• Journal of the Korean Crystal Growth and Crystal Technology
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• 제29권6호
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• pp.317-328
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• 2019

In this work, we investigated clay and raw materials from China (black clay, red clay, white clay) and Korea (Cheonan clay, Obu clay) used for the manufacture of porcelain products. According to chemical analysis results, feldspar components containing CaO, K₂O, Na₂O and quartz are found in clay materials besides primary clay such as kaollinte, for the clay materials from Korea, which is found more in clay materials from Korea than from China. For the Fe₂O₃ content, governing whiteness of porcelain products, more iron oxide (> 5 %) is found in Korean clays (Cheonan clay, obu clay, red clay) compared to those form China (black, white clay). Through X-ray diffraction analysis, kaolinite and Halloysite are found to be main phases for all the raw materials and second phases such as quartz and pyrophyllite are found. Using these clay materials, raw materials for porcelain products were produced, and the physicochemical properties were investigated for sintered samples. Absorption rate is in order of Baekja-A < Baekja-B < Yeonbuncheong < Jinbuncheong < Cheongja, and the sample, sintered at 1250℃ in reductive atmosphere, exhibits the lowest absorption rate. Comparing the color of the sintered samples, the samples sintered in oxidative atmosphere (L^* value: 86~95 %) show higher whiteness value than those sintered in reductive atmosphere (L^* value: 81~93 %). For the Cheongja and Buncheong, the samples sintered in reductive atmosphre shows higher whiteness, L^* values, and low a^*/b^* value, which is due to reduction of iron oxide (Fe₂O₃).

• Journal of the Korean Geotechnical Society
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• 제15권6호
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• pp.17-28
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• 1999

In order to analyze effects of strain rate on consolidation of natural clay, this paper presents a nonlinear elasto viscoplastic model in which viscoplastic behavior is modeled by a unique effective stress-strain-strain rate relationship (equation omitted). The predicted values using numerical analysis are compared with measured ones in several laboratory tests such as creep test, multistage load test, and relaxation test for Berthierville clay. It is possible to estimate consolidation behavior of natural clay with reasonable accuracy using the proposed nonlinear viscoplastic model.

• Journal of Navigation and Port Research
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• 제36권3호
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• pp.181-187
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• 2012

Highly plastic clays in their normally consolidated states are not always linear but are concave downwards. Thus their compression index deceases with the increase of consolidation pressure. The $e-{\log}{\sigma}_{\upsilon}{\prime}$ curves of plastic or non-plastic silty clays are not linear but are convex upwards. In this paper, consolidation tests were conducted with several undisturbed field soils of Korea south coast and their $e-{\log}{\sigma}_{\upsilon}{\prime}$ plots are not always linear. In case of using Butterfield's method(liquid limit 50~100%), ${\ln}{\upsilon}-{\ln}{\sigma}_{\upsilon}{\prime}$ plots are linear. But some undisturbed samples which have void ratio over 2.24, liquid limit over 100% and plasticity index over 60% are not linear. In results of consolidation tests with remolded samples which contain silt(fly ash) contents of 90% has compression index increasing with the increase in consolidation pressure.

• Journal of the Korea Institute of Building Construction
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• 제19권5호
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• pp.401-409
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• 2019

This paper aims to recycle red mud from a byproduct in the alumina industry as an alternative raw material for depleted natural resources. In order to apply red mud as a ceramic material, red mud ceramics were prepared according to mixing and temperature in a laboratory environment. Compared with KS L 4201 in terms of compression ratios and absorptions, it is found that two kinds of conditions for one type and three conditions for two types meet the standard. When red mud is used as a clay brick raw material, the substitution ratio of red mud is 10% or less, and the firing temperature is considered to be appropriate at $1200^{\circ}C$. In order to apply red mud to clay brick raw material in actual field, various samples and firing temperature should be considered in the future.

• Journal of the Korean Ceramic Society
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• 제39권8호
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• pp.728-734
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• 2002

Stabilization behavior of Cr, Cd, Cu, Pb, Fe and Zn heavy metals in the EAF dust was investigated by adding EAF dust to clay or white clay, respectively, up to 50 wt% with 10 wt% intervals and sintering at temperatures between 200 and $1200^{\circ}C$ with $200^{\circ}C$ intervals with an aid of ICP-AES followed by TCLP test to evaluate heavy metal cation exchange capacity of the clay or the white clay. The clay or the white clay had a better Cr ion exchange capacity than that of zeolite. The TCLP leaching test for the sintered specimens showed that Cr and Fe were rarely detected for all the specimens and the concentration of Cd and Zn decreased with increasing sintering temperature and decreasing EAF dust contents respectively. When the clay or the white clay were mixed with EAF dust, cation exchange may occur between the clay and the EAF dust so that the first stabilization of the mixtures containing semistabilized heavy metals may happen. Stabilization of heavy metals in the ceramic bodies was further completed probably due to the eutectic reaction caused by the sintering of semi-stabilized mixtures. It was conceivable that the white clay rather than the clay may be a better stabilizer for the EAF dust containing heavy metals.

