• Title/Summary/Keyword: 상호작용계수

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Thermodynamic Study of Poly(dimethylsiloxane)-Solvents Systems Using Inverse Gas Chromatography (Inverse Gas Chromatography를 이용한 Poly(dimethylsiloxane)-Solvent계의 열역학적 연구)

  • Cho, Joung-Mo;Kang, Choon-Hyoung
    • Applied Chemistry for Engineering
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    • v.10 no.5
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    • pp.718-725
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    • 1999
  • In order to investigate the interaction characteristics of poly(dimethylsiloxane) (PDMS) with various solvents such as water, ethanol, and iso-propanol, Inverse Gas Chromatography(IGC) at finite concentration, which is a very fast, accurate, and thus promising technique in thermodynamic study of polymer systems, is employed. By measuring the specific retention volumes of the probes, the interaction parameters are calculated by means of the Flory-Huggins equation. From the results, the interaction parameters of the probes are, as expected due to the hydrophobicity of the polymer, found to be of large positive values (2$2.0{\times}10^{-3}mol/g$. For the linear PDMS, interpretation of the space distribution of molecules is performed by the Kirkwood-Buff-Zimm(KBZ) integrals, which give intuitive information about physical properties. From the KBZ integrals, water does not show the tendency of preferential solvation with the PDMS but formed self-cluster. The larger solvent molecules show a stronger tendency to distribute more randomly in the mixture.

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A Study on Secondary Lining Design of Tunnels Using Ground-Lining Interaction Model (지반-라이닝 상호작용 모델을 이용한 터널 2차라이닝 설계에 관한 연구)

  • Chang, Seok-Bue;Huh, Do-Hak;Moon, Hyun-Koo
    • Journal of Korean Tunnelling and Underground Space Association
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    • v.8 no.4
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    • pp.365-375
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    • 2006
  • The structural analysis for the secondary lining of tunnels is generally performed by a frame analysis model. This model requires a ground loosening load estimated by some empirical methods, but the load is likely to be subjective and too large. The ground load acting on the secondary lining is due to the loss of the supporting function of the first support members such as shotcrete and rockbolts. Therefore, the equilibrium condition of the ground and the first support members should be considered to estimate the ground load acting on the secondary lining. Ground-lining interaction model, shortly GLI model, is developed on the basis of the concept that the secondary lining supports the ground deformation triggered by the loss of the support capacity of the first support members. Accordingly, the GLI model can take into account the ground load reflecting effectively not only the complex ground conditions but the installed conditions of the first support members. The load acting on the secondary lining besides the ground load includes the groundwater pressure and earthquake load. For the structural reinforcement of the secondary lining based on the ultimate strength design method, the factored load and various load combination should be considered. Since the GLI model has difficulty in dealing with the factored load, introduced in this study is the superposition principle in which the section moment and force of the secondary lining estimated for individual loads are multiplied by the load factors. Finally, the design method of the secondary lining using the GLI model is applied to the case of a shallow subway tunnel.

The Effect of Teachers' Teaching Efficacy and Happiness on Teacher-Infant Interaction (교사의 교수 효능감과 행복감이 교사-유아 상호작용에 미치는 영향)

  • Jeong Yeong Mi
    • The Journal of the Convergence on Culture Technology
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    • v.9 no.4
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    • pp.223-228
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    • 2023
  • This study examines the relationship between teacher-perceived teaching efficacy and happiness and teacher-infant interaction, and analyzes the effect of teaching efficacy and happiness on teacher-infant interaction. The purpose was to reveal that it was an important variable in the quality of action. Frequency analysis and descriptive statistics analysis were conducted for the Korean Children's Panel 7th year (2014) data, and Pearson's moment-moment correlation coefficient was calculated for correlation analysis between variables. Multiple regression analysis was conducted to examine the influence of teachers' teaching efficacy and happiness on teacher-infant and infant-infant interactions. The research results were as follows. First, teachers' teaching efficacy, teacher happiness, teacher-infant, and infant-infant interactions were all found to have significant positive correlations. Second, teachers' teaching efficacy was found to have a significant effect on teacher-infant and infant-infant interactions, and the influence increased when teacher's happiness was added. Therefore, we need to come up with a plan to increase teachers' teaching efficacy and teacher happiness at the same time so that the quality of teacher-infant and infant-infant interactions can be meaningfully improved.

