• Economic and Environmental Geology
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• v.22 no.4
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• pp.327-339
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• 1989

Cassiterite, tantalite, columbite and tantalian rutile are found as accessory minerals in Soonkyoung tin-bearing pegmatites. These minerals occur as finely disseminated specks of up to micro-size in diameter and coarse grain size varying from 0.5-50mm in albite, muscovite and quartz assemblage. Cassiterite geneally shows a moderate to intense pleochroism, having a color brownish yellow to deep reddish brown. The substitution of $Ta^{+5}$, $Nb^{+5}$, $Ti^{+4}$ and Fe* for $Sn^{+4}$ in cassiterite ranges 0.01-0.10 mol%. The zoned cassiterite give a higher Ta/Nb ratios in margin than the ratios in core. This is due to the preferential $Ta^{+5}$ affinity to lower temperature during the crystallization of cassiterite. Tantalite-columbite and tantalian rutile occur in cassitertie with exsolution texture and/or infiltrate into the micro-fissures of cassiterite with micro quartz vein. The compositions of tantalite-columbite show the wide ranges of $Ta_2O_5$ : 14-46 wt.%, $Nb_2O_5$ : 60-28 wt. % and FeO*: 10.15 wt.%. The variation of chemical composition in tantalit-columbite exhibits the decreasing trends of $Mn^{+2}/M^{+2}+Fe^*$ with $Ta^{+5}/Ta^{+5}+Nb^{+5}$ increasing. These trends of vatiations indicate that the Ta/Nb fractionation are enhanced by higher Ta-complex activity in late stage of pegmatite consolidation and lower activity of F in agreements with the F-and Li-micas not to be developed in Soonkyoung tin-bearing pegmatite.

• Economic and Environmental Geology
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• v.35 no.3
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• pp.179-189
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• 2002

The Geology of the Shizhuyuan W-Sn-Bi-Mo deposits, situated 16 Ian southeast of Chengzhou City, Hunan Province, China, consist of Proterozoic metasedimentary rocks, Devonian carbonate rocks, Jurassic granitic rocks, Cretaceous granite porphyry and ultramafic dykes. The Shizhuyuan polymetallic deposits were associated with medium- to coarse-grained biotite granite of stage I. According to occurrences of ore body, ore minerals and assemblages, they might be classified into three stages such as skarn, greisen and hydrothernlal stages. The skarn is mainly calcic skarn, which develops around the Qianlishan granite, and consists of garnet, pyroxene, vesuvianite, wollastonite, amphibolite, fluorite, epidote, calcite, scheelite, wolframite, bismuthinite, molybdenite, cassiterite, native bismuth, unidetified Bi- Te-S system mineral, magnetite, and hematite. The greisen was related to residual fluid of medium- to coarse-grained biotite granite, and is classified into planar and vein types. It is composed of quartz, feldspar, muscovite, chlorite, tourmaline, topaz, apatite, beryl, scheelite, wolframite, bismuthinite, molybdenite, cassiterite, native bismuth, unknown uranium mineral, unknown REE mineral, pyrite, magnetite, and chalcopyrite with minor hematite. The hydrothermal stage was related to Cretaceous porphyry, and consist of quartz, pyrite and chalcopyrite. Scheelite shows a zonal texture, and higher MoO) content as 9.17% in central part. Wolframite is WO); 71.20 to 77.37 wt.%, FeO; 9.37 to 18.40 wt.%, MnO; 8.17 to 15.31 wt.% and CaO; 0.01 to 4.82 wt.%. FeO contents of cassiterite are 0.49 to 4.75 wt.%, and show higher contents (4.]7 to 4.75 wt.%) in skarn stage (Stage I). Te and Se contents of native bismuth range from 0.00 to 1.06 wt.% and from 0.00 to 0.57 wt.%, respectively. Unidentified Bi-Te-S system mineral is Bi; 78.62 to 80.75 wt.%, Te; 12.26 to 14.76 wt.%, Cu; 0.00 to 0.42 wt.%, S; 5.68 to 6.84 wt.%, Se; 0.44 to 0.78 wt.%.

