• Proceedings of the Korean Society of Dyers and Finishers Conference
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• 2012.03a
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• pp.102-102
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• 2012

수분산 폴리우레탄 수지는 기능성이 뛰어나고 다양한 용도로 쓰임이 많기 때문에, 용제형 폴리우레탄 수지를 이용한 환경문제에 대처할 수 있는 대안으로 그 쓰임이 점차 늘어나고 있다. 그러나 수분산 폴리우레탄 수지는 용제형 폴리우레탄 수지에 비해 물리적 특성이 떨어지는 단점이 있다. 그래서 우수한 물리적 특성을 유지하면서 용제형 폴리우레탄 수지를 대체할 수 있는 환경친화성 폴리우레탄 수지에 대한 연구가 많이 이뤄지고 있다. 최근 산업환경 변화에 순응하는 환경 친화적 소재를 사용하여 자동차, 선박, 철도 등 수송용 인테리어 내장재를 구성하는 기술로서, 난연성 및 기계적 물성 유지 기술, 그리고 실내 쾌적감을 부여하기 위한 감성기술 및 심미적 요소를 부여하는 디자인 기술이 가미된 복합 기능화 기술개발이 요구되고 있다. 기존의 자동차용 시트 제품의 대부분은 습식 PU와 PVC를 사용하고 있고, 제조과정에서 용제와 가소제 사용 등으로 인해 환경적으로 많은 문제점이 있으며, 이를 대체하기 위한 노력이 많은 부분에서 이루어지고 있지만, 마땅히 대체할 소재를 찾지 못하고 있는 실정이다. 본 연구에서 제안하는 Frothing 기법을 이용한 친환경 foam 제조기술은 기존의 습식 PU foam과 PVC foam을 대체할 수 있는 기술로서, PUD foam의 기계적 물성 및 가공성이 보완된다면 상업적 용도로 많은 분야에서 활용될 것으로 판단된다.

• Journal of Adhesion and Interface
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• v.16 no.1
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• pp.22-28
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• 2015

In this study, Waterborne polyurethanes (WPU) using Epoxy group were synthesized with polyester polyol, epoxy resin, 4,4-dicyclohexylmethane diisocyanate ($H_{12}MDI$), dimethylol propionic acid (DMPA) to improve the hydrolysis resistance and adhesion. In addition, the properties of the synthesized waterborne polyurethane was evaluated through DSC, UTM, adhesion strength. Tg of the synthesized waterborne polyurethane is shown in the vicinity of $-50^{\circ}C$. Tg were increased with as epoxy resin contents increased. The tensile strength was increased as the content of epoxy resin increases, elongation was decreased. Optimum adhesion and hydrolysis-resistance strength were obtained when polyol : epoxy ratio was 99 : 1.

• Elastomers and Composites
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• v.37 no.1
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• pp.39-48
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• 2002

Linear and crosslinked polyurethane dispersions were synthesized with 2,4-toluene diisocyanate, dimethylol propionic acid, polyoxypropylene glycol and polyoxypropylene glycerin. The structures of these polyurethanes were characterized by $^1H-NMR$ and FT-IR and the properties were measured with DSC, TGA, Instron and AFM etc. In case of linear polyurethane dispersion, the particle size, viscosity and glass transition temperature of polyurethanes increased with higher molecular weight of polyol and the degree of crosslinking. The crosslinked polyurethanes which contains more than 15% of polyoxypropyleneglycerin didn't from dispersion, when mixtures by polyoxypropyleneglycol and polyoxypropyleneglycerin were used as polyols. Thus, we synthesized crosslinked polyurethanes with 5%, 8%, 13% and 15% weight percents of polyoxypropylene glycerin as polyol mixtures.

• Journal of the Korean Applied Science and Technology
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• v.37 no.6
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• pp.1619-1626
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• 2020

In this study, the physical properties of water-dispersible polyurethane resins synthesized with polyammonium phosphate and HMDI were studied by coating film samples and full-grain surfaces. Solvent resistance was found to be unchanged in all samples, and in terms of tensile strength, DPU-AP3 (1.887 kgf/㎟) containing the most ammonium polyphosphate showed the lowest physical properties. The elongation rate was measured as 54 8% in the sample containing a large amount of ammonium polyphosphate. Abrasion resistance was measured as 548 mg.loss of a sample containing a lot of ammonium polyphosphate, and it was confirmed that the physical properties of the blended resin of ammonium polyphosphate and water-dispersible polyurethane were changed.

