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Mechanical Properties and Antiplasticization Phenomena of Poly(${\varepsilon}$-caprolactone)(PCL)/Poly(vinyl chloride)(PVC) Blends (폴리카프로락톤 (PCL)/폴리염화비닐(PVC) 블렌드의 기계적 성질 및 반가소화 현상)

  • Kim, Wook-Soo;Kim, Il-Hyoung;Kang, Sun-Chul;Mori, Tetsuo;Tsuda, Yusuke;Ha, Ki-Ryong
    • Polymer(Korea)
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    • v.25 no.4
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    • pp.521-527
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    • 2001
  • The miscibility, molecular interaction and tensile properties of the blends of poly (${\varepsilon}$-caprolactone) (PCL) with poly(vinyl chloride) (PVC) have been studied. The measured glass transition temperature values of PCL/PVC blends were found to be well fitted by Fox equation. We found that PCL/PVC blends are amorphous up to 23% PCL content. The blends showed the highest Young's modulus and yield strength at 5% PCL content and the highest tensile strength at 11% PCL content. The blends with low contents of PCL(up to 13%) show increased tensile strength and decreased elongation of PCL/PVC blends. Consequently, the antiplasticization phenomenon is observed in the PCL/PVC blends.

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마그네트론 스퍼터링에 의해 제조된 CrAlSiN 박막의 화학성분에 따른 온도저항계수와 미세구조

  • Mun, Seon-Cheol;Ha, Sang-Min;Kim, Sang-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.02a
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    • pp.100-102
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    • 2013
  • Magnetron-sputtering법을 사용하여 기존에 연구하였던 CrAlN (Cr 7:Al 3)박막에 Si를 첨가하여 Si의 함량 변화에 따라 미세구조와 화학적 결합상태, 온도저항계수(TCR) 및 산화저항의 영향과 기계적특성 개선을 통한 multi-functional heater resistor layer로써의 가능성을 연구하였다. CrAlSiN 박막의 Si 함량에 변화에 따라 온도저항계수 변화를 확인하였으며 X-선 회절 분석(XRD) 패턴 분석결과 CrAlSiN 박막의 결정구조가 Bl-NaCl 구조를 가지고 있는 것을 확인하였으며 SEM과 AFM을 통한 표면 및 미세구조 분석결과 Si의 함량이 증가할수록 입자가 조밀해짐을 알 수 있었다. 최근 digital priting technology의 핵심 기술로 부각되고 있는 inkjet priting technology는 널리 태양전지뿐만 아니라 thin film process, lithography와 같은 반도체 공정 기술에 활용 할 수 있기 때문에 반도체 제조장비에도 사용되고 있으며, 현재 thermal inkjet 방식을 사용하고 있다. Inkjet printing technology는 전기 에너지를 잉크를 배출하기 위해 열에너지로 변환하는 thermal inkjet 방식을 사용하고 있는데, 이러한 thermal inkjet 방식은 기본적으로 전기저항이 필요하지만 electrical resistor layer는 잉크를 높은 온도에서 순간적으로 가열하기 때문에 부식이나 산화 등의 문제가 발생할 수 있어 이에 대한 보호층을 필요로 한다. 하지만, 고해상도, 고속 잉크젯 프린터, 대형 인쇄 등을 요구되고 있어 저 전력 중심의 잉크젯 프린터의 열효율을 방해하는 보호층 제거에 필요성이 제기되고 있다. 본 연구는 magnetron-sputtering을 사용하여 기존의 CrAlN 박막에 Si를 합성하여 anti-oxidation, corrosion resistance 그리고 low temperature coefficient of resistance 값을 갖는 multi-functional heater resistor layer로써 CrAlSiN 박막의 Si 함량에 따른 효과에 초점을 두었다. 본 실험은 CrAlN 박막에 Si 함량을 4~11 at%까지 첨가시켜 함량의 변화에 따른 특성변화를 확인하였다. 함량이 증가할수록 amorphous silicon nitride phase의 영향으로 박막의 roughness는 감소하였으며 XRD 분석결과 (111) peak의 Intensity가 감소함을 확인하였으며 SEM 관찰시 모든 박막이 columnar structure를 나타내었으며 Si함량이 증가할수록 입자가 치밀해짐을 보여주었다.Si함량이 증가할수록 CrAlN 박막에 비하여 면저항은 증가하였으며 TCR 측정결과 Si함량이 6.5 at%일 때 가장 안정한 TCR값을 나타내었다. Multi-functional heater resistor layer 역할을 하기 위해서, CrAlSiN 박막의 원소 분포, 표면 거칠기, 미세조직, 전기적 특성 등을 조사하였다. CrAlN 박막의 Si의 첨가는 크게 XRD 분석결과 주상 성장을 억제 할 수 있으며 SEM 분석을 통하여 Si 함량이 증가할수록 Si3N4 형성이 감소하며 입자크기가 작아짐을 확인하였다. 면저항의 경우 Si 함량이 증가함에 따라 높은 면저항을 나타내었으며 Si함량이 6.5 at%일 때 가장 낮은 TCR 값인 3120.53 ppm/K값을 보였다. 이 값은 상용되고 있는 heater resistor보다 높지만, CrAlSiN 박막이 더 우수한 기계적 특성을 가지고 있기 때문에 hybrid heater resistor로 적용할 수 있을 것으로 기대된다.