Study on the Seismic response Spectra of a Structure Built on the Deep Soil Layers Classified in UBC-97 (UBC-97에 분류된 깊은 지반위에 세워진 구조물의 지진응답 스펙트럽에 관한 연구)

  • 김용석
    • Journal of the Earthquake Engineering Society of Korea
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    • v.4 no.1
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    • pp.63-76
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    • 2000
  • 구조물-지반 상호작용에서 알려진 것처럼 구조물 지진응답은 구조물하부 지반조거에 따라 영향을 받는데 UBC-97을 포함한 여러내진설계규준에서 지반사태 영향을 반영하고 있다 이 연구에서는 기초크기 기초밑 지반깊이, 입력지진 작용점 및 기초 근입깊이 등의 영향을 살펴보고 깊은 지반 위에 세워진 구조물의 평균응답스펙트럼을 UBC-97 탄성응답스펙트럼과 비교하기 위해 구조물-지반 상호작용을 고려한 지진해석을 가상 3차원 유한요소법과 부구조물법을 이용하여 1952년 Taft와 1940년 El Centro 지진기록을 주파수영역에서 수행하였다 연구결과에 의하면 기초크기는 구조물 응답에 별 영향이 없고 기초저면 지반깊이는 구조물체계의 고유주기와 최대가속도를 변경시켰다 또 입력지진의 합리적 작용점은 기초저면이라는 것이 확인되었으며 깊은 지반위에 놓인 기초의 근입은 저주기영역에서 구조물 응답을 상당히 줄어들게 하였다 한편 30m 깊은 지반위에 세워진 구조물의 평균가속도와 UBC-97 가속도를 비교한 결과 UBC-97 탄성응답스펙트럼에 의한 구조물 내진설계가 안전하지 못할 수도 있으므로 UBC-97 지진계수의 할증이 필요하다.

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Experimental Study of Low-Frictional Behavior for Sliding Slab Track (슬라이딩 궤도의 저마찰 거동에 대한 실험적 연구)

  • Kim, Tae-Gu;Jung, Dong-Ki;Lee, Kyoung-Chan
    • Journal of the Korean Society for Railway
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    • v.20 no.2
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    • pp.241-247
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    • 2017
  • Railway bridges with continuously welded rail have a limitation of span length due to track-bridge interaction. In order to overcome this, a sliding slab track system has been developed that comprises with a low-frictional sliding layer between the bridge deck and the track slab to isolate the longitudinal behavior between the bridge and the track. In this study, a real scale track system is prepared to experimentally evaluate the longitudinal frictional behavior. Applied loading rates were 0.2, 1.0, 5.0 and 10mm/min; vertical mass on the track are track slab only, 5,000 and 10,000kg added mass, respectively. Test results showed that the resulting frictional coefficients varied from 0.22 to 0.33. In addition, 10,000 cycle loadings were applied to simulate repetitive sliding to represent 30 years of service life. The frictional coefficient increase was measured and found to be 7% of that of the initial loading stage, which means that the sliding layer is adequate to provide low-frictional behavior for the sliding slab track system. Effects of changes of the frictional coefficient of the sliding layer were analyzed by rail-structure interaction analysis.

Harmonic Excitation of Shear Building with Force-Controlled Shaking Table (힘-제어 진동대를 이용한 전단건물의 조화진동)

  • Lee, Sang Ho
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.16 no.1
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    • pp.853-859
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    • 2015
  • 1-DOF shear building was designed, built and tested to investigate the interactions between the shear building and the shaking table excited harmonically by the electro-magnetic forces. In the experiments horizontal accelerations of the shaking table and the shear building were measured. To understand the experimental results experimental setting was modeled as an unconstrained 2-DOF system under the hormonic forces. The responses of the shear building and the shaking table of the unconstrained 2-DOF system were found with the equations of motions. The magnification factors of the table and the shear building with respect to the amplitude of the harmonic forces and the transmission of the shear building with respect to the table excitations were found and compared with the experimental results.

Analysis of Unstable Vibration Modes due to KTX Brake Disc/Pad Interaction (KTX 제동디스크-패드의 상호작용에 의한 불안정 진동모드 해석)

  • Goo, Byeong Choon
    • Journal of the Korean Society for Railway
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    • v.16 no.4
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    • pp.253-261
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    • 2013
  • According to the measured results of KTX brake squeal noise in this study, high level brake noise occurred in a wide frequency range, 100~18,000Hz. To identify the sources of the brake squeal noise, unstable vibration modes due to brake disc/pad interaction were analyzed under various conditions by the finite element method. Complex eigenvalues for a brake unit with a disc and four pads were obtained. It was found that the real parts of the complex eigenvalues, that is, unstable vibration modes, were closely related to friction coefficients, pressure on the brake cylinders, elastic moduli of the components, and other conditions.

