• Title/Summary/Keyword: 수리화학적 특성

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Hydrogeochemistry and Origin of $CO_2$ and Noble Gases in the Dalki Carbonate Waters of the Chungsong Area (청송 달기탄산약수의 수리지화학과 탄산 및 영족기체 기원)

  • Jeong, Chan-Ho;Kim, Kyu-Han;Nagao, Keisuke
    • The Journal of Engineering Geology
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    • v.22 no.1
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    • pp.123-134
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    • 2012
  • Hydrochemical analyses, carbon isotopic (${\delta}^{13}C_{DIC}$) analyses, and noble gas isotopic ($^3He/^4He$ and $^4He/^{20}Ne$) analyses of the Dalki carbonate waters in the Chungsong area were carried out to elucidate their hydrochemical composition and to determine the source of $CO_2$ gas and noble gases. The carbonate waters have a pH of between 5.93 and 6.33, and an electrical conductivity 1950 to $3030{\mu}S/cm$. The chemical composition of all carbonate waters was Ca(Mg)-$HCO_3$, with a high Na content. The contents of Fe, Mn, and As in some carbonate waters exceed the limit stipulated for drinking water. The concentrations of major ions are slightly higher than those reported previously. The ${\delta}^{13}C_{DIC}$ values range from -6.70‰ to -4.47‰, indicating that the carbon originated from a deep-seated source. The $^3He/^4He$ and $^4He/^{20}Ne$ ratios vary from $7.67{\times}10^{-6}$ to $8.38{\times}10^{-6}$ and from 21.32 to 725.7, respectively. On the $^3He/^4He$ versus $^4He/^{20}Ne$ diagram, the noble gas isotope ratios plot in the field of a deep-seated source, such as mantle or magma. We therefore conclude that $CO_2$ gas and noble gas in the Dalki carbonate waters originated from a deep-seated source, rather than an inorganic $CO_2$ origin as suggested in a previous study.

Influence of Groundwater on the Hydrogeochemistry and the Origin of Oseepchun in Dogye Area, Korea (도계지역 오십천에서의 지하수 영향분석 - 수리지화학적 특성과 기원)

  • Hwang, Jeong Hwan;Song, Min Ho;Cho, Hea Ly;Woo, Nam C
    • Economic and Environmental Geology
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    • v.49 no.3
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    • pp.167-179
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    • 2016
  • Water quality of Oseepchun, Dogye area, was investigated quantitatively for its origin and hydrogeochemistry in relation to the influence of groundwater. Groundwater appears to be the principal source of Oseepchun from the water-quality monitoring data including redox potentials, composition of dissolved ions and their correlations, hydrogen and oxygen stable isotopic ratios, and the distribution and occurrence of contaminants. Water-quality type of the surface water was grouped by the water-rock interactions as $Ca-HCO_3$ type originated from carbonated bed-rocks in the Joseon Supergroup, (Ca, Mg)-$SO_4$ type related with dissolution of surfide minerals in coal beds of Pyeongan Supergroup, and (Ca, Mg)-($HCO_3$, $SO_4$) type of the mixed one. Locally water pollution occurs by high $SO_4$ from mine drainage and $NO_3$ from waste-treatment facility. Intensive precipitation in summer has no effect on the water type of Oseepchun, but increases the inflow of nitrate and chloride originated from land surface. Results of this study direct that groundwater-surface water interaction is intimate, and thus surface-water resource management should begin with groundwater characterization.

Treatment of AP Solutions Extracted from Solid Propellant by NF/RO Membrane Process (NF/RO 멤브레인 공정을 적용한 고체추진제에서 추출된 암모늄 퍼클로레이트 (AP) 처리 연구)

