• Proceedings of the Korean Vacuum Society Conference
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• 2014.02a
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• pp.472.1-472.1
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• 2014

현재 Cu(In,Ga)Se2나 Cu2ZnSn(S,Se)4 (CZTSSe)계 박막태양전지의 버퍼층으로 가장 많이 사용되는 물질은 CdS이다. 하지만 Cd의 독성 문제로 인해 사용에 제약이 있고, CdS의 작은 밴드갭(~2.4 eV)으로 인해 단 파장 영역에서 광활성층의 빛 흡수를 저해하는 문제 때문에 새로운 대체 물질을 찾으려는 연구가 많이 이루어지고 있다. 이러한 관점에서, ZnS계 물질은 독성 원소인 Cd을 사용하지 않고, 3.6 eV 정도의 큰 밴드갭을 가지기 때문에, CdS 버퍼층을 대체하기 위한 물질로 관심을 받고 있다. ZnS계 버퍼층을 증착하는 위해 chemical bath deposition (CBD), molecular beam epitaxy (MBE), thermal evaporation, spray pyrolysis, sputtering, elecrtrodepostion 등의 다양한 공정이 사용될 수 있다. 본 연구에서는 상기의 다양한 공정 가운데, 공정 단가가 낮고, 대면적 공정에 용이한 CBD 공정을 이용하여 ZnS계 버퍼층을 증착하는 연구를 수행하였다. 용액의 조성, 농도, 공정 온도, 시간 등을 비롯한 다양한 공정 변수가 ZnS계 박막의 morphology, 조성, 결정성, 광학적 특성 등 다양한 특성에 미치는 영향이 체계적으로 연구되었다. 또한, 상기 ZnS계 버퍼층을 CZTSSe 박막태양전지에 적용하여 CdS를 성공적으로 대체할 수 있음을 확인하였다. 본 연구를 통하여 ZnS계 버퍼층이 향후 친환경적인 박막태양전지 제조에 활용될 수 있는 가능성을 확인할 수 있었다.

• The Magazine of the Society of Air-Conditioning and Refrigerating Engineers of Korea
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• v.30 no.8
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• pp.54-59
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• 2001

바낙 공기 급기(UFAD, underfloor air distribution)는 사무실과 상업 건물의 공조를 위하여 바닥 하부 공간을 사용하는 혁신적인 기술이다. 북미에서는 UFAD가 기존 천장 공기 급기 방식에 비하여 많은 장점을 지니므로 그 수요가 날로 증가하고 있다. 잘 설계된 UFAD 시스템은 다음과 같은 장점을 지닌다. - 건물의 용도 변경에 따픈 유연성이 우수하므로 건물의 생애 주기 비용을 감소시킨다. - 개별 쾌적성 제어가 가능하므로 온열 쾌적성, 거주자의 만족도 그리고 생산성을 향상시킨다. - 거주자주변에 직접 선선한 공기를 공급하므로 환기 효율, 실내 공기질 그리고 건강 상태를 향상시킨다. - 이코노마이저 운전, 온도 성층화 그리고 낮은 정합 운전에 의하여 에너지 비용을 감소시킨다. - 설비 공간이 축소되고 표준 철골 구조에서는 콘크리트 구조체 변경이 가능하므로 새 건축 공법에서는 충고를 감소시킬 수 있다. 1995년까지만 해도 UFAD는 파격적인 설계 기법이라고 여겨졌지만, 이제 설계자와 건축업자들은 2004년까지 신축되는 사무용 건축품의 35%는 바닥을 높인 기법이 적용되며 이 중 반 정도가 UFAD를 채택할 것이라고 예측하고 있다. 2000년 2억불이라고 추정되던 바닥을 높이는 건축의 시장 규모가 2004년에는 최소 10억불이 되리라고 예측된다. UFAD는 기본 연구에 의한 정립된 표준화된 설계 기법과 지침이 아직 마련되지 않았음에도 불구하고 현재 설계, 시공되고 있다. 이라한 경향은 펄수적인 연구가 수행되어 관련 업계가 지식과 경험을 충분히 쌓기 전까지는 계속될 전망이다. 본고는 시스템 설계와 운영의 주요한 특징, 기존 방식과 비교하여 지니고 있는 잠재적인 장점, 한계와 기술 개발의 필요성, UFAD 기술 개발을 위하여 계속적으로 요구되는 연구 분야 등을 서술함으로써 현재 UFAD 기술에 대한 평가를 한다.

• 한국해양학회지
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• v.27 no.3
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• pp.228-236
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• 1992

Internal temperature oscillations of tidal periods were studied using data observed by a thermistor chain in summer of 1980 off Jukbyun on the mid-east coast of korea. The vertical stratification was well established during the observation period. The spectral energy was found to be predominant in the semidiurnal tidal band and its energy increased with depth with maximum near the bottom. The coherence in the semidiurnal band between different depths is high with a small phase difference. The results suggest the existence of the internal tide of semidiurnal period. The amplitude of internal tide was of the order of 10 m and the largest just before the disappearance of the internal tide signal.

