• Clean Technology
• /
• v.12 no.3
• /
• pp.151-156
• /
• 2006

Combined membrane process of ceramic microfiltration (MF) and polymer ultrafiltration (UF) was optimized for the removal of color and total organic carbon (TOC) from textile wastewater. Membrane regeneration was performed for the efficient operation by backflushing and chemical cleaning. Flux of 10.3% increased by the pulse backflushing of 1 second every 2 minutes in ceramic microfiltration. Membrane regeneration of 97% was obtained by chemical cleaning with 0.1% sodium hydroxide in polymer ultrafiltration. The removal efficiency of TOC, color and SS (suspended solid) were 84.6%, 97.4% and 100%, respectively. The combined process was found to be suitable for the removal of color and residual organics from textile wastewater.

• Proceedings of the Membrane Society of Korea Conference
• /
• 1995.04a
• /
• pp.67-67
• /
• 1995

Metal-working lubricants, metal-finishing bath wastes, mechanical oil-water emlsion 등과 같은 공업 폐수들은 보통 0.1 $\mu$m 이하의 크기를 가지는 oil-in-water 에멀젼이 약 2 wt% 정도 포함되어 있어, oil의 함량이 30 wt% 이상이 되도록 농축시킨다면 재사용이 가능하게 되며, 정밀여과막이나 한외여과막으로 oil을 분리할 수 있다. 본 실험에서는 압출성형법으로 제조한 튜브형 다공성 $\alpha-Al_2O_3$ 담체(평균 기공 크기 = 0.7 $\mu$m, 길이:200,600mm, 직경:8mm, 두께:0.8mm) 위에 슬립 캐스팅법을 이용하여 TiO$_2$ 막을 코팅한 후 925$\circ$C에서 2시간 동안 열처리하여 정밀여과용 세라믹 막을 제조하였다.

• Proceedings of the Membrane Society of Korea Conference
• /
• 1997.04b
• /
• pp.39-39
• /
• 1997

김치산업에서 원재료의 염적공정중에 발생하는 폐염적수를 처리하여 염적공정에 재사용하는 새로운 시스템을 개발하였다. 관형 정밀여과막을 사용한 본 연구에서 막오염의 감소와 높은 막투과유속의 유지를 위하여 산역세척과 투과수역세척이 도입되었고 대상이 되었던 세공크기가 비슷한 4종류의 막(Carbosep M14, Membralox Z100, Membralox A200, Microdyne MD020TP 2N)에 대하여 역세척의 효율이 각각 다르게 나타났다. 특히 지르코니아 재질의 막 표면과 탄소재질의 지지체로 이루어진 Carbosep M14 세라믹막은 투과수역세척시에 역세척을 하지 않았을 때 보다 오히려 투과유속이 감소하는 특이한 현상이 관찰되었고 이러한 역세척 효율의 차이의 원인을 규명하기위한 연구가 진행되었다. 4종류의 막에 대하여 전처리된 폐염적수의 여과시 진행되는 막오염 메카니즘을 알아보기 위하여 문헌에서 잘 알려진 4가지의 여과모델식을 적용하여 보았고 직렬여과저항모델을 이용하여 여과저항을 세분하여 측정하였다. 모델식의 적용결과 역세척의 효율이 좋은 3종류의 막에는 막표면의 케이크형성이 주된 투과유속의 감소원인임을 알아내었고 carbosep M14 막은 용존유기물의 비가역적인 흡착과 세공막힘이 주된 원인임을 알 수 있었다.

• Membrane Journal
• /
• v.22 no.4
• /
• pp.243-250
• /
• 2012

The effect of water back-flushing period (filtration time, FT) was investigated in hybrid process of alumina microfiltration and photocatalyst for advanced drinking water treatment in this study, and compared with the previous studies with carbon microfiltration or alumina ultrafiltration membranes. The FT was changed in the range of 2~10 min with fixed 10 sec of BT. Then, the FT effects on resistance of membrane fouling ($R_f$), permeate flux (J) and total permeate volume ($V_T$) were observed during total filtration time of 180 min. As decreasing FT, $R_f$ decreased and J increased as decreasing FT, which was same with the previous results with carbon microfiltration or alumina ultrafiltration membranes. The treatment efficiency of turbidity was high beyond 98.1%, and the effect of FT was not shown on treatment efficiency of turbidity, which was same with the previous result of carbon microfiltration. The treatment efficiency of organic matters was the highest value of 89.6 % at FT 8 min, which was a little higher than those of the previous results, and the effect of FT was not shown on treatment efficiency of organic matters.

