• Title/Summary/Keyword: 석영 용해

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Mineralogy and Geochemistry of the Jeonheung and Oksan Pb-Zn-Cu Deposits, Euiseong Area (의성(義城)지역 전흥(田興) 및 옥산(玉山) 열수(熱水) 연(鉛)-아연(亞鉛)-동(銅) 광상(鑛床)에 관한 광물학적(鑛物學的)·지화학적(地化學的) 연구(硏究))

  • Choi, Seon-Gyu;Lee, Jae-Ho;Yun, Seong-Taek;So, Chil-Sup
    • Economic and Environmental Geology
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    • v.25 no.4
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    • pp.417-433
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    • 1992
  • Lead-zinc-copper deposits of the Jeonheung and the Oksan mines around Euiseong area occur as hydrothermal quartz and calcite veins that crosscut Cretaceous sedimentary rocks of the Gyeongsang Basin. The mineralization occurred in three distinct stages (I, II, and III): (I) quartz-sulfides-sulfosalts-hematite mineralization stage; (II) barren quartz-fluorite stage; and (III) barren calcite stage. Stage I ore minerals comprise pyrite, chalcopyrite, sphalerite, galena and Pb-Ag-Bi-Sb sulfosalts. Mineralogies of the two mines are different, and arsenopyrite, pyrrhotite, tetrahedrite and iron-rich (up to 21 mole % FeS) sphalerite are restricted to the Oksan mine. A K-Ar radiometric dating for sericite indicates that the Pb-Zn-Cu deposits of the Euiseong area were formed during late Cretaceous age ($62.3{\pm}2.8Ma$), likely associated with a subvolcanic activity related to the volcanic complex in the nearby Geumseongsan Caldera and the ubiquitous felsite dykes. Stage I mineralization occurred at temperatures between > $380^{\circ}C$ and $240^{\circ}C$ from fluids with salinities between 6.3 and 0.7 equiv. wt. % NaCl. The chalcopyrite deposition occurred mostly at higher temperatures of > $300^{\circ}C$. Fluid inclusion data indicate that the Pb-Zn-Cu ore mineralization resulted from a complex history of boiling, cooling and dilution of ore fluids. The mineralization at Jeonheung resulted mainly from cooling and dilution by an influx of cooler meteoric waters, whereas the mineralization at Oksan was largely due to fluid boiling. Evidence of fluid boiling suggests that pressures decreased from about 210 bars to 80 bars. This corresponds to a depth of about 900 m in a hydrothermal system that changed from lithostatic (closed) toward hydrostatic (open) conditions. Sulfur isotope compositions of sulfide minerals (${\delta}^{34}S=2.9{\sim}9.6$ per mil) indicate that the ${\delta}^{34}S_{{\Sigma}S}$ value of ore fluids was ${\approx}8.6$ per mil. This ${\delta}^{34}S_{{\Sigma}S}$ value is likely consistent with an igneous sulfur mixed with sulfates (?) in surrounding sedimentary rocks. Measured and calculated hydrogen and oxygen isotope values of ore-forming fluids suggest meteoric water dominance, approaching unexchanged meteoric water values. Equilibrium thermodynamic interpretation indicates that the temperature versus $fs_2$ variation of stage I ore fluids differed between the two mines as follows: the $fs_2$ of ore fluids at Jeonheung changed with decreasing temperature constantly near the pyrite-hematite-magnetite sulfidation curve, whereas those at Oksan changed from the pyrite-pyrrhotite sulfidation state towards the pyrite-hematite-magnetite state. The shift in minerals precipitated during stage I also reflects a concomitant $fo_2$ increase, probably due to mixing of ore fluids with cooler, more oxidizing meteoric waters. Thermodynamic consideration of copper solubility suggests that the ore-forming fluids cooled through boiling at Oksan and mixing with less-evolved meteoric waters at Jeonheung, and that this cooling was the main cause of copper deposition through destabilization of copper chloride complexes.

