• Title/Summary/Keyword: 섬유면적비

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Preparation of Densified ACFs for Electrodes of Electrical Double Layer Capacitor (전기이중층 캐패시터용 고밀도 활성탄소섬유 전극의 제조)

  • 최영옥;김종휘;양갑승
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.91-94
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    • 2003
  • 탄소재료는 높은 전기전도도 및 기계적 강도, 화학적 안정성, 큰 비표면적(1000~3000 $m^2$/g) 등의 특성 때문에 연료전지, 리튬이온 이차전지, 전기이중층 캐패시터(electric double layer capacitor, EDLC)의 전극활물질로 주목받고 있다[1]. 일반적으로 활성탄소섬유는 1000~3000 $m^2$/g의 비표면적을 갖기 때문에 종래의 필름 콘덴서와 세라믹 콘덴서에 비해 비약적인 고용량(체적당 수천 배, Farad급)을 얻을 수 있다. 전기이중층 캐패시터는 수명이 반영구적이며 사용온도의 범위가 넓고 안전하다는 장점을 지니고 있으며 이러한 캐패시터의 성능은 전극으로 사용되는 활성탄소 섬유의 비표면적, 세공의 크기, 구조 및 형태, 표면의 관능기 및 전기 전도도 등의 특성에 크게 좌우된다[1-3]. (중략)

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Effects of Aspect and Area Ratio of Fiber on the Accuracy of Intensity Method in Measurement of Fiber Orientation-Angle Distribution (섬유배향각 분포측정에 있어서 농도법의 정밀도에 미치는 섬유종횡비와 면적비의 영향)

  • Lee, S.D.;Kim, H.;Lee, D.G.;Han, G.Y.;Kim, E.G.
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.22 no.4
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    • pp.953-959
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    • 1998
  • To investigate accuracy of intensity method for measurement of the fiber orientation distribution, fiber orientation function is calculated by drawing simulation figures for the fiber orientation as varying fiber aspect ratio, fiber area ratio, and fiber orientation state, respectively. The values of fiber orientation function measured by intensity method are compared with the calculated values of fiber orientation function. The results show that measurement accuracy of the fiber orientation angle distribution by intensity method is affected by the fiber aspect ratio when the total length of oriented fiber is same. The average gradient of fiber orientation function is 0.94 for 1000mm of the total fiber length and is 0.93 for 2000 mm when the fiber aspect ratio is over 50. Measurement accuracy by intensity method is about 94% and the reliable data can be obtained by intensity method.

Effect of KOH Activation on Electrochemical Behaviors of Graphite Nanofibers (KOH 활성화 효과에 의한 흑연나노섬유의 전기화학적 거동)

  • Yoo, Hye-Min;Min, Byung-Gak;Lee, Kyu-Hwan;Byun, Joon-Hyung;Park, Soo-Jin
    • Polymer(Korea)
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    • v.36 no.3
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    • pp.321-325
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    • 2012
  • In this work, we prepared the activated graphite nanofibers (A-GNFs) via chemical activation with KOH/GNFs ratios in a range of 0 to 5. The effect of KOH activation was studied in the surface and pore properties of the samples for electrochemical performance. The surface properties of A-GNFs were characterized by XRD and SEM measurements. The textural properties of the A-GNFs were investigated by $N_2$/77 K adsorption isotherms using Brunauer-Emmett-Teller (BET) equation. Their electrochemical behaviors were investigated by cyclic voltammetry and galvanostatic charge-discharge performance. From the results, electrochemical performances of the A-GNFs were improved with increasing the ratio of KOH reagent. It was found that specific surface area and total pore volume of the A-GNFs were increased by KOH activation.

Sensing Properties of TiO2/ZnO Double-Layer Hollow Fibers Synthesized by Atomic Layer Deposition (원차층증착법으로 제작된 TiO2/ZnO 이중층 중공 나노섬유의 가스 감응 특성)

