• Applied Biological Chemistry
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• v.43 no.1
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• pp.39-45
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• 2000

The stability of vitamin A, $B_1,\;B_2,\;B_6$, C in aqueous multivitamin solutions was carried out by means of estimation of reaction velocity and the results are described in this paper. The stability of vitamin A, $B_1$ and C due to thermal degradation method in aqueous multivitamin solutions was evaluated at 40, 50, 60 and $70^{\circ}C$ up to 40 days. The shelf-lives of vitamin A, B₁ and C in this preparation, calculated using the Arrhenius equation, were 1493, 449 and 639 days at $25^{\circ}C$ respectively. Examination was made on the effect of initial concentration of vitamin $B_2$$(C_0)$ on light fading of vitamin $B_2$ in aqueous multivitamin solutions and it was found that the fading progressed according to the following formula : $-{\frac {dc}{dt}}=K_c\;{\frac C{C_0}}$ where Kc is apparent light-fading rate constant relate to $C_0$. Photodecomposition of vitamin $B_6$ in aqueous multivitamin solutions was apparently first order kinetics and was stable in polyethylene>brown color>glass container to sunlight. Photodecomposition of vitamin $B_6$ in four seasons also investigated.

• Korean Chemical Engineering Research
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• v.59 no.2
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• pp.276-280
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• 2021

The oxygen transfer rate at the liquid surface of the reciprocally shaking vessel was studied. The required power of the reciprocally shaking vessel was not proportional to the shaking frequency, unlike the rotational shaking vessel, and the liquid level suddenly fluctuated greatly at a certain frequency as the flow pattern in the vessel was a left and right wave flow different from that of the rotational shaking that has a rotational flow. The effect of the shaking frequency on the required power in the reciprocally shaking vessel was very complex, such as less power required than the rotational shaking vessel when the shaking frequency is more than 3 s-1, but the required power for the range of the generated rotational flow in the reciprocally shaking vessel could be correlated with the equation that was reported for the rotational shaking vessel. The kLa (mass transfer capacity coefficient) in the reciprocally shaking vessel also increased in a complex pattern because the required power for shaking was not consumed in a simple pattern, unlike kLa in the rotational shaking vessel, which increases linearly with increasing frequency. The kLa of the reciprocally shaking vessel was larger than the kLa of the rotational shaking vessel, and as the kLa value increased, the difference between them increased sharply. As a result, the oxygen transfer rate in the reciprocal motion was greater than that of the rotational motion, and could be correlated with the required power per unit volume.

• Phonetics and Speech Sciences
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• v.14 no.4
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• pp.25-33
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• 2022

This study investigates the relationships between rhythm and fluency indices and listeners' ratings of the rhythm and fluency of Korean college students' English paragraph reading. 17 university students read and recorded a passage from "The North Wind and the Sun" twice before and after three months of English pronunciation instruction. Seven in-service and pre-service English teachers in graduate school assessed the rhythm and fluency of the utterances. In addition, the values of 14 indices of rhythm and fluency were extracted from each speech and the relationships between the indices and the listeners' ratings were analyzed. The rhythm indices of the speakers in this study did not differ significantly from those of native English speakers presented in previous studies in %V, VarcoV, and nPVIV, but were higher in ΔV, ΔC, and VarcoC and lower in speech rate. The level of rhythm and fluency demonstrated by Korean college students was comparable, at least in terms of objective values for certain indices. The fluency indices, such as percentage of pauses, articulation rate, and speech rate, significantly contributed more to predicting both rhythm and fluency ratings than the rhythm indices.

• 한국신재생에너지학회:학술대회논문집
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• 2010.06a
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• pp.59.2-59.2
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• 2010

결정형 태양 전지의 보급화를 위하여 고순도 실리콘을 저렴하게 제조할 수 있는 기술 개발이 필요하다. 본 연구에서는 고순도 실리콘을 경제적으로 제조하기 위하여 대역 정제에 의한 일방향성 응고법을 이용한 정련 연구를 진행하였으며, 응고 속도와 고 액상의 온도 구배가 정련도에 미치는 영향을 분석 하였다. 본 실험에 사용된 일방향 응고장치는 실리콘 용탕이 장입된 도가니 하부의 열 교환기를 통한 냉각에 의해 용탕 하부에서 상부 방향으로의 일방향성 응고가 진행되며, 응고 진행시 용탕의 흔들림에 의한 정련능의 감소를 방지하기 위해 가열 영역이 이동하는 Stober 공정을 채택하였다. 가열 영역은 실리콘 용융을 위한 상부 가열 영역과 응고 진행시 응고부의 온도 제어를 위한 하부 가열 영역으로 구성되어 있으며, 두 가열 영역의 온도 제어를 통해 응고중인 실리콘의 고 액상의 온도 구배를 조절하였다. 일방향 응고에 의한 정련법에서 고 액상의 온도 구배가 증가할수록 2차 수지상의 발달이 감소하고, 주상정의 수지상 형태를 유지하게 되어 고 액 공존영역에서 액상 영역으로의 확산이 원활하게 이루어져 분배계수를 이용한 정련도가 좋아지게 되며, ICP 분석을 통해 온도 구배의 증가에 따라 정련능이 증가하는 양상을 확인 할 수 있었다. 고 액상의 온도 구배의 조절을 통한 공정 시간 대비 정련도의 향상을 통해 결정형 태양전지의 생산성의 증가를 통한 저가화를 이룰 수 있을 것이다.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.12 no.2
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• pp.91-95
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• 2002