• Journal of the Mineralogical Society of Korea
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• v.25 no.4
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• pp.221-231
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• 2012

Uljin cassiterite deposit had been known to be a pegmatitic origin derived from the Wangpiri (Buncheon) granitic gneiss of Precambrian period. Lithium ore also shows the same origin and its lithium bearing mineral was ascertained to be a taeniolite. But the presence of leucocratic granites which played the role of host rocks haven't been clearly designated yet in these provinces. Even though Bonghwa and Youngweol sericite deposits situated in the vicinities of Hambaeg syncline had been known to have their host rocks as Hongjesa Granites of Precambrian period and Pegmatitic migmatite of unknown age respectively. But younger leucocratic granites are characterized by more amounts of albite and sericite (muscovite-3T type) than those of the older granitic rocks which contain plenty of biotite and chlorites. Although the younger granites show rather higher contents of alkalies such as $Na_2O$ (0.13~8.03 wt%) and $K_2O$ (1.71~6.38 wt%), but CaO (0.05~1.21 wt%) is very deficient due to the albitization and greisenization. Manisan granite, which is assumed to be Daebo granite which intruded the Gyunggi Gneiss Complex was again intruded by leucocratic granite whose microclinized part changed into kaolins. Taebaegsan region shows a wide distribution of carbonate rocks which are especially favorable to the ore depositions. And the presence of alkali granites which formed in the later magmatic evolution are well known to be worthwhile to the prospections of various rare metals and REEs resources.

• The Journal of the Petrological Society of Korea
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• v.16 no.4
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• pp.189-195
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• 2007

Pirquitas mine was Bolivian type deposits, which Tertiary quartz andesites caused various epithermal quartz veins and deposited minerals of Sn and Ag in it. Main mineral was cassiterite and necessaries were pyrite, arsenopyrite, pynhotite, Probable ore reserve and daily production are 200 million tons and 5 thousand tons, respectively, and both of exploration and pit development are being carried simultaneously, but in near future open pit works can be done. This mine is owned by the Canadian company of "Silver Standard Resources" and it is located on $S22^{\circ}30'25.0",\;66^{\circ}15'22.5"$, 4086m S.L. In view of infrastructure, geological environment and scale of ore reserves it is high potential area for domestic mining companies to participate share ownership.

• Economic and Environmental Geology
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• v.45 no.6
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• pp.709-719
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• 2012

Prospection was performed on the tin mineralized belt in Mwanza and Kongolo areas of Katanga, DR Congo. Most of deposits in Katanga areas are related to the granites which are located in Kibaran belt in NE and SW trends of mid Proterozoic. Metasedimentary rocks in the Kibaran belt are intruded by granites, and tin, niobium and tantalum deposits are especially developed along with tin-granite. Cassiterite, coltan and gold are developed in the pegmatite, quartz vein and greisen in related to the tin-granite in Mwanza and Katanga areas, and they are exploited by artisan in the smale scale. And we conducted the works with the alluviums and stream sediments in the case of no outcrops. With the results of analysis of samples, we will choose a few potential mineralized zones and con-tinue to prosepect precisely.

• Economic and Environmental Geology
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• v.28 no.6
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• pp.613-621
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• 1995

It is understood that many big tungsten deposits such as the Sangdong in Korea, Fugigatami in Japan, Yukon in Canada, Pine Creek in U.S.A and Vostok in Russia were formed at late Cretaceous ages. However, most of tungsten mineralization in China where half the total world tungsten ores is reserved took place in late Jurassic to early Cretaceous ages. While the close association of molybdenum with tungsten mineralization is observed in the deposits related with Cretaceous magma, tungsten deposits in China related with late Jurassic to early Cretaceous show a close association of tin as well as molybdenum mineralization. It is characteristic that tungsten mineralization in China was followed by tin mineralization. The mode of occurrence of tungsten ore deposits in China is various and may represent the origin of tungsten in general, since the larger half of total amount of tungsten ores in the world are reserved in China. In case of Korea, more than 90% of total production of tungsten was occupied by the Sangdong tungsten deposit, which produced molybdenite as a byproduct Even if tin is detected in ppm unit content, no cassiterite is found in the Sangdong tungsten orebody. A similar type of two tungsten deposits is comparatively studied in order to confirm the published data; one is the Moping tungsten deposit in China and the other is the Dehwa tungsten deposit in Korea. Mineral assemblages occurring in quartz veins of both deposits are more or less same except that zinnwaldite and cassiterite occur only in the former deposit Ages of zinnwaldite and muscovite closely with molybdenite in the former deposit are 181.1 Ma and 167.8 Ma respectively, while muscovites associated with molybdenite in the latter deposit show ages of 80.9 Ma and 80.2 Ma. These results may represent deficient supply of tin from the source granitoid from which tungsten was derived in Korean peninsula during Cretaceous period, while tin supplied during tungsten mineralization tended to increase and the active tin mineralization followed the Jurassic tungsten mineralization in China.

