• Resources Recycling
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• v.12 no.6
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• pp.38-46
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• 2003

In this study, nano-sized Ni-ferrite and $Fe_2$$O_3$＋NiO powder was fabricated by spray pyrolysis process in the condition of 1kg/$\textrm{cm}^2$ air pressure using the Fe-Ni complex waste acid solution generated during the manufacturing process of shadow mask. The average particle size of the produced powder was below 100 nm. The effects of the reaction temperature, the concentration of raw material solution and the nozzle tip size on the properties of powder were studied. As the reaction temperature increased from $800 ^{\circ}C$ to $1100^{\circ}C$, the average particle size of the powder increased from 40 nm to 100 nm, the structure of the powder gradually became solid, yet the distribution of the particle size appeared more irregular. Along with the increase of the reaction temperature, the fraction of the Ni-ferrite phase were also on the rise, and the surface area of the powder was greatly reduced. As the concentration of Fe in solution increased from 20g/l to 200g/l, the average particle size of the powder gradually increased from 30 nm to 60 nm, while the distribution of the particle size appeared more irregular. Along with the increase of the concentration of solution, tie fraction of the Ni-ferrite phase was on the rise, and the surface area of the powder was greatly reduced. Along with the increase of the nozzle tip size, the distribution of the particle size appeared more irregular, yet the average particle size of the powder showed no significant change. As the nozzle tip size increased from 1 mm to 2 mm, the fraction of the Ni-ferrite phase showed no significant change, while the surface area of the powder slightly reduced. As the nozzle tip size increased to 3 mm and 5 mm, the fraction of the Ni-ferrite phase gradually reduced, and the surface area of the powder slightly increased.

• Journal of Institute of Control, Robotics and Systems
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• v.14 no.4
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• pp.348-352
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• 2008

Deformation of the shadow mask is one of the problems encountered during the deposition of organic materials for manufacturing large size organic light emitting diode (OLED). The larger the glass substrate, the larger the shadow mask becomes. As the size of the shadow mask increases, its deformation becomes more severe, thereby making it difficult to deposit organic materials in a precise pattern on a substrate. In this paper, a new method for reducing drooping of the shadow mask for large size OLED vapor depositions is proposed. The proposed shadow mask with cross stripe wires has higher stiffness than the pure shadow mask, which results in reducing drooping of the shadow mask. A commercial FEM program, ANSYS, is used for the evaluation of the proposed shadow mask. The analysis showed that the shadow mask with cross stripe wires have an effect on reducing drooping about 18.6% or more.

• Clean Technology
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• v.13 no.4
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• pp.274-280
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• 2007

A liquid-liquid solvent extraction process was developed in this study to recover Fe and Ni from heavily concentrated aqueous ferric chloride solution, in an effort to substitute the conventional iron reduction method. Solvent composition and extraction conditions were first developed from the laboratory experiments, and the pilot system was designed and built for commercialization. Stage numbers for extraction and stripping were determined from pilot plant runs, and other operation data were obtained for mass production.

• Transactions of the Korean Society for Noise and Vibration Engineering
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• v.15 no.5 s.98
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• pp.595-603
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• 2005

In this work, the multiple dynamic absorber( MDA ) is introduced to reduce several vibration modes of shadow mask simultaneously and its design method is developed from the theory of the simple dynamic absorber. When designing the dynamic absorber, there are three significant design parameters such as mass, damping ratio and tuning frequency. Therefore the sensitivity analysis for those parameters has been executed in order to find out the design criteria of multiple dynamic absorber using the finite element model of shadow mask. The multiple dynamic absorber(MDA) designed by the proposed method is tested theoretically and experimentally to estimate the efficiency of vibration reduction. From the results, it is verified that the method is feasible to apply the system having the multiple nitration modes and more efficient than the thin wire-type damper used commercially to reduce the vibration of shadow mask.

• Applied Chemistry for Engineering
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• v.7 no.4
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• pp.614-622
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• 1996

Efficient removal of nickel from the ferric chloride etching solution has been studied. At first, $Fe^{3+}$ was reduced to $Fe^{2+}$ by the electrolytic iron flake or the waste shadow mask iron plate. And then, $Ni^{2+}$ was removed from the solution by electrolytic iron powder. Under the optimum conditions the reduced rates of nickel were 99 % and 98%, respectively at the initial $Ni^{2+}$ concentrations of 1.0% and 0.1%. Sludge formed during reduction of $Fe^{3+}$ in the solution were analyzed by XRD and SEM.

