• Title/Summary/Keyword: 세라믹섬유

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Novel Phenol Resin Carbonizing Method for Carbon Interlayer Coating between Reinforcing Fiber and Matrix in Fiber Reinforced Ceramic Composite (페놀수지 탄화 코팅법을 이용한 섬유강화 복합재료 계면 형성에 관한 연구)

  • Kim, Se-Young;Woo, Sang-Kuk;Han, In-Sub
    • Journal of the Korean Ceramic Society
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    • v.46 no.3
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    • pp.301-305
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    • 2009
  • The novel carbon coating process for interlayer of fiber reinforced ceramic composites between fiber and matrix was performed by carbonizing phenolic resin solution that coated on fiber surface in $N_2$ atmosphere at $600^{\circ}C$ to improve the strength and fracture toughness of CMC(ceramic matrix composite). 160 nm carbon layer was coated on fiber surface with 5 vol% of phenolic resin solution. Since the process temperature ($600^{\circ}C$) is lower than chemical vapor deposition($900{\sim}1000^{\circ}C$), the strength and toughness could be preserved. Furthermore the coating thickness uniformity was improved to 8% of deviation along the stacking sequence. Therefore, prevention from fiber degradation during coating process and controlling coating thickness uniformity along the preform depth were achieved by coating with phenolic resin carbonizing method.

Study on the Polymer Gel Fiber of Alkali Resistance Zirconia System for GRC (GRC 제조용 내알칼리성 지르코니아계 고분자 겔섬유에 관한 연구)

  • 신대용;한상목;김경남;강위수
    • Journal of the Korean Ceramic Society
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    • v.31 no.8
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    • pp.934-940
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    • 1994
  • Fibers of ZrO2-SiO2 system were prepared from the hydrolysis and condensation of Si(OC2H5)4 and Zr(OnC3H7)4 with different H2O/alkoxide molar ratios. It was found that fibers could be drawn in the viscosity range of 1~100 poise from HCl catalyzed solutions with lower water contents of the mole ratio H2O/alkoxide, r 2. The fibrous gels were converted into the corresponding oxide glass fibers by heating at 80$0^{\circ}C$. Mechanical test was performed on E, A and 20ZrO2-80SiO2 glass fibers reinforced cement in order to investigate the flexural strength. The flexural strength value of 20ZrO2-80SiO2 glass fibers reinforced cement was greater than those of E and A. The chemical durability of the fibers in alkaline solutions increased with ZrO2 content. The weight loss due to the corrosion by 2N-NaOH solutions at $25^{\circ}C$ for 160 hours was about 0.31$\times$10-2 mg/dm2 for the 20ZrO2-80SiO2 glass fibers, which was superior to that of Vycor glass.

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A Study of the Physical Properties of Slurry and Mineral Hydrate Insulation Mixed with Polypropylene Fiber (폴리프로필렌 섬유 혼입 슬러리와 미네랄 하이드레이트 단열소재의 물리적 특성에 관한 연구)

  • La, Yun-Ho;Park, Jae-Wan;Chu, Yong-Sik
    • Journal of the Korean Ceramic Society
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    • v.52 no.1
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    • pp.13-18
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    • 2015
  • The fabrication method used for mineral hydrate is similar to that of ALC (autoclaved lightweight concrete), but the fabrication of normal slurry with a considerable amount of a foaming agent is difficult due to material separation and collapse of the slurry. Therefore, the development of fabrication methods for normal slurry is necessary. The final product, mineral hydrate insulation, has excellent thermal properties but poor strength characteristic given the many pores. In this study, in order to fabricate normal slurry, the viscosity and foaming time of the slurry were controlled. The mixing ratio of the starting material and the polypropylene fiber was controlled to improve the strength. Mineral hydrate with polypropylene fiber showed a higher strength than that without this type of fiber. Specifically, the compressive strength of mineral hydrate with 2% polypropylene fiber added to it was more than 40% higher than that without the fiber.

