• Title/Summary/Keyword: 석유화학 공정

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Recent Advances in the Mechanistic Studies of Alkylaromatic Conversions over Zeolite Catalysts (제올라이트 촉매상에서의 알킬 방향족 화합물 전환 반응기구에 대한 최근 연구 동향)

  • Min, Hyung-Ki;Hong, Suk Bong
    • Korean Chemical Engineering Research
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    • v.51 no.1
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    • pp.1-9
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    • 2013
  • The transformation of alkylaromatic hydrocarbons using zeolite catalysts play big part in the current petrochemical industry. Here we review recent advances in the understanding of the reaction mechanisms of various alkylaromatic conversions with respect to the structural and physicochemical properties of zeolite catalysts employed. Indeed, the shape-selective nature of zeolite catalysts determines the type of reaction intermediates and hence the prevailing reaction mechanism together with the product distribution. The prospect of zeolite catalysis in the developement of more efficient petrochemical processes is also described.

투과증발막을 이용한 폐수중의 유기물 제거

  • 이영무
    • Membrane Journal
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    • v.1 no.1
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    • pp.24-33
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    • 1991
  • 합성고분자막을 이용하여 액체혼합물을 분리하는 공정은 오래전부터 알려져 왔다. 바다물로부터 역삼투법이나 전기투석법을 이용하여 탈염하는 공정이라든지 한외여과 또는 정밀여과법을 이용하여 초순수를 제조하는 공정등은 현재 대단한 기술적, 상업적 의미를 갖으며 산업적으로 발전하고 있다. 더욱 최근에는 합성고분자막이 여러 기체혼합물 분리에 응용되고 있다. 예를 들면 석유화학 폐가스나 암모니아 공장에서 수소의 회수나 공기중의 산소나 질소의 부화등은 막이 아주 유용한 도구로 사용되어 온 두가지 중요한 분야이다. 고분자막이 특정한 물질분리에 맞도록 고안될수 있게 된 이래로 재래식 방법으로는 곤란한 분리문제들이 막공정에 의해 다루어질수 있게 되었다. 이같은 문제중 하나가 폐수중 유기용제등 유기물의 제거이다. 특히 할로겐화 유기물, 살충제, 농약등 오래전부터 독극물로 알려져온 물질들을 폐수로 부터 제저하는데 많은 노력이 경주되어 왔다. 이러한 연구에도 한외여과법이나 역삼투법등의 막분리공정이 응용되어 보고된 바 있다.

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ESCO사업은 효율적인 공정개선의 든든한 첨병

  • 에너지절약전문기업협회
    • The Magazine for Energy Service Companies
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    • s.27
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    • pp.16-19
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    • 2004
  • 합성고무를 주로 생산하는 금호석유화학 울산공장은 대표적인 에너지과다소비사업장이지만 각종 공정개선을 통한 에너지절감이 상당히 이루어지고 있다. 특히 정부자금을 활용하여 자금부담이 덜하고 신뢰할 수 있는 ESCO사업을 적극 활용, 쿨링워터시스템 개선사업을 비롯해 폐가스 보일러, 폐열회수시스템, 고효율조명 등 다양한 아이템으로 사업을 추진했다. 또한 이 공장은 그룹 차원에서 진행되는 에너지절감활동이 다채롭다.

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Mistakes of Cooling Tower Performance Analysis (냉각성능 분석오류)

  • 권오익
    • Journal of Advanced Marine Engineering and Technology
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    • v.28 no.3
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    • pp.397-404
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    • 2004
  • 냉각탑이란 석유화학플랜트, 철강플랜트 등과 같은 생산 공정이나 냉동기를 비롯한 각종 기계장치에서 발생된 열을 수냉식 열 교환장치에서 물로 직접 냉각시킬 때 공정유체의 열을 전달받아 데워진 물을 대기의 공기와 직접 접촉시켜 물의 증발 잠열을 이용하여 원하는 온도로 냉각시켜 주는 기계장치이다.(중략)

Environmental Impact Evaluation on Landfill Treatment of Petro-Chemical Wastewater Sludge by Life Cycle Assessment (전과정평가를 이용한 석유화학 폐수처리슬러지의 매립처리에 대한 환경영향평가)

  • Kim, Hyeong-Woo;Park, Hung-Suck
    • Journal of Korean Society of Environmental Engineers
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    • v.38 no.11
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    • pp.589-595
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    • 2016
  • This study evaluated the environmental impacts for landfill treatment of the wastewater treatment sludge (WTS) from petrochemical firms by life cycle assessment (LCA) and reviewed the impact reduction by landfill gas (LFG) utilization. The functional unit was 'landfill of 1 ton of WTS', and the system boundary included the process of input and treatment for WTS in landfill site. The impacts were high at landfill process (LP) and leachate treatment process (LTP). Global warming (GWP) and photochemical oxidants creation (POCP) were high at LP, while abiotic depletion (ADP), acidification (AP), eutrophication (EP), ozone depletion (ODP) were high at LTP. The major substances of various impact categories were crude oil (ADP), $NO_X$ (AP, EP), $CH_4$ (GWP, POCP), $Cl_2$ (ODP), respectively. The major factor of ADP, AP, EP was attributed from the generation of electricity used in LTP, and the methane within uncollected LFG was main factor of GWP and POCP. Therefore, electricity consumption reduction is identified to be an impact improvement option, and the flaring system installation or enhanced LFG recovery could be an alternative to reduce impacts. Among the various categories, GWP accounted the highest impact (${\geq}90%$) followed by ADP, POCP. In the avoidance impact resulted from the utilization of LFG, to substitute B-C oil or LNG showed the impact reduction of 32.7% and 12.0%, respectively.

