• Transactions of the Korean Society of Automotive Engineers
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• v.13 no.5
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• pp.82-89
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• 2005

This study was performed to investigate the behavior and spatial distribution of fuel mixtures with different wall angle and diameter of piston cavity in a DI gasoline engine. The spatial distribution of fuel mixtures after impingement of the spray against a piston cavity is one of the most important. factors for the stratification of fuel mixture. Thus, it is informative to understand in detail the behavior and spatial distribution of fuel mixtures after impingement in the cavity. Two dimensional spray fluorescence images of liquid and vapor phase were acquired to analyze the behavior and distribution of fuel mixtures inside cylinder by exciplex fluorescence method. The exciplex system of fluorobenzene/DEMA in non-fluorescing base fuel of hexane was employed. Cavity wall angle was defined as an exterior angle of piston cavity. Wall angles of the piston cavity were set to 30, 60 and 90 degrees, respectively. The spray impinges on the cavity and diffuses along the cavity wall by its momentum. In the case of 30 degrees, the rolling-up moved from the impinging location to the round and fuel-rich mixture distributed at periphery of cylinder. In the case of 60 and 90 degrees, the rolling-up recircurated in the cavity and fuel mixtures concentrated at center region. High concentrated fuel vapor phase was observed in the cavity with 90 degrees. From. present study, it was found that the desirable cavity wall angle with cavity diameter for stratification in a Dl gasoline engine was demonstrated.

• Transactions of the Korean Society of Automotive Engineers
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• v.13 no.2
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• pp.178-185
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• 2005

The synergistic effect of ethylene/propane mixture on soot formation is studied experimentally using a concentric co-flow diffusion burner, which provides the stratified fuel mixture. The soot volume fraction, soot particle diameter, number density and PAH concentrations are measured with various fuel supply configurations and compared to the homogeneously mixed case. When propane is supplied through the inner nozzle, an increase of soot formation is observed. However, when propane is supplied through the outer nozzle, a decrease is observed. The reaction path of PAH's formed from the pyrolysis process of propane is likely to be responsible to the observed differences. When propane is supplied through the outer nozzle, PAH's are formed in the relatively near oxidation region and exposed to the oxidization environment; on the other hand, when propane is supplied through the inner nozzle, PAH's are not likely to be oxidized and thus get involved in soot formation process. The synergistic effect in ethylene/propane diffusion flames is found to be affected not only by the com position of the mixture but also by the way of mixing.

• Journal of the Korean Institute of Gas
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• v.14 no.6
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• pp.7-14
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• 2010

This study investigated the effect on reducing the pressure rise rate(PRR) in HCCI Engine by the variation of mixing ratio in the pre-mixture of DME and n-Butane that has different auto-ignition characteristics. In addition to measure of gas pressure in the engine cylinder, chemiluminescence image using the optical accessible engine and numerical analysis with multi-zones model were used to assess the combustion at each local area in the combustion chamber. The maximum PRR changes depending on mixing condition of DME and n-Butane. When DME is stratified and n-Butane is distributed uniformly, maximum PRR becomes lowest which is about 0.25MPa/ms and it corresponds to 5deg. retarding of CA50.

• Applied Chemistry for Engineering
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• v.20 no.6
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• pp.653-657
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• 2009

Nitrous oxide is a typical greenhouse gas which is produced from various organic or fossil fuel combustion processes as well as chemicals producing plants. $N_2O$ has a global worming potential of 310 times that of $CO_2$ on per molecule basis, and also acts as an ozone depleting material in the stratosphere. However, its removal is not easy for its chemical stability characteristics. Most SCR processes with several effective reducing agents generally require the operation temperature higher than $450^{\circ}C$, and the catalytic conversion becomes decreased significantly when NOx is present in the stream. Present experiments have been performed to obtain basic design data of actual application concerning the effects of $SO_2$ and $NH_3$ on the interim and long term activities of $N_2O$ reduction with CO over the mixed metal oxide (MMO) catalyst derived from a hydrotalcite-like compound precursor. The MMO catalysts used in the experiments, have shown prominent activities displaying full conversions of $N_2O$ near $200^{\circ}C$ when CO is introduced. The presence of $SO_2$ is considered to show no critical behavior as can be met in the $NH_3$ SCR DeNOx systems and the effect of $NH_3$ is considered to play as mere an impurity to share the active sites of the catalysts.