• Title/Summary/Keyword: 석회석 자원

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국내 석회석의 활용현황

  • 채영배;정수복;김완태
    • Proceedings of the KSEEG Conference
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    • 2002.10a
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    • pp.93-101
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    • 2002
  • 석회석은 우리 나라 광업법 제3조에서 규정한 법정광물로써 백운석, 대리석, 방해석 및 코퀴나 등을 포함하며, 최근 우리 나라 전체 광산물 생산량의 75%를 상회하는 단일광종 최대생산량을 나타내고 있는 광종이다. 이외에도 석회석 광은 여러 가지 통계적으로도 국내 최대임을 나타내는데, 즉, 2001년도 우리 나라 일반광(66종) 등록광구수 5,242개소 중에서 1,494개소를 차지하여 28.5%를 차지하며, 가행광산 수에서도 320개소 중 109개소(34%), 근로자 수에서는 4,291명중에서 2,748명(64%)으로 최대의 규모를 가지고 있다. 실제로 석회석 및 관련제품은 오늘날 화학공업이나 환경산업 등 각종의 산업에 널리 이용되고 있으며, 그의 이용 역사에서도 유구한 역사를 가지고 있다. 즉, 고대 유적분석 결과는 이미 신석기 시대에도 석회 재료가 쓰였을 것으로 보고되고 있으며, 성경(신명기 27장 1~5절)에도 소개되고 있고, 우리 나라에서의 석회 사용의 역사도 동국여지승람(성종16년), 세종실록, 문종실록 등에 석회 산지가 자세히 조사 기록되어 있으며 소성석회의 제조, 사용에 대하여도 기록하고 있다. 이외에도, 그리이스, 로마, 중국 등지의 역사에서는 건축재, 농업, 표백 및 제혁공업등에 사용되었다는 사실이 발견되고 있지만, 석회석의 용도가 크게 증가된 것은 역시 산업혁명 이후 20세기가 시작되면서부터 라고 할 수 있다. 석회석은 국가산업구조 및 인간의 삶의 양식에 따라 그의 용도가 다양하고, 광범위하게 변화하는 만큼, 그의 품질 또한 중요하게 취급되어야 하지만, 우리 나라의 경우에는 아직도 시장규모가 큰 일부용도이외에 사용자의 요구에 부합되는 다양한 품질의 석회제품을 제조하는 데에는 인색하고, 또한 사용자의 대부분은 용도가 명시되어 있는 외국의 제품을 선호하는 경향에 따라 석회석 및 관련제품의 수입량이 감소하지 않고 있다. 최근 우리 나라는 국제통화기금(IMF)이후에, 국내산업을 보호하는 정부의 규제나 지원은 폐지 또는 축소되고, 외국회사의 시장참여에 의한 국제경쟁기반이 약화되고 있는 것도 사실이지만, 고 환율에 의하여 일부제품의 수입은 자제되고, 국내산 대체 방향으로 진행되고 있기 때문에, 안정되고 신뢰할 수 있는 품질의 제품을 제조하는 경우에는 오히려 국내시장의 확장에는 좋은 시기가 될 수도 있다고 판단된다. 이에 본고에서는 최근 국내 석회석 관련제품을 활용하는 사례를 분석하고 향후 유효이용을 도모하는 데에 참고가 되었으면 하는 마음에서 작성하였다.

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The Attrition and Calcination Characteristics of Domestic Limestones for In-Situ Desulfurization in Circulating Fluidized Bed Boilers (순환유동층 로내 탈황을 위한 국내 석회석의 마모 및 소성 특성)

  • Kim, Ye Bin;Kang, Seo Yeong;Seo, Su Been;Keel, Sang In;Yun, Jin Han;Lee, See Hoon
    • Korean Chemical Engineering Research
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    • v.57 no.5
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    • pp.687-694
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    • 2019
  • In order to investigate the behavior of limestones which have been usually used for in-situ desulfurization reaction in circulating fluidized bed combustors, the attrition characteristics and calcination reactions of domestic limestones were analyzed in this study by using a thermogravimetric analyzer and an ASTM D5757-95 attrition tester. The average size distribution of limestones in circulating fluidized bed boilers have to be changed due to the attrition of particle-particle and particle-reactor wall and the calcination reaction. Domestic limestones might be used in commercial circulating fluidized bed boilers, but the attrition behaviors and particle size changes of limestones were varied. In calcination experiments at $850^{\circ}C$, the calcination reaction were varied with limestone samples. The calcination reaction time increased with an increase of particle size. Also, fine particles generated the attrition test of calcined limestone was 20% higher than those generated the attrition test of original limestone.