The Research of Process High Alarm Priority Analysis for Efficient Emergency Response (효율적인 비상대응을 위한 Process High Alarm의 Priority 분석)

  • Kim, Youngse;Cho, Gyusun;Jun, Jinwoo;Kim, Byungjick;Lee, Joonwon;Park, Kyoshik
    • Korean Chemical Engineering Research
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    • v.58 no.4
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    • pp.604-609
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    • 2020
  • The purpose of this study is to check the priority control status of the current operation process alarm by comparing the priority of the alarm set up in PV high trip point, which is being installed and operated in the domestic petrochemical industry, with the criteria presented in ISA 18.2 International Standard or EEMUA 191 Guidelines. In the event of a process problem, excessively set high alarm is provided to the driver in a short period of time, making it difficult to identify the alarm that needs to be handled first. As a result, it is likely that the operator will not be able to carry out appropriate actions within the specified time frame, and many cases have been reported leading to unexpected process shutdowns or process accidents. Therefore, this study aims to introduce international standards related to alarm management and identify the level of alarm control used at the domestic petrochemical industry site to inform potential risks that may occur in the petrochemical process of the national industrial complex in the future and suggest ways to reduce risk factors. This paper was submitted to Professor Lee Inbeom's retirement anniversary issue.

A Study on the Process Corrosion and Source of the Emitted $H_2S$ from Clay Tower of Petrochemical BTX Process (석유화학 BTX 공정 점토탑에서의 $H_2S$ 및 공정 부식 발생 원인규명에 관한 연구)

  • 서성규;정채훈;문정선
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 1999.10a
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    • pp.443-444
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    • 1999
  • 악취는 냄새를 유발하는 기체상 물질이 사람의 후각을 자극하여 불쾌감이나 혐오감을 주는 상태를 말한다. 악취물질은 정유공장, 화학공장, 하수처리장, 분뇨 및 축산 폐수처리장, 매립장 등의 다양한 발생원이 있으며, 여러가지 복합된 화합물이 원인이 되어 악취를 유발한다. 단위 물질로서 황화수소(H$_2$S)는 계란 썩는 냄새, 메르캅탄(mercaptan)류는 야채 썩는 냄새, 아민류는 생선냄새 등의 특이한 냄새를 유발하며, 최저 감지값은 물질별로 상당한 차이를 나타내고 있다(이광묵, 1993).(중략)

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A Study on Actual Conditions of Industrial Safety Regulations - Based on Petrochemical Plant - (산업현장에서의 안전규제 적용실태 연구 - 석유화학공장을 중심으로 -)

  • Oh, Hyeong-Geun;Baek, Dong-Seung
    • Journal of the Korean Society of Hazard Mitigation
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    • v.11 no.2
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    • pp.81-86
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    • 2011
  • Without a special mineral resources in Korea, such as petrochemical industries, electronics and automotive industries to supply the basic material, but remains a key industry locations. Gongjeongsang dealing with hazardous materials, such as a fire or explosion hazard, and from this site sangjonhae safety regulations to protect human and material disaster prevention activities are focused. However, depending on the actual implementation of standardized safety regulations as necessary if not originally intended, proper objectivity and reliability of safety regulations, as well as impaired resulting in a waste of public and private administrative power and petrochemical industries and the competitiveness of the entire drop factor will. Accordingly, this study petrochemical plant is applied to a representative safety regulations, items for their safety are needed and these regulations as being implemented that was identified, according to a study, some of the need for regulation and implementation both in terms of reliability was low.

Microbial Catalysts for the Production of Thermo-resistant Bioplastics (내열성 바이오플라스틱 생산을 위한 미생물 촉매 개발)

  • Oh, Young Hoon;Lee, Seung Hwan;Park, Si Jae
    • Prospectives of Industrial Chemistry
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    • v.17 no.3
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    • pp.27-37
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    • 2014
  • 온실가스축적으로 인한 지구온난화를 비롯한 기후변화 및 고갈되어가는 석유를 비롯한 화석원료에 대한 문제를 해결하기 위해 재생가능한 자원으로부터 바이오기반 케미칼 및 고분자 등의 화학제품을 생산하는 바이오화학 공정이 많은 관심을 받고 있다. 본 기고문에서는 바이오화학공정에 핵심적인 촉매로 사용되고 있는 재조합 미생물 및 효소의 최근 개발동향을 내열성 엔지니어링 플라스틱인 바이오나일론의 생산을 위하여 개발되고 있는 바이오촉매를 중심으로 살펴보고자 한다.

Economic Assessment of a Indirect Liquefaction Process using a Gasification with Petroleum Coke/Coal Mixtures (석유코크스/석탄 혼합 가스화를 이용하는 액화 공정의 경제성 평가)

  • Shin, Ji-Hoon;Lee, Lu-Se;Lee, See-Hoon
    • Korean Chemical Engineering Research
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    • v.54 no.4
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    • pp.501-509
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    • 2016
  • The economic feasibility of a commercial indirect liquefaction process with the co-gasification process of petroleum coke which has been recognized as hazardous waste because of high sulfur content and bituminous coal and sub-bituminous coal mixtures was assessed. The 2,000 ton/day scale indirect liquefaction process including co-gasification, clean up, Fischer-Tropsch conversion and so on was assumed and used to analyze economical efficiencies with various conditions. Financial data from previous studies were modified and used and economical sensitivities with various mixture ratios were evaluated in this study. As a result, economic values of petroleum coke were superior than those of coals because of increasing sulfur sale. Also, mixtures with petroleum coke and bituminous coal was more favorable that those with petroleum coke and sub-bituminous coal due to lower moisture content. In case of sub-bituminous coal, the mixture ratio with petroleum coke had to be over 40wt% for the IRR of mixture to surpass 10%.