• Journal of Conservation Science
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• 제32권4호
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• pp.511-520
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• 2016

The purpose of this study was to estimate the firing temperature of fired clay brick by applying high temperature X-ray diffraction(XRD) analysis. The clay bricks, which were excavated from a Buddhist temple in Karatepa, Uzbekistan were composed of quartz, plagioclase, alkali feldspar, mica, chlorite, limestone, hornblende, etc. Some clay bricks contained gypsum, which was presumed to have been used to improve the adhesive strength of the brick. Estimating the firing temperature using a geologic thermometer, the UZ-1 sample was identified as being in the quartz, plagioclase, pyroxene series, and the firing temperature was estimated to be $900-1200^{\circ}C$. On the other hand, applying the high temperature XRD method to the UZ-5 sample, it was found that the limestone was destroyed at $1000^{\circ}C$ and the diffraction peak of chlorite was weakened at $1050^{\circ}C$. Moreover, pyroxene series minerals developed at $1050^{\circ}C$ in the reproduction experiment. These results indicate that the clay bricks used in the temple were produced in a kiln that reached a temperature of more than $1000^{\circ}C$. Thus, high temperature XRD analysis can more accurately estimate firing temperatures as compared to the firing temperature mineral identification method and it can be used to determine the creation and extinction temperature range of minerals.

• Journal of the Korean Crystal Growth and Crystal Technology
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• 제17권6호
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• pp.277-282
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• 2007

The artificial lightweight aggregate (ALA) was manufactured using coal bottom ashes produced from a thermoelectric power plant with clay and, the sintering temperature and batch composition dependence upon physical properties of ALA were studied. The bottom ash (BA) had 13wt% coarse particle (>4.75mm) and showed very irregular shape so should be crushed to fine particles to be formed with clay by extrusion process. Also the bottom ash contained a many unburned carbon which generates the gas by oxidation and lighten a aggregate during a sintering process. Plastic index of green bodies decreased with increasing bottom ash content but the extrusion forming process was possible for the green body containing BA up to 40wt% whose plastic index and plastic limit were around 10 and 22 respectively. The ALA containing $30{\sim}40wt%$ BA sintered at $1100{\sim}1200^{\circ}C$ showed a volume specific density of $1.3{\sim}1.5$ and water absorption of $13{\sim}15%$ and could be appled for high-rise building and super-long bridge.

• Journal of the Korean Geosynthetics Society
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• 제17권3호
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• pp.9-18
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• 2018

The soil parameters important for the design of the soft ground are the compression index ($C_c$), the consolidation settlement and consolidation speed at the field. Compression index is obtained by laboratory consolidation test. In the laboratory consolidation test, sample disturbance always occurs. In order to correct the disturbance phenomena, the method of calculating the compression index proposed by Schmertmann (1955) is generally used. However, recent developments in sampling technology and Korean soil conditions are different from those proposed by Schmertmann. So it needs to be verified. In this study, each consolidation curve's cross void ratio is evaluated by doing consolidation test varying disturbance on high-plastic clay (CH), low-plastic clay (CL) and low-plastic silt (ML). The test results were $0.521e_0$ for low-plastic silt, $0.404e_0$ for low-plastic clay, and $0.458e_0$ for the high-plastic clay. This results were different from those of Schmertmann's suggested value of $0.42e_0$. Therefor we proposed a correction formula using the plastic index according to soil type. However, since the results of this study are limited test results, further studies on various korean soil are needed to suggest the compression index correction method according to the degree of plasticity index of soil.

• Resources Recycling
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• 제8권1호
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• pp.23-28
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• 1999

Firing characteristics, transverse rupture strength, and heat capacity were studied of the heat-reservoir refractory materials made of red-firing clay, mill scale, and water glass. The firing shrinkage increased with increase of the clay proportion in samples. The volume of fired bodies showed shrinkage by drying up to $300^{\circ}C$, steady expansion in the 300-$700^{\circ}C$ range due to phase transition of iron oxides. and drastic expansion above $1200^{\circ}C$. Flexural strength decreased from 5.6 Mpa to 2.35 Mpa with the decrease of the ratio of clay to mill scale from 1:1 to 1:3 Heat capacities changed from 1.1 Joul/g$^{\circ}$C to 1.35 Joul/g$^{\circ}$C with the ratio of millscale to clay ratio from 1:1 to 1:3. Mill scale in the specimen appears to exist as liquid phase during firing. Firing the specimens in air leads to the eruption of the molten mill scale to the sample surfaces. Contrarily, firing samples in a refractory sagger with a cover suppressed the eruption of the molten mill scale to the surfaces. The addition of mill scale gave rise to porous sintered bodies which would delay cooling rates of heat-reservoir brick.

• Journal of the Korean Recycled Construction Resources Institute
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• 제10권3호
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• pp.252-260
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• 2022

In Korea, low-quality kaolin has significantly greater reserves and superior economic efficiency than high-purity kaolin. However, the utilization is low because it does not match the demand conditions of the market, and it is difficult to find a suitable source of demand. The purpose of this study is to derive the possibility and optimal calcination temperature of domestic low-quality kaolin that can be used as a raw material for limestone plastic clay cement (LC³). Isothermal calorimetry, X-ray diffraction analysis, Thermogravimetric Analysis, and compressive strength tests were conducted to evaluate hydrate generation and mechanical properties of LC³ paste according to calcination temperatures (600 ℃, 700 ℃, 800 ℃, 900 ℃). As a result, although 50 % of the clinker was replaced, the domestic low-quality kaolin clay produced calboaluminate hydrate and C(A)SH from the 3rd day of hydration, showing almost equal or higher strength to OPC, and there was a big difference in strength depending on the firing temperature.