• Journal of the Mineralogical Society of Korea
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• v.31 no.2
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• pp.87-101
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• 2018

The Manjang deposit developed in the Hwajeonri formation of the Okcheon metamorphic belt consists of the Central and Main orebodies of Cu-bearing hydrothermal vein type and the Western orebody of Fe-skarn type. This study focuses on the Cu mineralization of the Central and Main orebodies to compare with the genetic environments of the Western orebody previously studied. The Central orebody produced pyrrhotite and chalcopyrite as major ore minerals with vein texture, while the Main orebody contains pyrite, arsenopyrite, and chalcopyrite as major ore minerals with vein, massive, and brecciated texture. Sphalerite, galena, magnetite, ilmenite, rutile, cassiterite, wolframite, and stannite are also accompanied. Local occurrence of skarn is dominated by grossular and hedenbergite, reflecting the reduced condition of the skarnization. Geothermometries of sphalerite-stannite in the Central orebody and arsenopyrite-pyrite in the Main orebody indicate the formation temperature of $204-263^{\circ}C$ and $383-415^{\circ}C$, respectively. Sulfur fugacity of $10^{-6}-10^{-7}atm$. in the Main orebody decreased toward the Central orebody. Sulfur isotope compositions of sulfide minerals from the Central and Main orebodies are 4.6-7.9‰ and 4.3-7.0‰, respectively, reflecting magmatic origin with slight influence by host rock. Considering ore mineralogy, texture as well as physicochemical conditions, the Main and Central orebodies of hydrothermal Cu mineralization reflect the characteristics of proximal and distal type ore mineralization, respectively, related to hidden igneous rocks, and they were generated under different hydrothermal systems from the Fe-skarn Western orebody.

• Economic and Environmental Geology
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• v.49 no.6
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• pp.491-504
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• 2016

Jinwon Au-Ag deposit is located in the Uijin gun which is southeast 300 km from Seoul. The deposit area consists of mainly Precambrian Hongjesa granite, which occurs as porphyroblastic texture, medium grain and composed of quartz, feldspar and mica. This deposit consists of four parallel hydrothermal quartz veins that fill NE oriented fractures in Precambrian Hongjesa granite. The grade of quartz veins contain from 3.0 to 21.4 g/t (average 6.4 g/t) gold and from 5.0 to 252.0 g/t (average 117.9 g/t) silver, respectively. They vary from 0.2 m to 0.6 m (average 0.3 m) in thickness and extend to about 200 m in strike length. Quartz veins occur as massive, network, cavity, breccia, crustiform, comb and zonal textures. Wallrock alteration has silicification, sericitization, pyritization and argillitization. The mineralogy of the quartz veins consists of quartz, arsenopyrite, cassiterite, pyrite, sphalerite, chalcopyrite, galena, electrum, tetrahedrite, canfieldite, argentite, Ag-Sb-S mineral, Mn-Fe-O mineral, Pb-O mineral and Pb-P-Cl-O mineral(chloro-pyromorphite). Chemical compositions of minerals from this deposit are as followed; Fe/Fe+Mg of sericite is from 0.32 to 0.71, As content of arsenopyrite ranges from 27.91 to 30.33 atomic %, FeS content of sphalerite range from 9.77 to 16.76 mole %, Ag content of electrum is from 29.42 to 37.41 atomic % and Ag content of tetrahedrite range from 32.17 to 36.53 wt.%, respectively. Baased on mineralogy and chemical compositions of minerals from Jinwon Au-Ag deposit, deposition of minerals was caused by a change in temperature, oxygen fugacity($fO_2$) and sulfur fugacity($fS_2$) from the near neutral hydrothermal fluid evolved by reaction with wallrock.