Formation of $Al_2O_3$-Ceramics by Reactive Infiltration of Al-alloy into Insulation Fiber Board (Al-합금의 단열섬유판 반응침투에 의한 $Al_2O_3$-세라믹스의 형성)

  • 김일수
    • Journal of the Korean Ceramic Society
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    • v.34 no.5
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    • pp.483-490
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    • 1997
  • Al2O3/metal composites were fabricated by oxidation and reaction of molten Al-alloy into two types of commercial Al2O3-SiO2 fibrous insulation board. The growth rate, composition and microstructure of these materials were described. An AlZnMg(7075) alloy was selected as a parent alloy. Mixed polycrystalline fiber and glass phase fiber were used as a filler. The growth surface of an alloy was covered with and without SiO2. SiO2 powder was employed as a surface dopant to aid initial oxidation of Al-alloy. Al-alloy, SiO2, fiber block and growth inhibitor CaSiO3 were packed sequentially in a alumina crucible and oxidized in air at temperature range 90$0^{\circ}C$ to 120$0^{\circ}C$. The growth rate of composite layer was calculated by measuring the mass increasement(g) per unit surface($\textrm{cm}^2$). XRD and optical microscope were used to investigate the composition and phase of composites. The composite grown at 120$0^{\circ}C$ and with SiO2 dopant showed rapid growth rate. The growth behavior differed a little depending on the types of fiber used. The composites consist of $\alpha$-Al2O3, Al, Si and pore. The composite grown at 100$0^{\circ}C$ exhibited better microstructure compared to that grown at 120$0^{\circ}C$.

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Preparation and Characterization of OXI-PAN Based Carbon Fibers Activated by Hydroxides (수산화물에 의해 활성화된 OXI-PAN계 섬유의 제조 및 특성)

  • Moon, Sook-Young;Han, Dong-Yun;Lee, Byung-Ha;Lim, Yun-Soo
    • Journal of the Korean Ceramic Society
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    • v.42 no.7 s.278
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    • pp.469-474
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    • 2005
  • Activated Carbon Fibers (ACFs) are widely used as adsorbents in technologies related to pollution abatement due to their highly porous structure and large adsorption capacity. The porous structure and surface area of ACFs depends strongly on both the activation processes arid the nature .of the precursors. The chemical activation with hydroxides has recently been, of great interest as it permits the preparation of activated carbon fibers with highly developed porosity. In this work, OXI-PAN fiber used as precursor for the preparation of activated carbon fibers by chemical activation with KOH and NaOH. The affects of several activation conditions on the surface properties, pore size distribution and adsorption capacity of Ag ion and Iodine ion on ACFs studied.

The Effect of Resin Impregnation Ratio on the Properties of Woodceramics Made from Broussonetia Kazinoki Sieb (수지함침율이 닥나무 우드세라믹의 성질에 미치는 영향)

  • Byeon, Hee-Seop;Kim, Jae-Min;Hwang, Kyo-Ki;Park, Seong-Cheol;Oh, Seung-Won
    • Journal of the Korean Wood Science and Technology
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    • v.38 no.3
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    • pp.178-184
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    • 2010
  • This study was carried out to investigate the properties of woodceramics made from woody part of Broussonetia Kazinoki at different impregnation ratios of phenolic resin of 40, 50, 60, 70%. The physical and mechanical properties increased with increasing impregnation ratio. The highest mean values of density, bending strength, Brinell hardness and compressive strength were 0.66 g/$cm^3$, 53 kgf/$cm^2$, 187 kgf/$cm^2$, 126 kgf/$cm^2$, respectively. There were close correlations between density and bending strength, Brinell hardness and compressive strength, and between MOE and MOR.

A Study of Fiber Reinforce Ceramic Composite for Protecting Antenna Cover of Ultrafast Aircraft (초고속 비행체 안테나 보호용 섬유강화 세라믹 복합체 특성 연구)

  • Jung Yeong-Chul;Lee Kyung-Won;Yook Jong-Gwan
    • The Journal of Korean Institute of Electromagnetic Engineering and Science
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    • v.17 no.3 s.106
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    • pp.295-306
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    • 2006
  • In this paper, we proposed and implemented a novel antenna cover mounted over a microstrip path antenna for ultrafast aircraft. A protective antenna cover prevents alteration in the electrical characteristics of the antenna due to environmental conditions. The permittivity of the cover materials should be practically invariable at all operating frequencies. We evaluated the characteristics of the antenna with both simulation and experiment. The experimental results show that the proposed antenna cover can be useful for ultrafast aircraft.

