• Korean Journal of Environmental Agriculture
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• v.26 no.2
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• pp.171-178
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• 2007

Diffusion and accumulation of ethoprophos in fruit such as apple and two types of pears were examined by dipping them into the solution of ethoprophos. The effective diffusivities of ethoprophos at the skin and flesh of apple and pear were determined by simulation their experimental accumulation curves with calculated ones from the model assuming consecutive diffusion of ethoprophos from skin to flesh. Its effective diffusivity at the flesh with higher content of water were higher, $\sim10^{-10}\;m^2/s$, regardless of the types of fruits, while that at the skin was small, $\sim10^{-12}\;m^2/s$ and increased with the order of 'Niitaka' pear < 'Whangkeumbae' pear < 'Fuji' apple. The variation in the concentration of ethoprophos in its solution did not induce any change in affecting its effective diffusivity at the flesh of 'Whangkeumbae' pear, but the increase in the concentration caused the increase in its effective diffusivity at the skin. The penetration rate of ethoprophos at the skin was an important factor in determining its accumulation rate in fruit.

• The Korean Journal of Ecology
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• v.17 no.3
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• pp.241-249
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• 1994

Leaf diffusive resistance (LDR), stomatal density, length of guard cell and hair density of leaves of 6 oak species were determined under withdrawal of water, and their strategies of drought stress were analyzed by principal component analysis. LDR of Quercus acutissima, Q. aliena and Q. serrata increased earlier than those of the other species at high leaf water potential $({\Psi}_{leaf})$ or low water saturation deficit (WSD), which was an avoidance mechanism reducing damage by water stress. Q. variabilis with low stomatal density, small stomatal size and high hair density had avoidance mechanisms increasing LDR at high $({\Psi}_{leaf})$ However, Q. mongolica and Q. dentata increased LDR at low $({\Psi}_{leaf})$ as xeric species do. Results from principal component analysis on the 15 variables related to strategies of drought stress indicated that the 6 oak species were divided into 2 groups: (1) Q. acutissima, Q. aliena and Q. serrata as mesic habitat species and (2) Q. variabilis, Q. mongolica and Q. dentata as xeric habitat species. Among three xeric species Q. acutissima differed from the other two species in the drought strategies such as high hair density, low stornatal density, high leaf area ratio, stomatal closing at low $({\Psi}_{leaf})$ and small cell wall elasticity. The results could reasonably explain their drought strategies in natural habitat.

• Applied Biological Chemistry
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• v.31 no.2
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• pp.211-216
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• 1988

Brown rices were abrasively milled to give 92% yield, and hydration and cooking rates of brown and milled rices were investigated. Diffusion coefficients of Japonica brown and milled rices at $30^{\circ}C$ were smaller than those of J/Indica counterparts. The bran layer controlled the diffusion coefficients of brown rices at initial stage of hydration. The diffusion coefficients for Japonica and J/lndica milled rices were $107{\sim}114$ and $74{\sim}87$ times greater than those for brown rices, respectively. The terminal points of cooking of brown and milled rices at $110^{\circ}C$ were similar among varieties. The cooking rate constants of milled rices were about 2-fold compared with those of brown rices.

• Applied Biological Chemistry
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• v.31 no.1
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• pp.13-20
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• 1988

The hydration characteristics of four naked baley varieties by different kernel sizes were investigated. The predominant kernel size was 7 mesh, followed by 10 mesh kernel, of which comprised $86{\sim}94%$ of the total kernel. Diffusion coefficients of naked barleys at $40^{\circ}C$ increased as the kernel sizes decreased. The volume increases of naked barleys were linearly related to the moisture gain, regardless variety and kernel size.

