• Title/Summary/Keyword: 속도의존성

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Kinetic Study on the Gelatinization of Barley Starch (보리전분의 호화에 관한 속도론적 연구)

  • Mok, Chul-Kyoon;Lee, Sang-Hyo;Nam, Young-Jung;Min, Byong-Yong
    • Korean Journal of Food Science and Technology
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    • v.17 no.6
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    • pp.409-414
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    • 1985
  • The gelatinization kinetics of barley starch in dilute system (1% w/v concn.) at the temperature range of $60{\sim}95^{\circ}C$ was investigated. The gelatinization rate was extremely temperature dependent. The gelatinization at the temperature above $90^{\circ}C$ was an one step 1st order reaction throughout the gelatinization time, but that below $85^{\circ}C$ consisted of two stages which showed different reaction rates. The reaction rate of the 1 st stage was greater than that of the 2nd stage. The activation energy of the 1 st stage was 31.93 Kcal/g mole and those of the 2nd stage were 78.49 and 23.41 Kcal/g mole above and below $75^{\circ}C$, respectively.

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Recycling of Crosslinked Polypropylene and Crosslinked Polyethylene in Supercritical Methanol (초임계 메탄올에서 가교폴리프로필렌과 가교폴리에틸렌의 재활용성 비교)

  • Lee, Hong-Shik;Jeong, Ju Hyeong;Hong, Soon Man;Koo, Chong Min;Cho, Hang-Kyu;Lee, Youn-Woo
    • Korean Chemical Engineering Research
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    • v.50 no.1
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    • pp.88-92
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    • 2012
  • Decrosslinking of crosslinked polypropylene(XLPP) in supercritical methanol was investigated compared with that of crosslinked polyethylene(XLPE). Effect of reaction temperature and initial gel contents was studied using a batch reactor. Gel contents of samples before and after reaction were measured for quantitative analysis. As reaction temperature and initial gel contents increased, the decrosslinking rate increased. The rate of decrosslinking reaction is dependent linearly on the gel contents. Experimental results indicated that the decrosslinking of XLPP was faster than that of XLPE, and it was confirmed quantitatively by the calculation of kinetic constants. In conclusion, it is considered that XLPP has better recyclability than XLPE.

Measurements on Effects of Locations of Obstacles in an Explosion Chamber

  • Han, Jae-Beom;Lee, Young-Soon;Park, Dal-Jae
    • Journal of the Korean Institute of Gas
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    • v.12 no.3
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    • pp.68-74
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    • 2008
  • Measurements were performed to investigate the effects on flame and pressure development by varying locations of multiple obstacles in a top-venting explosion chamber. The chamber dimension was 1000 mm in height with a $700\;{\times}\;700\;mm^2$ cross-section and a rectangular vent area of $700\;{\times}\;700\;mm^2$. Three different multiple obstacles with blockage ratio of 30% were used by changing from 200 mm, 500 mm to 800 mm in heights within the chamber. Temporally resolved flame front images were recorded by a high speed camera to investigate the interaction between the propagating flame and the obstacles. The results showed that the triangular bar caused the fastest flame developments at given times whereas the lowest was obtained with the cylindrical bar. It was also found that local flame displacement speeds of different obstacles were sensitive to the locations of obstacles. The local speed becomes larger in going from 200 mm, to 500 mm and to 800 mm in heights. The obstacles in height of 800 mm yielded the highest overpressure whereas the lowest was in height of 200 mm.

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Kinetic Study for Hygroscopic Behavior of Freeze Dried Soy Paste Powder (동결건조 분말된장의 흡습 거동에 대한 속도론적 연구)

  • Hwang, Eung-Soo;Lee, Chul-Won;Yu, Ju-Hyun;Lee, Shin-Young
    • Korean Journal of Food Science and Technology
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    • v.19 no.3
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    • pp.231-238
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    • 1987
  • Two kinds of soy pastes with different colors (reddish brown and yellowish white) were dehydrated by freeze drying in powder form. Hygroscopic behaviors of powdered soy pastes were investigated under the conditions of various water acitivities (0.11-0.88) and three different temperatures (25,40 and $50^{\circ}C$), and presented a kinetic and thermodynamic interpretatons in the view point of qualities and storage stability. Moisture absorption isotherms of powdered soy pastes were of type II according with BET classification and can be described by the Henderson's empirical equation. The safe storage moisture levels calculated by the Laurie's equation were ranging from 5.5 to 3.98% dry basis with oaring temperatures. The moisture absorption process for powdered soy paste followed the Ist order kinetic in the difference of equilibrium moisture content and arbitrary moisture content and the initial step was characterized by very fast absorption of moisture. The change of, dispersion capacity and color difference for powdered soy paste were extremely dependent upon water activity under the storage and the maximum stability was found at safe storage moisture levels. Also, the variation of thermodynamic parameters with moisture content was significant at safe storage moisture content levels and suggested d the considerable correspondence to storage stability of powdered soy paste.

