• Journal of the Korea Academia-Industrial cooperation Society
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• v.19 no.3
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• pp.112-118
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• 2018

In order to meet the strict emission regulations for internal combustion engines based on fossil fuel, the proportion of after-treatments for vehicles and vessels is gradually increasing. Diesel engines have high power, good fuel economy, and lower $CO_2$ emissions, and their market shares are increasing in commercial vehicles and passenger cars. However, NOx is generated in the localized high-temperature combustion regions, and particulate matter is formed in the zones of diffusion combustion. LNT and urea-SCR catalysts have been developed for after-treatment of the exhaust gas to reduce NOx in diesel vehicles. This study aims to improve the NOx reduction performance of Cu SCR catalyst, which is widely used in light, medium, and heavy-duty diesel engines. The de-NOx performance of $5Cu-2ZrO_2$/93Zeolyst(Si/Al=13.7) SCR catalyst was about 5-50% higher than that of $5Cu-2ZrO_2$/93Zeolite(Si/Al=2.9) at catalyst temperatures of $300^{\circ}C$ or higher. The zeolite had lower metal dispersion than zeolyst, and the reaction rate of the catalyst decreased as the average particle size increased. The $10Cu-2ZrO_2$/88Zeolyst catalyst loaded with 10wt% Cu had the highest NOx conversion rate of 40% at $200^{\circ}C$ and about 65% at $350^{\circ}C$. The ion exchange rate of Cu ions increased with that of Al, the crystalline compound of zeolite, and the de-NOx performance was improved by 20-40% compared to other catalysts.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.17 no.8
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• pp.200-207
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• 2016

The automotive seat is an important component that moves in sync with the driver and is actively being developed with various new functions. The aim of this work is to develop a lightweight seat cushion extension module using a lightweight material. To this end, a structural strength analysis, vertical strength test, and durability test were conducted. In the structural analysis, the maximum value of deformation under vertical load was 4.98 mm at the front of the upper panel. The maximum stress was approximately 105 MPa, which occurred at the point of contact between the upper and lower panels of the module. The vertical strength test showed a maximum vertical deformation of 5.31 mm under a vertical load, which differed from the analysis results by approximately 6.45%. The structural safety of the product was verified by the fact that it showed no harmful deformation or damage during operation after the vertical strength test and a durability test for 20,000 cycles. Furthermore, the use of engineering plastics made it possible to reduce the weight by approximately 30% compared to existing products. The lack of damage after tests verified the passenger safety, strength, and rigidity of the product. The results are expected to be applied for improving environmental and fuel efficiency regulations and preventing accidents due to driver fatigue. The applications of this module could be expanded various types of vehicles, as well as other industries in which eco-friendly and lightweight materials are used.

• Korean Chemical Engineering Research
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• v.61 no.1
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• pp.26-31
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• 2023

For durability improvement of polymer electrolyte membrane fuel cell (PEMFC) polymer membrane, accelerated durability evaluation methods that can evaluate durability in a short time have been researched and developed. However, the lifespan of fuel cells for large commercial vehicles such as trucks and buses is more than three times that of passenger cars, and the chemical accelerated stress test (AST) time is also longer, reaching 1,500 hours or more. Therefore, in this study, as a method to evaluate the chemical durability of a membrane within a short time, it was examined whether the durability could be predicted by the pristine membrane characteristics. Hydrogen crossover current density (HCCD) and short resistance (SR) were estimated as initial characteristics, and AST time was predicted through the Fenton experiment, which was possible as an out-of-cell experiment for 3 hours. As the HCCD and fluoride ion emission concentration increased, the AST time tended to be linearly shortened, but there was a deviation (R² ≒0.65). When the SR decreased, the AST time showed a linear increase, and the accuracy was high (R² =0.93), so the AST time could be predicted with the initial SR of the membrane.

• The Journal of The Korea Institute of Intelligent Transport Systems
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• v.22 no.2
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• pp.44-53
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• 2023

Recently, serious parking problems are occurring due to the difficulty of securing sufficient parking space, and it may lead to other traffic or social problems. In order to solve the parking problem in areas and districts beyond a certain range, a study on-roads and off-street parking lots reflecting regional characteristics is necessary. Therefore, this study establishing a parking demand calculation model for use as a basic study in establishing on-road and off-road characteristics. In order to conduct the study, Dong-fu, Daegu Metropolitan City was divided into dongs, and parking facilities and parking demand were investigated. The survey time was divided into daytime and nighttime on weekdays, and the types of vehicles were divided into three types: passenger car, small trucks and buses, large trucks and buses. As explanatory variables for calculating parking demand, the total floor area of buildings for each of six purposes was used, including detached houses, apartment houses, neighborhood living facilities, cultural and assembly facilities, business facilities, and sales facilities. As a result of the correlation analysis, among the six explanatory variables, the total area of neighborhood living facilities showed a significant correlation with on- and off-street parking demand. A regression analysis model was constructed using the total area of neighborhood living facilities as an explanatory variable, and statistically significant results were obtained.

• Korean Chemical Engineering Research
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• v.61 no.3
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• pp.362-367
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• 2023

Recently, research and development of proton exchange membrane fuel cells (PEMFC) membranes are progressing in the direction of thinning to reduce prices and improve performance. Demand for hydrogen-powered vehicles for commercial vehicles is also increasing, and their durability should be five times greater than those for passenger vehicles. Despite the thinning of the membranes, the durability of the membranes must be increased five times, so the improvement of the durability of the membranes has become more important. Since the acceleration durability evaluation time also needs to be shortened, the protocol using oxygen instead of air in the existing protocol was applied to a 10 ㎛ thin membrane to evaluate durability. The accelerated durability test (Open circuit voltage holding) was terminated at 720 hours. If the air-based department of energy (DOE) protocol was used, a lifespan of 450,000 km of driving hours would be expected, with a durability of about 1,500 hours. During the chemical durability evaluation, the active area of the electrode decreased by 51%, suggesting that catalyst degradation had an effect on membrane durability. Reducing the catalyst degradation rate is expected to increase membrane durability.

• Korean Chemical Engineering Research
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• v.62 no.1
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• pp.1-6
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• 2024

As the demand for hydrogen electric vehicles for commercial vehicles increases, the durability of PEMFCs must increase more than five times that of passenger cars, so research and development to improve durability is urgent. When the PEMFC membrane electrode assembly (MEA) undergoes chemical degradation, the MEA thickness decreases and pinholes occur. In this study, changes in the performance and durability of the MEA were measured while increasing the clamping pressure of the unit cell after open circuit voltage (OCV) holding, an accelerated chemical degradation experiment. As the clamping pressure increased, the resistance of the polymer membrane and the membrane/electrode contact resistance decreased, improving the I-V performance and reducing the hydrogen permeability. As the hydrogen permeability decreased, the OCV increased. When the pinhole area was removed and the MEA clamping pressure was increased, the hydrogen permeability decreased sharply, confirming that the local degradation has a large effect on the performance and durability of the entire cell. When the pinhole was removed and re-clamping and OCV holding was evaluated, it was confirmed that the durability improved according to the decrease in membrane resistance and hydrogen permeability.