  • Kong, Choongsik;Heo, Jiyong;Yoon, Yeomin;Han, Jonghun;Her, Namguk
    • Membrane Journal
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    • v.22 no.4
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    • pp.235-242
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    • 2012
  • Ammonium perchlorate (AP) is primarily derived from the process of liquid incineration treatment when dismantling a solid rocket propellant. A series of batch dead-end nanofiltration (NF) and reverse osmosis (RO) membrane experiments were conducted to explore the retention mechanisms of AP under various hydrodynamic and solution conditions. Low levels of silicate type of siloxane had been detected through the GC/MS and FTIR analysis of liquid solutions extracted from solid ammonium perchlorate composite propellant (APCP). It is indicated that NF/RO membranes fouling in the presence of APCP was mainly attributed to the AP interactions because the concentration of silicate type of siloxane was negligible compared to that of AP. The osmotic pressure of AP was presumably resulted in the flux declines ranging from 13 to 17% in the case of the application of low-pressure (551 and 896 kPa for NF and RO) compared to those in application of high-pressure. The retention of AP by NF/RO membranes significantly varied from approximately 10 to 70% for NF and 26 to 87% for RO, depending on the operating and solution water chemistry conditions. The results suggested that retention efficiency of AP was fairly increased by reducing concentration polarization (i.e. application of low-pressure and stirring speed of 600 rpm) and increasing the pH of a solution. The result of this study was also consistent with the previous modeling of 'solute mass transfer of NF/RO membranes' and demonstrated that hydrodynamic and solution water chemistry conditions are to be a key factor in the retention of AP by NF/RO membranes.

Case Studies of Site Investigation Factors and Methods for Site Selection for High-Level Radioactive Waste Disposal (고준위방사성폐기물 처분 부지선정을 위한 조사인자 및 조사기법에 대한 국외사례 분석)

  • Hyo Geon Kim;Si Won Yoo;Dae Seok Bae;Soo Hwan Jung;Ki Su Kim;Jun Kyum Kim;Man Ho Han;Junghae Choi
    • The Journal of Engineering Geology
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    • v.33 no.4
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    • pp.611-626
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    • 2023
  • Overseas examples of the characterization stage of site selection proposed by the International Atomic Energy Agency were reviewed to highlight the factors necessary for consideration in the deep disposal of high-level radioactive waste. Studies in Sweden, Finland, the USA, and Canada were considered. Site investigations in Sweden and Finland commonly covered the fields of geology, hydrogeology, and hydrogeochemistry using similar field investigation techniques. The USA considered survey groups and factors under pre- and post-lockdown guidelines, as well as those for desaturated and saturated surveys. involving geophysical, hydrological, hydrogeological, hydrogeochemical, mechanical/physical, and thermal-characterization investigations. Canada provided a list of investigative methods for both preliminary and detailed site assessments including geological, physical, boring, hydrological, laboratory testing, and chemical analysis studies. Results of this study should elucidate site-selection investigation factors and survey methods applicable to Korea.

Ecohydraulics - the significance and research trends (생태수리학의 의의와 전망)

  • Woo, Hyoseop
    • Journal of Korea Water Resources Association
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    • v.53 no.10
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    • pp.833-843
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    • 2020
  • Ecohydraulics is a newly born discipline in the early 1990s by the interdisciplinary approach combined with aquatic ecology in one discipline and geomorphology, hydrology, and fluid hydrodynamics in another. Major areas of ecohydraulics can be delineated as habitat hydraulics (including environmental flow), vegetation hydraulics, eco-corridor hydraulics, eutrophication hydraulics, and ecological restoration hydraulics. Reviews of relevant international journals and literature reveal that ecohydraulics has remained in the limited areas of fish response, hydraulic modeling, and physical habitat response. It has not reached a truly interdisciplinary stage. Literature reviews in Korea reveal that only 3% of the total number of the papers listed in the Journal of KWRA during the last 24 years is related to ecohydraulics. It is about 20% of the total listed in the Journal of Ecology and Resilient Infrastructure. Most of those related to ecohydraulics in Korea concern vegetation hydraulics, habitat hydraulics, and ecological restoration hydraulics. In contrast, dynamic flow modeling areas, including turbulence, fauna motion simulation, and eutrophication hydraulics, are not found. Areas of further research in ecohydraulics in Korea may be specified as follows: 1) environmental flows adapted to the traits of the rivers in Korea, 2) development of the dynamic floodplain vegetation models (DFVM) to assess the changes from the white river to green river, 3) development of the eutrophication hydraulic model to predict the freshwater algal blooms, and 4) development of the models to evaluate the physical, chemical, and biological impacts of the stream restoration, decommissioning and removal of old weirs or small dams.

