• Journal of the Korean Chemical Society
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• v.55 no.2
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• pp.177-182
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• 2011

A diketo-type ligand was synthesized by the Knoevenagel condensation reaction of thiophene-2-aldehyde with acetylacetone, subsequently its transition metal complexes with Cu(II), Ni(II), and Co(II) chlorides were also prepared. All the complexes were characterized by various physico-chemical methods. The molar conductivity data reveals ionic nature for the complexes. The electronic spectrum and the EPR values suggest square planar geometry for the Cu(II) ion. Interaction of the Cu(II) complex with CTDNA (calf thymus DNA) was studied by absorption spectral method and cyclic voltammetry. The $k_{obs}$ values versus [DNA] gave a linear plot suggesting psuedo-first order reaction kinetics. The cyclic voltammogram of the Cu(II) complex reveals a quasi-reversible wave attributed to Cu(II)/Cu(I) redox couple for one electron transfer with $E_{1/2}$ values -0.240 V and -0.194 V. respectively. On addition of CTDNA, there is a shift in the $E_{1/2}$ values 168 mV and 18 mV respectively and decrease in Ep values. The shift in $E_{1/2}$ values in the presence of CTDNA suggests strong binding of Cu(II) complex to the CTDNA.

• Journal of the Korea Society of Computer and Information
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• v.18 no.10
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• pp.141-148
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• 2013

This paper proposes an EMS algorithm designed to determine the optimal locations for Emergency Medical Service centers that both satisfy the maximum ambulance response time T in case of emergency and cover the largest possible number of residents given a limited number of emergency medical services p in a city divided into different zones. This methodology generally applies integer programming whereby cases are categorized into 1 if the distance between two zones is within the response time and 0 if not and subsequently employs linear programming to obtain the optimal solution. In this paper, where p=1, the algorithm determines a node with maximum coverage. In cases where $p{\geq}2$, the algorithm selects top 5 nodes with maximum coverage. Based on inclusion-exclusion method, this selection entails repeatedly selecting a node with the maximum coverage when nodes with lower numbers are deleted. Among these 5 selected nodes, the algorithm selects a single node set with the greatest coverage and thereby as the optimal EMS location. The proposed algorithm has proven to accurately and expeditiously obtain the optimal solutions for 12-node network, 21-node network, and Swain's 55-node network.

• Journal of the Economic Geographical Society of Korea
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• v.12 no.4
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• pp.521-539
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• 2009

This study investigates the time-space characteristics of the road traffic flows in Seoul and the relationship with land use patterns. For the purpose, we analyze the road traffic data collected at 118 observation sites over Seoul City area since 1993. We examine the time-trend of the annual average traffic flows per day during the last fourteen years. Three different trends are revealed: rapid increase during the time period between 1993 and 1997, maintenance same level after sharp decrease between year 1997 and 1998, and gradual decrease after sharp decrease between year 2003 and 2004. The spatial distribution patterns of road traffic flows have also been changed significantly during the period. The traffic flows in the urban center have been declined gradually, while the traffic flows in the boundary area and southern CBDs have increased dramatically. In order to examine the relationship with the changes in the land-use patterns and road traffic flows, we analyze the changes in the spatial distribution patterns of population and industries. We developed three multiple linear regression models to test the relationships between the changes in the land-use variables and road traffic flows.

