• Title/Summary/Keyword: 상압소결

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The effect of microstructure of electrical discharge machinable silicon nitride on wear resistance (방전가공용 질화규소의 미세조직이 내마모에 미치는 영향)

  • 이수완;김성호;이명호
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.8 no.1
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    • pp.111-116
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    • 1998
  • Silicon nitride is hard and tough ceramic material. Hereby, mechanical machinability is very poor. It has also high electrical resistance. Silicon nitride of extremely high electrical resistivity becomes conductive ceramic composite by adding 30 wt% TiN. Ceramics with high electrical conductivity can be electrical discharge machined. Using by the Electrical Discharge Machining (EDM) technique. $Si_3N_4-TiN$ ceramic composite with high electrical conductivity is utilized to make metal working tool. These tool materials have severe wear problem as well as oxidation. Post HIP processing after sintering $Si_3N_4-TiN$ ceramic composites was performed. The tribological property of $Si_3N_4-TiN$ composite as a function of content of TiN was investigated in air, at room temperature. The hardness, fracture toughness, and flexural strength were compared with the wear volume. SEM observation of wear tracks can make an explanation of wear mode of $Si_3N_4-TiN$ composite.

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Preparation and characterization of nanoporous monolith with high thermal insulation performance (나노 기공성 단열 실리카 모노리스 제조 및 특성 연구)

  • Choi, Hyun-Muk;Kim, Seong-Woo
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.1
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    • pp.83-91
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    • 2014
  • In this study, we synthesized two different silica monoliths by using sol-gel, solvent exchange, surface modification, ambient pressure drying processes, and surfactant-based templating technique followed by calcination process. All of the prepared two silica monoliths showed crack-free appearance with fairly good transparency, and furthermore were confirmed to have extremely high porosity, specific surface area, and mean pore size below 30 nm. The silica aerogel sample exhibited finer and more homogeneous nano-sized pore structure due to spring back effect caused by surface modification, which resulted in better thermal insulation performance. Based on measured thermal conductivities and theoretical relationship, multi-layered glass window system in which silica monolith prepared in this study was inserted as a middle layer was revealed to have superior thermal insulation performance compared to conventional air-inserted glass window system.

Biocompatibility of porous hydroxyapatite ceramics prepared from bovine bones (소 뼈로부터 제조한 다공형 하이드록시아파타이트 세라믹스의 생체친화 특성)

  • Lee, Jong-Kook;Ko, Young-Hwa;Lee, Nan-Hee
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.22 no.3
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    • pp.139-146
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    • 2012
  • Natural hydroxyapatite powder was obtained from the calcination of bovine bones and its porous compacts were fabricated by pressureless sintering at 1100 and $1200^{\circ}C$ for 1h. To evaluate and compare their biocompatibility with porosity, we investigated the support of osteoblast cells growth and cytotoxicity using the MG-63 cell line model in vitro. Sintered hydroxyapatite ceramics have a porous microstructure with a relative density of 65 % at $1100^{\circ}C$ and 82 % at $1200^{\circ}C$. Cells adherence to the surface of hydroxyapatite ceramics was observed in a day after the cell culture, and the spreading of cytoplasm around the nucleus was shown after 3 day cell culture. Most of cells were extended to the surface of hydroxyapatite through the wide area. Cell viability was nearly the same till 3 days culturing. But the rate of cell growth is higher in the specimen sintered at $1100^{\circ}C$ than that of $1200^{\circ}C$. It indicates that the porosity is an important factor to enhance the cell viability in the porous hydroxyapatite ceramics derived from bovine bones.

Dust Removal Efficiency and Operation Characteristics of Metal Filters for Coal Gasification Fines and Standard Dust Sample (금속필터를 사용한 석탄가스화 분진 및 표준 분진의 집진 효율과 운전특성)

  • Yun, Yongseung;Chung, Seok Woo;Lee, Seung Jong
    • Korean Chemical Engineering Research
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    • v.57 no.4
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    • pp.461-468
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    • 2019
  • Demand for improving dust removal efficiency in coal power plants and the dust removal requirement to the level of capturing fine particulate matter and ultrafine particles have been increasing. While bag filter and electrostatic precipitator (ESP) are typically used for dust removal in the processes operating at atmospheric pressure, metal filters or ceramic filters are employed for dust which is produced at high temperature/pressure system as in coal gasification. For dust removal at the high temperature/pressure conditions, two metal filters of five compressed/sintered layers were manufactured and applied to analyze the dust removal characteristics. Manufactured metal filters exhibited more than 99% dust removal efficiency on coal gasification fine particulates in mass basis. To evaluate the fine particulate removal efficiency of less than $2.5{\mu}m$, JIS standard fine sample was used and confirmed the removal efficiencies of 97% and 70~82% on the fine particulates of $1{\sim}2.5{\mu}m$ size range. For the size range of less than $1{\mu}m$, dust removal efficiency of manufactured metal filters significantly degraded with smaller particle size. Improving methods are proposed to overcome the limitations in applying to fine dust of less than $1{\mu}m$.