• Economic and Environmental Geology
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• v.24 no.2
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• pp.131-150
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• 1991

The Weolseong diatreme was temporally and spatially related to the intrusion of the Gadaeri granite, and was -mineralized by meteoric aqueous fluids. In the Nokdong As-Zn deposit, pyrite, aresenopyrite and sphalerite are the most abundant sulfide minerals. They are associated with minor amount of magnetite, pyrrhotite, chalcopyrite and cassiterite, and trace amounts of Pb-Sb-Bi-Ag sulphosalts. The AsZn ore probably occurred at about $350^{\circ}C$ according to fluid inclusion and compositional data estimated from the arsenic content of arsenopyrite and iron content of sphalerite intergrown with pyrrhotite + chalcopyrite + cubanite. Heating studies of fluid inclusions in quartz indicate a temperature range between 180 and $360^{\circ}C$, and freezing data indicate a salinity range from 0.8 to 4.1 eq.wt % NaCl. The coexisting assemblage pyrite + pyrrhotite + arsenopyrite suggests that $H_2S$ was the dominate reduced sulfur species, and defines fluid parameter thus: $10^{-34.5}$ < ${\alpha}_{S_2}$ < $10^{-33}$, $10^{-11}$ < $f_{S_2}$ < $10^{-8}$, -2.4 < ${\alpha}_{S_2}$ < -1.6 atm and pH= 5.2 (sericte stable) at $300^{\circ}C$. The sulfur isotope values ranged from 1.8 to 5.5% and indicate that the sulfur in the sulfides is of magmatic in origin. The carbon isotope values range from -7.8 to -11.6%, and the oxygen isotope values from the carbonates in mineralized wall rock range from 2 to 11.4%. The oxygen isotope compositions of water coexisting with calcite require an input of meteoric water. The geochemical data indicate that the ore-forming fluid probably was generated by a variety of mechanisms, including deep circulation of meteoric water driven by magmatic heat, with possible input of magniatic water and ore component.

• Korean Journal of Mineralogy and Petrology
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• v.35 no.3
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• pp.283-298
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• 2022

In this study, we investigated the mineral geochemistry of the albite-spodumene pegmatite, associated exogreisen, and wall rock from the Boam Li deposit, Wangpiri, Uljin, Gyeongsangbuk-do, South Korea. The paragenesis of the Boam Li deposit consists of two stages; the magmatic and endogreisen stages. In the magmatic stage, pegmatite dikes mainly composed of spodumene, albite, quartz, and K-feldspar intruded into the Janggun limestone formation. In the following endogreisen stage, the secondary fine-grained albite along with muscovite, apatite, beryl, CGM(columbite group mineral), microlite, and cassiterite were precipitated and partly replaced the magmatic stage minerals. Exogreisen composed of tourmaline, quartz, and muscovite develops along the contact between the pegmatite dike and wall rock. The Cs contents of beryl and muscovite and Ta/(Nb+Ta) ratio of CGM are higher in the endogreisen stage than the magmatic stage, suggesting the involvement of the more evolved melts in the greisenization than in the magmatic stage. Florine-rich and Cl-poor apatite infer that the parental magma is likely derived from metasedimentary rock (S-type granite). P₂O₅ contents of albite in the endogreisen stage are below the detection limit of EDS while those of albite in the magmatic stage are 0.28 wt.% on average. The lower P₂O₅ contents of the former albite can be attributed to apatite and microlite precipitation during the endogreisen stage. Calcium introduced from the adjacent Janggun formation may have induced apatite crystallization. The interaction between the pegmatite and Janggun limestone is consistent with the gradual increase in Ca and other divalent cations and decrease in Al from the core to the rim of tourmaline in the exogreisen.