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Structural Analysis for Optimal Design of Anchor Bolts and Brackets for Fixing External Finishing Materials (외부마감재 고정용 앙카볼트 및 브라켓의 최적설계를 위한 구조해석)

  • Lee, Suk Young
    • Journal of Energy Engineering
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    • v.29 no.3
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    • pp.91-96
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    • 2020
  • For the anchor bolts and brackets that fix the stone wall, which is an external finishing material, it is necessary to maintain the performance required for the mechanical structure from the initial design stage and secure high durability. For this, the design and safety evaluation in consideration of the load conditions are necessary, so the structural analysis applying the finite element analysis technique was performed as a method to verify durability. As a result of structural analysis for various shapes for optimal design, a reinforcing structure was added to alleviate the maximum stress generated at the rear part of the bracket in contact with the bolt. In addition, a reinforcing plate was additionally attached to the bracket to relieve the stress concentration of the L-shaped bracket to make the stress distribution uniform, so that the safety factor satisfies the standard conditions. In addition, the fatigue life analysis by cyclic load was performed, and the fatigue safety factor was analyzed. As a result, the durability was obtained.

Study on Magnetic Property Enhancement of Metal Powders for Magnetic Tape by Using Ultrasonic Dispersion (자기테이프용 Metal Powder의 초음파 분산에 의한 자기적 특성 향상에 관한 연구)

  • Kim, Chang-Gon;Choe, Hyeon-Seung;Jang, Hak-Jin;Yun, Seok-Yeong;Kim, Tae-Ok
    • Korean Journal of Materials Research
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    • v.11 no.11
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    • pp.972-977
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    • 2001
  • It was investigated the effect of ultrasonic treatment on magnetic property of ultra fine magnetic Fe powders ($\alpha$-Fe) for magnetic tape. The properties were characterized with vibrating sample magnetometer (VSM), particle size analyzer (PSA) and scanning electron microscope (SEM). At 4hours ultrasonic treatment of 70 kHz, magnetic properties such as squareness ratio (S.Q. : 0.8868), orientation ratio (O.R. : 2.45) and switching field distribution (S.F. D. : 0.394) before taping were relatively enhanced. Cumulative particle size distribution of less than 5$\mu\textrm{m}$ fine powder was above 90% below 1 hour leaving time after ultrasonic treatment and it was supposed that ultrasonic treatment prevent aggregation. The magnetic values of S.Q. and S.F.D. of tape manufactured at 70 kHz and 4hour ultrasonic treatment were improved from 0.7747, 0.3818 to 0.8037, 0.3706, respectively. Electro-magnetic property used as in-output signal characteristic was improved, which showed that ultrasonic treatment developed the magnetic properties.

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Archaeometric Characteristics of Roof Tiles in Baekje Kingdom from the Danjiri Site of Gongju, Korea (공주 단지리유적 출토 백제 기와의 고고과학적 특성)

  • Jang, Sung-Yoon;Lee, Chan-Hee;Park, Dae-Sun
    • Journal of Conservation Science
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    • v.22
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    • pp.15-30
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    • 2008
  • The roof tiles from the tomb in Baekje Kingdom of the Danjiri site in Gongju, Korea were studied for the production techniques and raw material provenance based on archaeometric characteristics. The roof tiles had traditional shapes of Baekje Kingdom, which show flow texture on the surfaces and sections with the roof tiles of hard or soft-type. These roof tiles were locally produced, using refining soils according to mineralogical and geochemical characteristics. Also roof tiles were divided to 2 groups by firing temperature and physical properties. One of them had soft with porous texture and fired probably about 700 to $900^{\circ}C$. The other had hard with vitrified texture and probably fired about 940 to $1,020^{\circ}C$. Buried for long time and used as a tomb, roof tiles had experienced chemical alteration due to the enrichments of trace elements abundant in human tissues.

