• Applied Chemistry for Engineering
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• v.31 no.6
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• pp.646-652
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• 2020

In this study, an NH3-selective catalytic reduction (SCR) experiment was performed to control NOx in the temperature range of 200~500 ℃. The reaction activity experiment was conducted by varying the firing temperature of Sb/TiO2 when using V/Sb/TiO2 composite as a catalyst. As a result, when the sintering temperature of Sb/TiO2 was 600 ℃, the efficiency was the best, and it was confirmed that the NOx conversion rate was close to 80% at the reaction temperature of 250 ℃. H2-temperature programmed reduction (TPR), X-ray diffraction (XRD), Brunauer-Emmett-Teller (BET), Raman spectroscopy, and X-ray photoelectron spectroscopy (XPS) analyses were employed to derive the cause of the activity enhancement when prepared at different firing temperatures as described above. As a result, when the sintering temperature of Sb/TiO2, which showed an excellent activity, was prepared at 600 ℃, it was confirmed that VSbO4 was generated. This indicates that the non-stoichiometric species of V increased, resulting in the excellent NOx conversion rate of V/Sb/TiO2.

• Journal of Navigation and Port Research
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• v.31 no.3 s.119
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• pp.271-279
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• 2007

Ship structures are basically an assembly of plate elements and estimation load-carrying capacity or the ultimate strength is one of the most important criterion for estimated safety assessment and rational design on the ship structure. Also, Structural elements making up ship plated structures do not work separately against external load. One of the critical collapse events of a ship structure is the occurrence of overall buckling and plastic collapse of deck or bottom structure subjected to longitudinal bending. So, the deck and the bottom plates are reinforced by a number af longitudinal stiffeners to increase their strength and load-carrying capacity. For a rational design avoiding such a sudden collapse, it is very important to know the buckling and plastic behaviour or collapse pattern of the stiffened plate under axial compression. In this present study, to investigate effect af modeling range, the finite element method are used and their results are compared varying the analysis ranges. When making the FEA model, six types of structural modeling are adopted varying the cross section of stiffener. In the present paper, a series of FEM elastoplastic large deflection analyses is performed on a stiffened plate with fiat-bar, angle-bar and tee-bar stiffeners. When the applied axial loading, the influences of cross-sectional geometries on collapse behaviour are discussed. The purpose of the present study is examined to numerically calculate the characteristics of buckling and ultimate strength behavior according to the analysis method of ship's stiffened plate subject to axial loading.

• Journal of the Korean Ceramic Society
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• v.39 no.10
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• pp.912-918
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• 2002

Ni-Mn-Co-Fe oxide thick films were coated on an alumina substrate by screening printing technique. The microstructure and electrical properties of the thick films, as a function of composition and sintering temperature, were investigated. The components of the NTC thick films sintered at 1150${\circ}C$ were distributed homogeneously. On the other hand, in the case of the NTC thick films sintered at 1200 and 1250${\circ}C$, Co element was distributed homogeneously, but Ni, Mn and Fe elements were distributed heterogeneously, resulting in the formation of Ni rich and Mn-Fe rich regions. All the thick film NTC thermistors prepared showed a linear relationship between log resistance (log R) and the reciprocal of absolute temperature (1/T), indicative of NTC characteristics. At a given NiO and $Mn_3O_4$ content, the resistance, B constant and activation energy of $(Ni_{1.0}Mn_{1.0}Co_{1-x}Fe_x)O_4$ (0.25${\le}$x${\le}$0.75) and $(Ni_{0.75}Mn_{1.25}Co_{1-x}Fe_x)O_4$ (0.25${\le}$x${\le}$0.75) thermistors increased with increasing $Fe_2O_3$ content.

• Journal of the Korean GEO-environmental Society
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• v.8 no.3
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• pp.27-33
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• 2007

The vertical drain method recently being used in Korea is one of the popular soft ground improvement methods, and it is divided into the sand drain method, the pack drain method, the paper drain method, and the PBD method according to the drainage. However, these methods generate the disturbed zone called the smear zone when the drainage is penetrated into the in-situ ground. The characteristics of the smear zone generated cause the problems that the coefficient of permeability decreases, and then the consolidation time in the design becomes longer than expected. Even though the coefficient of horizontal consolidation and the coefficient of permeability in the smear zone are very important design factors directly influencing the degree of consolidation, in the existing studies, these coefficients have been empirically derived by the coefficient of vertical consolidation and used for the design. However, in case that these coefficients derived by the coefficient of vertical consolidation are applied to the actual design, a loss of the duration of construction and a loss of economical efficiency can be happened because of the inaccuracy of the coefficient of horizontal consolidation and the coefficient of permeability. Hence, in this study, in order to understand such influence, the laboratory test was carried out so as to reasonably determine the coefficient of permeability and the coefficient of consolidation in diverse ground conditions. Then, the range of smear effect on clay and silt was estimated with monitoring data through the laboratory test.