• Clean Technology
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• v.13 no.3
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• pp.188-194
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• 2007

In the present study, we developed a methodology to minimize a waste solution produced in the etching process. The condition for the optimization of the GRS process was studied on the basis of laboratory experiment and field test as well as pilot test. Through the study, we analyse the relation of the main process variables and the yield of the GRS process. The application of the new operation condition and the reactor internal modification results in 10% yield improvement in the GRS process and accordingly decreases a wasted solution.

• Journal of the Korean Magnetics Society
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• v.9 no.5
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• pp.245-250
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• 1999

The effect of substrate and oxidization time on $substrate /Py/Al_2O_3/Co\;(Py=Ni_{81}Fe_{19})$ tunnel junction was studied. Samples were prepared without breaking vacuum by changing shadow masks in-situ. The resistance of tunnel junctions increased, but measured MR decreased with oxidization time. Negative MR observed for samples of tunnel resistivity lower than 0.17 M$\Omega$ $({\mu}m)^2$. MR resistivity decreased with the change of substrates in the order of thermally oxidized Si(111), Si(100), Coring Glass 2948, Corning Glass 7059. Sign change and the variation of MR was explained with non uniform current effect.

• Journal of Powder Materials
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• v.10 no.4
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• pp.262-269
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• 2003

Nano-sized Ni-ferrite powder was fabricated by spray pyrolysis process using the waste solution resulting from shadow mask processing. The average particle size of the powder was below 100 nm. The effects of the concentration of raw material solution, the nozzle tip size and air pressure on the properties of powder were studied. As the concentration increased, the average particle size of the powder gradually increased and its specific surface area decreased, but size distribution was much wider and the fraction of the Ni-ferrite phase greatly increased as the concentration increasing. As the nozzle tip size increased from 1 mm to 2 mm, the average particle size of the powder decreased. In case of 3 mm nozzle tip size, the average particle size of the powder increased slightly. On the other hand, in case of 5 mm nozzle tip size, average particle size of the powder decreased. Size distribution of the powder was unhomogeneous, and the fraction of the Ni-ferrite phase decreased as the nozzle tip size increasing. As air pressure increased up to 1 kg/$cm^2$, the average particle size of the powder decreased slightly, on the other hand, the fraction of the Ni-ferrite phase was almost constant. In case of 3kg/$cm^2$ air pressure, average particle size of the powder and the fraction of the Ni-ferrite phase remarkably decreased, but size distribution was narrow.

• Journal of the Korean Society for Precision Engineering
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• v.17 no.8
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• pp.100-105
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• 2000

In this study the structural design concepts of main parameters of a Cathode Ray Tube(CRT) such as frame spring and shadow mask were proposed to guarantee a failure-proof CRT under mechanical shock. With computer simulation and experiments some information on the structural design concept was obtained as followings: the frame and the shadow mask of the CRT needed designing to increase strength so double-beads shape at the corner of frame was newly designed for it, And the spring which interconnected frame with panel glass was required to deform elastically for the purpose of absorbing the shock energy in the direction of drop. A new type of spring 'twisting spring' was designed to achieve the flexibility in that direction. By using it the deformation energy of a shadow mask could reduced to some degree. To accomplish those simulations commerical codes Pam-Crash and I-DEAS were used and a typical CRT was analyzed as an example to prove the usefulness of this study.

• Resources Recycling
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• v.12 no.4
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• pp.20-29
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• 2003

In order to efficiently recycle the waste solution resulting from shadow mask processing, nano-sized Ni-ferrite powder was fab-ricated through spray pyrolysis process. The average particle size of the powder was below 100nm. In this study, the effects of the reaction temperature. the concentration of raw material solution and the injection speed of solution on the properties of powder were respectively investigated. As the reaction temperature increased from $800^{\circ}C$ to $1100^{\circ}C$, average particle size of the powder significantly Increased and power structure became more solid, whereat its specific surface area was greatly reduced. Formation rate and crystallization of($NiFe_2$$O_4$) phale increased along with the temperature rise. As the concentrations of iron and nickel components in wastere solution increased, particle size of the powder became larger, particle size distribution became more irregular, and specific surface area was reduced. Formation rate and crystallization of $NiFe_2$$O_4$ phase increased significantly along with the increase of the concentration of solution. As the inlet speed of solution increased, particle size of the powder became larger, particle size distribution became wider, specific surface area was reduced and powder structure became less solid. As the inlet speed of solution decreased, formation rate and crystallization of $NiFe_2$$O_4$ phase significantly increased.