• Title/Summary/Keyword: 색도제거

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Decolorization of Azo Dyeing Wastewater Using Underwater Dielectric Barrier Discharge Plasma (수중 유전체장벽방전 플라즈마를 이용한 아조 염색폐수 색도제거)

  • Jo, Jin Oh;Lee, Sang Baek;Mok, Young Sun
    • Applied Chemistry for Engineering
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    • v.24 no.5
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    • pp.544-550
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    • 2013
  • This work investigated the environmental application of an underwater dielectric barrier discharge plasma reactor consisting of a porous hydrophobic ceramic tube to the decolorization of an azo dyeing wastewater. The reactive species generated by the plasma are mostly short-lived, which also need to be transferred to the wastewater right after the formation. Moreover, the gas-liquid interfacial area should be as large as possible to increase the decolorization rate. The arrangement of the present wastewater treatment system capable of immediately dispersing the plasmatic gas as tiny bubbles makes it possible to effectively decolorize the dyeing wastewater alongside consuming less amount of electrical energy. The effect of discharge power, gas flow rate, dissolved anion and initial dye concentration on the decolorization was examined with dry air for the creation of plasma and amaranth as an azo dye. At a gas flow rate of $1.5Lmin^{-1}$, the good contact between the plasmatic gas and the wastewater was achieved, resulting in rapid decolorization. For an initial dye concentration of $40.2{\mu}molL^{-1}$ (volume : 0.8 L; discharge power : 3.37 W), it took about 25 min to attain a decolorization efficiency of above 99%. Besides, the decolorization rate increased with decreasing the initial dye concentration or increasing the discharge power. The presence of chlorine anion appeared to slightly enhance the decolorization rate, whereas the effect of dissolved nitrate anion was negligible.

Comparisons of Color Spaces for Shadow Elimination (그림자 제거를 위한 색상 공간의 비교)

  • Lee, Gwang-Gook;Uzair, Muhammad;Yoon, Ja-Young;Kim, Jae-Jun;Kim, Whoi-Yul
    • Journal of Korea Multimedia Society
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    • v.11 no.5
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    • pp.610-622
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    • 2008
  • Moving object segmentation is an essential technique for various video surveillance applications. The result of moving object segmentation often contains shadow regions caused by the color difference of shadow pixels. Hence, moving object segmentation is usually followed by a shadow elimination process to remove the false detection results. The common assumption adopted in previous works is that, under the illumination variation, the value of chromaticity components are preserved while the value of intensity component is changed. Hence, color transforms which separates luminance component and chromaticity component are usually utilized to remove shadow pixels. In this paper, various color spaces (YCbCr, HSI, normalized rgb, Yxy, Lab, c1c2c3) are examined to find the most appropriate color space for shadow elimination. So far, there have been some research efforts to compare the influence of various color spaces for shadow elimination. However, previous efforts are somewhat insufficient to compare the color distortions under illumination change in diverse color spaces, since they used a specific shadow elimination scheme or different thresholds for different color spaces. In this paper, to relieve the limitations of previous works, (1) the amount of gradients in shadow boundaries drawn to uniform colored regions are examined only for chromaticity components to compare the color distortion under illumination change and (2) the accuracy of background subtraction are analyzed via RoC curves to compare different color spaces without the problem of threshold level selection. Through experiments on real video sequences, YCbCr and normalized rgb color spaces showed good results for shadow elimination among various color spaces used for the experiments.

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Treatment of an Authentic Textile-dyeing Wastewater Utilizing a Fluidized Biofilter and Hybrid Recirculating System Composed of the Fluidized Biofilter and a UV/photocatalytic Reactor (실제 혼합염색폐수의 유동상 시스템을 활용한 미생물처리와 하이브리드 재순환시스템처리)

  • Lee, Eun Ju;Lim, Kwang-Hee
    • Korean Chemical Engineering Research
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    • v.53 no.1
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    • pp.71-77
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    • 2015
  • A fluidized biofilter was filled with Pseudomonas sp. and Bacillus cereus/thuringiensis-fixed waste-tire crumb media and was run to treat authentic textile-dyeing wastewater mixed with alkaline polyester-weight-reducing wastewater. As a result, its removal efficiency of $COD_{Cr}$ and color were 75~80% and 67%, respectively. In addition, upon constructing hybrid-recirculating system composed of the fluidized biofilter and a 450 W-UV/photocatalytic reactor, only fluidized biofilter was run bypassing UV/photocatalytic reactor at stage I. Subsequently, the hybrid system was continuously run at stage II-i, ii and iii. At stage II-i, the total removal efficiency of $COD_{Cr}$ was enhanced to be 80~85%, compared to 75% at stage I, owing to 20~30% removal efficiency of the UV/photocatalytic reactor. However, at stage II-i, the total removal efficiency of color was enhanced to be 65~70%, compared to 45~65% at stage I, even though the removal efficiency of the UV/photocatalytic reactor was tantamount to merely 0~5%. As far as the removal efficiency of fluidized biofilter of the hybrid-recirculating system is concerned, its removal efficiency of color was enhanced by the synergy effect of the hybrid-recirculating system unlike $COD_{Cr}$. Besides, despite of the increase of hybrid-recirculating system-recycle ratio, the deactivation of photo-catalytic activity was scarcely observed to eliminate the color while its irreversible deactivation was observed to eliminate $COD_{Cr}$.