호산성 방선균과 내중성 방선균

  • 강희일
    • The Microorganisms and Industry
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    • v.15 no.2
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    • pp.2-7
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    • 1989
  • Waksman과 Heinrich(1943)에 의해 Streptomyces속이 기술되고 actinomycin, streptomycin등의 많은 항생물질이 발견되면서 방선균(actinomycetes)은 산업적으로 중요한 미생물이 되어 왔으며, 근래에는 항생물질 뿐만 아니라 효소, 효소저해제, 면역조절물질 등 소위 생리활성물질(bioactive compound)의 생산균으로서 주목을 받고 있다. 그러나 지금까지 대부분의 스크리닝이나 연구의 대상은 주로 중성 pH에서 잘 자라는 호중성 방선균(neutrophilic actionmycetes)이었지만 산성이나 알칼리성 토양, 고온, 고열, 고압 등과 같은 특수환경에서 분리된 균주나 희귀 방선균(rare actinomyces)에 대한 관심도 점점 높아지고 있다. 산성 토양에서 분리된 방선균에 관한 연구는 Jensen(1928)의 연구로부터 시작하였지만 Lonsdale(1985)이 침엽수림, 산성탄광 등에서 분리된 방선균을 수리분류할 때까지 활발하게 이루어지지 못하였다. 본 고에서는 호산성 방선균위 분포, 생리적 특성, 수리분류학적 연구, 화학적 분류(chemotaxonomy), 산업적 응용가능성 등을 살펴보고자 한다.

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A Study on the Applicability of Machine Learning Algorithms for Detecting Hydraulic Outliers in a Borehole (시추공 수리 이상점 탐지를 위한 기계학습 알고리즘의 적용성 연구)

  • Seungbeom Choi; Kyung-Woo Park;Changsoo Lee
    • Tunnel and Underground Space
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    • v.33 no.6
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    • pp.561-573
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    • 2023
  • Korea Atomic Energy Research Institute (KAERI) constructed the KURT (KAERI Underground Research Tunnel) to analyze the hydrogeological/geochemical characteristics of deep rock mass. Numerous boreholes have been drilled to conduct various field tests. The selection of suitable investigation intervals within a borehole is of great importance. When objectives are centered around hydraulic flow and groundwater sampling, intervals with sufficient groundwater flow are the most suitable. This study defines such points as hydraulic outliers and aimed to detect them using borehole geophysical logging data (temperature and EC) from a 1 km depth borehole. For systematic and efficient outlier detection, machine learning algorithms, such as DBSCAN, OCSVM, kNN, and isolation forest, were applied and their applicability was assessed. Following data preprocessing and algorithm optimization, the four algorithms detected 55, 12, 52, and 68 outliers, respectively. Though this study confirms applicability of the machine learning algorithms, it is suggested that further verification and supplements are desirable since the input data were relatively limited.

Control of physical properties and characteristics of soil through combination of ingredients of clay (태토 성분조합을 통한 도자기용 흙의 물성조절 및 특성변화)

  • Kim, Duhyeon;Lee, Haesoon;Kim, Jihye;Han, Minsu
    • Conservation Science in Museum
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    • v.25
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    • pp.35-50
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    • 2021
  • This study analyzed the basic properties of soil material gathered around Maegok-dong in Gwangju, Gyeonggi-do Province (hereafter, "Maegok soil") and the physicochemical changes in the Maegok soil resulting from the addition of other clay materials in order to present scientific information about the properties of clay available for pottery production. Gravel, coarse sand, and fine sand account for 73% of the total mass of the Maegok soil. Therefore, it required refinement through sifting in order to serve in pottery clay. After sifting, the amount of silt and clay in the soil increased to 95% of the total mass. However, since it lacked plasticity and viscosity, buncheong soil was added. When it was mixed with bungcheong soil at a ratio of 7:3, Maegok soil improved as pottery clay as its viscosity increased, demonstrating compositional properties appropriate for ceramic clay even after firing. Further, its water-absorption rate was decreased to 0.40. This means that soil gathered from anywhere can be used for pottery-making by refining its original properties and through mixture with clay with specific components which help the pottery maintain its shape even after firing.

