• Journal of the Mineralogical Society of Korea
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• v.20 no.4
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• pp.313-325
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• 2007

In order to have better insights into adsorption of organic molecules on kaolinite surfaces, we performed quantum chemical calculations of interaction between three different model clusters of kaolinite siloxane surfaces and benzyl alcohol, with emphasis on the effect of size and lattice topology of the cluster on the variation of electron density and magnetic shielding tensor. Model cluster 1 is an ideal silicate tetrahedral surface that consists of 7 hexagonal rings, and model cluster 2 is composed of 7 ditrigonal siloxane rings with crystallographically distinct basal oxygen atoms in the cluster, and finally model cluster 3 has both tetrahedral and octahedral layers. The Mulliken charge analysis shows that siloxane surface of model cluster 3 undergoes the largest electron density transfer after the benzyl alcohol adsorption and that of model cluster 1 is apparently larger than that of model cluster 2. The difference of Mulliken charges of basal oxygen atoms before and after the adsorption is positively correlated with hydrogen bond strength. NMR chemical shielding tensor calculation of clusters without benryl alcohol shows that three different basal oxygen atoms (O3, O4, and O5) in model cluster 2 have the isotropic magnetic shielding tensor as $228.2{\pm}3.9,\;228.9{\pm}3.4,\;and\;222.3{\pm}3.0ppm$, respectively. After the adsorption, the difference of isotropic chemical shift varies from 1 to 5.5 ppm fer model cluster 1 and 2 while model cluster 2 apparently shows larger changes in isotropic chemical shift. The chemical shift of oxygen atoms is also positively correlated with electron density transfer. The current results show that the adsorption of benzyl alcohol on the kaolinite siloxane surfaces can largely be dominated by a weak hydrogen bonding and electrostatic force (charge-charge interaction) and demonstrate the importance of the cluster site and the lattice topology of surfaces on the adsorption behavior of the organic molecules on clay surfaces.

• The Korean Journal of Vision Science
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• v.20 no.4
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• pp.469-482
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• 2018

Purpose : We investigated the change of spherical and comma aberrations after wearing aspheric soft contact lens (ASCL) in young myopes. Methods : Fifty young myopes ($23.15{\pm}1.70years$, spherical equivalent: $-2.90{\pm}1.75D$) were recruited and refractive errors were corrected using ASCL (Biotrue, Bausch+Lomb, USA). High order aberrations were measured in the 4 mm pupil size using the wavefront analyze and pupil sizes were measured with a pupillometer at the modes of scotopic condition (light off) at 3.5 m in the 100 lx illuminance condition. Results : Spherical aberrations and coma aberration of the 20s myopes were $0.026{\pm}0.031{\mu}m$ and $0.078{\pm}0.039{\mu}m$ respectively, and $0.019{\pm}0.026{\mu}m$ and $0.082{\pm}0.038{\mu}m$ after ASCL wear that spherical aberration was decreased and coma aberration was increased. However, spherical aberration was decreased in the 68% of the subject have positive spherical aberration, and increased in the 11% of the subject have negative spherical aberration. Coma aberration was increased in the 53% of the subject, did not change in the 19% of the subjects, and decreased in the 28% of the subject. Spherical aberration was not different with the refractive errors in low and moderate myopies, however, coma aberrations was higher in the higher myopes. Conclusion : In a scotopic condition without accommodation stimuli, spherical aberration is decreased after wearing ASCL, however in the subject have negative spherical aberration spherical aberration could be increased, and which is thought to be the influence of contact lens design and pupil size.

• Journal of Korean Society of Forest Science
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• v.107 no.4
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• pp.351-360
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• 2018

This study was conducted to analyze the responses of chlorophyll contents and growth of Pinus densiflora and Quercus variabilis seedlings on distance from the well and $CO_2$ flux after the artificial $CO_2$ release. From June 1 to 30, 2016, $CO_2$ gas was injected at the rate of $6L\;min^{-1}$ at the study site in Eumseong. Chlorophyll content was analyzed in the middle of July, 2016, and root collar diameter (RCD), height (H), and biomass were measured in May and December, 2016 after planting 2-year-old P. densiflora and 1-year-old Q. variabilis seedlings in May, 2015. The chlorophyll content of P. densiflora seedlings did not show a significant correlation with $CO_2$ flux, whereas the chlorophyll content of Q. variabilis seedlings showed a significant negative correlation with increasing $CO_2$ flux (P<0.05). The RCD and H growth rates of both species showed the significant difference in the distance from the well of the $CO_2$ anthropogenic release treatment. In particular, the RCD and H growth rate of P. densiflora seedlings and the RCD growth rate of Q. variabilis seedlings increased significantly as the seedlings were closer to the well, but the H growth rate of Q. variabilis seedlings decreased significantly. In addition, as the $CO_2$ concentration in the ground increases, ${\Delta}R/S$ ratio increases in both species, suggesting that the high $CO_2$ concentration in the soil promotes carbon distribution relative to the root part. The results of this study can be used as data necessary to monitor the $CO_2$ leakage and physiological and growth responses of both species to leakage of stored $CO_2$ in the future.