• Proceedings of the Korean Vacuum Society Conference
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• 2000.02a
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• pp.111-111
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• 2000

최근 질화물 반도체를 이용한 단파장 laser diode (LD)와 ultraviolet light emitting diode (LED)에 관한 관심의 증가로 인하여 AlGaN의 성장에 관한 연구가 많이 진행되고 있다. Metalorganic chemical vapor deposition (MOCVD)법을 이용한 AlGaN 성장에 있어서는 Al의 전구체로 널리 사용되고 있는 trimethylaluminum (TMAl)과 암모니아와의 기상에서의 adduct 형성을 억제하기 위하여 주로 저압에서 성장을 하거나 원료 가스의 유속을 증가시키는 방법으로 연구가 되고 있다. 또한, AlN의 경우 GaN보다 녹는점이 매우 높기 때문에 일반적으로 Al을 포함하는 질화물 반도체의 성장에 있어서는 GaN보다 녹는점이 매우 높기 때문에 일반적으로 Al을 포함하는 질화물 반도체의 성장에 있어서는 GaN 성장 시보다 높은 온도에서 성장이 이루어지고 있다. MOCND법을 이용하여 AlGaN를 성장시키는 대부분의 연구들은 100$0^{\circ}C$ 이상의 고온에서의 성장 온도가 AlGaN특성에 미치는 영향에 대한 것으로 국한되고 있다. 그러나, InGaN/GaN multiple quantum wells (MQWs) 구조의 LD나 LED를 성장시키는 경우 In의 desorption을 억제하기 위하여 MQWs층 위에 저온에서 AlGaN를 성장하는 데 있어서 AlGaN의 성장 온도를 500-102$0^{\circ}C$로 변화시키면서 AlGaN의 성장거동을 고찰하였다. GaN는 사파이어 기판을 수소분위기하에서 고온에서 가열한 후 저온에서 GaN를 이용한 핵생성층을 성장하고 102$0^{\circ}C$의 고온에서 1.2$\mu\textrm{m}$정도의 두께로 성장하였다. AlGaN는 고온에서 성장된 GaN 위에 200Torr의 성장기 압력 하에서 trimethylgallium (TMGa)과 TMAl의 유속을 각각 70 $\mu$mol/min 으로 고정한 후 성장온도만을 변화시키며 증착하였다. 성장 온도가 낮아짐에 따라 AlGaN의 표면거칠기가 증가하고, 결함과 관련된 포토루미네슨스가 현저히 증가하는 것이 관찰되었다. 그러나, 성장온도가 50$0^{\circ}C$정도로 낮아진 경우에 있어서는 표면 거칠기가 다시 감소하는 것이 관찰되었다. 이러한 현상은 저온에서 표면흡착원자의 거동에 제한이 따르기 때문으로 생각되어진다. 또한, 성장 온도가 낮아짐에 따라 AlGaN의 성장을 저해하기 때문으로 판단된다. 성장 온도 변화에 따라 성장된 V의 구조적 특성 및 표면 거칠기 변화를 관찰하여 AlGaN의 성장 거동을 논의하겠다.

• Journal of the Korean GEO-environmental Society
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• v.7 no.6
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• pp.57-65
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• 2006

In this study, WASP6 was used to predict the water quality of the reservoir and the lake. This can help the managers make the right choice of water quality policy. The results through studying are below. Raw pollutant load caused by the tourists in pollutant load of the study area takes 91.66% and 92.75% in total amount T-N, T-P. It showed high value when compared to raw pollutant load by land and stock farm and it seems that the main contamination is the population of tourists. From the result of the prediction model, BOD will increase about 1.5 times, T-N and T-P will be 1.5 times in 2012. It means that some counter plan is needed to reduce pollutant load. Enviroment grade of Suokjeong reserver is in I~II grade which is in good condition comparatively. However, the water contamination will be in poor as the year passes. when considering T-N T-P, which are the nutrients to control eutrophication, the concentrated administration about contamination sources is in urgent.

• 한국해양학회지
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• v.29 no.3
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• pp.269-277
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• 1994

Process of resuspension and accumulation well explaines the characteristics of surface sediment size distribution and suspended material in Deukryang Bay. Most of the surface sediments of the bay show asymmetric unimodal size distribution, which is found also in sediments from western part of the inner shelf mud area between Keomundo and Yokchido islands. Investigation of the size curves indicates that surface sediment in Deukryang Bay is a deposit of suspended coastal sediment transported east along southern coast of Korea. The distribution pattern of coarse sit fraction content in the surface sediment is very similar to that of computed current velocity (Lee, 1994), suggesting that fine sediment on the bed may reassumed and accumulate repeatedly due to shallow depth and strong tidal current in Deukryang Bay. The process of repeated resuspension and accumulate repeatedly due to shallow depth and strong tidal current in Deukryang Bay. The process of repeated resuspension and accumulation seems to be responsible not only to the asymmetric size distribution of the surface sediment, but also to the amount of suspended material in the bay. The difference of suspended material concentration between surface and near bottom water in summer is two times as large as that the in winter. This seems to derive from the fact that stratification of water mass prevails in summer, while total water mass is vertically mixed in winter. It was found that the most important factors to decide distribution of suspended material in Deukryang Bay are the physical properties of water mass such as current velocity and stratification, and water depth, in part with the supply of suspended sediment by rivers.