A Study on the Students' Cognition of Chemistry in Science High School by Factor Analysis of Mathematics and Science Achievement (수학·과학 성취도의 요인 분석으로 본 과학고등학교 학생들의 화학 교과에 대한 인식 연구)

  • Shin, Dong-Seon;Choi, Hojun;Kim, Bong Gon
    • Journal of the Korean Chemical Society
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    • v.64 no.2
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    • pp.119-129
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    • 2020
  • For effective teaching-learning activities for students with diverse talents in science high schools, it is important for teachers to understand students' individual differences in perceiving and processing information in the natural world, depending on the students' various talents and subject characteristics. The purpose of this study is to examine the students' cognition of chemistry in science high school through correlations and factor analysis of mathematics/science achievement. In addition, this study attempted to examine the cognition of chemistry subject according to R&E classes. The main participants of the study were freshmen of G science high school (296 students) who entered after three times of curriculum reforms and new admission processes and the students in two other science high schools in Gyeongnam and Ulsan were included. The correlation and factor analysis were conducted by exploratory factor analysis by IBM SPSS Statistics 25 programs. The results of this study were as follows: First, in the correlation analysis between mathematics and science achievement, it was confirmed that the Pearson's coefficient of chemistry showed higher positive correlation coefficient than that of other science subjects. Second, in the factor analysis of mathematics and science achievements, it was found that the factor indicators were divided into two factors as logical-mathematical (mathematics and physics) and naturalistic (life science and earth science). Third, in the factor analysis, it was confirmed that the chemistry is recognized as the subject that requires both logical-mathematical and naturalistic intelligence. Finally, it was confirmed that students' cognitions of chemistry subject were found to differ according to the R&E classes. In other words, the participants of R&E chemistry class, unlike other students, were found to recognize chemistry as the subject that logical-mathematical intelligence is needed.

Hydrogeologic and Hydrogeochemical Assessment of Water Sources in Gwanin Water Intake Plant, Pocheon (포천 관인취수장 수원에 대한 수리지질 및 수리지구화학적 평가)

  • Shin, Bok Su;Koh, Dong-Chan;Chang, Yoon-Young
    • Journal of Environmental Impact Assessment
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    • v.25 no.3
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    • pp.209-221
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    • 2016
  • The section from water source to 2.6km upper stream of Hantan River is protected as the drinking water quality protection area according to guidelines of Ministry of Environment, because water source of the Gwanin water intake plant has been known the river. However, opinions were consistently brought up that the standard of water source protection zone must be changed with using underground water as water source because of contribution possibility of underground water as the water source of Gwanin water intake facility. In this regard, hydrogeologic investigation including resistivity survey and hydrogeochemical investigation were carried out to assess water source and infiltration of contaminant for the plant. Quaternary basaltic rocks (50m thick with four layers) covered most of the study area on the granite basement. As the result of the resistivity survey, it is revealed that permeable aquifer is distributed in the boundary of two layers: the basaltic layer with low resistivity; and the granite with high resistivity. Considering of outflow from Gwanin water intake facility, the area possessing underground water was estimated at least $5.7km^2$. The underground water recharged from Cheorwon plain was presumed to outflow along the surface of unconformity plane of basalt and granite. Based on field parameters and major dissolved constituents, groundwater and river water clearly distinguished and the spring water was similar to groundwater from the basaltic aquifer. Temporal variation of $SiO_2$, Mg, $NO_3$, and $SO_4$ concentrations indicated that spring water and nearby groundwater were originated from the basaltic aquifer and other groundwater from granitic aquifer. In conclusion, the spring of the Gwanin water intake plant was distinguished from river water in terms of hydrogeochemical characteristics and mainly contributed from the basaltic aquifer.