• Journal of the Korean Society of Radiology
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• v.13 no.4
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• pp.573-579
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• 2019

The purpose of this study is predicted easily the entrance surface dose (ESD) in chest digital radiography. We used two detector type such as flat-panel detector (FP) and IP (Imaging plate detector). ESD was measured at each exposure condition combined tube voltage with tube current using dosimeter, after attaching on human phantom, it was repeated 3 times. Phantom images were evaluated independently by three chest radiologists after blinding image. Dose-area product (DAP) or exposure index (EI) was checked by Digital Imaging and Communications in Medicine (DICOM) header on phantom images. Statistical analysis was performed by the linear regression using SPSS ver. 19.0. ESD was significant difference between FP and IP($85.7{\mu}Gy$ vs. $124.6{\mu}Gy$, p=0.017). ESD was positively correlated with image quality in FP as well as IP. In FP, adjusted R square was 0.978 (97.8%) and linear regression model was $ESD=0.407+68.810{\times}DAP$. DAP was 4.781 by calculating the $DAP=0.021+0.014{\times}340{\mu}Gy$. In IP, adjusted R square was 0.645 (64.5%) and linear regression model was $ESD=-63.339+0.188{\times}EI$. EI was 1748.97 by calculating the $EI=565.431+3.481{\times}340{\mu}Gy$. In chest digital radiography, the ESD can be easily predicted by the DICOM header information.

• Journal of the Mineralogical Society of Korea
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• v.32 no.1
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• pp.41-49
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• 2019

Probing the Na environments in Na silicate and aluminosilicate glasses is essential to the macroscopic properties of melts in the Earth. In particular, exploring the atomic structure of Na silicate and aluminosilicate glasses reveals Na-O distance, which plays an important role in transport properties of melts. Here we report the local environment around Na using $^{23}Na$ magic angle spinning (MAS) NMR. We also obtain $^{23}Na$ isotropic chemical shift (${\delta}_{iso}$) of Na silicate and aluminosilicate glasses with varying composition using Dmfit program. The Q mas 1/2 model simulates the experimental results with three simulated peaks while the CzSimple model simulates with one peak. The ${\delta}_{iso}$ decreases with increasing $SiO_2$ content in Na silicate and aluminosilicate glasses. The ${\delta}_{iso}$ increases with increasing $Na_2O$ content in Na-Ca silicate and Na aluminosilicate glasses when the $SiO_2$ content is fixed. Considering the ${\delta}_{iso}$ of Na aluminosilicate glasses available in the previous studies, together with the current simulation results, we confirm that the ${\delta}_{iso}$ has positive correlation with Al / (Al + Si). Those experimental results were reproduced better using Q mas 1/2 model. The disorder of Na in Na silicate and aluminosilicate glasses can be revealed through the simulation of 1D $^{23}Na$ MAS NMR spectra using Dmfit program in a short time.

• Journal of the Mineralogical Society of Korea
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• v.32 no.1
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• pp.51-61
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• 2019

Clay minerals, a major component of mud volcano (MV) sediments, are expected to provide important information for characterizing mud volcano formation mechanisms, but clay minerals have rarely been studied. The purpose of this study is to investigate the characteristics of 420 MV and surrounding marine sediments. Clay minerals and grain size were analyzed for 8 box cores from 420 MV and Mackenzie Trough. The relative proportions of the four major clay minerals in the Mackenzie Trough are almost constant in the order of illite, chlorite, kaolinite, and smectite, regardless of the distance from the Mackenzie River. However, the grain size tends to become fining as they move away from the Mackenzie River. Comparing the clay mineral characteristics of river (Colville River, Kuparuk River, Sagavanirktok River, Canning River, Mackenzie River) sediments entering the Beaufort Sea in order to determine the origin of the Mackenzie Trough and 420 MV sediments, the sediments of the Mackenzie Trough are characterized mainly by the Mackenzie River with a low ratio of smectite/illite and a high ratio of kaolinite/chlorite. In 420 MV sediments, the contents of clay minerals decrease in the order of illite, kaolinite, chlorite, and smectite, and the grain size with depth is almost constant. The content of smectite and coarse sediments is about two times higher than the reference core. No river with higher kaolinite content than chlorite exists in the Beaufort Sea, and the ratio of smectite/illite to kaolinite/chlorite is different from the reference core such as the ratio of the Mackenzie River. Compared to the reference core, the high contents of coarse sediments and the constant grain size with depth might be attributed to the ejection by MV. The reference core is interpreted as originating from Mackenzie River, and sediment of 420 MV is interpreted as originating from eruption of MV.

