqueous acrylic resin was proved as an excellent vehicle resin for Dan-Chung, because there was no flaking in Dan-Chung film after accelerated weathering and outdoor exposure. Discoloration of Dan-Chung using E was the smallest among the acceleratedly weathered panels. Adhesive property of Dan-Chung film using G was. remarkably improved by G-undercoating. On the contrary, G-undercoating lowered adhesive property of Dan-Chung film using E.

Hot Water Resistance of Polymer Mortar Composites Depending on Unsaturated Polyester Resin Types (불포화폴리에스테르 수지의 형태에 따른 폴리머 모르타르 복합재료의 내열수성)

  • Hwang, Eui-Hwan;Song, Min-Kyu;Kim, Yong-Yeon
    • Applied Chemistry for Engineering
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    • v.29 no.2
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    • pp.201-208
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    • 2018
  • The ortho- and iso- type unsaturated polyester resins were synthesized and used as a polymer binder of the polymer mortar composite. Styrene monomer and acrylonitrile were used as a diluent for the unsaturated polyester resin. Methyl ethyl ketone peroxide (MEKPO) and cobalt octoate (CoOc) were used as a curing agent and an accelerator, respectively. Four kinds of unsaturated polyester resins were prepared according to types of the resin and diluent, and used as a polymer binder in the preparation of the specimen. A total of 16 polymer mortar specimens were prepared according to the added amount of the polymer binder and subjected to a hot water resistance test, followed by compressive and flexural strength tests, and pore and SEM analyses. As a result, it was found that the strength of the specimen using the iso-type unsaturated polyester resin as the polymer binder was better than that of using the ortho-type unsaturated polyester resin. The total pore volume and diameter measured after the hot water resistance test were reduced compared to the values before the test. In the micrographs observed before the hot water resistance test, the polymer binder, filler and fine aggregate were firmly combined to the co-matrix, but the polymer binder was mostly decomposed in the micrographs observed after the test.

A Study on the Mechanical Characteristics and Waterproof Performance of Impermeable Asphalt Pavement Materials (불투수성 아스팔트 포장재료의 방수기능과 역학적 특성에 관한 연구)

  • Kim, Injoong;Kim, Kyeongjin;Lee, Seungyong
    • Journal of the Society of Disaster Information
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    • v.12 no.3
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    • pp.242-248
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    • 2016
  • This paper presents features of impermeable asphalt pavement material that uses thermoplastic GMA-based polymer(SIS, Stylene Isoprene Stylene) to improve the waterproof performance. Furthermore, as part of this study, the aerodynamic characteristics of the asphalt paving materials, using the newly suggested thermoplastic polymer, are identified through experiments. In the experiment, the aerodynamic characteristics were analyzed by testing on stability, flow values, porosity, dynamic stability, tensile strength ratio and skid resistance in accordance with KS standard and ASTM standard.

Properties of Polymer Modified Mortars Using Re-dispersible Polymer Powders (재유화형 분말수지를 이용한 폴리머 시멘트 모르타르의 특성)

  • Bae, Sang-Chan;Hyung, Won-Gil
    • Journal of the Korea Institute of Building Construction
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    • v.13 no.3
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    • pp.235-241
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    • 2013
  • In this study, a mortar was produced using re-dispersible polymer powders that addresses the defects of aqueous polymer and improves the durability of cement mortar. Also, an attempt was made to examine the properties of polymer modified mortars using re-dispersible polymer powders by strength and durability tests between ordinary Portland cement mortars and polymer modified mortars mixed with aqueous dispersion. The test showed that strength and durability are improved considerably compared with ordinary Portland cement mortar, and the performance of aqueous polymer cement mortar was considerably improved. Accordingly, it is expected that high-quality prepackaged polymer modified mortars can be produced using re-dispersible polymer powders.

A Study on the Acrylic Water-Soluble Coatings Containing Perfume of Lemon (Lemon 향을 함유하는 아크릴계 수성페인트에 관한 연구)

  • Kim Il-Chool;Kim Yeoung-Chan
    • The Journal of Information Technology
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    • v.5 no.4
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    • pp.139-144
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    • 2002
  • In this study, acrylic water-soluble coatings were prepared by the white pigment($TiO_2$) and acrylic resin. The basic properties of acrylic water-soluble coatings were measured, and the maintenance of perfume(lemon) was investigated by FT-IR spectrophotometer and sensory test.

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Durability of High Performance Polymer Concrete Composites (Focusing on Chemical Resistance and Hot Water Resistance) (고성능 폴리머 콘크리트 복합재료의 내구성(내약품성 및 내열성을 중심으로))

  • Hwang, Eui-Hwan;Kim, Yong-Yeon;Song, Min-Kyu
    • Applied Chemistry for Engineering
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    • v.28 no.3
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    • pp.360-368
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    • 2017
  • In order to investigate the durability of high performance polymer concrete composites, polymer concrete specimens were prepared using the ortho-type unsaturated polyester resin (UPR) and iso-type UPR as a polymer binder and the calcium carbonate and silica fine powder as a filler. The durability of polymer concrete specimens was measured by hot water resistance, chemical resistance, pore analysis and SEM observation. The compressive strength of the specimen using the iso-type UPR was higher than that of using the ortho-type UPR, and the compressive strength of the specimen using the silica fine powder was higher than that of using the calcium carbonate filler. From hot water resistance results, it was found that the specimen using the iso-type UPR was superior to that of using the ortho-type UPR and the specimen using the calcium carbonate filler was superior to that of using the silica fine powder. The compressive strength reduction rate was measured after the chemical resistance test and the sodium hydroxide solution showed the highest reduction rate, followed by sulfuric acid, hydrochloric acid and calcium chloride solutions. When using the alkaline solution of sodium hydroxide, the weight reduction rate of the specimen using calcium carbonate was lower than that of using silica fine powder, while for the acidic solutions of sulfuric acid and hydrochloric acid, the weight reduction rate of the specimen using the silica fine powder was lower than that of using calcium carbonate.

A study on Mechanical Properties of Acrylic-casein Hybrid Resins for Surface Protection (표면 보호용 수용성 Acrylic-casein Hybrid Resin의 합성 및 기계적 물성에 관한 연구)

  • Lee, Joo-Youb;Kim, Ki-Jun
    • Journal of the Korean Applied Science and Technology
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    • v.29 no.4
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    • pp.618-625
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    • 2012
  • In this study, prepared synthesis waterborne acrylic resin and water soluble milk casein resin. And than extent of casein contents in acrylic resin. We measured property of these samples by Lamb leather which is coated by acrylic-casein resins. According to measure data for solvent resistance, WAR resin and Hybrid resins had good property. Among this result knew that increase of casein constant did not influence to big change of hybrid resin property. As test of tensile strength, WAR had lowest strength($1.399kg_f/mm^2$) and WAC-3 had highest strength($1.426kg_f/mm^2$). Also we knew that best property of abrasion was WAC-3(69.774 mg.loss). In elongation case, WAR had best property(820%) in this experiment.