• Title/Summary/Keyword: 산화제

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Ignition Characteristics of Combustion Chamber with $LO_X$ Lead Cyclogram for Liquid Rocket Engine (액체로켓엔진 연소기 산화제 선공급 Cyclogram에 의한 점화특성)

  • Han, Yeoung-Min;Kim, Jong-Gyu;Lee, Kwang-Jin;Lim, Byoung-Jik;Ahn, Kyu-Bok;Kim, Mun-Ki;Seo, Seong-Hhyeon;Choi, Hwan-Seok
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2008.11a
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    • pp.137-142
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    • 2008
  • Ignition characteristics of combustion chamber with LOx lead cyclogram for liquid rocket engine were described. The combustion chamber has chamber pressure of 60 bar, propellant mass flow rate of 89 kg/s, and nozzle expansion of 12. Cold flow test to determine the filling time of propellant for cyclogram with LOx lead supply, ignition test to check the ability to ignite starting fuel from the ignitor, low pressure combustion test to check the propagation of flame into main fuel-oxidizer mixture from starting fuel and the main combustion stage, and design point combustion test to check the combustion performance were performed. Ignition and combustion tests with LOx lead supply were successfully performed and the stable cyclogram of start sequence for combustion chamber was developed.

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Design Point Operating Characteristics of an Oxidizer Rich Preburner (산화제 과잉 예연소기 설계점 운영 특성)

  • Moon, Ilyoon;Moon, Insang;Kang, Sang Hun;Ha, Seong-Up;Lee, Soo Young
    • Journal of the Korean Society of Propulsion Engineers
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    • v.17 no.4
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    • pp.81-88
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    • 2013
  • It was designed and tested at the design point that an oxidizer rich preburner for a staged combustion liquid rocket engine propelled by kerosene and LOx. The oxidizer rich preburner was designed as some of LOx injected from the mixing head was burned with kerosene and the rest of LOx injected from injection holes in the regenerative cooling chamber was vaporized by combustion gas. The preburner is operated at OF ratio of 60 and combustion pressure of 20 MPa. The Preburner has a honey-comb type mixing head with simplex swirl injectors, a turbulence ring improving combustion stability and uniformity of product gas temperature distribution, and a nozzle simulating the duct. With the combustion test results at the design point, the oxidizer rich preburner showed high combustion stability and uniformity of product gas temperature distribution.

Comparison of Combustion Characteristic with GN2O and GOX as Oxidizer in Hybrid Rocket (하이브리드 로켓의 산화제 종류에 따른 고체연료 연소특성 비교)

  • Lee, Jung-Pyo;Cho, Sung-Bong;Kim, Soo-Jong;Yoon, Sang-Kyu;Park, Su-Hayng;Kim, Jin-Kon
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.11a
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    • pp.223-227
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    • 2006
  • In this study, the combustion characteristics was studied with various oxidizer in hybrid propulsion system. In this experiments $GN_2O$ and GOX were used as oxidizer, and PE was used as fuel. The combustion behavior was explained by flame temperature with mass O/F ratio, and the use of $GN_2O$ as the oxidizer caused a increase in combustion efficiency with GOX in the same hybrid motor. The mass flow rate of gaseous oxidizer was controlled by the several chocked orifices that have different diameter, and the oxidizer supply range was $0.0138{\sim}0.0427kg/sec$. As result, the empirical relation for oxidizer type was represented by mass flux of solid fuel, it was obtained with mass transfer number, and mass flux of oxidizer.

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Oxidation Behaviors of STS Series in Oxidizer-Rich Environment Using H2O2/Catalytic Reaction (H2O2/촉매 반응을 이용한 산화제 과잉 환경에서의 STS 계열 산화 거동)

  • Shin, Donghae;Choi, Jiseon;Shin, Minku;Ko, Youngsung;Kim, Seonjin;Han, Yeongmin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.923-927
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    • 2017
  • Metal exposed to high temperature/high pressure/oxidizer-rich environment may cause rapid oxidation(ignition and combustion). Therefore, this study was performed for the selection of metal appropriate for high temperature/high pressure/oxidizer-rich environment. In order to make the high temperature, high pressure and oxidizer-rich environment, the test facility utilizing the catalytic reaction of hydrogen peroxide was constructed and the metal oxidation and ignition of the STS series metals were evaluated. The result showed that the change of the selected material (discoloration) and the surface roughness were observed, but the change in the weight and thickness of the specimen was not significant.