• Proceedings of the Korea Water Resources Association Conference
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• 2016.05a
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• pp.467-467
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• 2016

암거는 일반적으로 용수나 배수용의 수로가 도로, 철도, 제방 등의 아래에 매설 된 수로를 지칭한다. 이러한 암거는 산업발전으로 사회기반시설의 신설 및 확충, 재정비 등으로 많이 활용되고 있다. 최근 들어 기후로 인한 재해가 급증하면서 이러한 시설물에 대한 안정성 및 관리에 대한 관심이 높아지고 있는 것이 현실이다. 특히 소하천은 집수면적 및 유로연장이 짧고 하상경사가 급하기 때문에 홍수에 취약하다. 즉, 빨라진 유속으로 인해 구조물 주변의 세굴에 의한 유실, 토사유출로 인한 하상퇴적, 부유물로 인한 차단으로 인해 통수에 지장을 받아 피해가 발생하게 된다. 이러한 암거시설물 피해는 2차 피해로 이어질 수 있으며 사회기반시설 파괴로 도시기능이 마비되고 인근 주변지역에 침수로 인한 재산 및 인명피해까지 발생시킬 수 있는 피해 잠재능력을 보유하고 있다. 그러나 피해에 대한 예방대책은 유지관리를 통해 지속적으로 관리하는 것이 대부분의 지침 등에 소개된 내용들이다. 본 연구에서는 암거를 대상으로 암거의 폐색으로 인해 암거주변에서 변화되는 흐름특성을 축소모형을 통해 검토하고자 하였다. 암거 축소모형실험은 1.5m 폭을 갖는 직선수로에서 수행하였으며, 암거모형은 도로암거표준도(2008)를 참조하여 $3m{\times}3m$ 수로암거를 대상으로 1/10 축소모형을 제작하였다. 암거유입부 퇴적으로 인한 암거의 차단률(차단면적/암거단면적)은 차단이 발생하지 않는 0% 조건에서부터 10%, 20%, 30%, 40%, 50% 조건에 대해 실험을 수행하였다. 실험결과 차단에 따른 암거 상류단의 수위는 차단이 없는 암거의 경우에 비해 차단율이 높아질수록 암거유입부 수위는 20.4% ~ 82.7% 상승하는 것으로 나타났다. 암거의 차단률이 40% 이상일 경우 높아진 수위로 인해 암거통로의 윗상면부까지 다다르고 있으며 50%일 경우 암거를 통과하는 흐름이 자유수면흐름이 아닌 오리피스 흐름이 발생하는 것으로 나타났다. 암거유입부 차단으로 인한 암거주변의 최대유속은 암거 직하류부에서 주로 발생하여 암거 유출부에서의 최대유속은 차단율이 증가할수록 선형적으로 증가하는 것으로 나타났으며 암거 유출부에서의 유속은 차단전의 조건(0%) 대비 4.2% ~ 35.5% 까지 상승하는 것으로 나타났다. 이와 같은 결과를 토대로 고려하였을 때 대부분 산지부에서 설치되는 암거의 경우 유속이 불가피하게 증가하게 됨으로 유속에 따른 유속조절방안(차단 및 우회시설) 및 세굴대책을 세워야 할 것으로 판단된다.

• Proceedings of the Korea Water Resources Association Conference
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• 2018.05a
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• pp.248-248
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• 2018

