• Title/Summary/Keyword: 상수학

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Preparation of Nb doped SrTiO$_3$ Film by Pulsed Laser Deposition and Optimum Processing Conditions (Plused Laser Depositon을 이용한 Nb doped SrTiO$_3$ 박막의 제작과 최적 조건)

  • ;Seishiro Ohya
    • Journal of the Korean Ceramic Society
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    • v.36 no.2
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    • pp.116-121
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    • 1999
  • 0.5 wt%Nb-doped SrTiO3(Nb: STO) thin film was prepared on MgO(100) single crystal substrates by Pulsed Laser Deposition (PLD). The Crystallinity and the orientation of Nb:STO thin films were characterized by XRD with changing the thin film processing condition-oxygen partial pressure, substrate temperature, deposition time and the distance between target and substrate. The orientation of Nb:STO thin film showed (100), (110) and (111) orientations at the substrate temperature of $700^{\circ}C$. The lattice parameter of Nb:STO decreased with increasing Po2 and showed 0.3905 nm at Po2=100 Pa, which was similar to that of the bulk. The thickness of Nb:STO thin film increased with increasing the deposition time and with decreasing the distance between target and substrate.

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Fabrication and Characteristics of a-SiNx:H Thin Films (a-SiNx:H 박막의 제조 및 특성)

  • Park, Wug-Dong;Kim, Young-Jin;Kim, Ki-Wan
    • Journal of Sensor Science and Technology
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    • v.4 no.2
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    • pp.58-63
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    • 1995
  • The effects of substrate temperature, RF power, and $NH_{3}/SiH_{4}$ gas flow ratio on the dielectric constant and optical bandgap of amorphous silicon nitride (a-SiNx:H) thin films prepared by PECVD method using RF glow discharge decomposition of $SiH_{4}$ and $NH_{3}$ gas mixtures have been studied. The dielectric constant and optical bandgap of a-SiNx:H thin films were greatly exchanged as by increasing substrate temperature, RF power, and $NH_{3}/SiH_{4}$ gas flow ratio. The dielectric constant of a-SiNx:H films was increased and optical bandgap of a-SiNx:H films was decreased as the substrate temperature was increased. When the substrate temperature, RF power, gas pressure, $NH_{3}/SiH_{4}$ gas flow ratio, and thickness were $250^{\circ}C$, 20 W, 500 mTorr, 10 and $1500\;{\AA}$, respectively, the dielectric constant, breakdown field and optical bandgap of a-SiNx:H film were 4.3, 1 MV/cm, and 2.9 eV, respectively.

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Analyzing Differences of Binary Executable Files using Program Structure and Constant Values (프로그램의 구조와 상수 값을 이용하는 바이너리 실행 파일의 차이점 분석)

  • Park, Hee-Wan;Choi, Seok-Woo;Seo, Sun-Ae;Han, Tai-Sook
    • Journal of KIISE:Software and Applications
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    • v.35 no.7
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    • pp.452-461
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    • 2008
  • Binary diffing is a method to find differences in similar binary executables such as two different versions of security patches. Previous diffing methods using flow information can detect control flow changes, but they cannot track constant value changes. Biffing methods using assembly instructions can detect constant value changes, but they give false positives which are due to compiling methods such as instruction reordering. We present a binary diffing method and its implementation named SCV which utilizes both structure and value information. SCV summarizes structure and constant value information from disassembled code, and matches the summaries to find differences. By analyzing a Microsoft Windows security patches, we showed that SCV found necessary differences caused by constant value changes which the state-of-the-art binary diffing tool BinDiff failed to find.

Reduction of High Explosives (HMX, RDX, and TNT) Using Micro- and Nano- Size Zero Valent Iron: Comparison of Kinetic Constants and Intermediates Behavior (마이크로와 나노 철을 이용한 고성능 화약물질(HMX, RDX 및 TNT)의 환원처리: 중간산물의 거동과 도역학 상수의 비교)

  • Bae, Bum-Han
    • Journal of Soil and Groundwater Environment
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    • v.11 no.6
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    • pp.83-91
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    • 2006
  • Reduction kinetics and the behaviour of intermediate of three high explosives (HMX, RDX, and TNT) were studies in batch reactors using nano- or micro- size zero valent iron(nZVI or mZVI) as reducing agent. The kinetic constants normalized by the mass of iron ($k_M$) or by the surface area ($k_{SA}$) were measured and compared along with the changes in the concentrations of intermediates. Results showed that $k_M$ and $k_{SA}$ values were not suitable to fully explain the behaviour of mother compounds and reduced intermediates in the batch reactor. The concentrations of initial explosives degradation products, such as nitroso-RDXs, nitroso-HMXs, and hydroxylamino-TNTs, were higher in mZVI treated reactor than in nZVI treated reactor, whereas more reduced polar intermediates such as TAT were accumulated in the nZVI reactor. Therefore, a new parameter, which accounted for the intermediates reduction, needs to be developed.