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A Case of Pneumothorax Caused by Cystic Lung Metastasis of Angiosarcoma (혈관육종의 낭성 폐전이에 의한 기흉 1예)

  • Lee, Chan Joo;Choi, Jun Jeong;Jeon, Han Ho;Jung, Kyung Soo;Park, Byung Hoon;Park, Seon Cheol;Shin, Sang Yun;Chung, Wou Young;Byun, Min Kwang;Moon, Ji Ae;Kim, Young Sam;Kim, Se Kyu;Chang, Joon;Kim, Sung Kyu;Park, Moo Suk
    • Tuberculosis and Respiratory Diseases
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    • v.64 no.5
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    • pp.374-378
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    • 2008
  • Angiosarcoma is a rare but highly malignant tumorthat usually arises in the scalp or face of elderly males. Distant metastases favor the lung, liver, lymph nodes and skin. Metastatic pulmonary angiosarcoma commonly takes the form of a nodule but can sometimes appear as a thin-walled cyst. We report a case of 65 years-old male with a spontaneous pneumothorax, who underwent excision and radiotherapy for an angiosarcoma of the scalp 2 years ago. A chest CT scan revealed multiple cysts in the lung. The video-assisted thoracoscopic lung biopsy demonstrated subpleural cysts without tumor cells. A skin biopsy of the scalp showed an angiosarcoma. This case was diagnosed as a recurrence of an angiosarcoma with a supposed lung metastasis. This case suggests that a spontaneous pneumothorax in elderly people may be secondary to a pulmonary metastasis from an angiosarcoma of the scalp.

A Pilot Study of Brief Eye Movement Desensitization and Reprocessing(EMDR) for Treatment of Acute Phase Schizophrenia (급성기 정신분열병의 치료로서 단기적인 안구운동 민감소실 및 재처리요법에 대한 예비연구)

  • Kim, Daeho;Choi, Joonho;Kim, Seok Hyeon;Oh, Dong Hoon;Park, Seon-Cheol;Lee, Sun Hye
    • Korean Journal of Biological Psychiatry
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    • v.17 no.2
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    • pp.94-102
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    • 2010
  • Objectives : Eye movement desensitization and reprocessing(EMDR) is a novel, time-limited psychotherapy originally developed for treatment of psychological trauma. The effectiveness of this therapy has been validated only for posttraumatic stress disorder ; however, EMDR is often applied to other psychiatric illnesses, including other anxiety disorders and depression. This pilot study tested the efficacy of EMDR added to the routine treatment for individuals with acute stage schizophrenia. Methods : This study was conducted in the acute psychiatric care unit of a university-affiliated training hospital. Inpatients diagnosed with schizophrenia were randomly assigned to either three sessions of EMDR, three sessions of progressive muscle relaxation(PMR) therapy, or only treatment as usual(TAU). All the participants received concurrent typical treatments(TAU), including psychotropic medication, individual supportive psychotherapy and group activities in the psychiatric ward. The Positive and Negative Syndrome Scale(PANSS), the Hamilton Depression Rating Scale and the Hamilton Anxiety Rating Scale were administered by a clinical psychologist who was blinded to the patients' group assignment. Results : Forty-five patients enrolled and forty patients(89%) completed the post-treatment evaluation. There were no between-group differences in the withdrawal rates of patients during the treatment or at the three-month follow-up session. All three groups improved significantly across each of the symptomatic domains including schizophrenia, anxiety, and depressive symptoms. However, a repeated measures ANOVA revealed no significant differences among the groups over time. Effect size for change in total PANSS scores was also similar across treatment conditions, but effect size for negative symptoms was large for EMDR(0.60 for EMDR, 0.39 for PMR and 0.21 for TAU only). Conclusion : These findings supported the use of EMDR in treating the acute stage of schizophrenia but the results failed to confirm the effectiveness of the treatment over the two control conditions in three sessions. Further studies with longer courses of treatment, more focused target dimensions of treatment, and a sample of outpatients are necessary.

