• Journal of the Korean GEO-environmental Society
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• v.15 no.4
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• pp.5-11
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• 2014

Recently, there have been various lifeline installations constructed in the underground space of urban area due to the effective use of land. For newly installed lifelines or the management of the installed lifelines, many construction activities of excavation and backfilling are observed. Around these area, there are possibilities of collapse or excessive settlement due to the leaking of the pipe or unsatisfactory compaction of backfill material. Besides, construction costs can be saved since the on-site soils are used. The application of this liquidity filling material is not only to the lifeline installation but also to underpin the foundation under the vibrating machinery. On the evaluation of the applicability of this method to this circumstance, the strength should be investigated against the static load from the machine load as well as the vibration load from the activation of the machine. In this study, the applicability of the liquidity fill material on the foundation under the vibrating machinery is assessed via uniaxial compression and resonant column tests. The liquidity filling material consisting of the on-site soils with loess and kaolinite are tested to investigate the static and dynamic characteristics. Furthermore, the applicability of the reclaimed ash categorized as an industrial waste is evaluated for the recycle of the waste to the construction materials. The experimental results show that the shear modulus and 7 day uniaxial strength of the liquidity filling material mixed with reclaimed ash show higher than those with the on-site soils. However, the damping ratio does not show any tendency on the mixed materials.

• Korean Chemical Engineering Research
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• v.44 no.6
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• pp.623-630
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• 2006

The slag viscosity is an important factor determining the operation temperature of entrained flow type of gasifiers. The temperature of critical viscosity, $T_{cv}$, for 5 crystalline slags was predicted by empirical models and FactSage equilibrium calculations, and the validity of each method was tested. Two empirical models were employed: one using $T_h$ from the ash fusion test, and the other using the concentrations of 5 major components. The first model using $T_h$ over-predicted $T_{cv}$ by $20{\sim}100^{\circ}C$, while the model based on the slag composition under-predicted $T_{cv}$ by $80{\sim}120^{\circ}C$. In the equlibrium calculations, $T_{cv}$ was obtained from the liquidus temperature. When the 4-major component concentrations were used in the calculation, the predicted temperatures were higher than the observed. The liquidus temperature was very sensitive to the concentrations of minor components, and the addition of MgO and $Na_2O$ lowered the liquidus temperature. The results with 4 major and 3 minor components most closely described experimentally observed $T_{cv}$. In the case that a chromia refractory was used, it was shown that $Cr_2O_3$ concentration in the slag also needs to be included for more accurate prediction of $T_{cv}$.

• Journal of Energy Engineering
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• v.11 no.3
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• pp.247-253
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• 2002

Natural manganese ore was selected as main active component for a non-zinc desulfurization sorbent used in the gas clean-up process of the integrated gasification combined cycle (IGCC) because of excellent H$_2$S removal efficiency and economical aspect . In this study, the regeneration characteristics of sorbent after desulfurization reaction were determined in a thermobalance reactor and a fixed bed reactor in the temperature range of 350~55$0^{\circ}C$. The mixed gases of oxygen and nitrogen are used as the regeneration reaction gases for manganese sorbent. According to Mn-S-O phase diagram, the manganese sorbent has a low regeneration efficiency in medium temperature due to formation of MnSO$_4$ and the regeneration temperature must be over 85$0^{\circ}C$. To improve that problem, ammonia and steam was added in regeneration mixed gases. Effect of new regeneration method was determined by XRD and difference of desulfurization through multicycle tests.

• Journal of the Korean Society of Propulsion Engineers
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• v.15 no.3
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• pp.15-21
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• 2011

With petroleum reserves dwindling, interest has been increasing worldwide in Fischer-Tropsch synthesis (FT) as a method of producing synthetic liquid fuels and chemicals from coal, natural gas or biomass. In general, FT synthesis is operated through the gas phase fixed-bed reaction system. Recently, there are lots of study in supercritical fluid due to unique characteristics such as the quick diffusion of reactant gas, effective removal of reaction heat, and the in-situ extraction of high molecular weight hydrocarbon, such as wax. In this study, our major aim is to obtain a deeper insight into the effect of the type of support on the reaction performance over a supported cobalt catalyst in a fixed bed reactor.

