• Title/Summary/Keyword: 생체금속

Search Result 179, Processing Time 0.024 seconds

Biosorption and Desorption of Pb by using Sargassum horneri (괭생이모자반, Sargassum horneri를 이용한 Pb 흡착 및 탈착)

  • SUH Kuen-Hack;AHN Kab-Hwan;KIM Byong-Jin;CHO Jin-Koo;JIN Hyung-Joo;HONH Yong-Ki
    • Korean Journal of Fisheries and Aquatic Sciences
    • /
    • v.32 no.3
    • /
    • pp.333-337
    • /
    • 1999
  • Biosorption of Pb to Sargassum horneri was evaluated. An adsorption equilibrium was reached in about 15 min. for Pb and Pb uptake was 185.5 mg Pb/g biomass. When Ca and Mg concentration increases in Pb solution, Pb was selectively adsorbed. The Pb adsorbed by S. horneri could be recovered by desorption process, and the desorption efficiency of Pb by 0.1 M HCl, 0.1 M $HNO_3$, and 0.1 M EDTA was above $95\%$, whereas the elution by 0.1 M NaOH was less efficient in the desorption of Pb. S. horneri was reused 6 cycle repeatedly after adsorption/desorption and the sum of uptake was 636.6 mg Pb/g biomass.

  • PDF

Storage of Salted Chinese Cabbages for Kimchi - I. Physicochemical and Microbial Changes During Salting of Chinese Cabbages - (김치용 간절임 배추의 저장에 관한 연구 - I. 배추의 간절임시 일어나는 이화학적 및 미생물학적 변화 -)

  • Kim, Joong-Man;Kim, Ihn-Sook;Yang, Hee-Cheon
    • Journal of the Korean Society of Food Science and Nutrition
    • /
    • v.16 no.2
    • /
    • pp.75-82
    • /
    • 1987
  • This study was to investigate physicochemical and microbial changes that took place during the salting of chinese cabbages. Salinity(3%) that is suitable for kimchi preparation was reached when chinese cabbages were salted for seven hours in 10%, three hours in 15% and one hour in 20%. In the case of 5% it was not reached though they were salted for over twelve hours. In order to decrease salinity from 7% level of salted chinese cabbages to 3% level by soaking in tap water, 1.2 hours for leaf and three hours for patiole were spent. Volume, moisture, firmness and internal space of raw chinese cabbages were significantly decreased by salting (15%, 10 hours) : volume, 59.90%, moisture, about 31.92% and internal space rate, 35.06%. Contents of mono-and divalent cations$(K^+,\;Mg^{2+}\;and\;Ca^{2+})$ were reduced whereas $Na^+$ content was greatly increased; therefore, in the future the increase of Na-content remains open to question. By salting and washing, mold, yeast and bacteria were decreased by 58%, 40%, 45%, respectivity.

  • PDF

Evaluation of Biocompatibility of Anodized and Hydrothermally Treated Pure Niobium Metal (양극산화와 열수처리한 순수 니오비움 금속의 생체활성 평가)