Characterization and Cloning of a Phytase from Escherichia coli WC7. (Escherichia coli WC7가 생산하는 Phytase의 효소특성과 그 유전자의 클로닝)

  • 최원찬;오병철;김형권;강선철;오태광
    • Microbiology and Biotechnology Letters
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    • v.30 no.1
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    • pp.1-7
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    • 2002
  • Phytase from Escherichia coli WC7 was purified from cell extracts and its molecular mass was estimated to be 45 kDa by SDS-PAGE. Its optimum temperature and pH for phytate hydrolysis was 6$0^{\circ}C$ and pH 5.0, respectively. The enzyme was stable up to 6$0^{\circ}C$ and over broad pH range (pH 2-12). The enzyme had higher affinity for sodium phytate than p-nitrophenylphosphate (pNPP). That is, the apparent Km value for sodium phytate and pNPP were $0.15\pm$0.02 mM and 2.82$\pm$0.05 mM, respectively. The gene encoding the phytase was cloned in E. coli XL1-Blue. Sequence analysis showed an open reading frame of 1241 Up encoding a signal peptide (22 aa) and a mature enzyme (410 aa). WC7 phytase was expressed up to 17.5 U/ml in the transformed E. coli XL1-Blue/pUEP, which was 23-fold higher than the activity from wild strain.

Effects of Loess on the Mycellial Pellet Formation of Phosphate-solubilizing Fungus, Aspergillus sp. PS-104 in the Submerged Culture (Aspergillus sp. PS-104의 액침배양증 mycellial pellet 형성에 미치는 황토의 영향)

  • Kang, Sun-Chul;Koo, Bon-Sung;Tae, Un-Hee
    • Korean Journal of Environmental Agriculture
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    • v.21 no.1
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    • pp.17-23
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    • 2002
  • In order to investigate effects if loess on the mycellial pellet formation a phosphate-solubilizing fungus. Aspergillus sp. PS-104 was cultured in potato dextrose broth containing loess. The strain formed an amorphous pellet or loose aggregates agitated at a low speed (50 rpm) while spherical and regular pellets at a high speed (150 rpm) The higher concentration of loess was added, the smaller size of a pellet was formed during the submerged culture of the strain. As shown in results, being cultured in the PDB medium supplemented with 1.0% loess the pellet size was maximally reduced to a fourth compared to the control. Evaluating the addition effect of several components of loess such as $SiO_2$, $Fe_2O_3$, $Al_2O_3$, $CaCO_3$, $CaSO_4$ and $MgCO_3$ on the reduction of mycellial pellet size the higher concentration was supplied, the smaller size of pellet was formed except $Al_2O_3$. And the smallest pellet size was recorded at the concentration of 1.0% (W/V) magnesium carbonate.

Improvement in Storage Stability of Export Peeled-Chestnuts Using Electrolyzed Acid-water (전해산화수를 이용한 수출용 깐밤의 저장성 향상)

  • Kang, Jeng-Yeol;Kang, Sun-Chul;Park, Shin
    • Applied Biological Chemistry
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    • v.41 no.7
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    • pp.545-549
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    • 1998
  • This study was carried out to improve the storage stability of export peeled-chestnuts using electrolyzed acid-water, because ice-cold tap water generally used to store export peeled-chestnuts grew turbid during the cold chain, decreasing the quality. The changes of pH and turbidity in the electrolyzed water used for storing peeled-chestnuts were investigated. The pH value rapidly changed when stored at $30^{\circ}C$, whereas it very slowly changed at $4^{\circ}C$. This was especially evident by the change in pH from 2.5 to 3.4 of the electrolyzed acid-water after 8 days. In the case of turbidity, closely correlated with the pH change, the electrolyzed water used for storing peeled-chestnuts was very turbid when stored at $30^{\circ}C$, but it was not even until 14 days at $4^{\circ}C$, as evident by the absorbance $(OD_{660})$ of electrolyzed acid-water at pH 2.5 and $4^{\circ}C$ being only 0.01 after 14 days and 0.11 after 35 days. Sensory evaluation, tested by expert panel, of the chestnuts stored in electrolyzed water was not significantly different compared to the control.