• Journal of the Korean Ceramic Society
• /
• v.36 no.3
• /
• pp.244-254
• /
• 1999

폐윤활유 재생용 TiO2 한외여과막은 정밀영과용 지르코니아 복합막(즉, 복층담채) 및 알루미나 단층 담체(기공크기 0.1$mu extrm{m}$)상에 졸-겔 코팅법에 의하여 TiO2 분리막 층을 코팅하여 제조 하였다. TiO2 졸의 특성 분석을 통하여 봉입침지(sealed dip-coating) 및 가압 코팅(pressurized coating)법으로 결함이 없는 TiO2 복합막을 제조할 수 있는 코팅조건을 최적화 하였다. 합성 TiO2 한외여과막의 분리막층 두께는 1$\mu\textrm{m}$이하의 범위에서 조절되었으며,기공값을 보여주었으며 75$0^{\circ}C$까지 열처리하여도 80%정도의 용질배제율(기공크기 22.5nm)을 유지하는 점으로 봐서 고온 공정을 요하는 폐윤활유 재생막으로서 충분한 열적 안정성을 갖고 있었다.

• Proceedings of the Membrane Society of Korea Conference
• /
• 2004.11a
• /
• pp.121-124
• /
• 2004

• Proceedings of the Membrane Society of Korea Conference
• /
• 2005.11a
• /
• pp.268-272
• /
• 2005

• Membrane Journal
• /
• v.23 no.3
• /
• pp.211-219
• /
• 2013

Effect of water back-flushing period (FT) was investigated in hybrid water treatment process of carbon ultrafiltration and polypropylene (PP) beads coated with photocatalyst, and membrane effect was studied by comparing the previous studies with carbon microfiltration or alumina ultrafiltration, microfiltration membranes. FT 6 min was the most effective to control initial membrane fouling and optimal condition because the membrane fouling resistance was low until initial 60 min and the maximum total permeate volume was acquired at this FT. The turbidity treatment efficiency was high beyond 98.6%, and did not depend on FT, which was same with the previous result of carbon or alumina microfiltration. The organic matters treatment efficiency was the highest value of 98.2% at FT 6 min, which was almost same trend with the previous result of alumina microfiltration. Then the organic matters treatment efficiency of carbon microfiltration was the minimum at no back-flushing (NBF) and increased as decreasing FT, but that of alumina ultrafiltration was the maximum at NBF and also increased as decreasing FT. Therefore it means that water back-flushing effect on the organic matters treatment efficiency had a different mechanism depending on pore size in spite of the same material membranes.

• Proceedings of the Membrane Society of Korea Conference
• /
• 1994.10a
• /
• pp.80-80
• /
• 1994

세라믹막을 이용한 oil 폐수 처리의 기초 연구로서 정밀여과용 세라믹막의 제조와 oil(kerosene)-in-water 타입 에멀젼에 대한 막분리 효율이 연구되었다. 정밀여과 막으로서는 압출(extrusion)법으로 성형하여 제조한 $\alpha$-알루미나 튜브(평균 기공크기 0.9 $\mum$)와 이들 튜브(담체)내부에 $ZrO_2$ 또는 $Al_2O_3$ 다공성 박막을 코팅한 2층 구조의 복합막들을 사용하였다. 담체의 높은 투과율 ($1700 l/m^2\cdot h$ at $\Deltap = 1$ atm)을 어느정도 유지하면서 막분리 효율을 증대시킬 수 있는 새로운 슬러리 코팅법이 개발되엇으며, 코팅후 950-1300$\circ$C 에서 열처리한 코팅층의 두께와 평균 기공크기는 각각 5 - 20 $\mum$정도 이었다. 정밀여과막의 특성평가를 위하여 막 제조조건에 따른 코팅층의 두께 및 결함유무를 SEM으로 일단 관찰한 후에 Bubble Point Test와 Mercury Porosimeter를 이용하여 측정한 최대 및 평균 기공반경과 물의 투과량으로부터 막 전체에 대한 결함 유무와 결함의 허용한도등을 비교 분석하였다.

• Membrane Journal
• /
• v.22 no.3
• /
• pp.216-223
• /
• 2012

The effect of water back-flushing period (FT) was investigated in hybrid process of carbon fiber microfiltration membrane and photocatalyst for advanced drinking water treatment in this study, and compared with the previous study using alumina ultrafiltration membrane. The FT was changed in the range of 2~10 min with fixed 10 sec of BT. Then, the FT effects on resistance of membrane fouling ($R_f$), permeate flux (J) and total permeate volume ($V_T$) were observed during total filtration time of 180 min. As decreasing FT, $R_f$ decreased and J increased, which was same with the previous result using alumina ultrafiltration membrane. The treatment efficiency of turbidity was high beyond 99.2%, and the effect of FT was not shown on treatment efficiency of turbidity, which was different with the previous result. The treatment efficiency of organic matters was the lowest value of 65.6% at NBF, and it increased as decreasing FT, which was different with the previous result, too. The reason was that the membrane fouling phenomena could show a different mechanism depending on ceramic membrane materials.