• 제목/요약/키워드: 생성모형

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Photochemical Reactivity of Chromium(III) Complexes (Chromium(III) 錯物의 光化學的 反應性)

  • Jong-Jae Chung;Jung-Ui Hwang;Jong-Ha Choi
    • Journal of the Korean Chemical Society
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    • v.30 no.2
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    • pp.181-187
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    • 1986
  • It is shown that the substitutive ligand on the photochemical substitution reactions of $trans-Cr^{Ⅲ}N_4XY$ complexes is predicted by considering the total stabilization energy of the hypothetical primary intermediates resulting from the loss of one ligand. The total stabilization energy and one electron energy level of d-orbital are calculated within the framework of angular overlap model. According to the calculated results, the intermediates with larger total stabilization energy are, as expected, more easily produced. Consequently, the relative values of the total stabilization energy are used to decide which of the ligands in $trans-Cr^{Ⅲ}N_4XY$ complexes is preferentially labilized on the lowest energy d-d irradiation. The prediction for the leaving ligand on the photoaquation of $trans-Cr^{Ⅲ}N_4XY$ complexes is consistent.

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A study on Similarity analysis of National R&D Programs using R&D Project's technical classification (R&D과제의 기술분류를 이용한 사업간 유사도 분석 기법에 관한 연구)

  • Kim, Ju-Ho;Kim, Young-Ja;Kim, Jong-Bae
    • Journal of Digital Contents Society
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    • v.13 no.3
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    • pp.317-324
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    • 2012
  • Recently, coordination task of similarity between national R&D programs is emphasized on view from the R&D investment efficiency. But the previous similarity search method like text-based similarity search which using keyword of R&D projects has reached the limit due to deviation of document's quality. For the solve the limitations of text-based similarity search using the keyword extraction, in this study, utilization of R&D project's technical classification will be discussed as a new similarity search method when analyzed of similarity between national R&D programs. To this end, extracts the Science and Technology Standard Classification of R & D projects which are collected when national R&D Survey & analysis, and creates peculiar vector model of each R&D programs. Verify a reliability of this study by calculate the cosine-based and Euclidean distance-based similarity and compare with calculated the text-based similarity.

Experimental Verification of Effectiveness of Stabilization Control System for Mobile Surveillance Robot (기동형 경계로봇 안정화 시스템의 실험적 검증)

  • Kim, Sung-Soo;Lee, Dong-Youm;Kwon, Jeong-Joo;Park, Sung-Ho
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.35 no.4
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    • pp.359-365
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    • 2011
  • A mobile surveillance robot is defined as a surveillance robot system that is mounted on a mobile platform and is used to protect public areas such as airports or harbors from invaders. The mobile surveillance robot that is mounted on a mobile platform consists of a gun module, a camera system module, an embedded control system, and AHRS (Attitude and Heading Reference System). It has two axis control systems for controlling its elevation and azimuth. In order to obtain stable images for targeting invaders, this system requires a stabilizer to compensate any disturbance due to vehicle motion. In this study, a virtual model of a mobile surveillance robot has been created and ADAMS/Matlab simulations have been performed to verify the suitability of the proposed stabilization algorithm. Further, the suitability of the stabilization algorithm has also been verified using a mock-up of the mobile surveillance robot and a 6-DOF (Degree Of Freedom) motion simulator.

Development of Verification and Conformance Testing Tools for Communication Protocol (통신 프로토콜 검정기 및 적합성시험 도구 개발)

  • Seo Mi-Seon;Hwang Jong-Gyu;Lee Jae-Ho;Kim Sung-Un
    • Journal of Korea Multimedia Society
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    • v.8 no.8
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    • pp.1119-1133
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    • 2005
  • As a very important part in development of the protocol, verification and conformance test for protocol specification are complementary techniques that are used to increase the level of confidence in the system functions as prescribed by their specifications. In this paper, we verify the safety and liveness properties of rail signal control protocol type 1 specified in LTS with model checking method, and experimentally prove that it is possible to check for the deadlock, livelock and rechability of the states and actions on LTS. The implemented formal checker is able to verify whether properties expressed in modal logic are true in specifications using modal mu-calculus. We also propose a formal method on generation of conformance test cases using the concept of UIO sequences from verified protocol specification. The suggested tools are implemented by C++ language under Windows NT.