새만금 종합개발계획(정부, 2011)에 따른 내부개발의 완료시점은 2030년이며, 방수제 공사와 준설 등과 같이 만경강 및 동진강 유역 내 흐름을 변화시킬 수 있는 공사를 포함하고 있으므로 현재와 2030년의 하천 및 호의 수리특성은 다를 것이라 예상된다. 2030년까지 준설상황 등을 예측하여 반영하는 것은 사실상 불가능하기 때문에 새만금 종합개발계획에서 제시하고 있는 내부개발의 완료시점을 기준으로 홍수사상을 모의하였다. 새만금 호의 물리적인 변화는 수리특성의 변화로 이어질 수 있으며, 이는 상류지역으로 전파가 될 수 있으므로 호내 뿐만 아니라 만경강과 동진강 전역에 대한 홍수시의 수리특성을 검토하였다. 새만금 호와 연결된 만경강과 동진강의 설계홍수량은 대부분의 구간에서 100년 빈도이기 때문에 본 연구에서는 100년 빈도 홍수사상에 대한 분석을 기초로 홍수위 검토를 수행하였고, RCP8.5 시나리오를 적용한 100년 빈도 홍수량과 500년 빈도 홍수량에 대한 추가적인 연구를 수행하였으며, 이 결과를 토대로 취약지구 분석 및 대책 등을 제시하였다. 수치모의는 Delft3D를 이용하였으며, 새만금 유역의 동진강 지구의 실측치와 비교함으로써 모델의 적용성을 검증하였다. 서해안 조위 특성상 새만금 방조제는 조위 영향이 크므로, 이에 본 연구에서는 외조위의 특성을 고려하기 위해 새만금 유역 주변의 12개 조화상수(tidal harmonic constant)를 이용하여 조위에 대한 모의를 별도로 수행하고, 이 결과를 배수갑문의 경계조건으로 이용하였다. 상류 경계조건은 하천기본계획상에 제시된 하천은 이를 이용하였으며, 그 외의 소하천은 유역면적을 이용한 계산법을 사용하여, 선형적 면적 비유량(Specific Discharge, SD) 방법을 적용하여 본류의 유량에 부가하는 방식으로 수행하였다. 수치해석 결과, 준설 구간의 수위는 전반적으로 저하되었으며, 거리에 따른 수면의 경사를 분석한 결과 기존의 하천구역이 준설 등으로 인하여 호수의 특성으로 변화된 것으로 확인하였다. 본 연구에서 취약지구는 홍수위가 제방고의 약 80% 이상 되는 지역으로 결정하였으며, 이를 토대로 취약지구 분석을 수행한 결과 기존 100년 빈도에서 1지점, RCP 8.5 시나리오가 적용된 100년 빈도에서 88지점, 500년 빈도에서 125지점이 잠재적인 치수 위험이 있는 것으로 파악되었다. 기존의 1차원 연구결과와는 차이가 있는 부분은, 다수의 취약지구가 만곡부 또는 합류부 인근에 위치한 것이다. 향후 이러한 상대적인 치수 취약지점에 대해 정밀하고 국부적인 연구를 수행하여 정확한 홍수위 예측을 수행해야 할 것이다.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.6
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• pp.349-356
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• 2021

Since the 1960s, traffic infrastructure, such as bridges, has increased rapidly in Korea as urbanization and industrialization progressed due to economic growth. As the scale of the bridge becomes larger, stability analysis of the superstructure of the bridge is being conducted actively, but scour stability analysis for the substructure of the bridge has not been conducted sufficiently. This study is a basic investigation to prevent large-scale disasters caused by scouring in bridge piers. A simple linear regression model was used to analyze the scour depth calculated through seventeen scour depth calculation formulae, and the scour depth measured through hydraulic model experiments. As a result, the Coleman (1971) formula was the best method among the scour depth calculation formulae, and the Froehlich (1987) formula was the most effective method for calculating the scour depth. In addition, a review using a simple regression model confirmed that the scour depth calculation formulae of CSU (1993), Coleman (1971), and Froehlich (1987) can predict a similar scour depth by reflecting domestic stream characteristics. This study can calculate the scour depth reflecting the environmental conditions of Korea in future stream design.

• Journal of Wetlands Research
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• v.24 no.1
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• pp.59-67
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• 2022

The interest in LID facilities is increasing worldwide for recovery of natural water cycle system to destroy by urbanization. However, problems are raised when installation of LID because comprehensive analysis about design capacity adequacy of LID facilities was not conducted completely. In this research, removal efficiency and design volume adequacy of LID facilities were analyzed based on rainfall monitoring data in four LID facilities(Vegetated Swale, Vegetative Filter Strip, Bio-Retention and Permeable Pavement). As a result, group of LID facility designed on WQV was shown higher flow(37%) and pollutants(TSS, BOD, TN and TP) removal efficiencies(20 ~ 37%) than group of LID facility designed on WQF. SA/CA graph was drawn for evaluation of design volume adequacy based on rainfall monitoring data. In this SA/CA graph, coefficient of determination show over 0.5 in all parameter, especially, Flow and TP were show over 0.95. And, 'SA/CA & L/CA' graph considering difference of structure mechanism in LID facility suggested in this research was confirmed that improved coefficient of determination in flow, TSS and TP than SA/CA graph. According to this research results, feasibility of applying 'SA/CA & L/CA' graph for evaluation of design volume adequacy in LID facility, and it is necessary to follow up research for generalization and normalization.