  • Won, Dae-Hee;Choi, Un-Jae;Lee, Min-Ho;Bae, Tae-Sung
    • Journal of Technologic Dentistry
    • /
    • v.27 no.1
    • /
    • pp.79-88
    • /
    • 2005
  • This study was performed to investigate the surface properties of electrochemically oxidized pure niobium by anodic oxide and hydrothermal treatment technique. Niobium specimens of $10\times10mm$ in dimension were polished sequentially from #600, #800, #1000 emery paper. The surface pure niobium specimens were anodized in an electrolytic solution that was dissolved calcium and phosphate in water. The electrolytic voltage was set in the range of 250 V and the current density was 10 $mA/cm^2$. The specimen was hydrothermal treated in high-pressure steam at 300$^{\circ}C$ for 2 hours using an autoclave. Then, specimens were immersed in the Hanks' solution with pH 7.4 at 37$^{\circ}C$ for 30 days. The surface of specimen was characterized by scanning electron microscope(SEM), energy dispersive X-ray microanalysis(EDX), potentiostat/galvanostat test, and cytotoxicity test. The results obtained was summarized as follows; According to the result of measuring corrosion behavior at 0.9% NaCl, corrosion resistance was improved more specimens treated with anodic oxide than in hydrothermal treated ones. The multi-porous oxide layer on surface treated through anodic oxidation showed a structure that fine pores overlap one another, and the early precipitation of apatite was observed on the surface of hydrothermal treated samples. According to the result of EDX after 30 days deposition in Hanks' solution, Ca/P was 1.69 in hydrothermal treated specimens. In MTT test, specimens treated through anodic oxidation and hydrothermal treated ones showed spectrophotometer similar to that of the control group. Thus no significant difference in cytotoxicity was observed (P>0.05).

  • PDF

아크로 증착된 TiN 박막의 특성 연구

  • Jang, Seung-Hyeon;Yang, Ji-Hun;Park, Hye-Seon;Jeong, Jae-In
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2010.08a
    • /
    • pp.177-177
    • /
    • 2010
  • 티타늄 화합물은 뛰어난 물리적 특성과 인체 무해성을 가지고 있어 생체, 내식 및 내마모 재료 등에 널리 응용되고 있으며, 다양한 색상 구현을 통한 미려한 외관 등 기능성을 위한 표면처리 분야에도 많은 관심을 받고 있다. 이중 질화 티타늄은 금색을 대체할 수 있는 물질로 코팅방법과 기판온도, 바이어스, 질소유량 등과 같은 공정변수 제어를 통해 그 물성을 변화시킬 수 있어 기능적 측면과 함께 미려한 외관처리에 응용이 가능하다. 본 연구에서는 아크(cathodic arc) 코팅 시스템을 이용하여 다양한 조건에서 TiN 박막을 제조하고 그 특성을 평가하였다. 아크 장비는 화합물 박막을 코팅할 수 있는 아크 소스와 시편 홀더, 가스 주입구, 시편 가열장치 그리고 배기 장치로 구성되어 있고, 아크 소스에 장착된 타겟은 99.5%의 Ti 타겟을 사용하였다. 시편과 타겟 간의 거리는 약 31cm이며, 시편은 알코올과 아세톤으로 초음파 세척 된 강판(냉연 강판), 실리콘 웨이퍼를 사용하였다. 시편을 진공용기에 장착하고 ${\sim}10^{-6}$ Torr까지 진공배기를 실시하고, Ar 가스를 진공용기 내로 공급하여 ${\sim}10^{-4}$ Torr에서 시편에 bias (Pulse : 400V)를 인가한 후 아크를 발생시켜 약 5분간 청정을 실시하였다. 플라즈마 청정이 끝나면 시편에 인가된 bias를 차단하고, 질소 유량, 온도, bias, 시간 등의 공정변수에 따라 코팅을 실시하였다. 질소의 유량이 80sccm 일 때, Ti 금속 결정구조가 나타났는데, 이는 질소와 충분하게 반응하지 못한 Ti이 기판에 코팅되어 나타나는 현상으로 판단된다. 색상변화에서는 질소 유량이 증가함에 따라 노란색이 짙어지며, TiN은 시편에 인가되는 bias 전압이 높아질수록 붉은색이 증가하고, 온도에 따른 큰 변화는 관찰되지 않았다. 공정변수에 따른 반사율 변화는 TiN의 경우 질소 가스 유량이 200sccm, bias 150V, 공정 온도 200도에서 반사율이 가장 높았으며, 코팅 시간이 짧을수록 반사율이 높아지는 경향을 나타냈다. 따라서 본 연구에서 얻어진 결과를 외관 코팅 분야에 응용한다면 장식성과 외관의 경도, 내마모성, 내식성의 향상 등 많은 장점을 가질 것으로 예상된다.

