• Title/Summary/Keyword: 소성환경

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Study on Mineralogical Characteristics and Firing Condition of the 4-6th Century Earthenware Excavated from the Seonggok-ri, Cheongdo-gun, Gyeongsangbuk-do (경상북도 청도군 성곡리에서 출토된 4-6세기 토기의 광물학적 특성 연구 및 소성환경 추정)

  • Woo, Hyeon Dong;Kim, Ok Soon;Jang, Yun Deuk
    • Journal of the Mineralogical Society of Korea
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    • v.29 no.3
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    • pp.123-129
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    • 2016
  • This study is conducted to estimate the firing temperature and condition of the 4-6th Century earthenwares excavated from the ancient tombs in the Seonggok-ri, Cheongdo through mineralogical approaches, and to contrast to the characteristics of the earthenware from the Changnyeong the adjacent area to the Cheongdo. The Cheongdo earthenware was mainly composed of quartz, pores and vitric matrix with minor parts of feldspars, felsic volcanic fragments and opaque minerals, of which quartz crystals frequently show embayed texture and pores was partly filled with amorphous quartz. Mullite, hematite and cristobalite were found by XRD spectrometer additionally, and in the SEM image the Mullite contents are evenly distributed from the central part to the marginal part. As a result, the firing temperature of the Cheongdo earthenware could be 1,100 to $1,200^{\circ}C$, which is higher than that of the Changnyeong. Distribution characteristics of mullite in the Cheongdo and the Changnyeong earthenware indicate that the Cheongdo earthenware was under the longer firing time or more homogeneous thermal condition in the kiln than the Changnyeong.

The Characteristic for Undrainded Shear Behavior of in Low-Plastic Silt and its Prediction (저소성 실트의 비배수 전단거동 특성과 예측)

  • Kim, Daeman
    • Journal of the Korean GEO-environmental Society
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    • v.9 no.6
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    • pp.61-70
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    • 2008
  • In this study, undrained triaxial (CU) tests were performed on low-plastic silt of Nakdong River in order to investigate the undrained shear behavior of low-plastic silt. In experimental results, the deviator stress showed the hardening behavior after reaching its yield stress like the tendency of common sand, and the pore water pressure was gradually decreased to critical state after the maximum value. In the effective stress paths, regardless of consolidation stress or overconsolidation ratios, both a critical state line (CSL) and a phase transformation line (PTL) exist in the effective stress path that is similar to the case of sand. The behavior of low-plastic silt was predicted by the Modified Cam-Clay (MCC) model, the Jordan and the Elman-jordan model that is artificial neural network model. According to predicted results, the overall undrained shear behavior of low-plastic silt could not be predicted with the MCC model, but the Jordan and Elman-Jordan model showed well-matched experiment results.

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Characteristics of Artificial Soils Produced from Sludge (슬러지를 이용하여 생산한 인공토양의 특성)

  • Yoon, Chun-Gyeong;Kim, Sun-Joo;Kwun, Tae-Young;Lee, Nam-Chool
    • Korean Journal of Environmental Agriculture
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    • v.17 no.3
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    • pp.200-204
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    • 1998
  • Physical and chemical properties of artificial soil produced by firing process were analyzed and compared with normal dry field soil and soil quality standards. Material used for production was water and wastewater treatment sludge, chabizite, and lime. The mixed material was thermally treated in the firing kiln at about $300^{\circ}C$ and $1,000^{\circ}C$, respectively, as per designed process. General properties of the artificial soil were classified as sand by unified soil classification method and similar to the dry-field soil, and even soil conditioning effect were expected when it is mixed properly with normal soil. The artificial soil is high in pH and permeability compared to the dry-field soil. Heavy metal concentrations of the artificial soil met the soil quality standards for the farmland. Overall, the artificial soil was thought to be an appropriate soil which can be returned safely to the nature without significant adverse effect. The cost for the artificial soil production process needs to be lowered for practical application as a sludge treatment, therefore, commercializing of the artificial soil is under review.

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건축 재료로서 하수 슬러지 소각재의 활용

  • 이기환;이태호;전기석;한기석;이승구
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2001.11a
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    • pp.151-152
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    • 2001
  • 본 연구는 하수슬러지 소각재를 이용하여 건축재료로서의 응용 가능성을 조사하였다. 소각재를 주성분으로 하여 $950^{\circ}C$에서 소성한 시편과 보통 포틀랜드 시멘트 (OPC)를 첨가하여 습윤양생을 한 시편을 제작하여 압축 강도를 비교하였다. 소성 시편에서는 전반적으로 압축강도가 150 kgㆍf/$\textrm{cm}^2$ 이상의 높은 강도를 얻을 수 있었으나 변형율이 증가하는 것이 단점으로 나타났다. 또한, 습윤양생한 시편의 경우 소량의 OPC 첨가 만으로도 일정한 압축강도를 유지할수 있었으며, 시편의 변형 또한 줄일 수 있었다.

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인산이온의 흡착에 의한 Apatite의 표면전위의 변화와 흡착 특성

  • 신학기
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2001.11a
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    • pp.149-150
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    • 2001
  • 질산, 인산, 불산을 페수처리한 슬러지를 가열함에 따라서 아파타이트 결정으로 발달하는 과정을 살펴보면 질산칼슘의 분해에 따라서 아파타이트가 생성되지만 HF는 분해되지 않고, 결정내에 잔류하고 있다는 것을 알 수가 있다. 따라서 $900^{\circ}C$에서 2시간 소성한 아파타이트를 물에 용출시킬 대 HF가 용출되어 나오므로 그 사용에 제한이 되고 있다. 이러한 현상을 방지하고, 양론적인 아파타이트를 제조하기 위하여 인산 이온을 흡착 시키고 $900^{\circ}C$에서 2시간 소성한 결과 불소이온은 대폭적으로 감소되었고, Ca/P의 몰비는 양론적인 1.67에 근접하였고, 이 조건에서 합성한 아파타이트는 중금속의 흡착, 인 및 COD의 흡착, 제거율이 우수하였다.

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A Study on the NH3-SCR Activity of the VWSbTi According to the Calcination Temperature of WSbTi (WSbTi의 소성온도에 따른 VWSbTi 촉매의 NH3-SCR 효율 연구)

  • Eo, Eun Gyeom;Shin, Jung Hun;Hong, Sung Chang
    • Applied Chemistry for Engineering
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    • v.33 no.1
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    • pp.64-70
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    • 2022
  • In this study, an experiment was performed by adding Sb during NH3-selective catalytic reduction (NH3-SCR) while varying calcination temperatures from 400 to 700 ℃ to improve the low temperature denitrification efficiency of VWTi catalyst. As a result, VWSbTi(500) and VWSbTi(600) catalysts corresponding to Sb calcination temperatures of 500~600 ℃ showed the best denitrification performance at low temperatures below 300 ℃. BET, XRD, Raman, XPS, H2-TPR, and NH3-TPD analyses were performed In order to confirm physicochemical properties according to the calcination temperature. In the case of VWSbTi(500) and VWSbTi(600), an acid site increased with the generation of W=O species, and superb activity at low temperatures was exhibited due to the excellent redox characteristics and increase in electron density of tungsten. Furthermore, in the case of VWSbTi(700), as the crystalline V2O5 structure was formed, the denitrification efficiency decreased. Thus the optimum calcination temperature during Sb addition process was confirmed.