• Korean Journal of Veterinary Research
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• v.38 no.3
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• pp.664-673
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• 1998

초음파학적 검사에 따라 미만성 저에코 영역, 낭포, 다병소성 낭포 및 비후된 피막 등 비정상적 소견을 보이는 전립선에서 추출한 전립선액과 생검조직에서의 LDH 분획비(LDH I/V)의 평균치는 각각 $0.92{\pm}0.55$, $2.69{\pm}0.82$, 정상군(각각 $0.23{\pm}0.20$, $0.57{\pm}0.36$)에 비하여 유의성(p<0.01) 있게 높았다. 세포병리학적 검사에서 전립선 비대증 및 전립선염으로 나타난 비정상군($2.76{\pm}0.77$의 생검조직 LDH 평균분획비는 정상군($1.38{\pm}1.19$)에 비해 유의성 있게 높았으나 전립선액에서는 분획비의 유의차가 인정되지 않았다. 배양결과에 따른 전립선액 및 조직시료의 LDH 분획비는 정상군과 비정상군 사이에서의 유의성은 인정되지 않았다. 결론적으로 저에코 영역 및 낭포부위는 생검조직과 전립선액의 배양 및 세포병리학적 검사에 따른 비정상성 및 높은 LDH 분획비와 밀접한 연관성을 보였다. 특히 경직장 초음파상에 나타나는 미만성 저에코 영역은 전립선 비대증 및 만성 전립선염 등과 같은 병적 관련성을 내포하고 있는 것으로 사료된다.

• Explosives and Blasting
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• v.27 no.1
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• pp.21-31
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• 2009

An excavation damaged zone (EDZ) is created by fracturing, excavation or stress redistribution of tunnels. In this zone the mechanical and hydraulic properties of rock are changed, which makes additional cracks and serves as a dominant pathway of groundwater flow. In this study, an assessment on an EDZ size was practiced by the measurement of the deformation modulus at the KAERI underground research tunnel (KURT), and the information was applied to the modelling analysis using FLAC2D software. The EDZ at KURT fell into the range of 0.6~1.8m and the deformation moduli of the EDZ generally correspond to about 40% of intact rock mass. With a consideration of the EDZ in numerical analysis, tunnel displacements increased by about 65% and the maximum principal stress decreased to 58% from the case without EDZ. The plastic zone of the tunnel was enlarged to the crown and invert zones of the tunnel within the range of the length of rock bolts. About 2% of the total tunnel displacement with EDZ was suppressed by the KURT support system. It is anticipated that the investigation of an EDZ can be used as an important and fundamental research for validating the overall performance of a high level waste disposal system.

• Journal of the Korean Chemical Society
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• v.39 no.8
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• pp.627-634
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• 1995

Layered double hydroxides ($Mg-Al-CO_3$ systems, LDH), which are hydrotalcite-like anionic clay minerals, having different $Mg^{2+}\;to\;Al^{3+}$ ratio were synthesized by coprecipitation method. The subsequent products were characterized by the following methods; elemental analysis, X-ray powder diffraction, thermal analysis (DSC and TGA), FT-IR and $^{27}$Al-MAS NMR. X-ray powder patterns showed that the products formed were layered structure materials. Two heat absorption peaks were observed around 20 ∼280$^{\circ}C$ (surface water and interlayer water) and 280∼500$^{\circ}C$ (water from lattice hydroxide and carbon dioxide from interlayer carbonate) in DSC diagrams, and they were quantitatively analyzed by TGA diagrams (in case LDH4 16.2% and 28.6% respectively). FT-IR spectra indicate that the interlayer carbonate ions occupied symmetrical sites between two adjacent layers in a parallel direction. $^{27}$Al-MAS NMR spectra show only single resonance (8.6 ppm) of the octahedrally coordinated aluminum similar magnesium. When LDH4 was calcined at 560$^{\circ}C$ for 3 hours in air, its layered structure was destroyed giving a mixed metal oxide. However it readily became rehydrated in aqueous chromate solution to its original structure.

