• Title/Summary/Keyword: 선택적 추출법

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Study on purification and extraction of nitrate salts from waste scrubbing liquid of de-SOx/de-NOx (탈질/탈황 폐 세정액으로부터 질산염 추출 및 정제 연구)

  • Kim, Woo-Ram;Jo, Young-Min;Lee, Heon-Seok;Oh, Soo-Kwan
    • Journal of the Korean Applied Science and Technology
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    • v.32 no.1
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    • pp.48-55
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    • 2015
  • IMO to issue some restricted maritime legislation for reducing the adverse environmental impacts arising from such ship exhaust emissions. According to the IMO policy, every ship entering the Baltic SECAs has to equip the gas cleaning scrubber. The discharged waste solution by gas cleaning scrubber contains many types of salts, which to recover some valuable materials before disposal. This study try to achieve valuable salts including AN and AS throughout a few process such as selective organic solvents salting out, low temperature extraction and thermal evaporation. Amongst them, Thermal evaporation with repetition extraction using inorganic solvent was the most optimum to purify the extracted AN. This valuable salt was evaluated by Elemental analysis and Differential scanning calorimetry.

Recovery of Pure Ni(II) Compound by Precipitation from Hydrochloric Acid Solution Containing Si(IV) (규소(IV)가 함유된 염산용액으로부터 침전법에 의한 고순도 니켈(II)화합물의 회수)

  • Moon, Hyun Seung;Song, Si Jeong;Tran, Thanh Tuan;Lee, Man Seung
    • Resources Recycling
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    • v.30 no.6
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    • pp.36-42
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    • 2021
  • Spent lithium-ion batteries are treated by reduction-smelting at high temperatures to recover valuable metals. Solvent extraction and precipitation of the HCl leaching solution of reduction-smelted metallic alloys resulted in a filtrate containing Ni(II) and a small amount of Si(IV). Adsorption and precipitation experiments were conducted to recover pure Ni(II) compounds from the filtrate. Si(IV) was selectively loaded onto polyacrylamide, but this method did not efficiently filter the solution due to an increase in viscosity. The addition of Na2CO3 as a precipitant to the filtrate led to the simultaneous precipitation of Ni(II) and Si(IV). However, it was possible to recover nickel oxalate with a purity higher than 99.99% by selectively precipitating Ni(II) with the addition of Na2C2O4 as a precipitant.

A Study on the Development of Analytical Methods and Behaviors of Environmental Pollutants(III) : On-Line System for Preconcentration and Separation of Trace Phenols by HPLC (환경 오염물질의 정량법 개발과 거동에 관한 연구(III) : 미량 페놀류의 HPLC 정량을 위한 온 라인 농축)

  • Lee, Dai Woon;Kim, Jin Young;Park, Young Hun;Moon, Myeong Hee
    • Analytical Science and Technology
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    • v.7 no.1
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    • pp.33-39
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    • 1994
  • The purpose on this study was to develop a new improved chromatographic method for determination of trace phenols from environmental waste water. The research was carried out with selected 8 phenols, and solid-phase extraction was employed as sample pretreatment method. The coupling of XAD-4 and Dowex $1{\times}8$ resin as preconcentration column increased the selectivities toward interferences coexisted in matrix. Automation was accomplished with on-line process of pretreatment and HPLC system. After elution of sample through XAD-4 column, phenols were adsorbed by dispersion force, then displaced from it by ACN basified, simultaneously and selectively readsorbed via anion exchange on Dowex $1{\times}8$. Dowex $1{\times}8$ column was washed by water. Phenols readsorbed were removed from Dowex $1{\times}8$ column by a minimum volumn of methanol containing HCl. Each pretreatment step was connected by switching valves and the eluate was directly on-line injected to obtain fast and reliable results into the HPLC. Recovery of phenols was greater than 90%. To examine utility of this method, analysis of phenols from laboratory waste water sample which was added some organic pollutants to find with phenols on environmental waste water were also accomplished without their interference effects.

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Recovery of Molybdenum from the Desulfurizing Spent Catalyst (석유 탈황 폐촉매로부터 몰리브덴의 회수에 관한 연구)

  • 김종화;서명교;양종규;김준수
    • Resources Recycling
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    • v.7 no.2
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    • pp.9-15
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    • 1998
  • Recovery af molybdenum in spent desulfuriring catalyst of petrochemical industries was studied from MfGnatc solulion which is a resultant of firstly remvercd vanadium by wet processes. In order to separate and recover molybdenum from upper mentioned rafinatz solution containing several mctal ions, such as molybdenum (1,100 ppm), vanadium (150 ppm), aluminium (19 ppm), and nickel (33 ppm), either adsorption technique by chelate resin or solvent extr~ction by tertiary amine as extractant was applied. In case of adsorption method, palyamine type chelate resin showed the highest selectivily far molybdenum ion up lo 60 ddm' of ancentration aftcr eluting with 3.0 rnolld~n' of NH,OH. On the othcr hand. molybdenum ion wa cffectlvely cxtractcd in Ule whole ranges of equilibrilrm pR by solvent extraction method with 10 ~01%-alamine 336 which was pretreated with 2N-HCI

