• Membrane Journal
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• v.16 no.2
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• pp.153-158
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• 2006

The crosslinked poly(vinyl alcohol) (PVA) mwmbranes with poly(styrene sulfonic acid-co-maleic acid) (PSSA-MA) were used to measure the water vapor and air permeabilities at 25 and $35^{\circ}C$. In addition, the contact angles of crosslinked PVA membranes were observed and increased with PSSA-MA contents. The water vapor permeability of 15300 Baller (1 Baller=$10^{-10}cm^3(STP){\cdot}cm/cm^2{\cdot}s{\cdot}cmHg$) was shown the maximum value at $35^{\circ}C$ when PSSA-MA=7 wt% membrane was used. The gas permeability of 146 Barrer was indicated the maximum at PSSA-MA=7 wt% at $35^{\circ}C$ and $P(H_2O)/P(Air)$ was the highest value 109.2 at $25^{\circ}C$.

• Journal of the Korean Society for Nondestructive Testing
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• v.33 no.1
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• pp.20-25
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• 2013

Ultrasonic methods are widely used to degradation assessment. Remaining-life cycle of metal can be estimated by ultrasonic parameters because ultrasonic velocity and attenuation are affected by change of material properties with accumulated fatigue in the metal. Therefore, in this study, we will estimate overall change of material properties by 2D C-scan image. Fatigued aluminum alloy 6061-T6 samples from 0 to 85% were prepared for evaluating fatigue life cycle. Also, degraded image of materials using attenuation is proposed to estimate degree of material degradation for determining degraded area of fatigued samples. Finally, we will predicts process pf degradation with measured attenuation of fatigued aluminum alloy 6061-T6 samples.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.25 no.10
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• pp.1318-1326
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• 2001

The evaporation heat transfer coefficient and pressure drop for refrigerant R-22 flowing in the plate and shell heat exchanger were investigated experimentally in this study. Two vertical counterflow channels were farmed in the exchanger by three plates of commercial geometry with a corrugated trapezoid shape of a chevron angel of 45 ° Upflow boiling of refrigerant R-22 in one channel receives heat from the hot downf1ow of water in the other channel. The effects of the mean vapor quality, mass flux, heat flux and pressure of R-22 on the evaporation heat transfer and pressure drop were explored. The quality change of R-22 between the inlet and outlet of the refrigerant channel ranges from 0.03 to 0.05. The present data showed that both the evaporation heat transfer coefficient and pressure drop increase with the vapor quality. At a higher mass flux, the evaporation heat transfer coefficient and pressure drop are higher for the entire range of the vapor quality Raising the imposed wall heat flux was found to slightly improve the heat transfer, while at a higher refrigerant pressure, both the heat transfer and pressure drop are slightly lower.

• Membrane Journal
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• v.16 no.3
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• pp.235-239
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• 2006

This study illustrated the results of pervaporation separation using crosslinked poly(vinyl alcohol) (PVA) with poly(styrene sulfonic acid-co-maleic acid) (PSSA-MA) for water-ethanol system at 25, 35, and $45^{\circ}C$. The contents of the crosslinking agents were 7, 9, and ll wt% against PVA and the feed compositions of 50, 20, 10 and 4.4% in water were investigated. Typical trends of permeability and separation factor in pervaporation were observed for both the crosslinking agents and operating temperatures. For water : ethanol = 10 : 90, and at $45^{\circ}C$, PSSA-MA 11 wt% membrane showed the permeability $58.92g/m^2{\cdot}hr$ and the separation factor 12003 respectively.

• Journal of Sensor Science and Technology
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• v.4 no.3
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• pp.22-29
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• 1995

Lithium ionic solid electrolyte was synthesized at $60^{\circ}C$ in $N_{2}$ ambience by sol-gel method, using tetraethyl orthosilcate, lithium methoxide, zirconium n-propoxide, and tributyle phosphate as precursors. The prepared material was dried and crushed into powder, and it was pressed into disk type samples. These samples were sintered at $900^{\circ}C{\sim}1100^{\circ}C$ for 50 hours. The physical characteristics of the samples were investigated by TG/DTA, SEM, AES and XRD methods. $CO_{2}$ sensor based on lithium ionic solid electrolyte was fabricated and its operational characteristics were measured. The sensing characteristics of the sensor sintered at $1000^{\circ}C$ shows the variation of e.m.f. about $35{\sim}63\;mV/decade$ for the variation of $CO_{2}$ concentration at $200^{\circ}C{\sim}300^{\circ}C$ of operating temperature, and good linearity for $300{\sim}6000\;ppm$.