• Korean Journal of Plant Resources
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• v.32 no.2
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• pp.160-169
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• 2019

The this study was carried out to investigate the growth characteristics of wild-simulated ginseng by direct seeding and transplanting cultivation for develop standard cultivation techniques of wild-simulated ginseng. Bonghwa experimental field were confirm to be suitable location environment for cultivation of wild-simulated ginseng. As a result of this study, the germination rate of wild-simulated ginseng was significantly highest when seed size was over 6.5 mm in the spot seeding cultivation. In the case of transplanting, survival rate was significantly increased when the diameter of root was over 10 mm, planting distance was 7 cm, and the thickness of soil covering was less then 2 cm. The result of growth characteristics of wild-simulated ginseng by cultivation type, growth of stem in spot seeding cultivation was showed significantly increased when seed size over 6 mm, seeding number was 3 grains, and the seeding distance was less then 5 cm. Strip seeding cultivation was showed significantly increased in stem and root growth when seeding distance was 30 cm grains and quantity of seeding was less then 23 g. In the case of transplanting cultivation, it's was showed significantly increased in stem growth when diameter of root was over then 10 mm and direction of rhizome was top and bottom. The results of this study was that to clearly establish the techniques of cultivation of managements and it's will be suggest contribute to the industrial activation of wild-simulated ginseng.

• Economic and Environmental Geology
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• v.54 no.1
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• pp.77-89
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• 2021

In this study, a method has been proposed to improve the performance of hydraulic property estimation model developed by Jeong et al. (2020). In their study, low-dimensional features of the annual groundwater level (GWL) fluctuation patterns extracted based on a Denoising autoencoder (DAE) was used to develop a regression model for predicting hydraulic properties of an aquifer. However, low-dimensional features of the DAE are highly dependent on the precipitation pattern even if the GWL is monitored at the same location, causing uncertainty in hydraulic property estimation of the regression model. To solve the above problem, a process for generating the GWL fluctuation pattern for conditioning the precipitation is proposed based on a conditional variational autoencoder (CVAE). The CVAE trains a statistical relationship between GWL fluctuation and precipitation pattern. The actual GWL and precipitation data monitored on a total of 71 monitoring stations over 10 years in South Korea was applied to validate the effect of using CVAE. As a result, the trained CVAE model reasonably generated GWL fluctuation pattern with the conditioning of various precipitation patterns for all the monitoring locations. Based on the trained CVAE model, the low-dimensional features of the GWL fluctuation pattern without interference of different precipitation patterns were extracted for all monitoring stations, and they were compared to the features extracted based on the DAE. Consequently, it can be confirmed that the statistical consistency of the features extracted using CVAE is improved compared to DAE. Thus, we conclude that the proposed method may be useful in extracting a more accurate feature of GWL fluctuation pattern affected solely by hydraulic characteristics of the aquifer, which would be followed by the improved performance of the previously developed regression model.

• Journal of Korean Society of Forest Science
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• v.112 no.3
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• pp.280-289
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• 2023

Diverse native tree species are distributed in Korean forests; however, information on their regeneration strategies is limited. This study analyzed seed rain from 2011 to 2013, seedling emergence, seedling survival, lifespan distribution, and the relationship between seedling mortality and herbaceous vegetation for 3 years, from 2012 to 2014, to understand the natural regeneration and early survival characteristics of Fraxinus rhynchophylla Hance in natural broad-leaved forests. Seed rain and emerged seedling density significantly differed among the years (p < .05). An increase in seed rain was followed by an increase in seedling emergence in the following year. Seed rain in 2013 and seedling emergence in 2014 showed a significant correlation (p < .05), confirming the trait of F. rhynchophylla seeds that germinate in the following year after seed production. Seedlings emerged in late spring and early summer. Of the seedlings, 78% emerged in the early summer of 2014. Most seedlings died immediately after emergence. Of the seedlings that emerged in August 2012, 56% died within 2 months, and 38% of those that emerged in July 2014 died within 1 month. Shade and competition against ground vegetation chiefly affected the seedling survival of F. rhynchophylla. Fraxinus rhynchophylla showed mast seeding, with a large number of seed production in a particular year. A surge of seedling emergence followed in the early summer of the next year. However, most seedlings died in the same year of emergence. Fraxinus rhynchophylla has a high seedling mortality, but mast seeding and the resulting high seedling emergence produce a few survived seedlings, enabling the continuation of the F. rhynchophylla population. Efforts and research on the natural regeneration of native tree species are required to effectively manage natural forests in Korea.

• Journal of Korean Port Research
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• v.12 no.1
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• pp.35-46
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• 1998

The CY can be said to function in various respect as a buffer zone between the maritime and overland inflow-outflow of container. The amount of storage area needed requires a very critical appraisal at pre-operational stage. A container terminal should be designed to handle and store containers in the most efficient and economic way possible. In order to achieve this aim it is necessary to figure out or forecast numbers and types of containers to be handled, CY area required, and internal handling systems to be adopted. This paper aims to calculate the CY area required for each container handling system in Mokpo New Port. The CY area required are directly dependent on the equipment being used and the storage demand. And also the CY area required depends on the dwell time. Furthermore, containers need to be segregated by destination, weight, class, FCL(full container load), LCL(less than container load), direction of travel, and sometimes by type and often by shipping line or service. Thus the full use of a storage area is not always possible as major unbalances and fluctuations in these flow occuring all the time. The calculating CY area must therefore be taken into account in terms of these operational factors. For solving such problem, all these factors have been applied to estimation of CY area in Mokpo New Port. The CY area required in Mokpo New Port was summarized in the conclusion section.