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Feature Extraction of Images By Using Independent Component Analysis of Modified Fixed-Point Algorithm (수정된 고정점 알고리즘의 독립성분분석을 이용한 영상의 특징추출)

  • 조용현;민성재
    • Proceedings of the Korea Multimedia Society Conference
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    • 2002.11b
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    • pp.133-136
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    • 2002
  • 본 연구에서는 뉴우턴법과 모멘트를 이용한 수정된 고정점 알고리즘의 독립성분분석기법을 이용한 영상의 특징추출을 제안하였다. 여기서 뉴우턴법은 엔트로피 최적화로부터 유도된 기법으로 그 계산을 간략화하여 역혼합행렬의 빠른 경신을 위함이고, 모멘트는 접선을 구하는 과정에서 함수의 기울기변화 계산에서 발생하는 발진을 줄여 좀 더 빠른 학습을 위함이다. 제안된 기법을 13개 자연영상들로부터 선택된 12×12 픽셀(pixel)의 10,000개 패치를 대상으로 시뮬레이션 한 결과, 추출된 16×16픽셀의 160개 독립성분 기저벡터 각각은 자연영상들에 포함된 공간적인 주파수 특성과 방향성을 가지는 경계 특성이 잘 드러나는 국부적인 특징들임을 확인할 수 있었다. 또한 모멘트의 이용으로 개선된 특징추출을 얻을 수 있었다.

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Experimental Study on Reduction of Nitrogen-Containing Compounds Contained in Crude Methylnaphthalene Oil by Solvent Extraction (I): Reduction of Nitrogen-Containing Compounds Contained in Model Crude Methylnaphthalene Oil of 5 Components System (용매 추출에 의한 조제 메틸나프탈렌유에 함유된 함 질소화합물의 저감에 관한 실험적 연구(I): 5성분계 모델 조제 메틸나프탈렌유에 함유된 함 질소화합물의 저감)

  • Kang, Ho-Cheol;Kim, Su Jin
    • Applied Chemistry for Engineering
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    • v.33 no.4
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    • pp.431-435
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    • 2022
  • The reduction of nitrogen-containing compounds (NC) containing the model crude methylnaphthalene oil (CMNO) of 5 compounds system was experimentally studied by solvent extraction. The model CMNO consisting of 3 kinds of NC including quinolone (QU), iso-quinoline (IQU), indole(IN) and 2 kinds of bicyclic aromatic compounds such as 1-methylnaphthalene (1MNA), 2-methylnaphthalene (2MNA) as raw materials, as well as the aqueous solution of formamide as a solvent, were used. The increase in the volume fraction of water to the solvent at the initial state (yw,0) sharply decreased, but the distribution coefficient and the yield of NC conversely increased the selectivity of NC based on 2MNA, and an increase in the volume fraction of solvent to feed (S/F) simultaneously increased the distribution coefficient, yield and selectivity of NC. The yields of QU, IQU and IN under constant conditions (yw,0 = 0.1, S/F = 1, equilibrium temperature 303 K) were 30%, 31% and 10%, respectively, and selectivity was 15, 15 and 20, respectively. From the excellent yield and selectivity of NC, the formamide extraction method of this study was expected as a method for reducing the NC contained in the model CMNO.

Mass Spectrometry-based Comparative Analysis of Membrane Protein: High-speed Centrifuge Method Versus Reagent-based Method (질량분석기를 활용한 막 단백질 비교분석: High-speed Centrifuge법과 Reagent-based법)

  • Lee, Jiyeong;Seok, Ae Eun;Park, Arum;Mun, Sora;Kang, Hee-Gyoo
    • Korean Journal of Clinical Laboratory Science
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    • v.51 no.1
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    • pp.78-85
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    • 2019
  • Membrane proteins are involved in many common diseases, including heart disease and cancer. In various disease states, such as cancer, abnormal signaling pathways that are related to the membrane proteins cause the cells to divide out of control and the expression of membrane proteins can be altered. Membrane proteins have the hydrophobic environment of a lipid bilayer, which makes an analysis of the membrane proteins notoriously difficult. Therefore, this study evaluated the efficacy of two different methods for optimal membrane protein extraction. High-speed centrifuge and reagent-based method with a -/+ filter aided sample preparation (FASP) were compared. As a result, the high-speed centrifuge method is quite effective in analyzing the mitochondrial inner membranes, while the reagent-based method is useful for endoplasmic reticulum membrane analysis. In addition, the function of the membrane proteins extracted from the two methods were analyzed using GeneGo software. GO processes showed that the endoplasmic reticulum-related responses had higher significance in the reagent-based method. An analysis of the process networks showed that one cluster in the high-speed centrifuge method and four clusters in the reagent-based method were visualized. In conclusion, the two methods are useful for the analysis of different subcellular membrane proteins, and are expected to assist in selecting the membrane protein extraction method by considering the target subcellular membrane proteins for study.

