• Journal of Conservation Science
• /
• v.27 no.4
• /
• pp.345-356
• /
• 2011

To remove metal stains of the ceramics, chemical cleaning is essential case by case. This study investigated the removal characteristics of iron stains by oxalic acid and citric acid including their application methods of soaking and poultice. The soaking method in cleaning agents showed removal process by color difference and released iron contents from iron stains on ceramics. Iron stains were removed successfully from ceramics, which soaked in oxalic acid for 60 hours. However, it is recommendable to soak in 0.25M oxalic acid for one to three hours because most iron stains were disappeared in 3 hours soaking. Citric acid is less effective than oxalic acid in removing iron stains because of heavy molecular weight and low acidity. Poultices (bentonite, sepiolite, activated carbon fiber and celite) with oxalic acid were applied on contaminated ceramics. After ten hours, iron stains on ceramics were removed successfully by poultice. Among them, bentonite and sepiolite have better application. Therefore, sepiolite with 0.25M oxalic acid was applied on the iron stains of whiteware and celadon from Ma Island, and then stains were removed. However, it is judged that the application methods can be varied according to the form and depth of contaminant. In addition, the residues of poultice on the ceramics will be considered for preventing contamination.

• Journal of the Mineralogical Society of Korea
• /
• v.29 no.1
• /
• pp.11-22
• /
• 2016

The black fault gouge having 5-10 cm width occurs at the center of the fault fracture zone developed at the early Miocene basaltic rocks that is located at the Geumkwang-ri area in Donghae-myeon, Pohang city. The fault gouge was analyzed with XRD, FTIR, DTA/TGA, SEM, TEM, XRF, EPMA. Analyses reveal that the fault gouge is Fe-rich sepiolite having high iron content. Alteration minerals observed in the fault fracture zone are mainly smectite. The significant amount of smectite also observed in the basaltic parent rocks. The occurrence of constituent minerals indicates that the Fe-rich sepiolite was crystallized by faulting and hydrothermal alteration after the consolidation of basaltic rock at the deep place.

• Mineral and Industry
• /
• v.19 no.2
• /
• pp.33-39
• /
• 2006

• Journal of the Mineralogical Society of Korea
• /
• v.25 no.1
• /
• pp.37-40
• /
• 2012

• Proceedings of the Korean Institute of Building Construction Conference
• /
• 2023.11a
• /
• pp.71-72
• /
• 2023

As industrialization and urbanization accelerate, environmental issues have moved from local concerns to global issues. Among them, air pollution is the most important issue. Modern people spend more than 88% of their day indoors, but the concentration of fine dust and pollutants flowing indoors is increasing. The indoor environment has its own complexity, and various substances used indoors, such as building materials, furniture, electronics, and cleaning agents, emit chemical substances and cause various diseases. Therefore, when selecting building materials and interior finishing materials, the pollutant emission and adsorption capacity must be greatly considered. These considerations will ensure the construction of a sustainable future environment and a healthy life within that environment. Therefore, in order to reduce the generation of indoor air pollutants, this study aims to examine the fine dust adsorption properties of cement hardening materials using sepiolite, which has a porous structure and high absorption power among clay minerals. As a result of the experiment, it was found that the concentration of fine dust decreased as the addition rate of sepiolite increased. It is believed that the fine dust concentration was reduced due to the high porosity due to the microfibrous structure and large specific surface area of sepiolite, which has a porous structure among clay minerals. It is believed that these experimental results can be used as basic research for future use of sepiolite as a construction material.

