• Journal of the Korean Society of Marine Environment & Safety
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• v.27 no.4
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• pp.492-499
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• 2021

In this study, the benthic environmental and microbial community structure were investigated by mixing granulated coal ash(GCA) and contaminated estuary sediments. Estuary sediments and GCA were mixed in a ratio of 8:2 and allowed to interact for 1 month, then sediment environmental factors were investigated. The pH of the experimental sediment was mixed increased to 11. The concentration of DIP(Dissolved inorganic phosphorus) in the experimental case decreased by 30 % compared to the control case, and this should be due to formation of calcium phosphate through the chemical reaction of DIP and calcium which diluted from GCA. The high abundance of Gammaproteobacteria seen in the experimental sediment compare to the control can af ect the DIP reduction. The DIN(Dissolved inorganic nitrogen) concentration increased over two times in the experimental case than the control, and this should be due to the high pH condition and release of NH₄⁺-N from the GCA. Microorganisms related to nitrogen circulation were not identified in both the control and experimental cases. It was confirmed that the GCA were effective in reducing the DIP concentration in contaminated estuary sediment, and that benthic microbial communities were shown to influenced the phosphorus circulation.

• Journal of the Korean Society of Marine Environment & Safety
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• v.25 no.1
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• pp.67-73
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• 2019

We carried out basic research to evaluate covering material for improving and managing contaminated benthic environments in coastal areas. Changes in nutrient concentration such as phosphate, hydrogen sulfide of contaminated sediment, and pH, Oxidation Reduction Potential (ORP) were investigated through mesocosm experiments for 6 months by covering contaminated sediment with granulated coal ash. Calcium oxide eluted from the granulated coal ash was confirmed to neutralize acidified sediment by increasing pH through hydrolysis. Also, calcium oxide and silica eluted from the granulated coal ash adsorbed and precipitated with phosphate in the sediment. The concentration of phosphate in the sediment investigated decreased by ca. 84.31 %. Similarly, the concentration of hydrogen sulfide decreased by 133.5 mg/L in one month. The hydrogen sulfide is considered to have reacted with substances such as manganese oxide which were eluted from the granulated coal ash and precipitated. Also, it was concluded that the hydrogen sulfide was reduced since anaerobic conditions in the sediment weakened. According to the results of these mesocosm experiments, granulated coal ash was found to be effective to remediate and manage benthic environments by covering the surface layer of sediment.

• Journal of the Korean Society for Marine Environment & Energy
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• v.17 no.1
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• pp.1-7
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• 2014

This paper aims to explain the safety assessment and remediation mechanism of Granulated Coal Ash (GCA) as a material for the remediation of coastal sediments and to evaluate the improvement of the sediment in Kaita Bay, where GCA was applied. The concentrations of heavy metal contained in GCA and the dissolved amounts of heavy metal from GCA satisfied the criteria for soil and water pollution in Japan. The mechanisms on the remediation of coastal sediments using GCA is summarized as follows; (1) removal of phosphate and hydrogen sulfide (2) neutralization of acidic sediment (3) oxidation of reductive sediment (4) increase of water permeability (5) increase of soil strength (6) material for a base of seagrass. From the results obtained from the field experiment carried out in Kaita Bay, it was clarified that GCA is a promizing material for remediation of coastal sediment. This remediation technology can contribute to promote waste reduction in society and to decrease cost of coastal sediment remediation by applying GCA in other polluted coastal areas.

• Journal of Korean Society of Coastal and Ocean Engineers
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• v.30 no.5
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• pp.201-206
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• 2018

This study investigated the changes in pore water quality of polluted sediment by mixing ratio of granulated coal ash. The mesocosm experiments were carried out with 0%, 10%, 30% and 50%, respectively, of the material mixture ratio relative to the sediments. According to the results of the experiments, pH increased depending on the mixing ratio. Phosphate and ammonia concentrations were significantly decreased in the mixing ratio of 30% and 50% compared to the control (p < 0.05). The concentration of hydrogen sulfide was reduced by 72% at the mixing ratio of 10%, and it was not detected at the mixing ratio of 30% and 50%. This study was confirmed that granulated coal ash can change the pore water quality of polluted sediments in proportion to the amount of material. However, the effect of the mixing ratio between 30% and 50% was not significantly different, thus it is concluded that mixing of 30% of the volume of the sediment is economically feasible.

• Journal of the Korean Society of Marine Environment & Safety
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• v.22 no.7
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• pp.814-820
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• 2016

In order to utilize coal ash for eelgrass beds, a pilot plant experiment was carried out. Eelgrass was transplanted to on artificial bed made of granulated coal ash. Successful settlement of eelgrass was achieved and the density of the eelgrass increased at an exponential rate through vagetative propagation after 24 months. An increase in biodiversity in and around the artificial eelgrass bed was observed after the transplant took place. From the results of this experiment, it can be concluded that granulated coal ash is a suitable material for creating eelgrass beds.

• Proceedings of KOSOMES biannual meeting
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• 2017.11a
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• pp.73-73
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• 2017

• Proceedings of KOSOMES biannual meeting
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• 2018.06a
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• pp.125-125
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• 2018

• Proceedings of KOSOMES biannual meeting
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• 2017.11a
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• pp.74-74
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• 2017

• Proceedings of KOSOMES biannual meeting
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• 2018.06a
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• pp.124-124
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• 2018

• Journal of the Korean Society of Marine Environment & Safety
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• v.25 no.7
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• pp.914-919
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• 2019

A mesocosm experiment considering water exchange was conducted to evaluate the change in the properties of contaminated coastal sediment. The contaminated coastal sediment sample was prepared by mixing with granulated coal ash(GCA), which is an alkaline industrial by-product. During one month of observation time, the phosphate concentration of the GCA sample case was measured to be 19.0 and 0.4 mg/L lower than that of the control sample at the pore water and overlying water, respectively. The hydrogen sulfide concentration of the GCA sample case was 5.0 mg/L, which is significantly lower than that of the control sample(112.5 mg/L). Further addition of GCA in the sediment reduced the concentrations of phosphate and hydrogen sulfide, and could enhance the adsorption reaction, when compared to the sediment without GCA. The dissolved oxygen concentration in the overlying water of the GCA sample was measured to be 3.47 mg/L higher than the control sample. From the above results, we confirmed that GCA is an effective material for reducing pollutants in coastal sediment.