• Proceedings of the Korean Powder Metallurgy Institute Conference
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• 2001.11a
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• pp.29-29
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• 2001

열전재료는 열전현상을 가지고 있어 열전발전과 열선냉각이 가능하기 때분에 해저용, 우주용, 군사용의 특수 전원으로 이미 실용화되어있고, 반도체, 레이저 다이오드, 적외선 검출소자 등의 냉각기로 쓰여지고 있어 많은 연구자들이 이들 재료에 대한 연구에 관을 갖고 열전특성을 향상시키기 위하여 많은 연구를 진행하고 있다 이들 열전재료는 사용 온도구역에 따라 3종류로 구분하고 있으며, 실온부근의 저온 영역(20$0^{\circ}C$)이하에서는 $Bi_2Te_3$계 재료, 중온영역(20$0^{\circ}C$~50$0^{\circ}C$)에서sms (Pb,Ge) Te계 재료, 고온영역(50$0^{\circ}C$~lOoo$^{\circ}C$)에서는 Si-Ge계 Fe Si계 재료가 이용되고 있다. 본 연구에서는 실온에서 성능지수가 높은 Bi_2(Te,Se)_3$에 대한 연구를 진행하였다. Bi_2(Te,Se)_3$계 열전재료는 기존의 공법인 Zone melting법을 이용하는 경우 성능지수가 높으나, 단위정이 Rhombohedral 구조파 기저면(basal plane)에 벽개성이 있는 관계로 재료의 적지 않은 손실과 가공상의 어려움이 있다. 또한 사료전체에 걸쳐 화학적으로 균질한 고용체를 얻는 것도 어려운 문제점으보 부각되고 있디 따라서 이와같은 문제점을 보완하기 위하여 용질원자의 편석감소, 고용도의 증가, 균일 고용체 형성, 결정립의 미세화등의 장점이 있는 급속응고법을 본 연구에 응용하였다. 본 연구에서는 위에서와 같은 급속응고의 장점과 대량 가공이 능늪한 연간압출공정을 이용하여 제조된 분말을 성형화 하였다. 특히 열간압출 가공에 있어서 압축다이 각 변화는 재료의 소성유동에 매우 중요한 역하을 하게되며, 이와 갇은 소성유동은 본 재료의 열전특성에 중요한 영향을 미치는 C 면 배양에 중요한 역할을 한 것으 로 기대된다. 이에 본 연구에서는 압출다이 각도 변화에 따른 미세조직변화와 이들 조직이 강도와 열전특성에 미치는 영향을 석하고자 한다. 압출재의 미세조직은 XRD(X Ray Diffraction), SEM(Scanning Electron Microscopy)으로 분석하였으며, 열전특성인 Seebeck계수($\alpha$)와 전기비저항( $\rho$ )은 열전측정장치로, 기계적 강도는 MTS장비를 이용하여 이루어졌다. 또한 압축다이각도 변화에 따른 결정방위 해석은 모노크로미터가 장착된 X RD장비감 이용하여 분석되었다.

• Journal of the Korean Geosynthetics Society
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• v.7 no.3
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• pp.31-40
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• 2008

The deformation behavior of the excavated behind ground due to the displacement shape of retention walls is predicted by numerical analysis, which can be performed using the artificial displacement method with elasto-plastic constitutive model. The displacement shape of the behind ground around the retention wall is similar to the displacement shape of the retention wall. However, far from the retention wall, it changes to the displacement shape of cantilever. The deformation (the settlement, the lateral movement) of the excavated behind ground can be decreased by restraining the upper displacement of the retention wall. The displacement shape of the retention wall due to excavation affects on the plastic failure zone and decreasing zone of stability of the excavated behind ground.

• Journal of the Korean Society of Safety
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• v.19 no.4 s.68
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• pp.135-140
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• 2004

Wear mechanisms may be briefly classified by mechanical, chemical and thermal wear. A plane strain finite element method is used with a new material stress and temperature fields to simulate orthogonal machining with continuous chip formation. Deformation of the workpiece material is healed as elastic-viscoplastic with isotropic strain hardening and the numerical solution accounts for coupling between plastic deformation and the temperature field, including treatment of temperature-dependent material properties. Effect of the uncertainty in the constitutive model on the distributions of strait stress and temperature around the shear zone are presented, and the model is validated by comparing average values of the predicted stress, strain, and temperature at the shear zone with experimental results.