• Elastomers and Composites
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• v.34 no.1
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• pp.20-30
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• 1999

In this study, binary polyamide 6,6(PA 6,6)/ethylene-propylene rubber(EPM) or EPM-g-maleic anhydride(EPM-g-MA) blends and ternary PA 6,6/EPM/EPM-g-MA blends with various elastomer content were prepared in order to investigate the degree of influence of elastomer content and average particle size, morphology, and distribution of dispersed elastomer on mechanical and thermal properties of blends. According to the results, notched Izod impact strength and relative crystallinity of binary blends modified with EPM-g-MA as well as average particle size and distribution of dispersed elastomer in such blends were more improved than those of binary blends modified with EPM. Notched Izod impact strength of blend whose composition ratio(wt % ) was 70:30(PA 6,6 : EPM-g-MA) was the highest among the binary PA 6,6/EPM-g-MA blends. The impact strength was increased by 25 times and its relative crystallinity was increased by 7 times when compared with those of polyamide 6,6. In the case of ternary PA 6,6/EPM/EPM-g-MA blend of which composition ratio was 70:15:15(PA 6,6:EPM:EPM-g-MA), the elastomer was finely distributed with the average particle size of $0.56{\mu}m$. The Izod impact strength of this blend was the highest of all blends prepared with different elastomer content.

• 한국신재생에너지학회:학술대회논문집
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• 2010.11a
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• pp.158.1-158.1
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• 2010

국내 최초의 생활폐기물고형연료(RDF) 생산플랜트인 원주시 RDF플랜트의 2009년도 운영실적을 정리하여 폐기물 처리단가를 분석하였으며 에너지 생산 효과도 분석하였다. 실적분석에 사용된 자료는 원주 RDF플랜트 위탁운영업체가 운영비를 청구 및 정산하기 위해서 원주시에 상시 측정 및 보고하는 항목으로서, 내용은 트럭으로 플랜트에 반입되는 폐기물 전체량, RDF생산 전체량, 불순물 매립 전체량, 건조 및 탈취용 연료사용 전체량, 전기사용 전체량 등이다. 2009년도 원주시 RDF플랜트에 반입된 폐기물 량은 총 17,504톤이었고, RDF를 총 7,044톤 생산하였으며, 4,120톤의 불연물을 선별하였다. 1년간 사용한 건조 및 탈취용 연료는 총 596,268 리터였으며 연료인 부생유의 가격은 리터 당 평균 864.6원이었다. 사용한 전기량은 총 2,435,397 kWh였고, 이 중에서 성형공정에 사용된 전기량은 총 사용량의 19%였다. 이상의 기록자료들을 분석해 본 결과, 폐기물 1톤을 처리하는데 전기 비용이 14,334원이었고, 연료비가 29,452원이었다. 여기에 폐기물 1톤당 불연물 매립비 6,573원과 위탁인건비를 합하면 폐기물 1톤당 처리비용은 약 116,573원으로 나타났다. 현재 원주시 RDF는 톤당 25,000원에 판매되고 있으므로 이 비용을 감안하면 폐기물 1톤당 처리비용은 105,298원으로 산출되었다. 현재 알려진 유사 규모의 소각로 운영비가 폐기물 1톤당 136,736원인데, 이것은 RDF기술보다 31,438원/톤-폐기물 정도 처리비용이 비싸다. 따라서 100톤 이하 규모의 폐기물처리시설 설치를 할 경우에는 RDF 시설이 경제적으로 타당함을 나타낸다. 원주시 RDF플랜트의 물질수지를 분석해 본 결과, RDF생산 수율은 40.2%였으며 총 투입된 에너지는 8,0587 Gcal였다. 생산된 에너지 총량은 RDF발열량 4,500 kcal/kg으로 했을 때 31,699 Gcal로 나타났다. 투입대비 생산에너지 비율은 25.4%로 계산되었고, 전기의 발전효율을 40%로 감안했을 경우에는 35.3%로 계산되었다. 성형하는데 사용되는 총 에너지는 전체 투입에너지의 4.9%로 나타났고, 비용으로는 폐기물 1톤당 2,723원 이었다.