  • PDF

Comparative Study on Biomechanical Behavior of Various Cervical Stand-Alone Cage Designs (경추용 일체형 추간체 유합 보형재의 디자인 변화에 따른 생체역학적 효과 비교 연구)

  • Park, Kwang Min;Jung, Tae Gon;Jeong, Seung Jo;Lee, Sung Jae
    • Journal of the Korean Society for Precision Engineering
    • /
    • v.33 no.11
    • /
    • pp.943-950
    • /
    • 2016
  • The purpose of this study was to evaluate and compare by finite element analysis the biomechanical performance, in terms of cervical stand-alone cage screw insert angle (Type 3 - 5: 2 Screws) and screw arrangement (Type 6 and 7: 3 Screws / Type 8 and 9: 4 Screws), and the range of motion (ROM) of traditional anterior cervical discectomy of a fusion device (Type 1: Cage / Type 2: Cage + ACP). Our study suggests that the biomechanical behavior of a postoperative cervical spine could indeed be influenced by design features, such as screw angle and number of screws. In particular, ROM and the risk of subsidence were more sensitive during extension about type 5 (Insert Angle $20^{\circ}$). Our study also suggested that the number of screw asymmetries between up and down for type 6 and 7 could result in differences in the risk of screw fracture manifesting in different clinical aspects.

Effect of Biodegradable Polymer Coating on the Corrosion Rates and Mechanical Properties of Biliary Magnesium Alloy Stents (생분해성 고분자 코팅이 담관용 마그네슘 합금 스텐트의 분해 속도와 기계적 물성에 미치는 영향)

  • Kim, Hyun Wook;Lee, Woo-Yiel;Song, Ki Chang
    • Korean Chemical Engineering Research
    • /
    • v.58 no.1
    • /
    • pp.36-43
    • /
    • 2020
  • A biliant stent was fabricated using a magnesium alloy wire, a biodegradable metal. In order to control the fast decomposition and corrosion of magnesium alloys in vivo, magnesium alloy wires were coated with biodegradable polymers such as polycaprolactone (PCL), poly(propylene carbonate) (PPC), poly (L-lactic acid) (PLLA), and poly (D, L-lactide-co-glycolide) (PLGA). In the case of PPC, which is a surface erosion polymer, there is no crack or peeling compared to other polymers (PCL, PLLA, and PLGA) that exhibit bulk erosion behavior. Also, the effect of biodegradable polymer coating on the axial force, which is the mechanical property of magnesium alloy stents, was investigated. Stents coated with most biodegradable polymers (PCL, PLLA, PLGA) increased axial forces compared to the uncoated stent, reducing the flexibility of the stent. However, the stent coated with PPC showed the axial force similar to uncoated stent, which did not reduce the flexibility. From the above results, PPC is considered to be the most efficient biodegradable polymer.

Superhydrophilic Coating on Platinum Substrate by Sulfonic Self-Assembled Monolayer (술폰산기 자가 조립 단분자막 형성을 이용한 백금 기재 표면의 초친수성 코팅)

  • Lee, Haesung;Lee, Haeshin
    • Journal of Adhesion and Interface
    • /
    • v.16 no.4
    • /
    • pp.152-155
    • /
    • 2015
  • Platinum (Pt) is an easily moldable, anti-corrosive and also good catalyst in a variety of chemical reactions. Platinum can be used in many fields, however, however, the low wettability of platinum substrate in many platinum-based devices has been made a problem when they contact with liquid state environment. In this study, we report a simple and effective self-assembled monolayer coating method which provides tremendously increased wettability on platinum substrate device by using Sodium 3-mercapto-1-propanesulfonic acid solution. After surface modifications, water contact angle of the surfaces displayed less than $10^{\circ}$, representing that surfaces are successfully coated to be super-hydrophilic surface by simple dip coating method.