Simulation on the Alternation of Limestone for Portland Cement Raw Material by Steel By-products Containing CaO (CaO 함유 철강 부산물을 활용한 시멘트 원료 석회석 대체 시뮬레이션)

  • Jae-Won Choi;Byoung-Know You;Min-Cheol Han
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.1
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    • pp.1-8
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    • 2023
  • In this study, to reduce CO2 emission in the cement manufacturing process, we evaluated the limestone that is used as a raw material for cement, substituted with steel slag by the various substituted levels. Based on the chemical composition of each raw materials including limestone, and blast furnace slow cooling slag, converter slag, and KR slag as an alternative raw material, we simulated the optimal cement raw mixture by the substitution levels of limestone. Test results indicated that the steel slags contain a certain level of CaO that can be used as alternative decarbonated raw materials, and it has enough to partially reduce the amount of limestonem. And we estimated the maximum usable levels of each raw material. In particular, it was confirmed that by using a mixture of these raw materials rather than using them one by one, the effect of reducing limestone was increased and CO2 emission from the cement manufacturing process could be reduced.

A study on the Effects of Crystal Structure of Domestic High-Ca Limestones on the Grinding and Dissolution Rates in the Simulated Spray Type Absorption Tower (스프레이 모사 흡수탑에서 국내 고품위 석회석의 결정구조가 분쇄 및 용해도에 미치는 영향 연구)

  • Seo, Jun-Hyung;Baek, Chul-Seoung;Cho, Jin-Sang;Ahn, Ji-Whan;Cho, Kye-Hong
    • Resources Recycling
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    • v.26 no.6
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    • pp.10-19
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    • 2017
  • It is studied the effect of crystal structure of domestic High-Ca limestones using absorbent for desulfurization on the grinding characteristics and dissolution rates in wet flue gas desulfurization process of domestic coal fired power plant. It compared the crystal structure, grinding work index and dissolution rates with 4 Limestones from Jecheon-Danyang with different crystal structure, and we found that grinding work index differ in crystal size and crystal structure of limestones : The lower the value of the grinding work index is, the higher the dissolution rates of limestones. Confirmed that we have important indicators of grinding characteristics for crystal structure with CaO content of limestones.

A Effect of Chemical Composition and Replacement Ratio of Limestone Admixture on Initial Cement Characteristics (석회석 혼합재의 화학성분과 치환량이 시멘트 초기 물성에 미치는 영향)

  • Dong-Kyun Suh;Gyu-Yong Kim;Jae-Won Choi;Kyung-Suk Kim;Ji-Wan Woo
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.11 no.4
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    • pp.440-448
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    • 2023
  • Utilizing admixture, which is one of the raw material replacement method in the cement industry, is expected to be easily and quickly put to practical use as it is relatively more accessible than other methods. Among cement admixtures, limestone powder is reported to be able to improve cement performance through nucleation effects, chemical effects, and filler effects, so it is a material expected to be suitable as a cement admixture. Meanwhile, as high-quality limestone is depleted around the world, the use of limestone with clay or high magnesia (MgO) content is becoming increasingly inevitable. Therefore, in this study, we attempted to evaluate the suitability of limestone cement as a admixture by measuring the basic properties of limestone cement mixed with limestone of different qualities commonly used in Korea. As a result, the effect of alite reaction promotion was confirmed regardless of the chemical composition of the limestone binder. However, the dilution effect depending on the substitution amount was greater than the chemical composition. It is believed that normal-grade limestone can be used as a mixture as long as the limestone content in cement is within 15 % in this scope of study. In the future, we plan to evaluate the impact of the chemical composition of the limestone mixture through additional experiments depending on the chemical composition of cement.

A Cost-benefit Analysis of Developing Project for Lime Mineral on the Basis of Case Study (석회석광산 개발사업의 비용-편익분석 -사례 중심으로-)

  • Kwack, Tae-Won;Kim, Hong-Kyun
    • Environmental and Resource Economics Review
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    • v.15 no.4
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    • pp.713-740
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    • 2006
  • In this paper, we examine what factors should be considered in cost-benefit analysis of a resource-developing project as cos and benefit item. According to this study, the reduction in forest product value and the reduction in function to clean air pollution should be included as a environmental cost. However, the reduction in recreation function and function in cleaning water need not to be included. We also calculated a cost-benefit of developing project for lime mineral of A company by applying these factor just mentioned. This paper concluded that the net benefit of this project is positive and the range of the value is from 689,900million won to 1,784,000million won.

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