• Journal of the Korean Ceramic Society
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• v.44 no.7
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• pp.393-402
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• 2007

Polyaluminocarbosilane was synthesized by direct reaction of polydimethylsilane with aluminum(III)-acetylacetonate in the presence of zeolite catalyst. A fraction of higher molecular weight polycarbosilane was formed due to the binding of aluminium acetylacetonate radicals with the polycarbosilane backbone. Small amount of Si-O-Si bond was observed in the as-prepared polyaluminocarbosilane as the result. Polyaluminocarbosilane fiber was obtained through a melt spinning and was pyrolyzed and sintered into SiC fiber from $1200{\sim}2000^{\circ}C$ under a controlled atmosphere. The nucleation and growth of ${\beta}-SiC$ grains between $1400{\sim}1600^{\circ}C$ are accompanied with nano pores formation and residual carbon generation. Above $1800^{\circ}C$, SiC fiber could be sintered to give a fully crystallized ${\beta}-SiC$ with some ${\alpha}-SiC$.

• Journal of the Korean Ceramic Society
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• v.45 no.4
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• pp.238-244
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• 2008

Modeling and FEM analysis on Boron Nitride and/or Pyrolytic Carbon coating layers on SiC fibers under indentation contact loadings are investigated. Especially this study attempts to model the mechanical behavior of the SiC fibers with and without coatings. Tyranno S grade and Tyranno LoxM grade of SiC are selected for fiber and Boron Nitride and/or Pyrolytic Carbon as coating material. The modeling is performed by SiC fiber without coating layer, which includs single(BN or PyC) and double(BN-PyC or PyC-BN) coating layer. And then the analysis is performed by changing a type of coating layer, a type of fiber and coating sequence. In this study, the concepts of modeling and analysis techniques for optimum design of BN and PyC coating process on SiC fiber are shown. Results show that stresses are reduced when indentation contact loading applies on the material having lower elastic modulus.

• Journal of the Korean Ceramic Society
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• v.51 no.6
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• pp.523-526
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• 2014

PZT($Pb(Zr_{0.53}Ti_{0.47})O_3$)/PVDF(poly vinylidene fluoride) nanofibers were prepared based on DMF (dimethylformamide) and acetone solvent by electrospinning. The optimum concentration of a PZT and PVDF composite solution for the formation of nanofibers was found by SEM (scanning electron microscopy) observations. XRD (X-ray diffraction) measurements indicated that the characteristics of PZT and PVDF coexisted. The effects of the PZT concentration on the tensile strength were investigated.

• Journal of the Korean Ceramic Society
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• v.40 no.5
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• pp.468-474
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• 2003

Activated carbon fibers were prepared from stabilized PAN fibers by physical and chemical activation to compare their characteristics. In this study, stabilized PAN fibers were activated by physical activation with steam and CO$_2$, and by chemical activation with KOH. The fabricated activated carbon fibers were evaluated and compared such as specific surface area, pore size distribution, pore volume, and amount of iodine adsorption. In the steam activation, a specific surface area of 1635 m$^2$/g was obtained after heat treatment at 990$^{\circ}C$. Otherwise, in the CO$_2$ activation, produced activated carbon fibers had been a specific surface area of 671 m$^2$/g after heat treatment at 990$^{\circ}C$. In chemical activation using KOH, a specific surface area of 3179 m$^2$/g was obtained with a KOH/ stabilized PAN fiber ratio of 1.5 : 1 at 900$^{\circ}C$. Nitrogen adsorption isotherms for fabricated activated carbon fibers showed type I and transformation from type I and II in the Brunauer-Deming-Deming-Teller (B.D.D.T) classification. Increasing specific surface area Increased the amount of iodine adsorption in both activation methods. Because the ionic radius of iodine was smaller than the interior micropore size of activated carbon fibers.

• Journal of the Korean Ceramic Society
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• v.38 no.10
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• pp.928-935
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• 2001

In this study, two kinds of activated carbon fibers were prepared from PAN-based stabilized fibers by physical activation with steam. The variations in specific surface area, amount of iodine adsorption and pore size distribution of the activated carbon fibers after the activation process were discussed. The activated carbon fibers were prepared by two different methods, namely a 1- and 2-step method. For the 2-step method, carbonization of fibers in $N_2$ atmosphere was carried out to make carbon fibers and then activated by steam. In normal two step steam activation, BET surface area of about $1019m^2/g$ was obtained in the study. In the 1-step steam activation process, the carbonization and activation were simultaneously carried out. In the one step steam activation, BET surface area of $1635m^2/g$ was obtained after heat-treatment at $990^{\circ}C$. However, nitrogen adsorption isotherms for oxidized PAN based activated carbon fibers that were prepared by both methods were type I in the Brunauer-Deming-Deming-Teller (BDDT) classification even though they have different BET surface areas, amounts of iodine adsorption and pore size distributions.