• New & Renewable Energy
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• v.7 no.1
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• pp.29-35
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• 2011

The waste treatment fee and energy production effect of Wonju city RDF plant, the first RDF manufacturing plant in Korea, were investigated in the study. All plant operation data, like total weight of received wastes, produced RDF and separated rejects in processes were fully recorded for mass balance calculation of the plant in 2009. Also all consumed oil and electricity were recorded for energy balance calculation. The results showed that the waste treatment fee not including the RDF sales price of 25,000 won/ton-RDF was 116,573 won/ton-MSW and it went down to 105,298 won when included the RDF price. Produced RDF was 40.2% of total received waste in weight. Three components analysis by mass balance calculation of total received waste showed that Wonju city's MSW was 32.4% of combustible, 37.5% of water and 30.1% of incombustible respectively. Energy effect was found that total amount of produced energy was about 4 times more than that of consumed energy.

• Proceedings of the KAIS Fall Conference
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• 2009.05a
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• pp.848-850
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• 2009

화석에너지 고갈로 인한 유가 상승으로 폐기물 에너지화가 이슈화 되고 있다. 폐기물 고형 연료 RDF는 에너지 문제를 해결하기위한 대안 중 하나로 수송성, 저장성, 연소안정성이 우수하나 환경오염 물질의 발생이 문제가 된다. 이러한 오염물질을 처리하기 위한 배가스 오염 물질처리를 위한 plant 설비 비용과 시간이 많이 투자된다. Aspen plus는 mass energy balance와 화학적평형, 열역학을 이용하여 공정 모사를 할 수 있는 프로그램으로 검증되었다. RDF의 삼성분, 원소분석, 발열량을 입력을 통해 HCl, SOx, NOx, CO의 배출량을 예측하고 이에 맞는 SNCR, SDA 등과 같은 반응기를 적용 하므로써 다양한 배가스 처리를 모사 할 수 있다. NOx를 제어하기위에 urea주입과 SOx와 HCl을 제거하기 위한 CaO를 주입을 모사 하므로써 실제 운영 적용 전 단계에 역할로 유용한 도구로 판단된다.

• Korean Journal of Materials Research
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• v.6 no.8
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• pp.808-816
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• 1996

(100) Si 기판위에 전자 빔 증착법을 이용하여$ 90\AA$두께의 Ti과 $120\AA$두께의 Co를 순차적으로 증착시켰다. 그 후 질소분위기하의 $350-900^{\circ}C$온도구간에서 급속열처리함으로써 (100) Si 기판위의 Co/Ti 이중 박막의 실리사이드화 반응이 일어나게 했으며 이를 XRD, AES, TEM을 이용하여 분석하였다. $500^{\circ}C$이하의 온도에서는 Co원자들이 Ti층쪽으로 빠르게 확산하여 Si와 반응하기 이전에 Ti원자들과 상호 혼합되어 어떠한 실리사이드도 형성되지 않았다. $500^{\circ}C$에서 열처리된 시편의 고분해능전자현미경 영상을 통해 Co-Ti 혼합층과 실리콘 기판과의 계면에서 (100)Si 기판과 정합관계를 가지는 CoSi2가 형성되었음을 확인했다. $600^{\circ}C$열처리에 의해 Co-Ti-Sitka성분 실리사이드가 형성되기 시작하였으며, 형성된 삼성분 실리사이드는 Ti의 out-diffusion에 의해 $900^{\circ}C$ 이상의 온도에서는 불안정하였다. Co/Ti이중 박막에 의해 형성된 CoSi2는 실리콘 기판과 평탄한 계면을 가지며 실리콘 기판에 대해 (100)우선성장방위를 가졌다.