Slow-Cooling Calcination Process to Potassium Tetratitanate and Potassium Hexatitanate Fibers (서냉소성법에 의한 사티탄산칼륨 및 육티탄산칼륨 섬유의 합성)

  • 최진호;한양수;송승완
    • Journal of the Korean Ceramic Society
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    • v.30 no.8
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    • pp.664-670
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    • 1993
  • Potassium tetratitanate (K2Ti4O9) and Potassium hexatitanate (K2Ti6O13) fibers have been prepared by the slow-cooling calcination process in a temperature range from 125$0^{\circ}C$ to 95$0^{\circ}C$ using the K2CO3 and TiO2 as the starting materials. Optimum fiber growth conditions have been also investigated by changing the physical parameters, such as calcination time and temperature, and cooling rate. Relatively long K2Ti4O9 fibers ( 1.2mm) have been grown with quite a high aspect ratio (c/a 500)when the starting material with a nominal composition of K2O and TiO2 with 1:4 was calcined at 115$0^{\circ}C$ for 4h, and then was slowly cooled to 95$0^{\circ}C$ with a rate of 2$0^{\circ}C$/h. In case of a K2O.6TiO2 composition, acicular shaped K2Ti6O13 fibers with 20~300${\mu}{\textrm}{m}$ long and low aspect ratio (c/a 10~15) have been formed irrespective of the coolign rate. The growth condition of fibers have been discussed based upon the phase diagram of K2O-TiOa2.

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Fracture Behavior of $Al_2O_3$ Macro-composites with Layered and Fibrous Structure (층상 및 섬유상 $Al_2O_3$ 거시복합체의 파괴거동)

  • 신동우;윤대현;박삼식;김해두
    • Journal of the Korean Ceramic Society
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    • v.34 no.7
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    • pp.758-766
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    • 1997
  • Non-brittle fracture behaviour of the two composite structures made of two different brittle materials was investigated using 3-point bending test. First, the layered and fibrous macro-composites were fabricated using the material easily formed, yet showing a brittle fracture behaviour similar to ceramics. The layered and fibrous Al2O3 /Al2O3 composites with weak interface were also fabricated using plate of 2 mm thickness and rod of 3 mm diameter respectively. Comparison of the mechanical properties between these two structures was performed in the lights of flexural strength and work of fracture for the composites consisting of Al2O3 and simulated materials respectively. The strength ratio of layered structure to the monolith of same volume was 0.6 and the ratio of fibrous one was about 0.2 for the composites made of simulated brittle material. The ratio of the work of fracture of the fibrous to the layered was 0.47. For Al2O3/Al2O3 composites, the strength ratio of layered and fibrous structures to the monolith with same volume were about 0.6 and 0.2 respectively. The ratio of work of fracture of the fibrous to the layered was 0.6. These confirmed that the layered structure was superior to the fibrous one in terms of flexural strength and work of fracture.

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Structural Analysis and Characterization of PZT Fiber Fabricated by Electrospinning (Electrospinning법으로 제조된 PZT 섬유의 구조분석 및 특성평가)

  • Park, Chun Kil;Yun, Ji Sun;Jeong, Young Hun;Nam, Joong-Hee;Cho, Jeong Ho;Paik, Jong-Hoo;Jeong, Dae Young
    • Journal of the Korean Ceramic Society
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    • v.50 no.6
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    • pp.466-469
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    • 2013
  • Currently, piezoelectric ceramics are being applied in various fields, such as ultrasonic sensors, vibration devices, sound filters, and various energy conversion devices. Flexible piezoelectric ceramics are widely studied in an effort to mitigate the disadvantages of their brittle and inductile properties. Structural damage to piezoelectric fibers is much less than that to thin films when piezoelectric fibers are twisted or bent. Therefore, stretchable devices can be fabricated if piezoelectric fibers are obtained using an elongated substrate. In this study, sintering processes of PZT ($Pb(Zr_{0.53}Ti_{0.47})O_3$) fibers prepared by electrospinning were optimized through the TGA and XRD analyses. The crystal structure and microstructure of the piezoelectric fibers were investigated by XRD, FE-SEM and TEM.