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Hydrologic Scenarios for Sustained Drought in Han River (한강수계 장기 가뭄 수문시나리오 개발)

  • Lee, Gwang-Man;Cha, Hyung-Sun;Lee, Seung-Yoon
    • Journal of Korea Water Resources Association
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    • v.41 no.6
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    • pp.629-641
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    • 2008
  • Many studies on sustained droughts have often been limited to the analysis of historic flow series. A major disadvantage in this approach can be described as the lack of long historic flow records needed to obtain a significant number of drought events for the analysis. To overcome this difficulty, one of the present study idea is to use synthetically generated hydrologic series. A methodology is presented to develop flow series based on the probabilistic analysis of the stochastic properties of the observed flows. The method can be utilized to generate a flow series of desired length so as to include many multiyear drought events within the process. In this paper, a concept of creating multiyear drought scenarios is introduced, and its development procedure is illustrated by a case study of the water supply system in Han River Basin. Also, it was found that the generated flow series can be reliably used to predict the long drought duration and sustained drought hydrologic scenarios within a given return period.

Comparison of Various Discharge Estimation Methods in Straight Compound Channels (복단면 직선수로의 유량예측방법 비교 연구)

  • Kim, Ji-Sung;Kim, Keuk-Soo;Kim, Won
    • Proceedings of the Korea Water Resources Association Conference
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    • 2011.05a
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    • pp.238-238
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    • 2011
  • 복단면 하도는 홍수소통을 위한 상부 하도와 생태계 서식처 강화와 유사이송능력 개선, 경제적인 유지유량의 확보 등을 도모하는 자연적인 저수로 하도로 구성된다. 그러므로 갈수기와 홍수기의 유량차가 큰 하천에서, 복단면 하도는 하천 공학, 환경 생태 관점에서 다양한 이점을 제공한다. 그러나 복단면 하도에서의 흐름저항, 조도계수, 통수능, 수위-유량관계, 횡방향 유속분포, 그리고 하상전단응력 분포는 단단면 하도와 상이하며, 중요한 차이점은 주수로부와 홍수터부 사이의 유속차로 인하여 발생하는 활발한 운동량 교환에 의해 추가적인 전단층이 생성되는 점이다. 주수로와 홍수터 사이에서 발생된 경계전단력(Apparent Shear Force, ASF)은 하천의 전반적인 통수능을 감소시켜 홍수의 하도내 저류효과를 증가시킬 수도 있다. 또한 주수로 및 홍수터가 분담할 수 있는 유량은 경계전단력에 민감하기 때문에, 홍수터에 수목 식재, 구조물 설치 등을 계획할 경우 정량적인 항력저항의 산정을 위하여 매우 중요하다. 현재까지 복단면에서 발생하는 경계전단응력을 추정하는 다양한 방법들이 개발되었으며, 각각의 방법으로 부터 경계전단력을 정량적으로 예측할 수 있다. 그러나 대부분의 방법이 실험에 근거한 경험적 방법이므로 각 식의 개발에 사용된 자료에만 적합할 수 있는 한계가 있으며, 균일한 수로의 기하학적 변수(전단면과 주수로의 하폭비, 홍수터와 주수로의 수심비, 홍수터와 주수로의 조도비, 주수로의 하폭대 수심비 등)에 의한 식으로 구성되어 수치모형에서 직접 활용하기에는 한계가 있다. 따라서 본 연구에서는 복단면 경계전단력 산정을 위하여 개발된 다양한 연구결과들을 비교 검토하고, 기존문헌 또는 웹상에서 가용한 수리실험 자료들을 이용하여 각 방법에서 계산된 유량과 실측 유량을 비교함으로써 각 방법이 지닌 한계를 분석하였다. 본 연구에서 검토된 5가지 방법은 Knight and Demetriou (1983)(이하 KD), Wormleaton and Merret (1990)(이하 WM), Cristodoulou (1992), Bousmar and Zech(1999) (이하 BZ) 그리고 Moreta and Martin-Vide (2010)(이하 MM)이다. BZ 방법을 제외하고 나머지 방법들은 전체 유량의 비교에서 5% 이내의 오차를 나타내었다. 그러나 나머지 4가지 방법 중 주수로부 유속의 비교에 있어서는 소규모 수로 실험자료만 이용한 KD 방법이 5% 이상의 오차를 나타내어 정확도가 떨어지는 것으로 나타났다. 따라서 비교적 단순한 형태의 Cristodoulou (1992) 방법이 적용하고자 하는 수로의 규모와 무관하게 복단면 유량예측에 적합할 것으로 판단된다.