The study of ferroelectric properties for Pb(Mg1/3Ta2/3)O3-PbTiO3 solid solution modified with ZrO2 (ZrO2 첨가에 따른 Pb(Mg1/3Ta2/3)O3-PbTiO3 고용체의 강유전 특성 연구)

  • Kim, B.G.
    • Journal of the Korean Vacuum Society
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    • v.17 no.4
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    • pp.317-321
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    • 2008
  • The $0.65Pb(Mg_{1/3}Ta_{2/3})O_3-0.35PbTiO_3$ (PMT-PT)ceramics were near morphotropic phase boundary. The dielectric constant, the loss, and pyroelectric coefficient of the ceramics were measured as a function of temperature ($25^{\circ}C\;{\sim}\;250^{\circ}C$). The dielectric constant, the loss, and the pyroelectric coefficient could be improved with the addition of small amounts of $ZrO_2$ up to 0.2 mol%. The dielectric and pyroelectric peak temperature are slightly shifted to lower temperatrues with the addition of amount of $ZrO_2$.

Determination of the Bioconcentration Factor in Some Pesticides by Flow-through Fish Test (Flow-through fish test를 이용한 일부 농약의 생물농축예수의 측정)

  • 민경진;차춘근
    • Journal of Environmental Health Sciences
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    • v.27 no.2
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    • pp.37-42
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    • 2001
  • Zebrafish(Brachdanio rerio)를 실험어류로 하여 methidathion 과 phosalone의 생물농축계수(bioconcentration factor : BCF)와 배설속도상수 (depuration rate constant) 및 LC$_{50}$를 측정하였다. Methidathion의 24, 48, 72, 96시간 LC$_{50}$는 각각 28.34, 35.98, 24.43, 22.03 mg/$\ell$로 측정되었다. Methidathion 0.22 mg/$\ell$(고농도)와 0.022 mg/$\ell$(저농도)에서 어류 체내에서의 농축정도는 두 농도군에서 각각 12시간 이후에 정류상태에 도달하여 72시간동안 거의 일정하였고, BCF값도 12시간에서 72시간 사이에 고농도와 저농도에서 8.72(n=4)와 11.25(n=4)로 조사되었다. 배설속도상수는 고농도와 저농도에서 6시간 이내에 모두 배설되어 배설속도상수를 구할 수 없었다. Phosalone의 24, 48, 72, 96시간 LC$_{50}$는 각각 3.76, 2.43, 1.86, 1.05 mg/$\ell$로 측정되었다. Zebrafish 체내에서의 농축정도와 BCF값은 고농도(0.01 mg/$\ell$)에서 12시간 이후에 정류상태에 도달하여 72시간동안 거의 일정하였고, BCF값은 12시간에서 72시간 사이에 48.88(n=4)로 측정되었다. 저농도(0.001 mg/$\ell$)에서는 실험 전기간동안 zebrafish 체내에서 phosalone이 검출되지 않아 BCF값을 산출할 수 없었다. Zebrafish 체내에서 phosalone(고농도)의 배설속도상수와 반감기를 구하기 위하여 6,12시간의 배설실험 결과 각각 0.17$hr^{-1}$과 4.01 시간이었다. Methidathion과 phosalone의 BCF값은 phosalone이 methidathion 보다 약 5배 정도 높게 나타났으며, 농약의 배설속도는 phosalone이 methidathion보다 빨랐다.