  • Kim, Jae-Hun;Park, Yu-Jeong;Kim, Jin-Yeong;Kim, Sang-Seop
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.133-133
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    • 2016
  • 화학저항식(Chemiresistive) 가스센서의 저항변화를 향상시키기 위해서는 센서 소재의 비표면적을 향상시키는 방향 및 전자천이를 증가시키는 방향으로 연구가 진행되어야 하며, 그 중 센서의 비표면적을 향상시키는 예로써 중공 나노섬유가 있을 수 있다. 본 연구에서는 비표면적의 향상뿐만 아니라 중공 나노섬유의 전자천이를 증가시켜 센서의 검출 성능을 더욱 향상시키기 위한 목적으로 $TiO_2/ZnO$ 이중층 중공 나노섬유를 제안하었다. 제안된 $TiO_2/ZnO$ 이중층 중공 나노섬유는 템플레이트 합성법을 통해 제작되었으며, 그 공정은 다음과 같다; 전기방사(Electrospinning) 공정을 통해 폴리머 나노섬유를 제작한 후 $TiO_2$ 층과 ZnO 층을 ALD(Atomic Layer Deposition) 공정을 통해 차례대로 증착시킨다. 그 후 후열처리 공정을 통해 코어 폴리머를 제거함으로써 $TiO_2/ZnO$ 이중층 중공 나노섬유를 얻을 수 있다. 이 때, ZnO 층의 두께는 각각 달리하여 제작되었으며, 최종적으로 이들에 대한 가스 센싱 특성 및 메커니즘에 대한 체계적인 조사를 진행하였다. 단층 중공나노섬유는 셀 층의 두께가 Debye length와 유사할 때 셀 층 표면이 완전공핍층이 형성되고, 그 보다 크게 되면 부분적인 공핍층이 형성되게 되어 감응도가 감소하게 된다. 그러나 이중층 중공 나노섬유의 경우 셀 층의 두께가 Debye length 보다 더 크게 되더라도 TiO2와 ZnO의 헤테로접합으로 인해 ZnO에서 TiO2로 전자의 이동을 야기시키게 되어 환원성 가스에 대한 감응도가 단층 ZnO 중공 나노섬유에 비해 향상되게 된다.

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Characteristics of Carbon Nano-fibers and Their Applications (탄소나노섬유의 특성과 응용)

  • Yang, Kap-Seung;Kim, Bo-Hye;Lee, Wan-Jin
    • Polymer Science and Technology
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    • v.21 no.2
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    • pp.149-156
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    • 2010
  • 전기방사 탄소섬유와 s-VGCFs는 그 미세구조의 특성 때문에 응용분야가 서로 다르다. 전기방사 탄소나노섬유는 유기물을 섬유화하고 그것을 탄화하기 때문에 VGCFs에 비해서 낮은 가격에 대량생산이 가능하고 촉매를 사용하지 않기 때문에 전극으로 사용할 경우 금속불순물에 대한 부반응의 우려가 없다. 한편, 결정성이 낮고 세공이 잘 발달되어 비표면적이 크기 때문에 이온을 흡착해서 에너지를 저장하는 전기화학 캐패시터나 가스 흡착 분리나 촉매의 지지체로 사용하는데 장점이 있다. 이에 비해서 s-VFCFs는 섬유의 직경이 기존의 VGCF에 비해서 작으면서 잘 발달된 흑연구조가 동심원 구조를 하고 있어 굴곡강도가 크고 열 및 전기전도도가 우수하여 납축전지나 Li 이온전지의 충전제로 사용하여 역학적 특성과 향상시켜 주는 역할을 한다. 또한, 금속과 복합화하여 가벼우면서도 강도를 증가시켜주는 보강재로 사용가능하다.

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Wettability Evaluation of Resin on the Glass Fabric (유리섬유직물에 대한 수지의 젖음성 평가)

  • Han, Seung-Wook;Choi, Nak-Sam;Lee, Min-Soo;Ahn, Hung-Kun
    • Composites Research
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    • v.24 no.2
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    • pp.30-37
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    • 2011
  • Analysis of wettability between epoxy resin and glass fabric was studied. The mixing ratios of epoxy resin and anhydride hardener were varied as 1:0.5, l:l and l:1.2. Catalyst content was fixed as 0.1wt% of the mixed resin. A curing analysis by differential scanning calorimeter(DSC) showed a possible impregnation of the mixed resin at the room temperature. An effective contact angle of the mixed epoxy resin drop onto the glass fabric being preset on a flat glass plate was measured as a function of time. The wet area of the epoxy resin drop was also measured. Behaviors of the contact angle, the droplet height, the neat wet area and the coefficient of wettability were used to evaluate the wettability of the epoxy resin onto the glass fabric. It was concluded that the equivalent ratio of 1: 1.2 was the most suitable for the wettability.