• Proceedings of the Korean Vacuum Society Conference
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• 2012.02a
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• pp.169-169
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• 2012

현재 디스플레이 시장은 LCD (Liquid Crystal Display), PDP (Plasma Display Panel) 등과 같이 평판 디스플레이가 주류를 이루고 있으며 현재에는 기존의 디스플레이와는 달리 잘 휘어지고 높은 투과성을 가지는 플렉시블 디스플레이에 대한 연구가 활발히 진행 중이다. 하지만 이러한 플렉시블 디스플레이에 사용되는 플라스틱 기판의 경우 용제에 대한 화학적 저항성 및 기계적인 안정성이 취약한 점과 대기중의 수분이나 산소가 플라스틱 기판을 통하여 소자내로 침투하게 되어 금속전극을 산화시키거나 기포 또는 흑점 등과 같은 비 발광 영역이 확산되어 소자의 수명을 단축시키는 치명적인 단점을 가진다. 이에 본 실험에서는 고밀도 플라즈마 형성이 가능하고 저온공정이 가능한 FTS (Facing Target Sputtering) 장비를 이용하여 Polyethylene terephthalate (PET) 기판위에 낮은 수분 투과율 또는 산소 투과율을 갖는 양질의 무기 산화막을 적층하기 위해 저 투습도 및 기계적인 경도 향상을 위한 비 반응성 박막으로 $Al_20_3$층을 Ar분위기에서 증착하였고 그 위에 박막의 stress 감소, 유연성 향상을 위한 반응성 박막으로 Al을 Ar과 $O_2$를 비율별로 증착하여 비교 실험하였다. 이와 같이 제작된 무기산화막들을 Uv- spectrophotometer를 이용하여 광학적 특성을 조사한 결과 가시광 영역에서 모두 80% 이상의 높은 투과율을 나타내었으며, 그 외 XRD (X-ray Diffraction)를 사용하여 결정성을 확인, SEM (Scanning Electron Microscope), AFM (Atomic Force Microscope)을 이용하여 박막의 구조와 표면향상 및 표면조도를 측정한 결과 모든 박막에서 밀집도가 좋으며 거칠기가 작은 것으로 확인되었다. 마지막으로 수분 투과율(WVTR)을 알아보기 위해 Mocon (Permatran W3/31)장비를 이용하여 측정한 결과 $1.0{\sim}3.0{\times}10^{-3}g/m{\cdot}day$의 낮은 수분 투과율을 볼 수 있었다. 이러한 측정 결과로 볼 때 향후 FTS 장비를 이용하여 양질의 플라즈마를 형성하여 알루미늄 무기산화막을 이용한 고밀도 다층막을 형성하면 더욱 낮은 수분투과율을 갖는 가스차단막을 제작할 수 있을 것으로 보여지며 반도체 소자 및 디바이스의 Pachaging으로도 사용가능 할 것이라 사료된다. 본 연구는 한국산업기술진흥원에서 지원하는 2011년도 지역산업기술개발사업의 연구수행으로 인한 결과물임을 밝힙니다.

• Transactions of the Korean hydrogen and new energy society
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• v.17 no.3
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• pp.347-352
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• 2006

분자전해질연료전지 내의 다공성 기체확산층은 반응가스의 확산과 전자이동통로의 역할을 수행할 뿐만 아니라 전기화학반응에 의해 공기극에서 생성된 수분(기상 혹은 액상)을 반응면으로부터 분리판 채널 방향으로 이동시켜 배출시키는 중요한 역할을 한다. 따라서 물관리를 통한 성능향상을 위해서는 기체 확산층의 구조 및 재료특성에 대한 심도 릴은 연구가 필요하다. 실제 단위전지 체결시 기체확산층은 분리판의 리브(rib)에 의해 눌리게 되며, 그 부분의 기공 크기 분포의 변화를 야기한다. 또한 리브 전단부분에서 탄소 섬유가 손상을 입으며, 탄소 섬유를 감싸고 있는 PTFE coating이 벗겨지게 되어 표면화학적 특성이 달라진다. 본 연구에서는 단위전지 체결 시 분리판에 의해 눌리는 기체확산층의 기공 크기 분포 변화를 측정하였으며, 기공의 소수성에서 친수성으로의 변화를 알아보았다. Mercury 기공 측정기와 PMI 기공 측정기는 큰 기공 분포의 변화에, 질소의 흡/탈착을 이용한 BET 방식은 작은 크기의 기공 분포 변화 관찰에 사용되었다. 체결압에 의한 탄소섬유의 구조적 변화와 아울러 표면의 습윤 정도의 변화를 XPS와 물/알콜 Uptake를 이용해 알아보았다. 이 연구를 바탕으로 물관리를 통한 연료전지 성능 향상을 위한 최적 GDL 선정에 기반이 되는 자료를 도출하였다.