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The Characteristics of the White Clay Pigment Manufactured from the White Clay of Producing Area Recorded in Old Documents (고문헌 산출지 백토로 제조된 백토안료의 특성 연구)

  • Kang, Yeong Seok;Mun, Seong Woo;Jeong, Hye Young
    • Journal of Conservation Science
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    • v.33 no.6
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    • pp.497-506
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    • 2017
  • An investigation on the records of old document was conducted to identify the producing area of white clay and there were on-the-spot surveys to secure raw materials of white clay pigment. Based on the survey results, six raw materials were obtained from the region of Gangwon-do and Gyeongsang-do, South Korea and white clay pigment was subsequently manufactured by applying the hydraulic elutriation method. The results show that the major constituent minerals of YBW, HBW, and MCW were quartz and plagioclase, whereas SGW, HOW, and HGW were composed of clay minerals such as kaolinite and illite. HGW showed the highest $L^*$-value of 92.9. HOW and HGW showed an opacity of 94.1% and 89.6%, respectively, and they had excellent spreadability (270.3 mm and 223.3 mm, respectively). Therefore, HGW, HOW, and SGW have excellent characteristics in terms of color, opacity, and spreadability, and are considered to be highly applicable as white pigments for the Dancheong.

The Study on Structural Strength Test Technique for Cylindrical Supersonic Vehicle Subjected to Severe Heating Environment (원통형 초음속 비행체 내열구조시험 기법 연구)

  • Lee, Kyung-Yong;Kim, Jong-Hwan;Lee, Kee-Bhum;Jung, Jae-Kwon
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.33 no.6
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    • pp.83-91
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    • 2005
  • This paper describes the structural strength test technique and the results for cylindrical supersonic vehicle subjected to both aerodynamic load and thermal load. The special positioning system using spring links was designed to float, support and restrain the test airframe during the test and the down-time. The hydraulic system and the electric heating system were utilized to apply the aerodynamic load and the thermal load to the test airframe together. Particularly, several hundreds of infrared quartz lamps were used for the heating system, and the thermal test conditions were successfully simulated. The test results showed that this kind of high temperature test is adequate to verify the structure integrity and produce useful engineering data which is necessary for the possible structural modification under thermal environments.

Measurement of Backscattering Coefficients of Rice Canopy using a Polarimetric Scatterometer System (Polarimetric Scatterometer 시스템을 이용한 벼 군락의 후방산란계수 측정)

  • Hong, Suk-Young;Hong, Jin-Young;Kim, Yi-Hyun;Oh, Yi-Sok
    • Proceedings of the KSRS Conference
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    • 2007.03a
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    • pp.153-157
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    • 2007
  • 본 논문은 지표면 현상의 관측에 날씨의 영향을 거의 받지 않는 마이크로파 L-밴드(1.95 GHz)와 C-밴드(5.3 GHz) scatterometer 시스템을 이용하여 농업과학기술원 내의 논에서 자라는 추청벼를 대상으로 2006년 5월 29일부터 10월 9일까지 생육에 따른 군락의 후방산란계수를 관측한 데이터와 작물의 생육과의 관계를 살펴보고 또한,측정 시스템의 개요,측정 시스템의 보정 방법들을 기술하고자 한다. Scatterometer 시스템의 송 수신기로 HP 8753D 벡터 네트워크 분석기를 사용하며,타워 위에 안테나를 설치하여 3.4 m의 높이에서 측정하도록 하였다. L-밴 드와 C-밴드 scatterometer는 VV-, VH-, HV-, HH-편파를 측정하여 fully polarimetric한 데이터를 얻도록 설계된 레이더시스템으로 입사각을 $30^{\circ}{\sim}60^{\circ}$에서 $10^{\circ}$간격으로 각각 30개의 독립적인 샘플을 측정하여 통계적으로 후방산란계수를 얻었다. 타워에서 발생하는 전파 잡음과 안테나 패턴의 부엽에 의한 지면에서의 수직반사(coherent 성분) 전파를 제거하기 위해 네트워크 분석기의 time gating 기능을 사용하며,55 cm 크기의 trihedral 전파반사기를 보정용 반사기로 사용하고, STCT(single target calibration technique) 방법을 이용하여 시스템을 보정하였다. 측정 결과를 분석하여 주파수, 입사각도, 편파의 변화에 대한 벼의 후방산란 특성과 벼의 생육상태과의 관계를 살펴보았다. L-밴드와 C-밴드 모두 벼의 생육과 밀접한 결과를 나타내었으나,입사각이 작을 때는 C-밴드와의 상관이 높게 나타났고 입사각이 커질수록 L-밴드와의 상관이 높게 나타났다. 편파는 L-밴드 와 C-밴드 모두 hh 편파가,입사각은 50도에서 가장 생육의 변이를 잘 설명하는 것으로 나타났다. 생육 데이터 모두를 이용한 경우보다는 유수형성기 또는 출수기 등 벼 생육의 질적인 변화를 보이는 시기에 따라 나누어 분석하는 것이 변화추이를 더 잘 설명하는 것으로 나타났다.