$TiO_2$ nanopowder was successfully prepared using a titanium tetra-isopropoxide. Subsequently, the effect of pH on the characteristics of the prepared $TiO_2$ nanopowder was evaluated depending on the amounts of the catalysts such as HCI and NH40H. The morphology and phase transformation of $TiO_2$ powder prepared by hydrolysis of titanium tetraisopropoxide were strongly influenced by the presence of the catalysts. In the case of using $NH_4$OH, the morphology of the $TiO_2$ powder exhibited powder form. For the HCI catalyst, it showed bulk or granule form. The phase transformations of amorphous $Ti(OH)_4$ to anatase $TiO_2$ and the anatase to rutile was significantly influenced by the kind and amount of the catalysts.

• Proceedings of the Korea Water Resources Association Conference
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• 2006.05a
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• pp.1281-1285
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• 2006

하천제방 붕괴시 홍수파가 제내지에서 거동하는 양상을 파악하는 것은 홍수피해를 저감하는 데 있어서 매우 중요하다. 실제 제내지에서의 범람형태에 크고, 작은 영향을 미치는 인자들은 제내지 지형 및 구조물과 초기 제내지범람상태, 하도형태, 홍수수문곡선, 제방붕괴시 붕괴면 경사 및 붕괴시간 등 많이 있으나, 본 연구에서는 제방붕괴폭과 붕괴지속시간에 따른 홍수파의 형태, 유속, 수심, 방향 등의 일반적인 법칙성을 찾고자 한다. 본 연구에서 사용된 실험수조의 전체 크기는 가로 30m, 세로 30m이며, 수조 내부에 제내지, 제방, 하도를 제작하였다. 그림 1에서 보는 바와 같이 하도는 폭 5m, 길이 30m이며, 제내지는 폭 28m, 길이 24m이다. 하도와 제내지의 하상은 수평이며, 시멘트 모르타르로 표면을 처리하였다. 제방붕괴 재현장치는 최대붕괴폭 4m, 높이 0.6m가 되도록 하였으며, 하도의 중간지점에 설치하였다. 하도에서의 초기수심은 $h_o$이며, 제내지는 건조상태이다. 제방붕괴장치의 개방속도는 $0{\sim}18cm/sec$범위에서 조정이 가능하다. 실험결과, 제방붕괴폭과 제방붕괴지속시간은 제내지에서의 홍수파 전면(wave-front)의 이동속도와 제내지에서의 시간별 수심변화에 영향을 주는 것으로 나타났으며, 제내지에서의 최대수심은 제방붕괴폭과 제방붕괴 지속시간에 의한 영향이 거의 없는 것으로 나타났다.

• Journal of Korean Tunnelling and Underground Space Association
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• v.6 no.1
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• pp.41-50
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• 2004

The numerical investigation for the effects of blasting-induced vibration on adjacent dam and pore water pressure fluctuation was conducted through solid-water coupled analysis under dynamic loading. The stability of dam was examined by peak particle velocity of core. Pore water pressure distributions were calculated by steady state flow analysis using coupled analysis on ground water and blasting-induced vibration. The influence of pore water pressure and the effective stress distribution in the ground were also investigated. Furthermore, effective stress alteration was examined by applying Finn & Byrne Model to monitor the generation and dissipation of pore water pressure.

• Korean Journal of Materials Research
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• v.2 no.6
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• pp.443-451
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• 1992

Effects of various pretreatments on the nucleation of CVD-W deposited on the reactively sputter-deposited TiN was investigated. Incubation period of nucleation and deposition rate decreased by the pretreatment of Ar rf-sputter etching for the depth below 300k, but they increased for the etchig depth over 200A. The preteatment of Ar ion implantation decreased the incubation period of nucleation, but increased deposition rate. Also Si$H_4$flushing pretreatment decreased the incubation period of nucleation slightly due to the absorption of Si by TiN surface.

• Nuclear Engineering and Technology
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• v.20 no.3
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• pp.155-164
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• 1988

A rate equation for UO$_2$ pellet leaching has been derived and compared with some experimental results. The leach rate model comprises the processes of oxygen penetration into UO$_2$ pellets and the dissolution and transport of oxidized UO$_2$ depending on the penetration depth of oxygen. The model may be analyzed with two regions of transient and steady state behaviors, which should depend on the initial oxidation state of pellets. Also this model can be utilized in the analyses of general leach processes if the oxidation reaction of UO$_2$ is replaced with similar mechanism of those processes.

• Journal of the Korean Crystal Growth and Crystal Technology
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• v.7 no.2
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• pp.235-243
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• 1997

The high-$T_c$ superconducting phase, $YBa_2Cu_3O_x$, was deposited on the single crystal MgO substrate, using a liquid aerosol feed method in a plasma enhanced chemical vapor deposition(PECVD) reactor. The effect of the plasma distribution depending on the design of a reactor was studied by the analysis of the microstructures of thin films. The particles landed were frequently observed on the films and the two causes that were responsible for the particle deposition were explained. The particles were deposited by the unstable and non-uniform plasma and the low evaporation rate of the precursors. Also, the thin film deposition rate decreased significantly as the distance between the evaporating location and the substrate increased.