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Spray Characteristics of the Oxidizer-rich Preburner Injector in Ambient Pressure Environment (상압 환경에서 산화제 과잉 예연소기용 인젝터의 분무특성 연구)

  • So, Youn-Seok;Yang, Joon-Ho;Choi, Seong-Man
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2007.04a
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    • pp.97-101
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    • 2007
  • The spray characteristics of the oxidizer-rich preburner are investigated. From the PDPA measurement, droplet SMD of $210{\mu}m$ and droplet axial velocity of 38 m/s are measured at 100 mm distance from the nozzle tip on the fuel pressure of $25kgf/cm^2$ and oxidizer pressure of $10kgf/cm^2$. The droplet velocity is decreased with the axial distance and the oxidizer spray makes dominant effect on the combined spray characteristics of the oxidizer-rich preburner injector.

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Results of Cold Flow Test and Design of Injectors for Oxidizer-rich Preburner (산화제 과잉 예연소기용 분사기 설계 및 수류 시험 결과)

  • So, YoonSeok;Woo, SeongPil;Lee, Kwang-Jin;Yu, ByungIl;Kim, Jinhyung;Cho, Hwangrae;Bang, Jeongsuk;Han, YeongMin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.22 no.1
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    • pp.52-57
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    • 2018
  • This paper presents the design and cold flow test results of oxidizer-rich preburner injectors for a 9 tonf-class staged combustion engine cycle. Three types of coaxial swirl injectors were designed, and 12 injectors were designed for each type. The diameters of the fuel tangential holes are identical. The diameters of the oxidizer tangential holes were varied to investigate the influence of combustion in the oxidizer-rich preburner according to the momentum ratio of the gas oxidizer generated from combustion in the injector chamber and liquid oxidizer through the cooling channel. It will be verified through a powerpack and combustion test using an oxidizer-rich preburner. In the cold flow test, the fuel flow rate and oxidizer tangential hole flow rate reached the target value based on the designed differential pressure.

Water Treatment Method for Removal of Trihalomethanes, Pesticides, Heavy Metals and Detergent in Drinking Water (2). -Effective Removal Method of Pesticides, Heavy metals and Detergent in Drinking Water- (상수중 Trihalomethanes, 농약, 중금속 및 합성세제의 효율적인 제거를 위한 수처리 방법 제 2보. -상수중 농약, 중금속 및 합성세제의 효율적인 제거방법-)

  • Park, Jong-Woo;Kim, Jang-Eok
    • Applied Biological Chemistry
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    • v.37 no.6
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    • pp.480-486
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    • 1994
  • The present series of investigations have been undertaken to know the effective removal method of some pesticides, heavy metals and detergent when the doses of oxidants and coagulant were changed in the treatment process of drinking water containing organic material. Three pesticides, IBP, diazinon and CNP, were removed by about 68 to 100% by treatment of oxidant, $Cl_2$. Especially, diazinon was completely removed by treatment of $Cl_2$ and other oxidants such as $Cl_2,\;KMnO_4\;and\;O_3$. However, butachlor removal measured only 20.3 to 26.7% due to treatment of all oxidant used. A detergent, sodium dodecylbenzenesulfonate, was effectively removed by treatment of $O_3$ but remained stable in the presence of other oxidants. The heavy metals of Cd, Pb, Cu and Zn in water were not affected by treatment of all oxidants used. By changing the concentration of humic matter and the dosage of coagulant, the removal of heavy metals was increased according to the increase of coagulant dosage, and decreased when increasing the concentration of humic matter, whereas the pesticides and detergent were not effectively removed.

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Fomulation Study for GAP/ADN Propellant (GAP/ADN 추진제 조성 연구)

  • 유지창
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1998.10a
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    • pp.25-25
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    • 1998
  • 최근의 선진국의 전략미사일에 사용되는 추진제 개발 방향은 고에너지, 저민감, 무연 및 무공해 추진제를 목표로 하고 있다. 현재까지 가장 널리 사용되어온 AP는 성능이나 기계적 특성에서 우수한 산화제이나 로켓 모타 배출기체 중에 HC1을 생성함으로써 2차 연기를 생성하며, HC1 자체가 인체에 유해한 물질이라는 단점들을 가지고 있다. 또한 RDX나 HMX는 에너지가 높은 반면 쇽(shock)에 대해 매우 민감한 단점을 가지고 있다. AN은 이러한 HC1을 생성하는 AP의 단점과 쇽에 민감한 RDX와 HMX의 단점을 해결할 수 있는 대체 산화제로 사용할 수 있으나, 성능이 대외적으로 떨어지며 상변이와 흡습성이 높은 단점이 있다. ADN은 -100~+10$0^{\circ}C$범위에서 상 변이가 없고 밀도는 1.801g/㎤, Hf는 -290cal/g이다. ADN을 산화제로 사용하면 HTPB/AP 추진제와 동등하거나 그 이상의 성능을 갖는 추진제를 만들 수가 있으며, 유해 기체인 HC1을 배출하지 않음으로 인하여 2차 연기를 없애는 장점이 있다.