• Journal of the Korean Geotechnical Society
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• v.23 no.7
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• pp.57-64
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• 2007

This study proposes a method to estimate drilling torque during ground boring with an aid of electrical energy required for rotating a boring-auger. Ground boring is commonly used in geotechnical engineering such as preboring precast pile installation, soil-cement grouting, ground exploration and so forth. In order to understand the correlation between required electrical energy to rotate the boring auger and the drilling torque, a small laboratory apparatus was designed and a pilot study was performed. The apparatus rotates common drill bits of $D=5{\sim}25mm$ in CBR specimens. The velocity of a bit is 19 RPM and predefined using a reduction gear which connects a main rotation axis to a 25 Watts AC electrical motor shaft. In the middle of drilling the motor current increments and the drilling torque were measured and the correlation between the current and the torque was obtained through linear square fits. Based on the correlation the acquired motor current during drilling was applied to predict the drilling torque in consequent testing and the prediction results were compared to the measured torque. The comparison leads a conclusion that the motor current during drilling using electrical power may be a good indicator to estimate/determine strength characteristics of the ground.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.1B
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• pp.65-77
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• 2008

The effects of climatic changes owing to urbanization, geographical and topographical conditions on annual and monthly FAO Penman-Monteith (FAO P-M) reference evapotranspiration, and energy and aerodynamic terms of FAO P-M reference evapotranspiration were studied. In this study, 21 climatological stations were selected. The statistical methods applied for trend analysis are Spearman rank test, Sen's test, linear regression analysis and analysis of actual variation ratio. Furthermore, the cluster analysis was applied to cluster 21 study stations by considering the geographical and topographical characteristics of study area. The study results indicate that urbanization affects the trend and amount of FAO P-M reference evapotranspiration, energy term and aerodynamic term; however, the result of Sen's test indicates that urbanization does not significantly affect the magnitude of trend (Sen's slope). The energy term increased at study stations located in coastal area; however, decreased at study stations located in inland area. The topographical slope of study area did not significantly influence on the trend of energy term. The aerodynamic term increased in both coastal area and inland area, indicating much significantly increasing trend in inland area, and it was also affected by the topographical slope of the study area.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.2B
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• pp.215-224
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• 2008

The effect of streamflow considering future land use change and vegetation index information by climate change scenario was assessed using SLURP (Semi-distributed Land-Use Runoff Process) model. The model was calibrated and verified using 4 years (1999-2002) daily observed streamflow data for the upstream watershed ($260.4km^2$) of Gyeongan water level gauging station. By applying CA-Markov technique, the future land uses (2030, 2060, 2090) were predicted after test the comparison of 2004 Landsat land use and 2004 CA-Markov land use by 1996 and 2000 land use data. The future land use showed a tendency that the forest and paddy decreased while urban, grassland and bareground increased. The future vegetation indices (2030, 2060, 2090) were estimated by the equation of linear regression between monthly NDVI of NOAA AVHRR images and monthly mean temperature of 5 years (1998-2002). Using CCCma CGCM2 simulation result based on SRES A2 and B2 scenario (2030s, 2060s, 2090s) of IPCC and data were downscaled by Stochastic Spatio-Temporal Random Cascade Model (SST-RCM) technique, the model showed that the future runoff ratio was predicted from 13% to 34% while the runoff ratio of 1999-2002 was 59%. On the other hand, the impact on runoff ratio by land use change showed about 0.1% to 1% increase.