Decolorization of Reactive Black 5 by Photocatalytic Oxidation (광측매반응에 의한 Reactive Black 5의 색도제거 연구)

  • Yang, Jeong-Mok;Song, Jin-Su;Park, Chul-Hwan;Kim, Sang-Yong
    • Clean Technology
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    • v.14 no.3
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    • pp.211-217
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    • 2008
  • We investigated the reduction of pollutants such as TOC (total organic carbon) and decolorization of Reactive Black 5 (RB5) by photocatalytic oxidation. The optimal values of major parameters for the reaction were obtained including the concentration of RB5, the amount of $TiO_2$ dosage and pH of solution. The values were 100 mg/L, 2 g/L and 4.9, respectively. As the concentration of oxygen increased, removal rate of pollutants increased. After $TiO_2$ was regenerated and used again by micro filtration (MF) ceramic membrane, the removal efficiency of color and removal rate of pollutants did not decrease significantly.

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Advanced Oxidation Process for the Treatment of Terephthalic Acid Wastewater using UV, H2O2 and O3 : Organic and Color Removal Studies (UV, H2O2, 오존을 이용한 고급산화공정에서의 테레프탈산 제조공정 폐수 처리 : 유기물 및 색도제거 연구)

  • Kwon, Tae-Ouk;Park, Bo-Bae;Moon, Il-Shik
    • Korean Chemical Engineering Research
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    • v.45 no.6
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    • pp.648-655
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    • 2007
  • UV/H_2O_2$, $O_3$, $O_3/H_2O_2$, $UV/H_2O_2/O_3$ processes were tested for the removal of COD and color from terephthalic acid wastewater. COD removal efficiencies were 10, 48, 56, 63% in the $UV/H_2O_2$, $O_3$, $O_3/H_2O_2$, $UV/H_2O_2/O_3$ process respectively. Color removal efficiency of $UV/H_2O_2$ process was 80% and $O_3$, $O_3/H_2O_2$, $UV/H_2O_2/O_3$ processes were almost more than 99%. Terephthalic acid, isophthalic acid and benzoic acid were completely destructed in terephthalic wastewater within 120 min by $UV/H_2O_2/O_3$ process and shows high COD and color removal efficiencies. The optimum concentration of $H_2O_2$ dosage was found to be 0.5 M, 25 mM and 5 mM for $UV/H_2O_2$, $O_3/H_2O_2$ and $UV/H_2O_2/O_3$ processes respectively, Organic destruction efficiency was enhanced and also reducing the consumption of $H_2O_2$ dosage by combining UV, $H_2O_2$ and $O_3$ process.

Decolorization of Landfill Leachate by White-Rot Fungi (백색부후균에 의한 매립지 침출수의 색도 제거)

  • 김현영;송홍규
    • Korean Journal of Microbiology
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    • v.33 no.1
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    • pp.43-48
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    • 1997
  • 여러가지 난분해성 물질에 대한 생분해능을 지닌 백색부후균에 의한 매립지 침출수의 탈색을 조사하였다. 국내에서 분리한 Coriolus versicolor KR-11W와 Irpex lacteus KR-39W가 이제까지 주로 연구되어 온 Phanerochaete chrysosporium보다 높은 탈색능을 나타내었는데 I. lacteus KR-39W는 산소공급시 10%의 침출수가 함유된 YMG 배지의 진탕배양에서 85%의 색도제거율을 나타내었으며 최소배지에서도 80%의 탈색율을 보였다. P. chrysosporium에 의한 리그닌 분해능 및 분해효소 생성 보고들과 달리 진탕배양이 정치배양보다 탈색능이 높았으며 산소공급은 색도제거에 증가효과가 있었다. 균체 접종량(10-30%)과 온도(25,37.deg. C)는 탈색에 큰 차이를 보이지 않았으나 탄소원과 질소원의 농도는 상당한 영향을 나타내었다. 리그닌 분해효소군의 여러 가지 inducer와 cofactor를 C. versicolor KR-11W 배양에 첨가한 결과 많은 경우 균접종 대조군보다 2배 이상의 탈색율과 lignin peroxidase 활성의 증가를 보였으며 FeS $O_{5}$ 첨가시에는 최대 2.9배의 증가를 나타내었다. 탈색에 관여하는 효소군은 접종물에 이미 어느 정도 존재할 수 있으며 배지 및 배양조건에 따라 그 생성이 변화할 수 있으므로 이런 조건들을 잘 맞출 경우 보다 높은 탈색능이 기대된다.