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1, 2성분계 DSA 전극의 제조와 성능 평가

  • Park, Yeong-Sik;Kim, Dong-Seok
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 2008.11a
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    • pp.464-467
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    • 2008
  • 성능이 우수한 다성분계 전극을 개발하기 위하여 Pt, Ru, Sn, Sb 및 Gd의 5 종류 금속을 이용하여 1성분계 전극의 성능과 산화제 생성량 및 2성분계 전극의 성능과 산화제 생성 경향을 고찰하여 다음의 결과를 얻었다. 1. RhB 농도 감소는 Ru/Ti > Sb/Ti > Pt/Ti > Sn/Ti > Gd/Ti 전극의 순서로 나타났으나 단위 전력당 2분간 제거된 RhB 농도 감소는 Ru/Ti > Sb/Ti > Pt/Ti > Gd/Ti > Sn/Ti 전극의 순서로 나타났다. 생성된 산화제 농도는 ClO$_2$ > free Cl > H$_2$O$_2$ > O$_3$의 순서였으며 Gd/Ti 전극의 경우 산화제가 거의 생성되지 않는 것으로 나타났다. 모든 전극에서 OH 라디칼이 거의 생성되지 않는 것으로 나타났다. Ru/Ti와 Sb/Ti 전극의 높은 RhB 분해와 산화제 생성 농도는 정확하지는 않지만 상관관계가 있는 것으로 나타났다. 2. Ru계 2성분 전극(Ru-Gd/Ti, Ru-Pt/Ti, Ru-Sn/Ti 및 Ru-Sb/Ti)은 모두 1성분계 전극보다 RhB 분해성능이 높아지는 것으로 나타났으며, Ru계 2성분 전극 중 가장 성능이 우수하였던 전극은 Ru:Sn=9:1 전극으로 나타났다. Sn-Sb/Ti 전극은 Sn:Sb=1:9의 전극 성능이 우수한 것으로 나타났으나 Sb/Ti 전극과의 차이는 크지 않은 것으로 나타났다. Pt계 전극(Pt-Gd/Ti, Pt-Sn/Ti, Pt-Sb/Ti)은 대체로 두 성분 혼합에 따른 RhB 분해효과 상승은 없는 것으로 나타났다. 2성분계 전극 중 RhB 제거 성능이 가장 우수하였던 Ru:Sn=9:1 전극에서 4종류의 산화제 생성 농도가 높은 것으로 나타났다. Ru:Pt=9:1 전극은 RhB 분해 성능이 5 전극 중 가장 낮았으며, 산화제도 생성량이 가장 적은 것으로 나타났다. Ru-Sn/Ti 계 전극의 RhB 분해 성능과 산화제 생성 농도가 실험한 모든 1, 2성분계 전극에서 높은 것으로 나타나 향후 3, 4성분계 전극 제조시 이를 바탕으로 제조하고 다른 물질들은 보조재료로서 사용할 필요성이 있는 것으로 사료되었다.

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Effect of Oxidizing Agents on the Burning Characteristics of Smoke Rod of Pesticides Using Rice Chaff as a Combustible Carrier (왕겨를 가연성 담체로 하는 봉상 농약 훈연제의 연소성에 미치는 산화제의 영향)

  • Lim, He-Kyoung;Kim, Yong-Whan;Cho, Kwang-Yun;Yu, Ju-Hyun
    • Applied Biological Chemistry
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    • v.47 no.3
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    • pp.332-338
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    • 2004
  • An investigation in search of the best oxidizing agent for smoke generators using rice chaff as a combustible carrier was carried out. Smoke rods formulated with active ingredients (AIs) such as inorganic oxidizing agents, glue, and powdered rice chaff, showed constant and high burning rate and high smoking rate on 11 kinds of pesticides. Sodium chlorate was the most suitable oxidizing agent for smoke rod. Even though the sodium chlorate content of the formulation showing the highest smoking rate of AI was variable to pesticides, the smoking rate appeared to increase as the burning rate increased. Active ingredients in smoke generator using rice chaff as a combustible carrier were stable for 60 days when stored at $50^{\circ}C$. An apparatus designed for smoke trapping was useful to collect smoked active ingredients.