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Determination of Flow Stress of Zircaloy-4 Under High Strain Rate Using Slot Milling Test (슬롯밀링시험을 이용한 높은 변형률 속도 조건하에서 Zircaloy-4의 유동응력 결정)

  • Hwang, Jihoon;Kim, Naksoo;Lee, Hyungyil;Kim, Dongchoul
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.37 no.1
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    • pp.67-75
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    • 2013
  • The flow stress of zircaloy-4 used in the spacer grid supporting a nuclear fuel rod was determined by the Johnson-Cook model, and model parameters were determined using reverse engineering. Parameters such as A, B, n and $\dot{\varepsilon}_0$ were determined by the tensile test result. To obtain the parameters C and m, a slot milling test and numerical simulation were performed. The objective functions were defined as the difference between the experimental and the simulation results, and then, the parameters were determined by minimizing the objective function. To verify the validity of the determined parameters, cross-verification for each case was conducted through a shearing test and simulation. The results tend to show agreement with the experimental results, such as the features of sheared edges and maximum punch force, with the correlation coefficients exceeding at least 0.97.

Equilibrium Kinetics and Thermodynamic Parameters Studies for Eosin Yellow Adsorption by Activated Carbon (활성탄에 의한 Eosin Yellow의 흡착에 대한 평형, 동력학 및 열역학 파라미터에 관한 연구)

  • Lee, Jong Jib
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.15 no.5
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    • pp.3319-3326
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    • 2014
  • Eosin yellow is used a dye and colorant but it is harmful toxic substance. In this paper, batch adsorption studies were carried out for equilibrium, kinetics and thermodynamic parameters for eosin yellow adsorption by activated carbon with varying the operating variables like pH, initial concentration, contact time. Equilibrium adsorption data were fitted into Langmuir, Freundlich, Temkin and Dubinin-Radushkevich isotherms. By estimated Langmuir constant value, $R_L$=0.067-0.083, and Freundlich constant value, $\frac{1}{n}=0.237-0.267$, this process could be employed as effective treatment for removal of eosin yellow. From calculated Temkin constant, value, B=1.868-2.855 J/mol, and Dubinin-Radushkevich constant, value, E=5.345-5.735 kJ/mol, this adsorption process is physical adsorption. From kinetic experiments, the adsorption process were found to confirm to the pseudo second order model with good correlation coefficient($r^2$=0.995-0.998). The mechanism of the adsorption process was determined two step like as boundary and intraparticle diffusion.

Dynamics and motion control of an underactuated manipulator (비구동 관절을 가지는 매니퓰레이터의 동력학과 운동제어)

  • Yu, Kee-Ho
    • Journal of Institute of Control, Robotics and Systems
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    • v.3 no.5
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    • pp.476-481
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    • 1997
  • 본 논문에서는 비구동 관절을 가지는 2링크 매니퓰레이터의 동력학 해석과 운동제어를 제1적분을 기초로 하여 전개하고 있다. 매니퓰레이터의 운동이 제1적분의 적분상수에 의해서 기술되는 것을 보이고, 제1적분을 이용하여 매니퓰레이터의 동력학을 해석하고 있다. 그리고 해석된 동력학을 적극적으로 이용하는 운동제어 알고리즘을 구성하고 시뮬레이션을 통하여 확인하고 있다. 끝으로 비구동 관절에 마찰이 작용하는 경우, 브레이크등의 보조수단을 이용하지 않고도 매니퓰레이터의 제어가 가능함을 보이고 있다.

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Optical Properties of Sputtered Ta2O5 Thin Films Using Spectroscopic Ellipsometty (분광타원법을 이용한 스퍼터된 Ta2O5 박막의 광학적 특성)

  • Kim, Sun-Hee;Lee, Eui-Hyun;Jung, In-Woo;Hyun, Jang-Hoon;Lee, Sung-Young;Kang, Man-Il;Ryu, Ji-Wook
    • Journal of the Korean Vacuum Society
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    • v.18 no.2
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    • pp.133-140
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    • 2009
  • $Ta_{2}O_{5}$ thin films were deposited by RF magnetron sputtering method under various RF power, substrates and oxygen partial pressure. Elliptic constants were measured by using a phase modulated spectroscopic ellipsometer and analyzed with the Tauc-Lorentz dispersion formula and best fit method in the range of 310$\sim$1239 nm. Also, transmittance spectra of the films were measured by UV -Vis spectrophotometer in the range of 300$\sim$1000 nm. From these data, thickness of $Ta_{2}O_{5}$ and surface layer were analyzed and changes of magnitude and shape of dispersion of optical constants according to fabricated conditions were measured. Also, to evaluate thickness and optical constants data analyzed by Tauc-Lorentz dispersion formula, the measured and analyzed transmittance spectra were compared. In result of the comparison, two spectra were in good agreement each other. Accordingly, it indicates that our ellipsometric analysis is valid.