• Korean Chemical Engineering Research
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• v.56 no.5
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• pp.631-640
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• 2018

The application of an oxy-combustion circulating fluidized bed combustor (Oxy-CFBC) for low grade coals has recently developed in the world to meet the continuous increase of energy demand and to achieve the reduction of greenhouse gases. Since demo plants for Oxy-CFBC have been developed, the combustion properties of Oxy-CFBC in various operation conditions, such as gas flow rates, combustion temperature, fuel, and so on, should be investigated to develop design criteria for a commercial Oxy-CFBC. In this study, a computational simulation tool for Oxy-CFBC was developed on the basis of the IEA-CFBC (International Energy Agency Circulating Fluidized Bed Combustor) model. Simulation was performed under various conditions such as reaction temperature ($800^{\circ}C{\sim}900^{\circ}C$), oxygen contents (21%~41%), coal feeding rate, Ca/S mole ratio (1.5~4.0), and so on. Simulation results show that the combustion furnace temperature is higher in oxy 1 than air fired. However, the temperature gradient tended to decrease with increasing oxy mixing percent. In case of $SO_x$, the higher the Ca/S mole ratio and oxy mixing percent, the higher the desulfurization efficiency.

• Clean Technology
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• v.27 no.1
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• pp.61-68
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• 2021

Selective catalytic reduction (SCR) is widely used as a method of removing nitrogen oxide in large-capacity thermal power generation systems. Uniform mixing of the injected ammonia and the inlet flue gas is very important to the performance of the denitrification reduction process in the catalyst bed. In the present study, a computational analysis technique was applied to the ammonia injection system design process of a denitrification facility. The applied model is the denitrification facility of an 800 MW class coal-fired power plant currently in operation. The flow field to be solved ranges from the inlet of the ammonia injection system to the end of the catalyst bed. The flow was analyzed in the two-dimensional domain assuming incompressible. The steady-state turbulent flow was solved with the commercial software named ANSYS-Fluent. The nozzle arrangement gap and injection flow rate in the ammonia injection system were chosen as the design parameters. A total of four (4) cases were simulated and compared. The root mean square of the NH3/NO molar ratio at the inlet of the catalyst layer was chosen as the optimization parameter and the design of the experiment was used as the base of the optimization algorithm. The case where the nozzle pitch and flow rate were adjusted at the same time was the best in terms of flow uniformity.

• 한국신재생에너지학회:학술대회논문집
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• 2007.11a
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• pp.417-423
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• 2007

Oxy-gasification or oxygen-blown gasification, enables a clean and efficient use of coal and opens a promising way to CO2 capture. The coal gasification process of a slurry feed type, entrained-flow coal gasifier was numerically predicted in this paper. The purposes of this study are to develop an evaluation technique for design and performance optimization of coal gasifiers using a numerical simulation technique, and to confirm the validity of the model. By dividing the complicated coal gasification process into several simplified stages such as slurry evaporation, coal devolatilization, mixture fraction model and two-phase reactions coupled with turbulent flow and two-phase heat transfer, a comprehensive numerical model was constructed to simulate the coal gasification process. The influence of turbulence on the gas properties was taken into account by the PDF (Probability Density Function) model. A numerical simulation with the coal gasification model is performed on the Conoco-Philips type gasifier for IGCC plant. Gas temperature distribution and product gas composition are also presented. Numerical computations were performed to assess the effect of variation in oxygen to coal ratio and steam to coal ratio on reactive flow field. The concentration of major products, CO and H2 were calculated with varying oxygen to coal ratio (0.2-1.5) and steam to coal ratio(0.3-0.7). To verify the validity of predictions, predicted values of CO and H2 concentrations at the exit of the gasifier were compared with previous work of the same geometry and operating points. Predictions showed that the CO and H2 concentration increased gradually to its maximum value with increasing oxygen-coal and hydrogen-coal ratio and decreased. When the oxygen-coal ratio was between 0.8 and 1.2, and the steam-coal ratio was between 0.4 and 0.5, high values of CO and H2 were obtained. This study also deals with the comparison of CFD (Computational Flow Dynamics) and STATNJAN results which consider the objective gasifier as chemical equilibrium to know the effect of flow on objective gasifier compared to equilibrium. This study makes objective gasifier divided into a few ranges to study the evolution of the gasification locally. By this method, we can find that there are characteristics in the each scope divided.