Forecasting Short-Term KOSPI using Wavelet Transforms and Fuzzy Neural Network (웨이블릿 변환과 퍼지 신경망을 이용한 단기 KOSPI 예측)

  • Shin, Dong-Kun;Chung, Kyung-Yong
    • The Journal of the Korea Contents Association
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    • v.11 no.6
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    • pp.1-7
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    • 2011
  • The methodology of KOSPI forecast has been considered as one of the most difficult problem to develop accurately since short-term KOSPI is correlated with various factors including politics and economics. In this paper, we presents a methodology for forecasting short-term trends of stock price for five days using the feature selection method based on a neural network with weighted fuzzy membership functions (NEWFM). The distributed non-overlap area measurement method selects the minimized number of input features by removing the worst input features one by one. A technical indicator are selected for preprocessing KOSPI data in the first step. In the second step, thirty-nine numbers of input features are produced by wavelet transforms. Twelve numbers of input features are selected as the minimized numbers of input features from thirty-nine numbers of input features using the non-overlap area distribution measurement method. The proposed method shows that sensitivity, specificity, and accuracy rates are 72.79%, 74.76%, and 73.84%, respectively.

Rapid Gas Chromatographic Screening of Dairy Products for Volatile and Nonvolatile Organic Acids (기체크로마토그래피법에 의한 유제품내 휘발성 및 비휘발성 유기산의 신속한 스크리닝)

  • Kim, Jung-Han;Kim, Kyoung-Rae;Chai, Jeong-Young;Oh, Chang-Hwan;Park, Hyung-Kook;Choi, Kyoung-Sook
    • Korean Journal of Food Science and Technology
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    • v.26 no.6
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    • pp.665-669
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    • 1994
  • A rapid gas chromatographic (GC) profiling method was applied to dairy products (milk and cheeses) for the simultaneous analysis of volatile and nonvolatile organic acids. Cheese samples were first made into aqueous samples by dissolving in water. The aqueous samples were then extracted with organic solvents after the acidification and NaCI saturation. The organic layers (diethyl ether : hexane= 1 : 1) were extracted with $NaHCO_3$ saturated solution with subsequent solid-phase extraction of the aqueous phases using Chromosorb P column/diethyl ether followed by triethylamine treatment. The resulting triethylammonium salts of acids were directly converted into volatile tert.-butyldimethylsilyl derivatives, which were analyzed by dual-capillary column GC, and GC-mass spectrometry. From milk and four cheese samples studied, 31 organic acids including 21 fatty acids and other hydroxy and dioic acids were tentatively identified. The amounts of the fatty acids were different among the kinds of cheese and thus the simplified retention index (RI) spectra of organic acids were useful for the visual pattern recognition of each sample, when the Direct Comparision method between cheese and a blind sample were attempted, it was quickly recognized to be a gouda cheese with the 999 ppt match quality value.

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The Study on the Efficacy of Herbal Plant Extracts by the Part and Solvent Extraction (약용식물의 부위별 및 추출용매에 따른 효능 연구)

  • Kim, Hyung-Dong;Kim, Sang-Jin
    • Journal of the Society of Cosmetic Scientists of Korea
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    • v.33 no.2
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    • pp.127-135
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    • 2007
  • This study was to evaluate the efficiency of different solvent systems to extract active ingredients from different parts of medicinal plants used as oriental medicinal herb in the cosmetic industry. We tested efficacies related to the antioxidative effects and UV absorption of herbal extracts as complex of active ingredients, not each single ingredient. When extracting medicinal plant which is used effective medicine, we should consider the collecting conditions like collecting time, place, part and extracting conditions like solvent, temperature, time, and etc. Among them, extraction solvent and collecting part are very important factors for the efficacy. As increased interest in medicinal plants, more intensive studies on collecting conditions and extracting processes were needed for the developments in the herbal ingredient industry. We evaluated the efficiency of different solvent systems to extract active ingredients from different parts of plants (Terminalia chebula, Syzygium aromaticum, Paeonia lactiflora, Morus alba, Scutellaria baicalensis) widely used as medicine and food. As results, we found that proper condition can make better data and decrease the required quantity.