• Applied Chemistry for Engineering
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• v.32 no.1
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• pp.68-74
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• 2021

Gas diffusion layer (GDL) compression is important parameter of polymer electrolyte membrane fuel cell (PEMFC) performance to have an effect on contact resistance, reactants transfer to electrode, water content in membrane and electrode assembly (MEA). In this study, the effect of GDL compression on fuel cell performance was investigated for commercial products, JNT20-A3. Polarization curve and electrochemical impedance spectroscopy was performed at different relative humidity and compression ratio using electrode area of 25 ㎠ unit cell. The contact resistance was reduced to 8, 30 mΩ·㎠ and membrane hydration was increased as GDL compression increase from 18.6% to 38.1% at relative humidity of 100 and 25%, respectively. It was identified through ohmic resistance change at relative humidity conditions that as GDL compression increased, water back-diffusion from cathode and electrolyte membrane hydration was increased because GDL porosity was decreased.

• The Journal of the Convergence on Culture Technology
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• v.7 no.2
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• pp.443-451
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• 2021

This study compared and analyzed the thermal characteristics based on the ratio of moisture content of infected and non-infected Bursaphelenchus Xylophilus by heat of combustion experiment. The experiment results are as follows. The analysisresult of the ratio of water content shows that 19.92% on average for infected Bursaphelenchus Xylophilus and 26.27% for non-infected which decreases water content as the size of conduction, convection, and radiant heat increases in case of fire. As the vaporization of the moisture content accelerates, the average moisture content is reached, and the result is contrary to the thermal characteristics of the wood that the moisture content is not ignited by a heat source when the moisture content is under 15%. The combustion heat analysis result showed that infected and non-infected Bursaphelenchus Xylophilus had no significant difference in combustion heat at about 3%. However, it shows that combustion heat is higher than other species. In conclusion, decreasing in moisture content based on the increasing conduction, convection, and radiant heat is one of the direct causes of ignition, and the lower the moisture content, the faster the fire spreads.

• Korean Journal of Weed Science
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• v.30 no.4
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• pp.445-453
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• 2010

This study was conducted to investigate herbicidal efficacy and diffusibility of halosulfuron-methyl+mefenacet in water treated with 500 g great granule (GG) and 3 kg granule (GR). The 500 g GG was been spreading on the surface of the water within 6 minutes, 53 seconds, and it's active ingredient was diffused in the water bath of $10m^2$ size between 30 and 60 minutes. In addition, the diffusion of 500 g GG was influenced by moisture contents, so it have to immediately use 500 g GG in paddy fields when it was been unpacked. The herbicidal efficacy of the 500 g GG and 3 kg GR of halosulfuron-methyl+mefenacet was excellent to most weed species, but showed different efficacy for the control of Aneilema keisak and Scirpus juncoides, that was may be distribution pattern of active ingredient as different formulation.

• Proceedings of the Korea Concrete Institute Conference
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• 1998.04a
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• pp.303-308
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• 1998

In the concrete structures exposed to environmental conditions at early ages, water movement occurs by moisture diffusion in the concrete, and self-desiccation of concrete is also occurred. Thus the internal relative humidity is changed from moisture diffusion and self-desiccation. Thus the internal relative humidity at each location in concrete includes the decrease by self-desiccation. Especially, for high-strength concrete the much unit cement content is used, so that the non-uniform relative humidity distribution is affected form self-desiccation at early ages. In this study, the internal relative humidity in concrete was measured at early ages, and the moisture diffusion component and self-desiccation component of total relative humidity were discussed.