• Journal of the Korean Ceramic Society
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• v.41 no.7
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• pp.560-566
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• 2004

To fabricate the continuously porous alumina bodies by multi-extrusion process, carbon powder and ethylene vinyl acetate were used as a pore forming agent and a binder, respectively. As the change of extrusion pass number, reduction ratio as well as the volume fraction of core and tube, the porous alumina bodies having various kind of pore size and porosity could be obtained. The porous bodies showed continuous pore shape, high specific surface as well as high bending strength, which were compared with those of commercial alumina bodies. In-vitro study was carried out using MG-63 osteoblast cells to investigate of their biocompatibility. As a result, the cells grew well on top and bottom as well as inside surface of pore. From the result of in-vivo study of 3-dimensional porous alumina bodies using rats, it was confirmed that any inflammatory response was not found in the subcutaneous tissue around porous body. Also the porous bodies removed from the rats were fully covered with well-developed fibrous tissues and showed the formation of new capillary blood vessels.

• Journal of agriculture & life science
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• v.44 no.4
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• pp.21-27
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• 2010

This study was carried out to investigate the properties of woodceramics made from woody part of Broussonetia Kazinoki at different carbonizing temperatures of $600^{\circ}C$, $800^{\circ}C$, $1000^{\circ}C$and $1200^{\circ}C$. The physical and mechanical properties increased with increasing carbonizing temperature. The highest mean values of density, bending strength, Brinell hardness and compressive strength were $0.62g/cm^3$, $79kgf/cm^2$, $203kgf/cm^2$ and $129kgf/cm^2$, respectively. There were close correlations between density and bending strength, Brinell hardness and compressive strength and MOE and MOR.

• Journal of the Korea Organic Resources Recycling Association
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• v.17 no.2
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• pp.73-80
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• 2009

Biofilters use porous solid media to support microorganisms and allow access to the contaminants in the airflow. The characteristics of media used in biofilters vary greatly, and therefore it is important to select the appropriate media in order to obtain a large enough surface attachment area and uniform pore. This study was performed to compare hydrogen sulfide ($H_2S$) removal efficiencies of three biofilter media; coconut fiber, ceramic, and polyurethane. The biofilter packed with coconut fiber showed stable removal activity when inlet loading was changeable, and was restored rapidly when the moisture content decreased. However, the coconut fiber suffered from low durability. To cope with this problem a media of fibrinous polypropylene was developed to strengthen the durability of the coconut fiber. Biofilter column experiments using the fibrinous polypropylene media demonstrated over 99% of removal efficiencies at pH as low as 3 and 6 seconds of EBRT (empty bed gas residence time). Due to its superior physical characteristics, it is expected that the $H_2S$ treatment performance will increase when the new fibrinous polypropylne media is applied in commercial biofilter systems.

• Korean Journal of Materials Research
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• v.14 no.1
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• pp.59-66
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• 2004

In the present study, ceramic brake pads without fiber phases were manufactured by the low temperature heat treatment below$ 700 ^{\circ}C$. The manufacturing parameters of ceramic brake pads and those levels were investigated by the analysis results of signal-to-noise ratios, ANOVA based upon the Taguchi method. The ceramic brake pads prepared in the Mg experiment had a friction coefficient of 0.30～0.55 very close to the target coefficient (0.35～0.45) of commercial brake pads utilized in the automobiles. The frictional properties of ceramic brake pads could be stabilized with the adjustment of amounts of lubricating additives. The optimum preparation conditions as well as batch formulations for the fabrication of non-fibrous ceramic brake pads were finally determined using Taguchi method in this study.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.04a
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• pp.135-138
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• 2000

본 논문에서는 열팽창계수(CTE)가 거의 없는 카본게폭시, PZT 세라믹 박판, 그리고 열팽창계수가 큰 글래스/에폭시 층으로 이루어진 곡면형 복합재료 작동기(LIPCA)의 설계, 제작 및 성능실험에 대한 연구성과를 제시하고 있다. LIPCA의 른 요점은 기존 THUNDER의 성능을 유지하면서 이를 경량화 하기 위하여 THUNDER의 금속 층을 상대적으로 가벼운 섬유 강화 복합재료로 대체하는 것이다. 이러한 경량화 작업으로 LIPCA는 기존 THUNDER 보다 약 30~40% 정도의 무게를 감소시킬 수 있으며, 복합재료의 특성에 따라 설계의 유연성을 가질 수 있는 장점이 있다. 또한, 에폭시 수지를 사용함으로써 접착제 없이 평판 몰드에서 오토클레이브에서 177$^{\circ}C$로 경화되어, 탈형된 후 충분한 곡률을 형성하였다. 작동 성능 실험에서, LIPCA는 기존 THUNDER보다 작동변위가 향상됨을 보였다.