Study on Radial Force of Helical Structure for Biodegradable Polymer Stents (생분해성 고분자 스텐트를 위한 나선헝 구조의 팽창력 연구)

  • Park, Chul-Ho;Park, Ga-Ram;Choi, Ji-Yeon;Park, Kwi-Deok;Han, Dong-Keun
    • Polymer(Korea)
    • /
    • v.35 no.3
    • /
    • pp.260-264
    • /
    • 2011
  • Biodegradable polymeric stents have been issued to replace the existing non-degradable metal stents due to relatively improved biocompatibility and low side effects. Fundamentally, all the stents must possess the desired mechanism strength, especially, compression or radial force to maintain the diameters of expanded vessels. Therefore, this study suggests a helical structure and focused on the relation between the lateral compression and structural factors, Unlike a cylindrical model, the radial force of the helical model is proportional to the thickness and the length to the power of one, whereas the diameter to the power of 1.6. The function obtained from these results might provide the fundamental information to design and prepare the stem for clinical applications.

Improved IPMCs and It's Application for Flapping Actuator (IPMCs(Ionic Polymer Metal Composites) 성능 개선 및 날갯짓 작동기로의 응용)

  • Lee, Soon-Gie;Yoo, Young-Tai;Heo, Seok;Park, Hoon-Cheol
    • Proceedings of the Korean Society for Noise and Vibration Engineering Conference
    • /
    • 2005.11a
    • /
    • pp.723-726
    • /
    • 2005
  • The two major obstacles in the application of IPMC to flapping actuators operated in the air are solvent loss and actuation force. In this paper, solvent loss of various IPMCs made of Nafion$^{TM}$117(183$\mu$m thickness) has been experimentally investigated to find out the best combination of cation and solvent for minimal solvent loss in IPMCs and higher actuation force. For this purpose. experiments for the internal solvent loss measurement of IMPCs have been conducted for various combinations of cation and solvent. From the experiments, it was found that heavy water showed improvement in the operating time up to more than two minutes. in the tip force measurement of IPMCs, it was found that smaller and thicker IPMCs produced larger tip forces. However, the shorter IPMCs generated reduced actuation displacements and created flapping motion with decreased natural frequency. For the design of flapping device actuated by 5mm wide, 10mm long, 0.2mm thick IPMCs were used in the stacked form. Since the actuation force is a few gram-force, we stacked five IPMCs to improve actuation force. To amply the actuation force, rack-and-pin ion type hinge was used for the flapping device and insect (Cicadidae) wing was attached to the stacked IPMC actuator. In the flapping test, the device could generate flapping angle of 15$^{\circ}$ at 6Hz excitation by 2.5 voltage square wave input.

  • PDF

Development of the Novel Intraoperative Neuromonitoring for Thyroid Surgery (갑상선 수술을 위한 새로운 수술 중 신경감시시스템의 개발)

  • Sung, Eui Suk;Lee, Byung Joo
    • International journal of thyroidology
    • /
    • v.11 no.2
    • /
    • pp.109-116
    • /
    • 2018
  • It is very important to identify recurrent laryngeal nerve (RLN) and prevent RLN injury during thyroid surgery. The intraoperative neuromonitoring (IONM) for the prevention of RLN injury is a useful method because it can identify the location and status of RLN and predict postoperative vocal cord function easily. The IONM consists of a stimulating side that applies electrical stimulation to the nerve and a recording side that measures the surface electromyography (EMG) of the vocal cord muscle through electrode endotracheal tube. The nerve stimulator and surgical dissector are separate instruments. So, during IONM for the prevention of the RLN injury in conventional, endoscopic, or robotic thyroid surgery, repeated exchanging between surgical instruments and the nerve stimulator is inconvenient and time consuming. On the recording side, the accuracy of the electrode endotracheal tube which measures the EMG of the vocalis muscle can be affected by contact with between electrode and vocal fold and position change of patient. We would like to introduce recent several researches to overcome the current limitations of IONM.