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Quantitative Incision Skill Assessment for Computer-based Surgery Simulator (컴퓨터 기반 수술 훈련 시뮬레이터를 위한 정량적 절개 숙련도 평가 기법)

  • Kim, Seok-Yeol;Park, Jin-Ah
    • Proceedings of the Korean Information Science Society Conference
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    • 2011.06b
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    • pp.282-285
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    • 2011
  • 효과적인 수술 훈련 시뮬레이터를 구축하기 위해서는 사실적인 훈련 환경을 제공하는 것뿐만 아니라 훈련 결과를 바탕으로 사용자의 숙련도를 객관적으로 측정하고 평가하는 과정 또한 중요하다. 이를 위해 본 연구는 수술 훈련 중 큰 비중을 차지하는 절개 동작에 대한 정량적 평가 척도를 제공하는 것을 목표로 한다. 사용자가 가상 장기 모델에 대해 절개를 수행하는 동안 평가 시스템은 절개 경로와 깊이를 일정 간격으로 샘플링하여 저장하고, 이를 두 곡선 간의 유사성 측정 알고리즘을 통해 훈련 시나리오 상에 정의된 표준 절개 경로와 깊이, 속도를 각각 비교한다. 이렇게 계산된 두 경로 사이의 거리가 가까울수록 유사성이 높은 것으로 간주하며, 사전에 설정된 기준치 이상의 유사성을 기록할 경우 훈련 목표를 충족한 것으로 판단할 수 있다. 본 연구에서는 단순 거리 측정에 의존한 일반적인 경로의 유사성 판단 알고리즘의 문제점을 제시하고, 전체 절개 경로의 길이 대비 현재까지 진행된 정도를 매개변수로 하는 방법을 이용하여 절개 경로의 방향을 고려한 유사성 측정 알고리즘을 제안하였다. 이와 같이 정량적이며 자동화된 절개 숙련도 평가 기법을 제안함으로써 사용자의 훈련 결과에 대해 보다 객관적인 피드백을 제공 할 수 있다.

Deposition of 3C-SiC Films by Plasma-enhanced Chemical Vapor Deposition (I): Deposition Behaviors of SiC with Deposition Parameters (PECVD법에 의한 3C-SiC막 증착(I): 증착변수에 따른 SiC 증착거동)

  • 김광호;서지윤;윤석영
    • Journal of the Korean Ceramic Society
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    • v.38 no.6
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    • pp.531-536
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    • 2001
  • SiCl$_4$/CH$_4$/H$_2$계를 사용한 플라즈마 화학증착법(PECVD)으로 실리콘(100) 기판 위에 3C-SiC막을 117$0^{\circ}C$~1335$^{\circ}C$의 온도범위에서 증착하였다. 증착온도, 유입가스비, R$_{x}$ [=CH$_4$/(CH$_4$+H$_2$)], 그리고 r.f. power를 변화시켜 증착막의 결정성에 대해 검토하였다. Thermal CVD에 비해 PECVD법은 박막의 증착속도를 향상시켰다. 증착된 3C-SiC은 (111) 면으로 최대의 우선배향성을 지님을 알 수 있었다. 실리콘 기판 위의 3C-SiC막의 결정성은 R$_{x}$값에 의존하였으며, R$_{x}$가 감소할수록 결정성이 더욱 향상되었다. Free Si가 3C-SiC막과 함께 증착되었으나, 증착온도와 r.f power가 증가함에 따라 free Si의 함량은 감소하였다. 증착온도 127$0^{\circ}C$, 유입가스비 R$_{x}$=0.04, r.f. power가 60W에서 비교적 결정성을 가진 3C-SiC막을 얻을 수 있었다.