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분말과 고정화 $TiO_2$를 이용한 Rhodamin B의 색도 제거 비교

  • 박영식
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2003.05a
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    • pp.267-270
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    • 2003
  • 수용성 양이온 안료인 RhB를 대상으로 분말 $TiO_2$와 고정화 $TiO_2$를 이용하여 색도제거실험을 수행한 결과 다음과 같은 결론을 얻었다. 1) 분말 $TiO_2$의 최적 투입량은 0.2 g/L였으며, 대부분 광촉매 반응에 의하여 제거되었다. 고정화 $TiO_2$의 최적 투입량은 210.7 g/L이었고, 광촉매와 흡착에 의해 제거되었다. Langmuir - Hinshelwood 식으로 표현되지 못하였다. 2) 고정화 $TiO_2$를 이용하여 Rhodamine B를 제거할 경우 광촉매 분리 문제는 해결할 수 있으며, 광 투과율을 증가시킬 수 있으나 같은 제거율을 얻기 위해 투입량이 분말에 비해 매우 높은 것이 문제점으로 나타났다.

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Removal of Color from a Biological Piggery Wastewater Treatment Effluent by Chemical Coagulation (화학적 응집을 이용한 생물학적 돈분폐수 처리수의 색도제거)

  • Park, Noh-Back;Seo, Tae-Kyeong;Choi, Woo-Young;Jun, Hang-Bae
    • Journal of Korean Society of Environmental Engineers
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    • v.30 no.10
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    • pp.1047-1053
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    • 2008
  • This study was to evaluate the optimum conditions for chemical coagulation to remove color from the effluent of a piggery wastewater treatment process. The DOC concentration in the effluent was about 227.3 mg/L, color was 2,430 CU, turbidity was 22.1 NTU, and UV$_{254}$-absorbance was 3.7 cm$^{-1}$. The fractions of hydrophobic, transphilic, and hydrophilic substance of the effluent was about 55.3%, 17.4%, 27.3% respectively. Also, molecular weight cut-off(MWCO) of below 0.5 K, 0.5 K to 1 K, 1 K to 10 K, 10 K to 30 K, and over 30 K were 74.2%, 7.3%, 5.5%, 7.1%, and 5.9% respectively. SCD(streaming current Detector) was used to find out the optimum pH values and coagulant dosages. The optimum dosages and pH of Al$^{3+}$ were 5.84 mM and 5.3, while those of Fe$^{3+}$ were 9.25 mM and 5.0, respectively. At optimum conditions of coagulation, color removal efficiencies for aluminium sulfate and ferric chloride were as high as 91.9 and 98.7%, respectively. Chemical coagulation showed good performance to remove color from on biologically treated piggery wastewater.

Shadow Removal Based on Chromaticity and Entropy for Efficient Moving Object Tracking (효과적인 이동물체 추적을 위한 색도 영상과 엔트로피 기반의 그림자 제거)

  • Park, Ki-Hong
    • Journal of Advanced Navigation Technology
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    • v.18 no.4
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    • pp.387-392
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    • 2014
  • Recently, various research for intelligent video surveillance system have been proposed, but the existing monitoring systems are inefficient because all of situational awareness is judged by the human. In this paper, shadow removal based moving object tracking method is proposed using the chromaticity and entropy image. The background subtraction model, effective in the context awareness environment, has been applied for moving object detection. After detecting the region of moving object, the shadow candidate region has been estimated and removed by RGB based chromaticity and minimum cross entropy images. For the validity of the proposed method, the highway video is used to experiment. Some experiments are conducted so as to verify the proposed method, and as a result, shadow removal and moving object tracking are well performed.

Removal of COD and Color from Anaerobic Digestion Effluent of Livestock Wastewater by Advanced Oxidation Using Microbubbled Ozone (마이크로버블 오존 고도산화를 이용한 축산폐수 혐기소화 배출수의 COD와 색도의 제거)

  • Lee, Inkyu;Lee, Eunyoung;Lee, Hyejung;Lee, Kisay
    • Applied Chemistry for Engineering
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    • v.22 no.6
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    • pp.617-622
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    • 2011
  • Ozone-based advanced oxidation was applied for the treatment of anaerobic digestion effluent of livestock wastewater. Initial COD and color value were 930 mg/L and 0.04, respectively, and the 1/10-diluted wastewater was used for the study. The treatment characteristics were compared between the conventionally generated ozone ($105{\mu}m$) and microbubbled ozone ($13{\mu}m$). The use of microbubbled ozone improved the removal of chemical oxygen demand (COD) and color by 85% and 26%, respectively, compared with the conventionally bubbled ozone. The application of microbubbled $O_3/UV$, $O_3/H_2O_2$, $O_3/UV/H_2O_2$ combinations resulted in 5~10% higher color removal than ozone alone, which implies that the contribution of UV or $H_2O_2$ is not significant in color removal. On the other hand, COD removal could be increased two folds compared with ozone alone through $O_3/UV/H_2O_2$ combination. The contribution of $H_2O_2$ was bigger than UV for COD removal with microbubbled ozone. Due to the enhancement of dissolved ozone and radical activity, the microbubbling enabled us to additional COD removal even after stopping ozone supply in the presence of UV or $H_2O_2$.