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Availability Review of Tailings from the Sangdong Tungsten Mine as a Material for Construction (건설용 재료로서 상동광산광미의 활용성 검토)

  • Kim, Yong-Jic;Kim, Young-Jin;Choi, Yun-Wang;Kim, Sang-Chel
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.1 no.3
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    • pp.204-210
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    • 2013
  • This study has focused on the possibility for recycling tailings from the Sangdong tungsten mine (TA) as admixture for concrete. TA has been accumulating for several decades in Sangdong, a region in Korea, and there is a growing demand for alternative uses for this hazardous substance. In particular, the use must be in accordance with the hazardous materials stipulations under the Korean waste control act. This study showed that TA presented pH of 8.0-9.3, 18.7-22.0% of water content, 2.7% of maximum ignition loss. The chemical composition of TA showed minute differences from each depth of sampling that represented approximately 50% of $SiO_2$ and 13% of both $Al_2O_3$ and $Fe_2O_3$. The chemical composition of Cd, Cu, Zn and Pb from mortar incorporating TA showed lower levels of hazardous materials which met the specifications of the waste control act in Korea. The TA mortar also appeared very effective for stabilizing/solidifying heavy metals particularly when used in conjunction with SG.

Genesis of Clay Minerals in the Vicinity of Gwangpo Bay, Southern Coast of Korea (광포만 집수유역내에 분포하는 점토광물의 성인에 관한 연구)

  • PARK Maeng-Eon;SONG Yong-Sun;KIM Hee-Joon;KIM Dae-Choul;PAIK In-Sung;CHUNG Sang-Yong;SONG Shi-Tae
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.21 no.4
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    • pp.259-268
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    • 1988
  • Clay deposits in the vicinity of the Gwangpo Bay, southern coast of Korea, occur restrictively in anorthositic masses. Laumontite and meta-halloysite are the predominant clay minerals with iron oxides at the uppermost surface. Chlorite and halloysite occur in deeper zone. Beneath the main clay horizon, but not above, some anorthositic rocks are pervasively altered to quartz, sericite, chlorite, pyrite and montmorillonite along the hydrothermal channels. The hypotheses of hydrothermal and weathering origins of the clay minerals are tested by multi-component equilibrium calculations of the reactions of modified hydrothermal water and rain water with anorthositic rocks at $100^{\circ}C\;and\;25^{\circ}C$, respectively. The calculated mineralogy from the reaction with rain water resembles natural mineral assemblage except for abundance in laumontite. The result implies that the weathering process is the main machanism of the formation of clay deposits in the area.

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Refinement of Low-grade Clay using Iron-reducing Bacteria [I] : Comparison of Traditional Ripening and Biotechnological Ripening (철환원세균을 이용한 저품위 점토의 개량[I] : 전통적 수비법과 생물공학적 숙성법의 비교)

  • 류희욱;조경숙;김민주;강석영;최희락
    • KSBB Journal
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    • v.15 no.2
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    • pp.201-207
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    • 2000
  • The traditional ripening method of clay was analyzed. An advanced refining method of clay using enrichment cultures of iron r reducing bacteria was developed. After the traditional ripening, the whiteness of the clay was increased due to removal of | iron impurities by inhabitant dissilmaltien with iron reducing bacteria. Other characteristics of the refined clay such as v viscosity, plasticity, and strength were also improved by iron reducing bacteria. An advanced method of clay refinement with a anaerobic enrichment cultivation of iron reducing bacteria supplemented with an extra carbon source such as glucose was s suggested. When the clay was treated by the advanced method. the refinement time could be reduced to 1/6 of that r required by the traditional method. The physical properties of the refined clay by the advanced method were better than t those of the traditionally refined clay.

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