• Applied Chemistry for Engineering
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• v.17 no.6
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• pp.625-632
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• 2006

Dependence of the critical micelle concentration (CMC) on temperature is examined from a statistical-mechanical point of view. A simple and primitive model examined in this article yields ln CMC= A+BT+C/T+D ln T with T being temperature and A, B, C, D being constants depending on the properties of the surfactant molecules which comprise the micelles. The resulting equation combines Muller's and Lim's equations, which have already been proven to fit well measured CMC data with temperature. The statistical-mechanical model on micellization discussed in this article provides a theoretical basis on these equations.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.28 no.2D
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• pp.227-234
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• 2008

This study examines which models are more suitable for representing mechanical property of unbound materials to analyze behavior of asphalt pavement structure. Results from FWD (Falling Weight Deflectometer) test were used to apply to nonlinear elastic model. The new method which can deduct material constants of nonlinear elastic model is suggested from FWD test data rather than laboratory resilient modulus ($M_R$) test. It is confirmed that the material constants are within the common range in subbase. Test output from FWD and MDD (Multi-Depth Deflectometer) was used to verify reliability of the model. From the results of verification, this study shows that a non-linear elastic model agrees to MDD test data more than a linear elastic model does.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.36 no.3
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• pp.264-270
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• 2008

Most of burning rate models used in hybrid combustion depend solely on oxidizer flux. But this empirical relation can not represent well the important effect of the thermo-chemical properties of solid fuel and thereby requires different value of empirical exponent and constant for each fuel considered. In this study, a new burning rate correlation was proposed using the mass transfer number(B number) which encompasses the thermochemistry effect of solid fuel and the aerodynamic effect caused by the combustion on the solid fuel surface where the effect of aerodynamic property in the mass transfer number was studied. The PMMA, PP, and PE were chosen as fuel, and gas oxygen as oxidizer. The new empirical burning rate expression depending on both the oxidizer flux and the mass transfer number was able to predict the burning rate of each fuel with just a single exponent value and constant, and it was found that the aerodynamic effect on the blowing effect did show a minor effect on the burning rate correlation.

• Korean Chemical Engineering Research
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• v.56 no.1
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• pp.112-118
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• 2018

Adsorption equilibrium, kinetic and thermodynamic parameters of a brilliant green from aqueous solutions at various initial dye concentration (10~30 mg/L), contact time (1~24 h) and temperature (298~318 K) on zeolite were studied in a batch mode operation. The equilibrium adsorption values were analyzed by Langmuir, Freundlich and Dubinin-Radushkevich model. The results indicate that Langmuir and Freundlich model provides the best correlation of the experimental data. Base on the estimated values of Langmuir dimensionless separation factor ($R_L=0.041{\sim}0.057$) and Freundlich constant (1/n=0.30~0.47), this process could be employed as effective treatment method. calculated values of adsorption energy by Dubinin-Radushkevich model were 1.564~1.857 kJ/mol corresponding to physical adsorption. The adsorption kinetics of brilliant green were best described by the pseudo second-order rate model and followed by intraparticle diffusion model. Thermodynamic parameters such as activation energy, free energy, enthalpy and entropy were calculated to estimate nature of adsorption. negative Gibbs free energy (-10.3~-11.4 kJ/mol), positive enthalpy change (49.48 kJ/mol) and Arrehenius activation energy (27.05 kJ/mol) indicates that the adsorption is spontaneous, endothermic and physical adsorption process, respectively.

• Microbiology and Biotechnology Letters
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• v.17 no.4
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• pp.365-369
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• 1989

Thermal inactivation of Tyichoderma viride cellobiohydrolase was investigated by immunoassay and residual enzyme assay such as carboxymethyl cellulase (CMCase) and filter paper degradation activity (FPase). Arrhenius plots of cellobiohydrolase were appeared as straight line. The Z-values of cellobiohydrolase calculated by CMCase, FPase and immunoassay were 5.2$^{\circ}C$, 6.4$^{\circ}C$ and 5.8$^{\circ}C$, respectively. The thermodynamic parameters obtained from FPase were better agreement with those of immunoassay than CMCase assay.