• Proceedings of the Korea Concrete Institute Conference
• /
• 2006.05b
• /
• pp.49-52
• /
• 2006

Extrusion concrete panel is made by extrusion of high viscosity paste. The high viscosity paste is made by mix of cement, silica, reinforced fiber and thickening agent in the dry mixer and wet mixer subsequently, extrusion in the extruder, and curing in the normal steam curer and high pressure steam curer subsequently. To increase a flexural strength of the panel, it is used inorganic fiber as like asbestos. But it was known that the asbestos was harmful to human being lately, in the domestic area it is restricted usage in the construction materials. So, it is demanded the alternative material for asbestos in the extrusion concrete panel. This study is to investigate that the sepiolite is possible to be the alternative of asbestos. The 3 types of sepiolite is applied to the extrusion concrete panel. To investigate the properties of the panel with sepiolite, it is compared the control with asbestos in the flexural strength, the specific density and the spot compressive strength. From the test results, it was found that the panel with sepiolite B is higher than the control with asbestos in the flexural strength and in the density.

• Journal of the Mineralogical Society of Korea
• /
• v.26 no.2
• /
• pp.87-99
• /
• 2013

The occurrence, mineralogical characteristics, and origin of the dolomite ores were investigated from major dolomite mines in South Korea. Mineralogical and textural properties of the ores and associated minerals were analyzed using X-ray diffraction, thin section petrography, and scanning electron microscopy. Dolomite ores were light to dark gray in color and mainly composed of dolomite in varying particle size with minor amounts of calcite, quartz and micas. Calcite, quartz, illite, feldspar, kaolin minerals, and chlorite occurred in local veins, dikes and alteration zones. Sepiolite and wollastonite occurred in the altered part of some mine. Asbestos minerals such as chrysotile and tremolite, however, were not identified in the present study. Reddish brown to yellow clay materials were mainly composed of illite, occasionally associated with kaolin minerals and smectite. These clay minerals might be a product of the local hydrothermal alteration related to the dyke intrusion and subsequent weathering. As well indicated in the previous studies, mineral composition, texture, and occurrence of the dolostone beds suggest their formation through the diagenesis of carbonate sediments deposited in the shallow sea during the Precambrian to Paleozoic period.

• Journal of the Mineralogical Society of Korea
• /
• v.29 no.2
• /
• pp.35-45
• /
• 2016

Clays, which are abundant in nature and eco-friendly, have been utilized throughout human history due to their characteristic physicochemical properties. Recently, a variety of clays such as montmorillonite, kaolinite, sepiolite and layered double hydroxide with or without chemical modification have been extensively studied for potential application in industries. Clays that possess a large specific surface area, high aspect ratio, nanometer sized layer thickness and controllable surface charge could be utilized as polymer fillers after appropriate chemical modifications. These modified clays can improve mechanical and gas barrier properties of polymer materials but also provide sustained antibacterial activity to polymer films. Furthermore, engineered clays can be utilized as scavengers for chemical or biological pollutants in water or soil, because they have desirable adsorption properties and chemical specificity. In this review, we are going to introduce recent researches on engineered clays for potential applications in future industries such as food packaging and environmental remediation.

• Journal of the Mineralogical Society of Korea
• /
• v.23 no.4
• /
• pp.347-356
• /
• 2010

Bauxite is a main raw material for the production of alumina and aluminum hydroxide in the processing plant of KC company. It is a NORM (Naturally Occurring Radioactive Materials), and its waste, red mud, is a TENORM (Technologically Enhanced Naturally Occurring Radioactive Materials). The purpose of the geochemical and mineralogical investigations of the bedrock and soils in and around the plant, a large NORM source, was to provide basic data for measuring the radiation dose and protecting from radioactive hazards. Soils were mixtures of minerals derived from the country rock (quartz, feldspar, mica, kaolin, gibbsite, and sepiolite) and bauxite (hematite, boehmite, and calcite) of open-air storage. Average U and Th contents of the soil samples were 4.7 ppm and 23 ppm, respectively, indicating somewhat Th anomaly. The average concentrations of radionuclides are $^{40}K$ 100~1,433 Bq/kg, $^{226}Ra$ anomaly in the red mud open-air storage. Soil external hazard indices range from 0.10 to 1.66 with an average of 0.63. Although most of the indices are below 1.0 that is a regulation value, those of 4 samples of total 41 soil samples exceed 1.0, requiring further detailed investigation.