• Journal of the Korea Organic Resources Recycling Association
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• v.14 no.3
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• pp.138-147
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• 2006

In this study, the composition and physico-chemical characteristics of municipal solid waste (MWS) which was treated in national park area kyungnam-do landfill were investigated. It is necessary to measure the characteristics of MSW and sludge to build a waste treatment facility, the data-base and total managing of the landfill. This MSW was composed of 34.62% of food wastes, 36.05% of papers, 15.37% of plastics & vinyls, 2.28% of textiles, 3.33% of wood, 0.49% of rubber & leathers and others, respectively. Most of MSW are composed of food, paper and plastic waste and more than 90% was combustible waste. For three components, moisture is 29.84%, combustible component is 62.30% and ash is 7.86%. The chemical element has the high order of carbon, oxygen, hydrogen on the dry basis of wastes. Also, the low heating value of the MSW which is measured by calorimeter is calculated as 2377.8kcal/kg. low heating value of the sludge is calculated as 338.06kcal/kg.

• Journal of the Korea Organic Resources Recycling Association
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• v.21 no.1
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• pp.76-84
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• 2013

In this study, thermal weight loss, non-isothermally experiment, chemical composition analysis, calorific value, activation energy (E) were investigated to analysis the kinetic study of RDF, wood pellets, waste wood, waste textile and waste vinyl. When the chemical composition of solidification fuel was compared, the moisture content of RDF was less than the wood pellet and when the kinetic study was compared, the combustion reaction rate of the waste vinyl was higher than any other solidification fuels. However when the combustion efficiency was compared by the activation energy, the RDF had the higher efficiency than other wastes. RDF can be found that the reaction takes place between $320{\sim}720^{\circ}C$ depending on the heating rate.

• Journal of the Korea Organic Resources Recycling Association
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• v.16 no.1
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• pp.70-78
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• 2008

In this study, the composition and physico-chemical characteristics of school waste which is located in B area, kyunggi-do was investigated. It is necessary to measure the characteristics of school waste to build the data-base for resource and recycling of waste. This school waste was composed of 12.25% of food wastes, 56.26% of papers, 9.26% of plastics&vinyls, 1.52% of textiles, 3.70% of wood, 0.11% of rubbers&leathers and others, respectively. Most of school wastes are mainly composed of paper and plastic waste and composition of combustible waste was about as 90%. From 3-components analysis, contents of moisture, combustible component, and ash was 5.72%, 88.29% and 5.98%, respectively. Moisture content was higher in Agricultural Dwelling school area compare to the urban dwelling school area. The chemical element of the school waste has the high order of carbon, oxygen, hydrogen on the dry basis of wastes and the low heating value of the MSW which is measured by calorimeter is shown as 3720.44kcal/kg.

• Journal of the Korea Organic Resources Recycling Association
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• v.21 no.2
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• pp.51-55
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• 2013

This research conducted component analysis of pellet fuel using livestock waste and agricultural by-product and combustion characteristics. As the result of analyzing the characteristics of solid fuel using livestock waste, three components, element analysis, and heating value were suitable for the standard of solid fuel. In addition, content of ash consisted of high concentration of K, P, Na indicating the possibile usage as a soil conditioner. However, it was not suitable for solid fuel using only livestock waste due to the relatively low heating value. To improve the heating value and early ignition, we mixed agricultural by-products (i.e., chaff and sawdust) into livestock waste. The mixed material showed significant increase of combustibles and heating value with decrease of moisture content compared to the livestock waste only.

• Journal of the Korea Organic Resources Recycling Association
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• v.24 no.3
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• pp.45-52
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• 2016

This study is to predict the biogas production and the content analysis of the organic wastes of three islands located in the City of I. Content analysis for a total of six sections, including pH, BOD, COD, three components (Moisture, Ash, Combustibles)was conducted on the specimens of organic wastes from the representative spots of three islands. From the analysis result of organic waste, it is confirmed that more than $1,750,000m^3$ of methane gas per year will be generated through the calculation of the total methane generation for the COD value. Therefore, if the incineration facility for the organic waste in island region is converted into a biogas production facilities which is non-incineration facility, it seems that the organic waste of efficient utilization is available.