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Two independent mechanisms mediate discrimination of IID textures varying in mean luminance and contrast (평균밝기와 대비성의 차원으로 구성된 결 공간에서 결 분리에 작용하는 두 가지 기제)

  • 남종호
    • Korean Journal of Cognitive Science
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    • v.10 no.3
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    • pp.39-49
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    • 1999
  • The space of IID([ndependently, Identically Distributed) textures was built with axes of mean luminance and contrast, and studied on what kind of mechanisms were required to mediate texture segregation in this space. The conjecture was tested that one of these mechanisms is sensitive to the differences between the means of textures to be discriminated, whereas the other is sensitive to the differences between variances. The probability of discrimination was measured for various pairs of textures in the lID space The data were well fit by a model in which discrimination depends on two mechanisms whose responses are combined by probability summation. The conjecture was rejected that two mechanisms respectively tuned to mean and variance of texture function in segregation. Discrimination within space is mediated by 2 independent channels however: the 2 independent channels are not exactly tuned to texture mean and variance. One m mechanism was primarily sensitive to texture mean, whereas the other was sensitive to b both texture mean and variance.

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Removal of Trihalomethane Using Activated Carbon (활성탄(活性炭)을 이용(利用)한 Trihalomethane의 제거(除去)에 관한 연구(研究))

  • Chung, Tai Hak;Chung, Jae Chul
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.3 no.1
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    • pp.73-79
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    • 1983
  • Activated carbon has been widely used in water and wastewater treatment for removal of trace organics. The objective of this study was to define adsorption characteristics of trihalomethane(THM) on granular activated carbon(GAC) surfaces by laboratory experiments. Synthetic samples were prepared by adding chloroform into distilled and deionized water. The experiments conducted were a batch run and isotherm studies with five different temperature-pH levels. Adsorption of THM on GAC at an equilibrium condition was well described by the Freundlich isotherm equation. Lower temperature favored the adsorption, but the effect of pH was negligible. Utilizing the results of a batch run and the isotherm results, three parameters, mass transfer coefficient, pore diffusion coefficient, and surface diffusion coefficient, were evaluated by comparing with simulation results of an adsorption model. The results also showed that the pore diffusion was much greater than the surface diffusion.

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Analysis of Abnormal Wave at the West Coast on 31 March 2007 (2007년 3월 31일 서해안에 발생한 이상파랑에 대한 원인 분석)

  • Eom, Hyun-Min;Seung, Young-Ho;Woo, Seung-Buhm;You, Sung-Hyup
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.24 no.3
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    • pp.217-227
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    • 2012
  • On 31 March 2007, the abnormal wave occurred along western coast of Korean including Yeonggwang. In this paper, this event is studied using available field measurement data for the event analysis and numerical model for reproducing the unknown waves. We found several 1-min interval tidal elevation and mean sea level pressure (MSLP) data along the western coast of Korea and analyzed it using wavelet technique. We computed the arrival time and the propagation direction of abnormal wave using wavelet results and performed the numerical simulation using 2 dimensional shallow water wave model. The sea level under the forcing of air pressure jump was obviously amplified by the Proudman resonant effect. The computed sea levels compared with observations are underestimated, but the order of arrival time at the tidal station showed good agreement.

Numerical Modeling of Ebb-Dominant Tidal Flow in the Mokpo Coastal Zone (목포해역 낙조류 우세현상의 수치모의)

  • Jung, Tae-Sung;Choi, Jong-Hwa
    • Journal of Korean Society of Coastal and Ocean Engineers
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    • v.22 no.5
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    • pp.333-343
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    • 2010
  • In Mokpo coastal zone, the characteristics showing ebb-dominant tidal flow was confirmed by analysis of observed tide and tidal currents, Physical factors occurring ebb-dominant flow were reviewed. Influence of critical depth for drying, bottom shear stress, coastal reclamation, tidal amplitude, nonlinear tide, and eddy viscosity on the change of ebb-dominant flow was investigated by applying a two-dimensional circulation model. The simulation results for a variety of conditions showed that eddy viscosity and critical depth for drying does little or no impact on the generation of asymmetric flow. Strong bottom friction stress makes ebb-dominant flow clearly. Change of tidal flat into land swells ebb- dominant flow, and change of tidal flat into sea disappears ebb-dominant flow. Nonlinear tides play a decisive role in the generation of asymmetrical tidal flow. Non-linear tides should be included in the open boundary conditions of hydrodynamic modeling in the Mokpo coastal zone.