• Journal of Energy Engineering
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• v.11 no.2
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• pp.149-159
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• 2002

In the entrained flow gasifiers, the slag viscosity is an important parameter determining the operation conditions. The slag viscosities of 9 coals, which were selected and tested as possible gasification feedstock in Korea, were measured in a high temperature slag viscometer under gasification conditions. The type and size of crystalline phases that were known to affect the slag viscosity behavior were also determined. The slag samples were obtained from the IEA dry-feed gasifier. The slags of Alaska Usibelli, Curragh, Kideco, Adaro, Denisovsky, Baiduri and Drayton coals showed the behavior of crystalline slags, while those of Datong and Cypurus glassy slags. When a recommended minimum operating temperature was arbitrarily defined as $T_{1000}$poise/+$50^{\circ}C$ for glassy slags and $T_{cv}$ +$50^{\circ}C$ for crystalline slags, the Drayton slag required the lowest temperature, while Denisovsky slag required the highest. All the slags contained C $r_2$ $O_3$ from the refractory. The crystalline slags with $T_{cv}$ at around 132$0^{\circ}C$ contained large anorthites as the major crystalline phase that would have caused the rapid inrease in viscosity. Denisovsky slag contained many pores which were formed by $O_2$ from F $e_{x}$O reduction..

• Korean Chemical Engineering Research
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• v.48 no.2
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• pp.268-274
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• 2010

Emission of heavy metals as hazardous air pollutants has been focused with tightening regulatory limits due to their hazardousness. Measurements and characteristic investigations of heavy metals emitted from a commercial power plant burning anthracite coal have been carried out. The plant consists of a circulating fluidized bed combustor, a cyclone, a boiler and an electrostatic precipitator(ESP) in series. Dust and gaseous samples were collected to measure main heavy metals including gaseous mercury before ESP and at stack. Dust emissions as total particulate matter (TPM), PM-10 and PM-2.5 at inlet of ESP were very high with 23,274, 9,555 and $7,790mg/Sm^3$, respectively, as expected, which is much higher than those from pulverized coal power plants. However TPM at stack was less than $0.16mg/Sm^3$, due to high dust removal efficiency by ESP. Similarly heavy metals emission showed high collection efficiency across ESP. From particle size distribution and metal enrichment in sizes, several metal concentrations could be correlated with particle size showing more enrichment in smaller particles. Mercury unlike other solid metals behaved differently by emitting as gaseous state due to high volatility. Removal of mercury was quite less than other metals due to it's volatility, which was 68% only. Across ESP, speciation change of mercury from elemental to oxidized was clearly shown so that elemental mercury was half of total mercury at stack unlike other coal power plants which equipped wet a scrubber.

• Transactions of the Korean hydrogen and new energy society
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• v.22 no.6
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• pp.925-933
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• 2011

The traditional feedstock for dimethyl ether (DME) has been natural gas obtained by pipeline from a nearby natural gas or oil field. This report focuses on other feedstock: Coal bed methane (CBM). The resource availability and suitability of CBM for DME manufacturing have been investigated. CBM in a short time has become an important industry, providing an abundant clean-burning fuel and also suggesting as a feedstock for gas industry. The use of CBM will have very little impact on the KOGAS' DME process design and economics up to 50 vol% of $CO_2$ in the CBM source. Many of the CBM sources in Asia are high in $CO_2$, but pose no difficulties for the KOGAS' DME plant. Since tri-reformer requires substantial $CO_2$ in its feed, no $CO_2$ removal from the CBM feed is needed. The $CO_2$ in the CBM means that less $CO_2$ needs to be recycled from the downstream in the process.