• The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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• v.2 no.2
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• pp.69-77
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• 1997

A 12-cm long sediment core was collected from a station in Lake Shihwa where high salinity-anoxic deep water is isolated from low salinity-oxic surface water by a strong halocline barrier. Unprecedented concentrations of porewater ammonia and lead are encountered: at 9 cm sediment depth ammonia builds up to 1420 ${\mu}M$ and at 3 cm lead to 1348 nM. As they are stable in anoxic condition, high concentrations of ammonia and lead suggest a development of notorious anoxic condition in the benthic environment of the lake. The degree of pollution of the deep water is likely to be directly proportional to the magnitude of benthic flux, because the deep water is isolated from the surface water by the halocline. Apparent coincidence of the ammonia residence time in the deep water with the elapsing time after the completion of the artificial lake construction, as about three years, suggests that the deep water pollution is being progressed entirely by benthic flux at least with respect to ammonia. The residence time for lead is such a short 20 days that it suggests a rapid return of the bottom water lead, which is originated from porewater by benthic flux, back to sediments probably as metal sulfide phases. The speculation on the return of lead as sulfide phases is likely to be supported by high concentration of hydrogen sulfide in the deep water and by high sinking rate of non-organic particles in Lake Shihwa.

• Journal of Conservation Science
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• v.36 no.5
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• pp.421-429
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• 2020

This study examined the manufacturing process of a furnace wall excavated from the Songdu-ri Site in Jincheon, and the difference in material composition between the 11 layers of the wall using physicochemical analyses. Based on microstructure observations, these layers could be largely divided into three groups: an undercalcined first layer, calcined second to ninth layer with evidences of partial heat, and non-fired soil layers from the tenth to the eleventh layer. Particle size analyses revealed that the fired layer constituted a relatively higher content of coarse sand than the non-fired layer. This difference was further confirmed by the results of the curvature coefficient analysis. An analysis of the constituent minerals showed similar overall XRD diffraction patterns between the different layers, but variations in the intensity of the low-temperature and high-temperature minerals. This indicates that the degree of heat was different. The thermal analysis results demonstrated that the heating peak of mullite was only reached in the first and second layers of the wall, thus implying these as the layers to be finally used. Consequently, no significant difference could be observed between the materials of the various layers of the wall. Thus, it can be suggested that the furnace wall was constructed using clay, which had a composition similar to that of the soil present in the area. However, the shape and characteristics of the constituent particles between the layers displayed partial variations, and it is possible that some external materials might have been added.

• Journal of Korea Water Resources Association
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• v.41 no.12
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• pp.1187-1198
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• 2008

Many reservoirs in Korea and their downstream environments are under increased pressure for water utilization and ecosystem management from longer discharge of turbid flood runoff compared to a natural river system. Turbidity($C_T$) is an indirect measurement of water 'cloudiness' and has been widely used as an important indicator of water quality and environmental "health". However, $C_T$ modeling studies have been rare due to lack of experimental data that are necessary for model validation. The objective of this study is to validate a coupled three-dimensional(3D) hydrodynamic and particle dynamics model (ELCOM-CAEDYM) for the simulation of turbid density flows in stratified Daecheong Reservoir using extensive field data. Three different groups of suspended solids (SS) classified by the particle size were used as model state variables, and their site-specific SS-$C_T$ relationships were used for the conversion between field measurements ($C_T$) and state variables (SS). The simulation results were validated by comparing vertical profiles of temperature and turbidity measured at monitoring stations of Haenam(R3) and Dam(R4) in 2004. The model showed good performance in reproducing the reservoir thermal structure and propagation of stream density flow, and the magnitude and distribution of turbidity in the reservoir were consistent with the field data. The 3D model and turbidity modeling framework suggested in this study can be used as a supportive tool for the best management of turbidity flow in other reservoirs that have similar turbidity problems.

• Korean Journal of Fisheries and Aquatic Sciences
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• v.27 no.5
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• pp.515-528
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• 1994

China Coastal Water(CCW) appeared in the neighbouring seas of Cheju Island has been analyzed and the results are as follows: The water with salinity below $32.20\%0$ in the neighbouring seas of Cheju Island in summer is thought CCW. During the period from April 1985 to August 1986, salinity of more than $34.00\%0$ was appeared in the Cheju Strait during January to mid May, but it decreased gradually from late May. CCW with salinity below $32.20\%0$ appeared in the Cheju Strait in early July and disappeared in October. The mean thickness of CCW in the Cheju Strait was about 25m and CCW had an influence of up to about 50m depth. And stratification structure of the Cheju Strait in summer was halocline between the surface and 50m depth and homogeneous salinity layer below 50m depth. It seems that although CCW appears in the wide area of neighbouring seas surface of Cheju Island in summer, the core of this CCW which has the lowest salinity flows into the Cheju Strait from the western seas of Cheju Island. This CCW flows out the east through the central part of the Cheju Strait and then seems to be transported further in the form of eddy.