An Experimental Study on the Properties of Engineering and Shrinkage Cracking Reduction of Fiber Reinforced Concrete Using Recycled Fine Aggregate (섬유보강 순환잔골재 콘크리트의 공학적 특성 및 수축균열저감특성에 관한 실험적 연구)

  • Kim, Gyu-Yong;Nam, Jeong-Soo;Kim, Moo-Han;Lee, Do-Heun;Song, Ha-Young
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.4 no.3
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    • pp.82-89
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    • 2009
  • Recently, the study is progressing actively about manufacture skill of concrete for promoted recycled aggregate and concrete made into recycled aggregate in the construction production field. But, application and study about recycled fine aggregate insufficient compared to recycled coarse aggregate. So, in this study, it presents basic data for development of environmental load reduction fiber reinforcement recycled fine aggregate concrete by comparison and investigation about engineering properties and shrinkage cracking of fiber reinforcement recycled find aggregate concrete for increasing shrinkage cracking reduction and long term stability of environmental load reduction concrete used recycled fine aggregate. In the result of the study, compared to natural fine aggregate, a crack-extent increased by applying recycled fine aggregate, moreover, as a water cement ratio increased, the crack size increased, as well. In addition, it's shown that the specimen mixed with PVA and Nylon, among all kinds of fibers, showed the smallest crack size, so it's verified that the mix of fiber had an effect on decreasing crack-extent.

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A Study on the Confined Effects of Highly Moistured Soils Reinforced with Geosynthetics (토목섬유가 보강된 고함수비 흙의 구속효과에 관한 연구)

  • Yoo, Jae-Won;Im, Jong-Chul;Kang, Sang-Kyun;Lee, Hyung-Jun;Choi, Moon-Bong
    • Journal of the Korean Geosynthetics Society
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    • v.18 no.1
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    • pp.25-37
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    • 2019
  • This study confirms reinforcing effect of geosynthetics in the use of soil at higher water contents as a compaction material on compaction tests, field compaction tests, and numerical analysis. To verify a confined effect, a large mold(area ratio of rammer / mold = 0.19) larger than D compaction mold(area ratio of rammer / mold = 0.33) was performed for compaction. It showed that in the D compaction test, dry density were 0.5~0.6% increases and in the compaction test using the large mold, it were 2.4~3.7% increases at high water contents. It shows that when the area of compacted area is large enough, a confined effect could be arising from the reinforcement of geosynthetics even at high water contents. As a result of analyzing of compaction effects according to 'depth(z/B) from compacted surface' in the field, when not reinforced, the compaction state deteriorated due to the over-compaction and the compaction did not work well. However, when reinforcement of geosynthetics, restraint effect by geosynthetics occurs, it is confirmed that the compaction energy is effectively transferred to the compaction layer and the dry density is increased. Also, through the conceptual model of the behavior of geosynthetic and soil layer, the mechanism in the ground due to reinforcement of geosynthetics is presented and it is verified through finite element analysis.

A Study on the Tear Behavior of Woven Fabric with Wire Mesh (매쉬 직물을 이용한 직물의 인열 거동 연구)

  • ;Seung-Yun Lee
    • Proceedings of the Korean Fiber Society Conference
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    • 2003.04a
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    • pp.130-131
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    • 2003
  • 산업용 직물은 다른 건축재료에 비해 유연성이 크고 재료무게에 비해 카버하는 면적이 넓어서 장기적인 고정 건축물이 아닌 경우에 그 이용도가 늘어나고 있다. 이러한 산업용 직물의 주 기능은 예정 사용기간 동안 직물 양면사이의 압력을 견디는 일이 주 부하 모드이며 이 이차원구조를 유지하는 부분은 이 구조를 잡고 있는 부분이다. 그러나 직물의 일부가 파손되어 압력차를 유지하지 못하면 공압을 이용한 건축물의 순간적인 파괴로 연결된다. (중략)

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Accuracy Comparison between Intensity Method and Count Method in Measurement of Planar Orientation of Fibers Using Image Processing (화상 처리를 이용한 섬유 배향각 분포 측정에서 농도법과 카운트법의 정확도 비교)

  • Lee, S.D.;Kim, H.;Lee, D.G.;Han, G.Y.;Kim, E.G.
    • Journal of the Korean Society for Nondestructive Testing
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    • v.18 no.5
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    • pp.357-364
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    • 1998
  • To investigate accuracies between intensity method and count method for measurement of the fiber orientation distribution, fiber orientation function is derived by drawing simulation figure for the fiber orientation as varying fiber aspect ratio, fiber area ratio, and fiber orientation state, respectively. The values of fiber orientation function measured by intensity method and count method are compared with the calculated ones from simulation figures. The results show that measurement accuracy of fiber orientation angle distribution obtained by count method is by 4% higher than that by intensity method.

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