• The Korean Journal of Rheology
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• v.7 no.1
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• pp.28-34
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• 1995

고체가 아닌 계인 마요네즈에 대해 Couette형 점도계를 사용하여 일정한 전단속도에 서 시간과 더불어 전단응력이 감소하는 응력완화 곡선을 온도 2$0^{\circ}C$, $25^{\circ}C$, 3$0^{\circ}C$, 34$^{\circ}C$, 4$0^{\circ}C$ 에서 얻었다 이현상을 설명하기 위하여 구조가 형성되는 flow unit 2와 구조가파괴되는 flow unit 3에 대한 fraction (X2, X3)사이의 평형을 생각하고 X2 와 X3 에 해당하는 항에 실 험적 조건인 s=p(t0+t)의 관계를 적용하여 다음과 같은 응력완화에 관한 식을 구하고 이식을 실험결과에 적용하여 유동파라메타를 구하였으며 그 파라메타중의 평형상수 k와 실험 온도 를 이용하여 열역학 파라메타를 구하였다.

• 한국전산유체공학회:학술대회논문집
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• 2005.04a
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• pp.223-227
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• 2005

최근 전산 유체의 발달로 이상 유동해석의 캐비테이션 모델 적용 방법이 발전되어 왔으나 다양한 수력학적 시스템에서 발생하는 캐비테이션 유동은 난류이며 물과 공기 사이에서의 복잡한 상호 작용을 가지고 있으므로 그 적용 예가 아직은 미흡한 상태이다. 본 연구에서는 수중에서의 캐비테이션 해석과 이상 유동 해석을 위한 코드 개발 및 검증을 목적으로 3차원 회전체 주위의 캐비테이션 유동을 여러 가지 조건들의 변화를 적용하여 해석하였다. 또한 캐비테이션 발생과 관련한 다른 난류 모델에 적용하여 비교 분석을 수행하였다. 해석을 위한 모델의 지배방정식은 이상유동 Wavier-Stokes 방정식, 질량$\cdot$모멘텀 방정식의 혼합된 형태로 구성되어 있으며 방정식의 해를 구하기 위한 방법으로 유한차분법을 이용하였다. 해석결과의 신뢰성을 고려하여 반구형 실린더 주위의 캐비테이션 유동의 실험치와 비교 분석하였다. 그 결과, 본 연구의 수치 해석 방법과 실험적 방법의 결과가 강한 양의 상관관계를 가짐을 알 수 있었으며, 이러한 수치적 뒷받침은 본 연구의 전산수치 해석 방법이 앞으로의 여러 유동 해석으로의 적용 가능성을 보여준다.

• Proceedings of the Korean Society for Noise and Vibration Engineering Conference
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• 2002.05a
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• pp.489-494
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• 2002

This paper presents hydraulic model which can capture the hysteric damping force behavior of ER damper. A flow mode rue ER damper is manufactured, and its field-dependent damping forces are measured. Newly proposed hydraulic model which derived from physical hydro-mechanical parameters of ER damper are conventional Bingham model are investigated to represent the field-dependent damping force characteristics of ER damper. After principal parameters of two models are estimated from the measured damping forces data, the force vs velocity hysteresis cycles are then reconstructed. The results show that the proposed hydraulic model can capture the hysteresis behavior of ER damper accurately.

• Proceeding of EDISON Challenge
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• 2014.03a
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• pp.597-602
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• 2014

본 연구에서는 다양한 모형의 실린더 주위의 균일한 유동에 대하여, 후류에 생기는 유동현상을 EDISON_CFD를 이용하여 분석하였다. 고정된 실린더에 대해 주어진 레이놀즈 수에서 시뮬레이션을 이용하여 실린더의 형상에 따른 $C_L$값과 주기를 분석하였다. 이 후 진동운동을 가정한 운동방정식을 이용하여 실린더의 운동 및 발전 효율을 예측하여 비교하였다. 또한 운동방정식을 Bode 선도를 이용하여 용수철 상수와 감쇠율에 따른 발전 효율의 변화를 살펴보았다.

• Journal of the Korean Chemical Society
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• v.20 no.6
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• pp.448-452
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• 1976

A simplified statistical mechanical method was developed for the calculation of the dehydration fraction, activation free energy of dehydration, and the relaxation times of hydrated ions. The model used includes the equilibrium constant between hydrated and dehydrated water, a water-ion interaction potential energy term, and a mixing factor for the species present. The agreement between theory and experiment is good. The pressure dependence of ion dehydration is also discussed.