Analysis of Atmosphere-Ocean Interactions over South China Sea and its Relationship with Northeast Asian Precipitation Variability during Summer (남중국해의 여름철 대기-해양 상호작용과 동아시아 강수량의 상관성 분석)

  • Jang, Hye-Yeong;Yeh, Sang-Wook
    • Atmosphere
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    • v.23 no.3
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    • pp.283-291
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    • 2013
  • This study investigates the changes in the atmosphere-ocean interactions over the South China Sea (SCS) by analyzing their variables in the period of 1979~2011 during the boreal summer (June-July-August). It is found that a simultaneous correlation coefficient between sea surface temperature (SST) and precipitation over SCS during summer is significantly changed before and after the late-1990s. That is, the variation of precipitation over SCS is negatively (positively) correlated with the SST variations before (after) the late-1990s. Our further correlation analysis indicates that the atmospheric forcing of the SST is dominant before the late-1990s accompanying with wind-evaporation feedback and cloud-radiation feedback. After the late-1990s, in contrast, the SST forcing of the atmosphere through the latent heat flux from the ocean to the atmosphere is dominant. It is found that the change in the relationship of atmosphere-ocean interactions over SCS are associated with the changes in the relationship with Northeast Asian summer precipitation. In particular, a simultaneous correlation coefficient between the precipitation over SCS and Northeast Asia becomes stronger during after the late-1990s than before the late-1990s. We argue that the increase of the SST forcing of the atmosphere over SCS may lead a direct relationship of precipitation variations between SCS and Northeast Asia after the late-1990s.

The Mediating Effect of Emotional Leadership of Daycare Center Directors on the Relation between Childcare Teachers' Emotional Intelligence and Teacher-Infant Interaction (보육교사의 정서지능이 교사-영유아 상호작용에 미치는 영향에서 원장 감성리더십의 매개효과)

  • Lee, Shin-Young
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.21 no.12
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    • pp.369-376
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    • 2020
  • The purpose of this study is to identify the relationships among childcare teachers' emotional intelligence, daycare center directors' emotional leadership, and teacher-infant interactions. Also, this study examines whether a daycare center director's emotional leadership would mediate the correlation between a childcare teacher's emotional intelligence and teacher-infant interactions. A questionnaire was given to 293 childcare teachers. Using SPSS version 21.0, the data were analyzed for Pearson's correlation, hierarchical regression analysis, the Sobel-test, and the meditation effect proposed by Baron and Kenny. The findings are as follows. First, there was a positive correlation between a childcare teacher's emotional intelligence, the director's emotional leadership, and teacher-infant interactions. Second, the influence on teacher-infant interactions from directors' emotional leadership was relatively greater than childcare teachers' emotional intelligence. Finally, the emotional leadership of daycare center directors partially mediated the relationship between childcare teachers' emotional intelligence and teacher-infant interactions. This study provides significant empirical data for improving childcare.

Analysis of Long-Term Performance of Geogrids by Considering Interaction among Reduction Factors (감소계수 상호영향을 고려한 지오그리드의 장기성능 해석)

  • Jeon, Han-Yong;Kim, Yuan-Chun;Jang, Yeon-Soo
    • Journal of the Korean Geotechnical Society
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    • v.28 no.7
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    • pp.55-65
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    • 2012
  • Total reduction factor that is used when calculating allowable tensile strength of geogrids is made by multiplying the installation damage reduction factor ($RF_{ID}$), chemical degradation reduction factor ($RF_D$), and creep reduction factor ($RF_{CR}$) etc. In case of a model estimating allowable tensile strength considering reduction factor over the short-term tensile strength of geogrids, it has a limit of not considering interaction force between reduction factors. Junction strength comes to be reduced by installation damages or chemical degradation in the same way as tensile strength. Single junction test method cannot properly test damaged samples and shows large deviations as it does not consider scale effect. Besides, regarding calculating shear strength, no reasonable study on reduction factors was conducted yet. Therefore, in this study, reduction factors that may affect the long-term performance of geogrids were revaluated considering various conditions and accurate long-term allowable tensile strength was calculated considering interrelation between reduction factors. Creep results after installation damage and chemical resistance test showed lower value than calculated value according to GRI GG-4. After the installation damage test and the chemical resistance test, the reduction factor of junction strength was less than that of tensile strength. Shear strength before and after installation damage showed no change or increase.