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Determination of Optimal Conditions by Response Surface Methodology and Quality Characteristics of Water Extracts of Phellinus linteus (반응표면분석을 이용한 상황버섯 열수추출액의 최적 추출조건과 품질 특성)

  • Youn, Sun-Joo;Cho, Jun-Gu;Kwoen, Dae-Jun;Choi, Ung-Kyu;Kang, Sun-Chul
    • Applied Biological Chemistry
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    • v.49 no.3
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    • pp.215-220
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    • 2006
  • Response surface methodology was implemented to determine an optimal extraction condition in Phellinus linteus water extract. Extraction was performed on 10 experimental conditions including independent variables such as extraction time $(1{\sim}5\;hrs)$ and water volume over sample (sample : $H_2O$ = 1 : $40{\sim}200$, W/V), color browning, reducing and total sugar, that were based on the significant levels of 10% of central composition design. Color browning, reducing and total sugar contents were found to be more affected when the water volume was increased rather than extraction time. Maximum extraction condition was acquired at extraction time of $3.0{\sim}4.5\;hrs$ and water volume of $40{\sim}58.2\;ml$. Being extracted at the optimal extraction condition two of the free sugars, sucrose (0.126%) and glucose (0.012%), were detected. Total content of the free amino acids was found to be $503.26\;{\mu}g%$. Among them, essential amino acid contents were revealed as 5.4%. One major peak from gel permeation chromatography contained polysaccharide(s) with the molecular weights of 10 KDa.

An Efficient Inter-Prediction Hardware Design for the H.264/AVC Decoder (H.264/AVC 디코더를 위한 효율적인 인터 예측 하드웨어 구조 설계)

  • Jin, Xianzhe;Ryoo, Kwangki
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2009.05a
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    • pp.112-115
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    • 2009
  • Inter-Prediction is always the main bottleneck in H.264/AVC Baseline Profile. This paper describes an efficient Inter-Prediction hardware architecture design. H.264/AVC decoder supports various block types such as $16{\times}16$, $16{\times}8$, $8{\times}16$, $8{\times}8$, $8{\times}4$, $4{\times}8$, $4{\times}4$ block types. Reference Software(JM) only considers the $4{\times}4$ block type when the reference block is being fetched. This causes duplicated pixels which needs extra fetch cycles. In order to eliminate some of the duplicated pixels, the $8{\times}8$ and $4{\times}4$ block types were considered in the previous design. If the block size is larger than or equal to the $8{\times}8$ block type, it will be separated into several $8{\times}8$ block types and if the block size is smaller than the $8{\times}8$ block type it will be separated into several $4{\times}4$ blocks. For further reduction of the fetch cycles, the various block types are considered in this paper. As a result, the maximum cycle reduction percentage is 18.6% comparing with the previous design.

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Distribution of Heavy Metal Concentrations in Surface Sediments of the eastern Yellow Sea (황해 동부해역 표층퇴적물의 중금속 농도 분포)

  • SUN, CHUL-IN;PARK, GEON-WOO;PARK, HYEON-SIL;PARK, JUN KUN;KIM, SEONG GIL;CHOI, MAN SIK
    • The Sea:JOURNAL OF THE KOREAN SOCIETY OF OCEANOGRAPHY
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    • v.23 no.4
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    • pp.179-191
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    • 2018
  • In order to determine the distribution characteristics of the heavy metals in surface sediments of the eastern Yellow Sea, heavy metal concentrations (Cu, Pb, Zn, Cd, Cr, Mn, As, Ni, Co, Li, Fe and Al) together with grain size and total organic carbon (TOC), were analyzed. The concentrations of all heavy metals, with the exception of Pb, Mn and As in some stations, were relatively high in the central area of the Yellow Sea and tended to decrease toward the Korean coast. A significant relationship between grain size and concentrations of heavy metals suggested that they were mostly controlled by quartz dilution effect. However, at some stations, Pb, Mn and As exhibited different distribution patterns. For Pb, the differences were caused by petrogenetic influences (feldspar) in coarse-grained sediments. In the case of Mn, biogenetic influences ($CaCO_3$) affected distribution patterns. As was distributed differently because of the existence of a heavy mineral (pyrite). A comparison with previous data (collected in 2000) shows that the heavy metal concentration in the eastern Yellow Sea has not increased over the past fifteen years. The sedimentary environment of dumping sites in the Yellow Sea has not been significantly improved during this period. The results of the pollution assessment revealed that the concentrations of heavy metals in the study area were lower than lower criteria (TEL, MSQ-1) in Korean and Chinese sediment quality guidelines. The enrichment factor (EF), geo-accumulation index ($I_{geo}$) and ecological risk index (ERI) of Cu, Pb, Zn and Cr were higher in the central area of the Yellow Sea.