• Journal of the Korean Chemical Society
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• v.43 no.3
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• pp.264-270
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• 1999

Enzyme electrodes for amperometric measurement of glucose were prepared by immobilization of glucose oxidase on an Immobilon-AV Affinity membrane and attachement to a Pt electrodes. The electrochemical oxidation of Hz02 was monitored at +0.8V vs. Ag/AgCl. Response was linear from 0.2 mM to 20mM. The detection limit was 10m3 mM. Response time, the optimum pH and life time of enzyme immobilized membrane was 12 seconds, pH 5.5(CH3COONaJCH3COOH) and about 27 days, respectively. When the enzyme electrode was applied for the determinaion of glucose with amperometric method, other physiolosical materials have not interfered. Also, we compared the result with that from AOAC(Association of Offical Analytical Chemists) method, measuring the glucose in sweet potato. The relative error was 0.1%.

• Journal of the Korean Chemical Society
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• v.35 no.4
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• pp.405-409
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• 1991

The electrochemical behaviors of copper-1-(2-thiazolylazo)-2-naphthol [Cu(II)-TAN] complex in acetonitrile (AN) solution have been investigated by the use of polarography, controlled potential coulometry and UV-Vis spectroscopy. Cu(II)-TAN complex exhibit three reduction waves at -0.91 V, -1.34 V and -1.65 V vs. S.C.E. in acetonitrile solution containing 5.0 ${\times}\;10^{-3}$M tetraethylammonium perchlorate. Every reduction wave is diffusion controlled. The first reduction wave is considerably reversible and this process is attributed to the formation of anion radical. The second reduction process to the dianion is followed by a chemical reaction producing a complex of hydrazo complex. The third reduction process produce Cu(Hg) amalgam and amine compound.

• Journal of the Korean Chemical Society
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• v.34 no.6
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• pp.582-592
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• 1990

Retention behavior of lanthanide-$\alpha$HiBA complexes was studied on the cation exchanger (LC-18 coated with $C_{20}H_{41}SO_4^-$). An equation predicting retention of lanthanides in isocratic or gradient elution with sodium ion and $\alpha$-HiBA concentration was derived from ion exchange equilibria of metal-ligand complex system, respectively. The relations between log k' and log [Na$^+$] /log [$\alpha$-HiBA) showed non-linearity in isocratic elution. In gradient elution a good linearity between log k' vs log R was obtained. The values of slopes (log k / log R) gave good agreements between calculation and experiment. Individual capacity factors ($k'_{Ln}^{3+}, k'_{LnL}^{2+}, k'{LnL2+}) and stability constant (${\beta}_1$, ${\beta}_2$, ${\beta}_3$) of lanthanide-$\alpha$HiBA complexes were calculated by the non-linear least square fittings using the retention equation. The correlation coefficients of lanthanides were shown better than 0.9996 between experiment and calculation.

• Journal of the Korean Chemical Society
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• v.44 no.6
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• pp.581-586
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• 2000

Separation and coulometric titration method were applied for the determination of plutonium content in samples of PWR spent fuel. Plutonium was separated on an anion exchange(AG MP-1) column and determined by the controlled-potential coulometric titration. In this study, we discussed some experimental conditions related to the separation and determination of plutonium in PWR spent fuel samples. Average accuracy(recovery of plutonium) for the determination of 0.230∼3.02 mg plutonium standard was 99.36%. Average precision(relative standard deviation, RSD) for the determination of 0.250∼0.450 mg plutonium in PWR spent fuel samples was 0.38%.

• Journal of the Korean Chemical Society
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• v.38 no.7
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• pp.502-508
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• 1994

The measurement of trace amounts of uranium(VI) and thorium(VI) in the solutions containing high concentration of dissolved salts was carried out. The procedure using reversed phase liquid chromatography with trace enrichment techniques has been developed to cope with the high salt content of the samples. 2 ml of sample were passed through a small C_{18}$ reversed phase enrichment column with ${\alpha}$-HIBA eluent (0.11 M, pH 5.5) where the uranium and thorium were separated from other constituents and concentrated. The uranium and thorium were then backflushed from the column onto a deactivated C_{18}$ reversed phase analytical column where furthe separation was achieved with a mixed eluent (pH3.0, 0.17M ${\alpha}$-HIBA/0.0038 M 1-pentanesulfonate). The separated species were determined spectrophotometrically by postcolumn reaction with Arsenazo III, the chromogenic reagent. Detection limits were found within 1 ppb range for both species.