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Effect of Loading Rate on the Deformation Behavior of SA508 Gr.1a Low Alloy Steel and TP316 Stainless Steel Pipe Materials at RT and 316℃ (상온과 316℃에서 SA508 Gr.1a 저합금강 배관과 TP316 스테인리스강 배관의 변형거동에 미치는 하중속도의 영향)

  • Kim, Jin Weon;Choi, Myung Rak
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.39 no.4
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    • pp.383-390
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    • 2015
  • This study conducted tensile tests on SA508 Gr.1a low alloy steel and SA312 TP316 stainless steel piping materials under various strain rates at room temperature (RT) and $316^{\circ}C$ to investigate the effects of loading rate on the deformation behavior of nuclear piping materials. At RT, the deformation behavior for both pipe materials showed a typical loading rate dependence, i.e., the strength increased and the ductility decreased as the loading rate increased. At $316^{\circ}C$, however, the strength and elongation of SA508 Gr.1a low alloy steel decreased as the loading rate increased, and its reduction of area non-linearly varied with the loading rate. For SA312 TP316 stainless steel, the strength, elongation, and reduction of area at $316^{\circ}C$ were almost the same regardless of the loading rate. At both temperatures, the strain hardening capacity was nearly independent of the loading rate for SA508 Gr.1a low alloy steel, while it decreased with increasing loading rate for SA312 TP316 stainless steel.

Rheological Properties of Spray Dried Protein-bound Polysaccharide Powder from Agaricus blazei Murill (아가리쿠스버섯에서 분리한 단백다당류 분무건조분말의 유동특성)

  • Hong, Joo-Heon;Youn, Kwang-Sup
    • Food Science and Preservation
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    • v.13 no.5
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    • pp.555-562
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    • 2006
  • This study was conducted to investigate the rheological properties of protein-bound polysaccharide powders (SD-1, 2, 3) using ultrafiltration (UF) and spray drying (SD) process from Agaricus blazei Murill. The calculated weight-average molar mass (Mw) in the positions at 29.7 mL (for SD-1), and at 27.8 mL (for SD-2), and at 18.7 mL (for SD-3) was $8.2{\times}10^3,\;9.6{\times}10^4$, and $5.9{\times}10^6g/mol$, respectively. As concentration increased the solution showed higher pseudoplasticity where the pseudoplasticity decreased as temperature increased. The flow behaviors of spray dried powder solutions were more fitted to Herschel-Bulkley equation than Power law equation. Apparent viscosity of SD-2 was more temperature-dependent than that of SD-1 and 3. However, the SD-3 tended to be more concentration-dependent than SD-1 and 2 as temperature increasing.

Effects of Glucose and Acetic Acid on the Growth of Recombinant E.coli and the Production of Pyruvate Dehydrogenase Complex-E2 Specific Human Monoclonal Antibody (유전자 재조합 대장균의 세포성장과 Pyruvate Dehydrogenase Complex-E2 특이성 인간 모노클론 항체 생산에 대한 포도당과 초산의 영향)

  • 이미숙;전주미;차상훈;정연호
    • KSBB Journal
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    • v.15 no.5
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    • pp.482-488
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    • 2000
  • The Fab fraction of PDC-E2 specific human monoclonal antibody was produced using recombinant E. coli, and the effects of glucose and acetate were investigated to develop an optimal strategy for recombinant human antibody production. Higher glucose concentration in the culture media resulted inn higher cell growth and glucose consumption rate, which in turn resulted in an increased acetate production rate. When glucose was depleted, cells began to consume acetate as an energy source, and this consumption rate depended on the glucose concentration. When the residual glucose concentration was high, the accumulation of acetate was accelerated due to an increase in the acetate production rate and a decrease in the acetate consumption rate. Futhermore, it was found that a high accumulation of acetate, accompanied by a high glucose concentration, inhibited human antibody formation; the critical acetate concentration was $0.6g/\ell$. During production, a high glucose concentration enhanced cell growth, but inhibited antibody formation due to catabolic repression. Therefore, it is important to keep the concentration of both glucose and acetate as low as possible to increase antibody production after induction. Accordingly, it is important to accurately control the concentration of glucose and acetate in the culture media to obtain high cell densities and high productivity levels of recombinant human antibody.

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Study on the Thermostability of Contractile Myofibrillar Proteins from Fish Species (어류의 수축성 근섬유단백질의 열안정성에 관한 연구)

  • Yang, Ryung;Hong, Sang-Pill;Shin, Wan-Chul;Song, Jae-Chul
    • Korean Journal of Food Science and Technology
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    • v.20 no.6
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    • pp.862-867
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    • 1988
  • Myofibrillar proteins were prepared from cold(pollack, salmon) and warm current fish(shark), and their thermostabilities were compared. Thermodynamic data for inactivation of myofibrillar proteins, such as D-value, Kd-value, revealed that thermostability of myofibrillar proteins from warm current fish was higher than that from cold current fish.

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