• Journal of Adhesion and Interface
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• v.23 no.2
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• pp.33-38
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• 2022

In this study, we report on the synthesis and properties of eco-friendly waterborne polyurethane (WPU) according to bio-polyol contents. It was successfully synthesized by the different polyester polyol (DT-1040) and castor oil based polyol (COP) ratios. The glass transition temperature (Tg) of the synthesized bio polyol based waterborne polyurethane was around -70 ℃ and -30 ℃, and it was confirmed that the Tg range was widened as the COP content increased. In addition, as the COP content increased, the tensile strength decreased, and optimum adhesive strength showed when DT-1040:COP ratio was 7:3.

• Journal of the Korean Applied Science and Technology
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• v.38 no.6
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• pp.1533-1542
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• 2021

Eco-friendly polyurethane can be defined as a highly utilized material used in various fields. The various structural properties of the synthesis of isocyanates and polyols provide versatility and customization for use in the manufacturing field. The characteristics of polyurethane vary widely from soft touch coatings to hard building materials like rocks. These mechanical, chemical and biological properties and ease of alignment are drawing tremendous attention not only in the field of research but also in related industries. In order to improve the performance of water-dispersible polyurethane materials, it can be derived through processes such as adjusting the blending of raw materials and adding additives and nanomaterials. This study highlights the basic chemical structure of eco-friendly water-dispersible polyurethane in the fields of medical science, automobiles, coatings, adhesives, paints, textiles, marine industries, wood composite materials, and clothing.

• Journal of the Korean Applied Science and Technology
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• v.32 no.4
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• pp.623-630
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• 2015

Prepared polyurethane resin for buffalo leather coating on surface was synthesized with addition reaction glycerol which had different mole ratio. Mechanical properties of the synthesized polyurethane resin were measured by the SEM, FT-IR, UTM. Growing concerns in the evnironment-friendly polymer resin, we have synthesized low late obtained solvent water dispersion resin to be coating on buffalo leather. The increase of aliphatic trihydric alcohol glycerol mole %, abrasion resistance and tensile strength had demonstrated reduce properties. On the contrary, elongation and flexibility properties had highly increased. In the result of toluene solvent resistance, there was no effect of increased or decreased by the ratio of glycerol mole %.

• Journal of the Korean Applied Science and Technology
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• v.32 no.1
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• pp.100-107
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• 2015

Prepared polyurethane resin for vegetable leather coating on surface was synthesized with glycerol which had different mole ratio. Mechanical properties of the synthesized polyurethane resin were measured by the SEM, FT-IR, UTM. Growing concerns in the evnironment-friendly polymer resin, we have synthesized low late obtained solvent water dispersion resin to be coating on vegetable leather. The increase of aliphatic trihydric alcohol glycerol mole %, abrasion resistance and tensile strength had highly stronger in intensity and longer durability. On the contrary, demonstrated reduce properties of elongation and flexibility. In the result of toluene solvent resistance, there was no effect of increased or decreased by the ratio of glycerol mole %.

• Korean Chemical Engineering Research
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• v.50 no.4
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• pp.632-638
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• 2012

Waterborne polyurethane dispersions (PUD) were synthesized from isophorone diisocyanate (IPDI), polycarbonate diol (PCD) and dimethylol propionic acid (DMPA) as starting materials. Subsequently, waterborne polyurethane-acrylic hybrid solutions were prepared by reacting the PUD with different amounts of the mixture of acrylate monomers, HEMA (2-hydroxyethyl methacrylate) and MMA (methyl methacrylate). As a result, the average particle size of waterborne polyurethane-acrylic hybrid solutions was increased with increasing the addition amounts of acrylate monomers. Also, the prepared coating films from waterborne polyurethane-acrylic hybrid solutions showed better abrasion resistance and chemical resistance than those of pure PUD.

• Korean Chemical Engineering Research
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• v.50 no.3
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• pp.410-416
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• 2012

Waterborne polyurethane dispersions (PUD) were synthesized from isophorone diisocyanate (IPDI), polycarbonate diol (PCD) and dimethylol propionic acid (DMPA) as starting materials. Subsequently, polyurethane-acrylic hybrid solutions were prepared by reacting the PUD with different types of acrylate monomers, such as HEMA (2-hydroxyethyl methacrylate):MMA (methyl methacrylate), HEMA:BA (butylacrylate), HEMA:BMA (butyl methacrylate), HEMA:HEA (2-hydroxyethyl acrylate), HEMA:PETA (pentaerytritol triacrylate) mixture. Also, the effects of acrylate types on the chemical resistance and the abrasion resistance of polyurethane-acrylic hybrid solutions were investigated. The test results showed that the HEMA:MMA mixture had the strongest chemical resistance, while the HEMA:PETA mixture had the strongest abrasion resistance among several types of acrylate mixtures.